Thermal Characteristics of Paraffin Wax for Solar Energy Storage

A thermal energy storage medium must meet the requirements of a stable storage material with high heat capacity. Heat storage based on the sensible heating of media such as water, rock, and earth represents the first generation of solar energy storage subsystems and technology for their utilization is well developed. However, recently the heat storage based on the latent heat associated with a change in phase of a material offers many advantages over sensible heat storage. The most important characteristic of such a subsystem is its sufficient storage capacity. The PCM (phase change material) behavior is visualized by constructing an idealized model thermal capacitor subjected to simulated solar system environmental conditions which include thermal cycling utilizing the latent heat of paraffin for heating and cooling. The proposed model of the capacitor is of a flat plate geometry consisting of two panel compartments forming the body of the capacitor containing the paraffin, leaving at their inner surfaces a thin passage allowing the water flow. The whole structure is assumed to be insulated to minimize heat loss. Analysis solution is used to generate data about the temperature distribution, the melt thickness, and the heat stored in the PCM under two conditions of: (a) constant mass flow rate tests for various water inlet temperatures, and (b) constant water inlet temperature for various mass flow rates. A FORTRAN computer program is constructed to perform the analysis. It is found that water outlet temperature increases with time until it becomes nearly equal to the inlet temperature. Increasing the mass flow rate for a given inlet temperature, decreases the time required for outlet temperature to reach a given value. Increasing inlet temperature for a given mass flow rate gives a very rapid decrease in the time required for the outlet water temperature to reach a given value. Instantaneous rate of heat storage is determined from the inlet-to-exit temperature differential and measured flow rate. This rate is then integrated numerically to determine the cumulative total energy stored as a function of time. It is found that the instantaneous rate of heat storage decreases till reaching a nearly constant value. The total or cumulative heat storage as a function of time, showed a nearly linear trend in the mid-range time, and it increased with increasing inlet temperature.     

Numerical analysis of an integrated storage solar heater

This work aims to evaluate the performance of an integrated phase change material (PCM) solar collector. The dynamic behavior of the system is investigated via a theoretical model based on the first law of thermodynamics and oriented to deliver a maximum outlet water temperature. A parametric study is used to assess the effects of the inlet water temperature, the PCM thicknesses and properties and the mass flow rates on the outlet water temperature and the melt fraction. A comparison with a conventional solar water heater without heat storage is made. Results indicate that charging and discharging processes of PCM offer six stages. It is observed that the complete solidification time is longer than the melting one. The latent heat storage system increases the heating requirements at night. The rise is most enhanced for higher inlet water temperature, melting PCM temperature and PCM thickness and for lower mass flow rate.     

Numerical and experimental investigation of heat transfer in a shell and tube thermal energy storage system

A numerical and experimental investigation of phase change process dominated by heat conduction in a thermal storage unit is presented in this paper. The thermal energy storage involves a shell and tube arrangement where paraffin wax as phase change material (PCM) is filled in the shell. Water as heat transfer fluid (HTF) is passed inside the tube for both charging and discharging cycles. According to the conservation of energy, a simple numerical method called alternative iteration between thermal resistance and temperature has been developed for the analysis of heat transfer between the PCM and HTF during charging and discharging cycles. Experimental arrangement has been designed and built to examine the physical validity of the numerical results. Comparison between the numerical predictions and the experimental data shows a good agreement. A detailed parametric study is also carried out for various flow parameters and system dimensions such as different mass flow rates, inlet temperatures of HTF, tube thicknesses and radii. Numerical study reveals that the contribution of the inlet temperature of HTF has much influence than mass flow rate in terms of storage operating time and HTF outlet temperature. Tube radius is a more important parameter than thickness for better heat transfer between HTF and PCM.     

Experimental investigation on a combined sensible and latent heat storage system integrated with constant/varying (solar) heat sources

The objective of the present work is to investigate experimentally the thermal behavior of a packed bed of combined sensible and latent heat thermal energy storage (TES) unit. A TES unit is designed, constructed and integrated with constant temperature bath/solar collector to study the performance of the storage unit. The TES unit contains paraffin as phase change material (PCM) filled in spherical capsules, which are packed in an insulated cylindrical storage tank. The water used as heat transfer fluid (HTF) to transfer heat from the constant temperature bath/solar collector to the TES tank also acts as sensible heat storage (SHS) material. Charging experiments are carried out at constant and varying (solar energy) inlet fluid temperatures to examine the effects of inlet fluid temperature and flow rate of HTF on the performance of the storage unit. Discharging experiments are carried out by both continuous and batchwise processes to recover the stored heat. The significance of time wise variation of HTF and PCM temperatures during charging and discharging processes is discussed in detail and the performance parameters such as instantaneous heat stored and cumulative heat stored are also studied. The performance of the present system is compared with that of the conventional SHS system. It is found from the discharging experiments that the combined storage system employing batchwise discharging of hot water from the TES tank is best suited for applications where the requirement is intermittent.     

Discharge characteristics of latent heat storage columns packed with cross-linked plastic particles

This investigation deals with experimental and numerical analyses carried out to investigate the discharge characteristics of latent heat storage columns, using cross-linked cylindrical plastic particles as a phase-change type of heat storage material and ethylene glycol as a heat transfer medium. In the experiment, the transient response of the outlet temperature of the heat transfer medium was measured under conditions of varying the initial temperature in the column, the inlet temperature of the heat transfer medium, the mass flow rate of the heat transfer medium, and the mass of the heat storage material packed in the column. In the numerical analysis, the transient temperature distributions in the column was calculated by using an empirical formula for estimating the heat transfer coefficient for a fixed bed, which was recommended in the authors' previous paper. The experimental results were found to be in fair agreement with the numerical results. © 1998 Scripta Technica. Heat Trans Jpn Res, 26(3): 193–206, 1997     

Parameter survey of thermally highly loaded,porous and cooled multi-layer systems for turbine blades

This study is an advanced investigation for the cooling of high temperature turbine vanes and blades.The efficientheat exchanging near the surface of a blade may be achieved by forcing a cooling air flow emitting out of a thinlayer of the porous metal which is pasted on the structural high strength metal.The contents include the consid-eration on the computational model of heat transfer through a layer of porous material,the concrete modeling andthe analysis of the model,the numerical survey of key parameters for both the two-layer porous materials and theheat transfer fluid flow passing through the model channels.The results revealed that the constructed system isreasonable.Proposed an evaluation formula for the porous material heat transfer efficiency.     

Performance of an inexpensive constant flow solar collector/storage system in ground

This paper presents an analysis of the performance of an inexpensive constant flow solar collector/storage system, which has been validated by experiments. the system consists of a network of pipes buried in the ground, the top surface of the ground being blackened by black board paint spray and suitably glazed. the heat can be extracted by flow of fluid in the pipes at a constant flow rate. It is seen that for a 7 cm depth of the plane of heat retrieval and 81/min flow rate of water, the collection efficiency of the system is 20.0 per cent. the efficiency increases with flow rate and decreases with the depth of the plane of heat retrieval.     

Numerical investigation of free-cooling system using plate type PCM storage

Free cooling night ventilation is the process of storing the coolness in the night time and releasing this coolness in hot day time. In this paper, a numerical study was carried out to simulate and to find out the optimum design for plate type storage filled with phase change material (PCM) which is used in night ventilation systems. The effect of different parameters such as thickness of PCM-plates, inlet air temperature and air mass flow rates on melting front, cooling power, outlet temperature and thermal performance of heat exchanger was studied. The results showed that cooling power can be increased by increasing the mass flow rate. Also, the thickness of the plates in the storage device plays an important role in the thermal performance of the unit and has a linear relation with the melting process duration of PCM for considered configuration.     

Energy and exergy analyses of an ice-on-coil thermal energy storage system

In this study, energy and exergy analyses are carried out for the charging period of an ice-on-coil thermal energy storage system. The present model is developed using a thermal resistance network technique. First, the time-dependent variations of the predicted total stored energy, mass of ice, and outlet temperature of the heat transfer fluid from a storage tank are compared with the experimental data. Afterward, performance of an ice-on-coil type latent heat thermal energy storage system is investigated for several working and design parameters. The results of a comparative study are presented in terms of the variations of the heat transfer rate, total stored energy, dimensionless energetic/exergetic effectiveness and energy/exergy efficiency. The results indicate that working and design parameters of the ice-on-coil thermal storage tank should be determined by considering both energetic and exergetic behavior of the system. For the current parameters, storage capacity and energy efficiency of the system increases with decreasing the inlet temperature of the heat transfer fluid and increasing the length of the tube. Besides, the exergy efficiency increases with increasing the inlet temperature of the heat transfer fluid and increasing the length of the tube.     

太阳能斯特林混凝土储热系统传热特性研究

设计碟式太阳能斯特林机混凝土储热系统,并对熔融盐及混凝土传热过程进行理论分析,对混凝土储释热过程进行模拟,运用多目标遗传算法进行优化,得到以下结论：在释热过程,选取290 ℃为流体出口的有效温度临界值,有效释热时间约2.1 h时,流体出口温度约为563 K,释热效率约为71%;高温混凝土和熔融盐沿着流程方向均存在一个温跃层区域,随着时间的延长,温跃层沿着流程方向逐渐向下游偏移,当温跃层移动到出口处时,熔融盐出口温度开始下降,温跃层占据的长度越小,储热系统效率越高;随着导热系数的增加,释热效率及有效释热时间提高。通过TOPSIS对解集进行重新排序分析,最优工况是蓄热量为2885 MJ、换热系数为672 W/（m·K）及储热效率为87%。     

Thermal performance of a south facing wall as solar collector storage system

This paper illustrates an analysis of the performance of a solar wall as a collector storage system. the south facing wall consists of a mass of concrete/brick whose one surface is blackened and glazed, and a network of pipes (metallic or plastic) is laid in a plane from which heat can be extracted by flow of fluid in such a manner that the temperature of the plane of heat retrieval keeps constant. the collection efficiency of the system is found to be 80·0 and 60·7 per cent for collection temperatures 20 and 25°C respectively on the surface; the maxima/minima of the rate of heat retrieval (Q(t)) occurs about 12 h after the maxima/minima of solar temperature at a depth of the plane of heat retrieval = π/α1, with a maximum efficiency of 21·47.     

Influence of natural convection on forced horizontal flow in saturated porous media for aquifer thermal energy storage

Estimation of the heat recovery rate in high-temperature underground storage (>50 °C) is required before such a system can be built. However, if high-temperature water is injected into and stored in the aquifer, large-scale natural convection could occur that might reduce the heat recovery rate. This study aims to clarify the universal quantitative condition under which natural convection appears and exerts an observable influence for a system with forced horizontal flow in the saturated porous medium. The authors investigated this using both experiments and computer simulations.A test section simulating an aquifer was made. Warm water was injected into the test section, which was filled with glass beads. The temperature distribution and the flow rate profile at the outlet were measured. The authors found that the limit condition at which natural convection influences the forced horizontal flow can be determined from the velocity profile and modified Rayleigh number Ra^*. In addition, the heat transfer coefficients of the upper and the lower side of walls were estimated. A computer simulation was made for calculation of the temperature field and the velocity vector in the porous medium under natural convection and under forced convection. As calculated temperature fields and flow rate distributions at the outlet were similar to the experimental results, it is thought that this program can be applied to evaluation of the temperature and the velocity of aquifer thermal energy storage. In addition, an index expressing the degree of influence of natural convection on forced convection was proposed.     

Numerical analysis of latent heat thermal energy storage using encapsulated phase change material for solar thermal power plant

Thermal energy storage improves the load stability and efficiency of solar thermal power plants by reducing fluctuations and intermittency inherent to solar radiation. This paper presents a numerical study on the transient response of packed bed latent heat thermal energy storage system in removing fluctuations in the heat transfer fluid (HTF) temperature during the charging and discharging period. The packed bed consisting of spherical shaped encapsulated phase change materials (PCMs) is integrated in an organic Rankine cycle-based solar thermal power plant for electricity generation. A comprehensive numerical model is developed using flow equations for HTF and two-temperature non-equilibrium energy equation for heat transfer, coupled with enthalpy method to account for phase change in PCM. Systematic parametric studies are performed to understand the effect of mass flow rate, inlet charging system, storage system dimension and encapsulation of the shell diameter on the dynamic behaviour of the storage system. The overall effectiveness and transient temperature difference in HTF temperature in a cycle are computed for different geometrical and operational parameters to evaluate the system performance. It is found that the ability of the latent heat thermal energy storage system to store and release energy is significantly improved by increasing mass flow rate and inlet charging temperature. The transient variation in the HTF temperature can be effectively reduced by decreasing porosity.     

Experimental investigation of a molten salt thermocline storage tank

Thermal energy storage is considered as an important subsystem for solar thermal power stations. Investigations into thermocline storage tanks have mainly focused on numerical simulations because conducting high-temperature experiments is difficult. In this paper, an experimental study of the heat transfer characteristics of a molten salt thermocline storage tank was conducted by using high-temperature molten salt as the heat transfer fluid and ceramic particle as the filler material. This experimental study can verify the effectiveness of numerical simulation results and provide reference for engineering design. Temperature distribution and thermal storage capacity during the charging process were obtained. A temperature gradient was observed during the charging process. The temperature change tendency showed that thermocline thickness increased continuously with charging time. The slope of the thermal storage capacity decreased gradually with the increase in time. The low-cost filler material can replace the expensive molten salt to achieve thermal storage purposes and help to maintain the ideal gravity flow or piston flow of molten salt fluid.     

Performance prediction of a solar water heater with intermittent output

A solar water heater constructed from readily available materials in the countryside has earlier been discussed in the continuous flow mode. Water flows in the tubes at a constant rate throughout the day. In any realistic situation, however, the rate of flow will be a function of time depending on the requirements of the user. In this paper a theoretical method is developed which is used to predict the outlet water temperature of the time dependent flows. The effect of various design parameters like the position of the water pipes, choice of sensible heat storage material etc. are discussed taking different functions of rate of flow. The inexpensive water heater can provide hot water for a small household even in the late evening hours provided no heat is withdrawn from the system during the day time.     

连续螺旋折流板管壳式换热器动态特性研究及预测

建立了可进行壳管式换热器动态特性试验研究系统,通过试验研究的方法对水-油为换热工质的连续螺旋折流板管壳式换热器动态特性进行了试验研究,进口流量扰动为等百分比流量特性,研究了4种流量扰动方式下水和油出口温度的动态响应。同时研究了在一定Re数下,不同的流体扰动量对换热器进出口温升的影响,得到了换热器进出口温升与流体扰动量之间的关联式。实验表明,液液换热系统温度的动态响应时间比较长,研究发现在正负的流量扰动下,换热器进出口温度变化呈现线性变化,进出口温升在正负流量扰动下其变化曲线具有对称特征。分别建立了有限差分数值预测模型及人工神经网络模型对换热器油侧的出口温度进行了动态预测,预测结果与试验值符合良好,人工神经网络的预测结果要好于数值模拟预测,其偏差绝对值在1.3%以内,表明人工神经网络在进行复杂的系统辨识时具有一定的参考及应用价值。     

Experimental and numerical study on charging processes of an ice‐on‐coil thermal energy storage system

In this study, an external melt ice‐on‐coil thermal storage was studied and tested over various inlet conditions of secondary fluid—glycol solution—flow rate and temperature in charging process. Experiments were conducted to investigate the effect of inlet conditions of secondary fluid and validate the numerical model predictions on ice‐on‐coil thermal energy storage system. The total thermal storage energy and the heat transfer rate in the system were investigated in the range of 10 l min ^?1?V??60 l min ^?1. A new numerical model based on temperature transforming method for phase change material (PCM) described by Faghri was developed to solve the problem of the system consisting of governing equations for the heat transfer fluid, pipe wall and PCM. Numerical simulations were performed to investigate the effect of working conditions of secondary fluid and these were compared with the experimental results. The numerical results verified with experimental investigation show that the stored energy rises with increasing flow rate a decreasing tendency. It is also observed that the inlet temperature of the fluid has more influence on energy storage quantity than flow rate. Copyright © 2006 John Wiley & Sons, Ltd.     

An operational high temperature thermal energy storage system using magnesium iron hydride

Metal hydrides have been demonstrated as energy storage materials for thermal battery applications. This is due to the high energy density associated with the reversible thermochemical reaction between metals and hydrogen. Magnesium iron hydride (Mg₂FeH₆) is one such material that has been identified as a thermal energy storage material due to its reversible hydrogenation reaction at temperatures between 400 and 600 °C. This study demonstates an automated thermal battery prototype containing 900 g of Mg₂FeH₆ as the thermal energy storage material with pressurised water acting as the heat transfer fluid to charge and discharge the battery. The operating conditions of the system were optimised by assessing the ideal operating temperature, flow rate of the heat transfer fluid, and hydrogen pressures. Overall, excellent cyclic energy storage reversibility was demonstrated between 410 and 450 °C with a maximum energy capacity of 1650 kJ which is 87% of the theoretical value (1890 kJ).     

Hydrogen release from a metal hydride tank with phase change material jacket and coiled-tube heat exchanger

Hydrogen fuel cells are received increasingly wide attention in order to develop green ships and reduce greenhouse gas emissions in the field of waterway transportation. Metal hydrides (MHs) can be used to store hydrogen for green ships due to their high volumetric storage capacity and safety. Various measures should be considered in the design and manufacture process of the MH reactor to strengthen its performance of heat and mass transfer and obtain an acceptable hydrogen storage capacity. In this work, LaNi₅ hydride is used as the hydrogen storage material and packed in the reactor. A basic axisymmetric numerical model for the hydrogen storage system without a heat exchanger has been developed and proved to be effective through the comparison between its simulation results and the published data during dehydriding. A hybrid heat exchanger, which is consisted of a phase change material (PCM) jacket and a coiled-tube, has been applied into the hydrogen storage system to relieve the thermal effect of MH in the dehydriding process on system performance. Effects of the heat transfer coefficient between the circulating heating water in the coil-tube and the MH bed, the temperature of circulating heating water and the pressure at the outlet on the dehydriding performance have been investigated. Based on parametric study, the relationships among the average dehydriding rate, the heat transfer coefficient, the heating water temperature and the outlet pressure have been found and fitted as simple equations. These fitted equations can be considered as a reference, which provides an important method to effectively control the dehydriding rate in order to satisfy the fuel requirement of the power unit and ensure the safe navigation of green ships in the future.     

Thermal performance analysis of a flat slab phase change thermal storage unit with liquid-based heat transfer fluid for cooling applications

This paper presents the results of a thermal performance analysis of a phase change thermal storage unit. The unit consists of several parallel flat slabs of phase change material (PCM) with a liquid heat transfer fluid (HTF) flowing along the passages between the slabs. A validated numerical model developed previously to solve the phase change problem in flat slabs was used. An insight is gained into the melting process by examining the temperatures of the HTF nodes, wall nodes and PCM nodes and the heat transfer rates at four phases during melting. The duration of the melting process is defined based on the level of melting completion. The effects of several parameters on the HTF outlet temperature, heat transfer rate and melting time are evaluated through a parametric study to evaluate the effects of the HTF mass flow rate, HTF inlet temperature, gap between slabs, slab dimensions, PCM initial temperature and thermal conductivity of the container on the thermal performance. The results are used to design a phase change thermal storage unit for a refrigerated truck.