共查询到20条相似文献,搜索用时 187 毫秒
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采用固相烧结工艺制备出了Sr0.4Pb0.6TiO3半导体陶瓷元件,其阻温特性具有独特的NTCR和PTCR复合效应,陶瓷室温电阻率及居里点以下的NTCR效应随着烧结温度的升高而提高,适当过量PbO则能降低陶瓷室温电阻率及其NTCR效应.利用XRD、SEM和EDS分别对样品的相结构、形貌及成份分布等进行分析,结果显示晶界中的Sr,Ti含量相对较高,而Pb含量相对较低,材料的阻温特性明显受其影响.铅挥发造成的阳离子空位是该类半导体陶瓷在居里点下出现NTCR效应的主要原因之一,同时探讨了Y3+离子掺杂(Sr,Pb)TiO3陶瓷的半导化机理和热敏特性. 相似文献
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采用化学共沉淀法成功地制备出适用于彩电显象管内荧光体着色的CoxR1-xAl2O4(R=Zn、 Mg, x=0.8~1.0)钴蓝颜料: 450nm波长处反射率最大提高18.2%, 600nm处反射率最大降低5%。通过对该颜料反射率的影响因素,如掺杂离子类型、掺杂浓度和Co2+离子浓度的探讨,结论如下:Zn2+、Mg2+改变钴蓝颜料反射性能的作用机理为晶格畸变引起Co2+3d轨道电子能级分裂程度的变化;对于掺杂离子Zn2+、Mg2+,x下限值分别约为0.85和0.8. 相似文献
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SiC/Fe-Cr合金界面反应的研究 总被引:3,自引:0,他引:3
使用XRD、EMPA和 SEM等对 900~1150℃高温处理后的SiC/Fe-20Cr合金界面反应区的显微结构和反应动力学进行了研究.界面反应区分为SiC反应区和金属反应区两部分:SiC反应区由组成为Fe3Si、Cr3Si和Cr7C3的白亮基体和其间随机分布的细小石墨颗粒构成;金后反应区则是一个由(Cr;Fe)7C3构成的均匀组织。SiC/Fe-20Cr合金界面反应为扩散控制,反应动力学方程为 K=1.9×10-4exp((-235×103)/RT)m2·s-1.金属反应区介于SiC反应区和合金之间,阻挡合金中的Fe原子通过它向SiC反应区中扩散,抑制界面反应,这种作用随合金中Cr含量的增加而加强. 相似文献
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利用离子束增强沉积技术, 在 Si (111) 和 G Cr15 轴承钢基体上沉积 Cr N 镀层研究氮分压、 N+ + N+2 离子轰击能量和 Nions Cr atoms 到达比对镀层组织结构的影响结果表明, Cr- N 镀层组织对氮分压敏感, 随着氮分压的增加, 镀层中 Cr N 组份增加, 金属 Cr 及 Cr2 N 组份减少; 随着氮离子轰击能量的增加, Cr- N 镀层中 Cr N (200) 择优生长; 但当 N ions/Cr atoms 比从145 ×10 - 2 增至5.87 ×10 - 2 时, 镀层中 Cr N 组份非但没有增多, 反而使镀层中的 Cr 以 Cr2 O3 形态存在. 相似文献
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用传统固相合成方法制备了Pb(sn1/3Nb2/3)O3-Pb(Zn1/3Nb2/3)O3-PbZrO3-PbTiO3(简写为PSN-PZN-PZT)四元系压电陶瓷材料,主要研究Cr离子掺杂对此材料的微观结构以及压电、介电性能的影响.通过对XRD衍射谱图分析可知,随着Cr的掺杂量的增大,该系统材料的三方相的含量减少,准同相界的位置向三方相移动;SEM照片显示,晶粒尺寸随Cr的量增大而增大,在0.5wt%含量时晶粒分布均匀且大小较为一致;ERP结果表明,Cr2O3在材料中主要以Cr3 、Cr5 存在.且结合材料的性能参数分析,增加Cr的含量会促使Cr离子由高价向低价转化.当Cr2O3的掺杂量为0.5wt%时,PSN-PZN-PZT材料的综合性能较好. 相似文献
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Yunwen Liao ) Dingquan Xiao) ) Institute of Applied Chemistry China West Normal University Nanchong China ) 《材料科学技术学报》2009,(6)
Lead-free piezoelectric ceramics (1-y)Bi0.5(Na1-xLix)0.5TiO3-yBaTiO3 with x=0-0.125 and y=0.02-0.12 were fabricated by a solid-state reaction process, and their dielectric, piezoelectric and ferroelectric properties were investigated. The results show that the addition of Li+ significantly improves the sintering performance and piezoelectric properties of the ceramics. X-ray diffraction (XRD) patterns indicate that the ceramics possess pure perovskite structure. At room temperature, the ceramics provide hig... 相似文献
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铌锰锆钛酸铅压电陶瓷烧结行为的研究 总被引:2,自引:0,他引:2
运用XRD、SEM、TEM、XPS等实验手段,研究了烧结温度对0.05PMnN-0.95PZT (PMnN—PZT)压电陶瓷微观结构、压电性能及锰元素价态的影响.实验结果显示:随烧结温度的降低平均晶粒尺寸减小,四方度也随之减小;机电耦合系数(kp)随烧结温度的升高而提高, 而机械品质因子(Qm)却呈波浪状变化. XPS及TEM实验分析证明:PMnN—PZT陶瓷在烧结过程中出现明显的液相烧结和成分偏离,低温烧结诱导了Mn2+的出现,产生更多的氧空位,从而使低温烧结下的样品Qm值不致降低. 相似文献
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采用固相合成法制备了Sm2O3掺杂的(Ba0.7Ca0.3)TiO3-Ba(Zr0.2Ti0.8)O3(BCZT)无铅压电陶瓷.借助XRD、SEM等手段对该陶瓷的显微结构与电性能进行了研究.结果表明,Sm2O3的掺杂降低了BCZT无铅压电陶瓷的烧结温度并使居里温度点Tc从85℃提高到95℃.当Sm2O3掺杂量为0.02wt%~0.1wt%时,样品具有典型ABO3型钙钛矿结构.Sm2O3掺杂量为0.02wt%时,所得陶瓷样品具有最优综合电性能,其压电常数d33、机电耦合系数kp、机械品质因子Qm、介电损耗tanδ和介电常数εr分别为590 pC/N、0.52、43、1.3%和3372. 相似文献
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Ryu J Choi JJ Hahn BD Park DS Yoon WH Kim KY 《IEEE transactions on ultrasonics, ferroelectrics, and frequency control》2007,54(12):2510-2515
This paper investigates the effect of K(1.94)Zn(1.06)Ta(5.19)O(15) (KZT) addition on the sintering behavior and piezoelectric properties in lead free piezoelectric ceramics of (K(0.5)Na(0.5))NbO(3) (KNN). The apparent density of sintered KNN ceramics was increased with KZT addition, and a relative density of above 96.3% was obtained with the doping of over 0.5 mol% KZT. The maximum dielectric and piezoelectric properties of epsilon(T)(3)/epsilon(0) = 590, d(33) = 126 pC/N, k(p) = 0.42, and P(r) = 18 microC/cm(2) were obtained from 0.5 mol% KZT-doped KNN ceramics. A small amount of KZT (about 0.5 mol%) was effective for improving the sintering behavior and piezoelectric properties, but KZT addition exceeding 1.0 mol% was effective only for densification. A small amount of KZT was effective for densification of KNN ceramics by promoting K(5.75)Nb(10.8)O(30) liquid phase formation. However, even though KNN with 1.0 to approximately -2.0 mol% KZT had a relative density of >98.5%, the piezoelectric properties were inferior to those of 0.5 mol% KZT-doped KNN, presumably due to the smaller grain size and excess liquid phase of the KNN ceramics doped with higher amounts of KZT. It is believed that a small amount of KZT could be one of the suitable sintering aids to obtain highly dense KNN based piezoelectric. 相似文献
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锰掺杂对硬性PZT材料压电性能的影响 总被引:25,自引:0,他引:25
研究了锰掺杂对PZT材料微结构及压电性能的影响,并用ESR确定了锰在PZT材料中的价态.结果表明,锰在PZT材料中主要以 Mn2+和 Mn3+的方式共存.锰在PZT陶瓷材料中的“溶解度”约为1.5mol%.锰含量<0.5mol%时,Mn将以Mn2+和Mn3+的方式优先进入晶格 Pb位,使材料的压电性能提高,表现出施主杂质特性;锰浓度处于 0.5~1.5 mol%时,部分Mn将以Mn3+或Mn2+的方式进入晶格中(Zr;Ti)位,而此浓度范围内锰掺杂的PZT材料同时表现出“软性”和“硬性”材料的压电特性.锰含量>1.5mol%时,过量的Mn将在晶界积聚,使压电活性降低.少量Fe的存在,可使Mn离子的溶解度降低,并起到抑制Mn2+和 Mn3+氧化的作用. 相似文献
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Zhenyong Cen Changrong Zhou Huabin Yang Qin Zhou Weizhou Li Changlai Yuan 《Journal of Materials Science: Materials in Electronics》2013,24(10):3952-3957
Mn modified BiFeO3–BaTiO3 (abbreviated as BFBT-Mnx%, x = 0.1, 0.3, 0.6, 0.9, 1.2) high-temperature lead-free ceramics were prepared by conventional oxide-mixed method and the effect of Mn doping on microstructure and electrical properties was investigated. The solid solutions show a single phase perovskite structure, and the content of Mn has a significant effect on the microstructure of ceramics. The addition of Mn can induce combinatory “hard” and “soft” piezoelectric characteristics due to aliovalent substitutions. In particular, x = 0.6 BFBT-Mnx% ceramic, with a Curie temperature, T c, of ~463 °C, shows optimum piezoelectric properties of d 33 = 131pC/N, k p = 0.298. The simultaneous existence of good piezoelectric properties and high T c makes these ceramics suitable for elevated temperature piezoelectric devices. 相似文献
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Baoshan LI Zhigang ZHU Guorong LI Aili DING State Key Lab of High Performance Ceramics Superfine Microstructure Shanghai Institute of Ceramics Chinese Academy of Sciences Shanghai China 《材料科学技术学报》2005,21(3):386-390
The microstructure and piezoelectric properties of Pb[(Zr0.52Ti0.48)0.95(Mn1/3Nb2/3)0.05]03 (PMnN-PZT) ceramics have been investigated at different sintering temperatures from 1070℃to 1280℃. The experimental results suggest that grain sizes and electromechanical properties of the ceramics show strong sintering temperature dependences. Double polarization to electric field (P-E) loops of the PMnN-PZT ceramics are assumed to be the result of the pinning effect of the defect dipoles. The results obtained through X-ray photoelectron spectrum suggest that sintering temperature affects valence of the Mn ion and quantity of oxygen vacancies. Hence, a proper explanation is proposed to illustrate the fluctuation of mechanical quality factor (Qm) due to the sintering temperature. 相似文献