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1.
In an effort to overcome some of the environmental problems associated with the use of dispersing agents, four temporarily solubilised disperse dyes had previously been synthesised and characterised for use in dispersant-free polyester dyeing. In this paper the dyeing and fastness characteristics of these dyes on polyester fabrics have been examined. It was found that the optimum pH to guarantee a moderate rate of hydrolysis was 5, which allowed temporarily solubilised disperse dyes to be successfully applied to polyester without the use of dispersants. The dyebath remained stable during the dyeing procedure. The dyes exhibited good levelling and fastness properties on polyester. 相似文献
2.
Temporarily solubilised disperse dyes derived from aminophenyl-4-(β-sulphatoethylsulphone) are exhausted on the polyester fibre mostly in the vinylsulphone form and to a lesser extent as their hydroxyethylsulphone analogues. After dyeing, to remove the unexhausted dyes on the polyester fibre, sulphite anions were added to the dyebath. The vinylsulphone residue of the dye was attacked by the sulphite anion via an addition reaction converting the dye into a soluble derivative, which then had little affinity for the polyester fibre. The effect of sodium sulphite on the conversion of the dye was investigated using HPLC. The wash and rub fastness properties of the dyed fabric aftertreated with sodium sulphite were similar to those obtained with reduction clearing. 相似文献
3.
Four temporarily solubilised disperse dyes were synthesised. To obtain the optimum application conditions for dispersant-free polyester dyeing, their conversion rates into insoluble derivatives were measured using HPLC and found to be more dependent on pH than on temperature. The results showed that it was possible to use these dyes in dispersant-free polyester dyeing for which the optimum application pH was between pH 5 and 6 at which the hydrolysis rate of the dyes was moderate. 相似文献
4.
Four temporarily solubilised azo disperse dyes based on 1-substituted-2-hydroxypyrid-6-one were synthesised and characterised. The dyes showed high extinction coefficients and had a yellow shade on polyester fabric. They were successfully applied to polyester without the use of dispersants and the optimum pH was found to be 5. It was found that the dyes could be alkali-cleared due to ionisation of the dye under mild alkaline conditions. The dyes exhibited good to excellent fastness properties on the polyester fabric. 相似文献
5.
Dispersant‐free dyeing of poly(lactic acid) fabric with temporarily solubilised disperse dyes from azopyridone derivatives
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Poly(lactic acid) fibre is derived from annually renewable crops and known to be 100% compostable. In order to extend its environmental friendliness into the dyeing process, dispersant‐free dyeing of poly(lactic acid) fabric with three temporarily solubilised azo disperse dyes based on hydroxypyridone moiety containing a β‐sulphatoethylsulphonyl group was investigated. The dyes were successfully applied to poly(lactic acid) fabric without the use of dispersants. The colour yields of the dyes on poly(lactic acid) fabric were observed to be dependent on dyebath pH and dyeing temperature. The optimum results were obtained at pH 4–5 and 110 °C. One of the dyes showed a colour yield as good as that of a commercial disperse dye and good build‐up on poly(lactic acid) fabric. All of the dyes could be alkali cleared owing to ionisation of the dye under mild alkaline conditions. Wash fastness was good to very good, and light fastness was good. The chemical oxygen demand levels of the poly(lactic acid) dyeing effluent from the dyes were considerably lower than those from a commercial disperse dye. 相似文献
6.
The dyeing properties of polyamide super-microfibres and conventional fibres dyed with disperse dyes have been studied by measuring the adsorption isotherm, the rate of dye uptake, the time of half-dyeing and the amount of equilibrium adsorption. The thermodynamic analysis shows that the adsorption isotherms of super-microfibres follow a Langmuir sorption model. The kinetic results show that super-microfibres have a faster dyeing rate and a higher equilibrium dye uptake compared to conventional fibres. This can be explained by the greater surface area and dye capacity of the super-microfibres. The wash and light fastness properties of the super-microfibres dyed with disperse dyes are lower than conventional fibres. 相似文献
7.
A. P. Mikhailovskaya M. S. Serenko 《Theoretical Foundations of Chemical Engineering》2016,50(4):513-517
The results of studying the effect of quaternary ammonium salts in colorimetric coloration characteristics and thermodynamic parameters of the process of dyeing polypropylene fiber with disperse dyes are presented. 相似文献
8.
The major possibility of dyeing PP fibres medium hues with disperse dyes using periodic technology was demonstrated. It was
found that dyeing as-spun PP fibres ensures diffusion of the dye inside the fibre material. Use of Neonol AF 9/6 nonionogenic
wetting agent during dyeing increases the amount of dye sorbed by PP fibre material.
Translated from Khimicheskie Volokna, No. 1, pp. 24-26, January-February, 2008. 相似文献
9.
Disperse dyes are not currently applied to wool commercially, in large part because of inadequate wash fastness, but they do have potential, especially for wool‐polyester blends. In this study, for the first time hydrogen peroxide was investigated to increase the wash fastness of disperse dyes on wool. In the absence of oxidants, 10 disperse dyes from seven classes imparted colours with a range of depths (K/S 2‐26) with wash fastness (grey scale ratings for colour change) grades of 3 to 4‐5. Hydrogen peroxide had only small effects on colours and gave only small enhancements to wash fastness, which were limited to anthraquinone, nitrodiphenylamine, disazo and coumarin dyes. The bleach activators Prestogen W and citric acid enhanced the bleaching effect of hydrogen peroxide but did not assist with raising wash fastness. Hydrogen peroxide in post‐dyeing scouring made the dyeings brighter but did not significantly enhance wash fastness. Ammonium persulphate, which was included for benchmarking with earlier studies, yellowed the wool and decomposed some dyes. This study extends the range of dye classes whose wash fastness on wool can be improved by ammonium persulphate to now include diazo, coumarin and methine, and confirms that oxidants/free radical initiators have potential for enabling the disperse dyeing of wool. 相似文献
10.
A series of water-soluble fibre-reactive arylating agents were synthesised and evaluated from the stand-point of improving fibre coloration with disperse dyes. In particular, the compound, sodio-2,4-dianilino-6-[4'- β -sulphatoethylsulphonylanilino]- s -triazine (FAA 200) was found to be promising; this compound could be applied in the same bath as a disperse dye at pH 5–6. Under the latter conditions this compound showed high substantivity to wool and at the boil readily underwent β -elimination of the sulphate ester residue to give the vinyl sulphone reactive group which adds on to nucleophilic sites in the fibre to form a covalent bond. Coapplication with commercially available disperse dyes gave bright, level dyeings that exhibited promising wet fastness. FAA 200 was used as an auxiliary to dye disperse dyes on both fibre components of a wool–polyester blend fabric; it was found that addition of hydrogen peroxide or sodium thiocyanate was necessary to obviate reduction of certain disperse dyes when dyeing at 120 °C. 相似文献
11.
The present work aims to investigate and develop a one–bath dyeing process for most common blend fibres to replace the conventional two–step process usually applied to dye each fibre constituent separately. The main objectives of the proposed process is the conservation of energy, raw materials, dyes, auxiliaries and labour. 相似文献
12.
The use of multilamellar lipid vesicles as carriers of disperse dyes on wool fibres has been studied. Liposomes made from egg phosphatidylcholine containing the anthraquinone dye CI Disperse Violet 1 at different phospholipid/dye concentrations were used. The physical stability of these systems was assessed by measuring the mean vesicle size distribution of lipid vesicle suspensions after preparation and during dyeing. Kinetic aspects involving dye adsorption and bonding on untreated and chlorinated wool samples by means of the liposomes at different dye/lipid ratios were also investigated. This process led to the controlled dye exhaustion on wool, directly dependent on the relationship between the dye and lipid components, with a clear improvement in the dye-fibre bonding forces and in the dispersing efficiency, compared with conventional dispersing agents. The optimum dye exhaustion was reached for the dye/phospholipid concentrations 0.53 and 1.0 mmol/l respectively. The maximum amounts of dye bonded on untreated wool fibre were obtained for the same dye/lipid molar ratio. However, chlorinated wool samples showed a slight decrease in the total bonded dye as the chlorination level increased. 相似文献
13.
Disperse dye distribution on polyester and wool during one-bath dyeing of wool/polyester blends is discussed. The addition of carriers increases the wool's intrinsic saturation value for disperse dye, thus raising the degree of staining on the wool component at the low dye uptakes. However, staining can be minimised if the dyeing is close to or attains equilibrium conditions. Sequestering agents can accelerate the disperse dye diffusion out of the wool fibre, further reducing staining on wool and transferring more disperse dyes from wool to polyester. Citric acid can be used as a sequestering agent as well as a pH adjusting agent. 相似文献
14.
Synthesis of temporarily solubilised azo disperse dyes containing a β‐sulphatoethylsulphonyl group and dispersant‐free dyeing of polyethylene terephthalate fabric
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Jae Pil Kim Ji Su Kim Jong Seung Park Seung Soon Jang Jung Jin Lee 《Coloration Technology》2016,132(5):368-375
Disperse dyes containing a β‐sulphatoethylsulphonyl group have temporary solubility and can be applied for dispersant‐free dyeing of hydrophobic fibre. Six novel temporarily solubilised azo disperse dyes having a β‐sulphatoethylsulphonyl group in their structures were synthesised, and their dyeing properties on polyester were investigated. As a dye intermediate, a diazo component having dibromo groups was prepared, and 4‐diethylamino‐4′‐(2‐sulphatoethylsulphonyl‐4,6‐dibromo)azobenzene dyes were prepared by a diazo‐coupling reaction. Then, the dyes containing dicyano groups were prepared by cyanation of corresponding dyes with dibromo groups. The absorption maxima of the dyes were affected by the substituents in the diazo and coupling component rings and varied from 434 to 616 nm in dimethylformamide. Polyethylene terephthalate woven fabric could be dyed with the synthesised temporarily solubilised dyes without using any dispersants. Dyebath pH affected the K/S value at maximum absorption as well as percentage exhaustion on polyethylene terephthalate fabric, and the optimum pH was 5. The dyes gave brownish orange, red, purple, and greenish blue hues on polyethylene terephthalate fabrics, and colour build‐up was good. Wash fastness was good to excellent, rubbing fastness was moderate to excellent, and light fastness was poor to moderate. 相似文献
15.
The colors of polyamide fibre obtained in dyeing with α-cyclodextrin (CD) additive are uniform and saturated. This effect
is also obtained on wool fibre and wool—polyamide fibre blend. It was found that the dyeability of the samples with α-CD is
much higher than for samples without the additive with an increase in the temperature. In spectrophotometric determination
of complexation in the dye—α-CD aqueous system, it was found that the dyeability of the samples was highest in a 1:1 ratio
than with the standard dyeing method. α-CD thus acts as a process booster.
__________
Translated from Khimicheskie Volokna, No. 3, pp. 37–39, May–June, 2007. 相似文献
16.
Polyurea microcapsules were prepared in this study, using disperse dye as the core material and diphenylmethane-4,4'-diisocyanate as the wall-former. Microencapsulated disperse dyes have been characterised in terms of their thermal properties, average particle size and size distribution, morphological structure and composition. Polyester fabric was dyed with microencapsulated CI Disperse Blue 56 using a high temperature dyeing process without dispersing agents, penetrating agents, levelling agents or other auxiliaries. The quality of the polyester fabric dyed in this manner – without reduction clearing – was at least as good as that dyed traditionally after washing and reduction clearing. After separating off the polyurea microcapsules, the dyebath was virtually colourless and was shown to be suitable for reuse. 相似文献
17.
Dyeing of natural and synthetic textiles in supercritical carbon dioxide with disperse reactive dyes 总被引:1,自引:0,他引:1
M. van der Kraan M.V. Fernandez Cid G.F. Woerlee W.J.T. Veugelers G.J. Witkamp 《The Journal of Supercritical Fluids》2007,40(3):470-476
Polyester, nylon, silk and wool were dyed with disperse reactive dyes in supercritical carbon dioxide (scCO2). The dyes were substituted with either vinylsulphone or dichlorotriazine reactive groups. Since earlier research showed that water, distributed over the scCO2 and the textile, increased the colouration, experiments were done with the vinylsulphone dye with varying amounts of water in the dyeing vessel, to investigate if there is an optimum water concentration. The amounts were such, that no liquid water was present. The maximum colouration was obtained when both the scCO2 and the textiles were saturated with water. At the saturation point, deep colours were obtained with the vinylsulphone dye for polyester, nylon, silk and wool, with fixation percentages between 70 and 92% when the dyeing time was 2 h. The positive effect of water was due to its ability to swell fibres or due to an effect of water on the reactivity of the dye–fibre system. Also the dichlorotriazine dye showed more colouration when the scCO2 was moist. With this dye, experiments were conducted in water-saturated scCO2, varying the pressure from 225 to 278 bar and the temperature from 100 to 116 °C. The colouration of polyester increased with pressure, the results for silk and wool were not sensitive to pressure. Increasing the temperature had no influence on the dyeing of polyester, silk and wool. The fixations on polyester, silk and wool, being between 71 and 97%, were also independent of pressure and temperature. 相似文献
18.
Two models of temporarily anionic sulphatoethylsulphone reactive disperse dyes were applied to wool, polyester and wool/polyester blend fabrics at different dyeing pH. Maximum exhaustion values and colour yield were observed at pH 7. The results showed that reactive disperse dyes containing bis‐sulphatoethylsulphone reactive groups were more convenient for neutral dyeing of wool and wool/polyester blend fabrics if compared with a dye containing a mono‐sulphatoethylsulphone group. Excellent to very good wet fastness properties on all dyed fabrics were achieved. 相似文献
19.
Ozan Avinc Emine Bakan Aykut Demiral Grkem Gedik Fikret Karc 《Coloration Technology》2020,136(4):356-369
Poly(lactic acid) (PLA) is the first melt‐processable, renewable, sustainable and biodegradable natural‐based synthetic fibre. It has a broad range of uses and combines ecological advantages with outstanding performance in textiles. PLA fibre, as an aliphatic polyester, can be dyed with disperse dyes. Apart from the limited number of commercial disperse dyes, disperse dye exhaustion on PLA is generally lower than that on poly(ethylene terephthalate) (PET). In this study, new heterocyclic disazo disperse dyes, substituted with methyl, nitro and chloro groups at their ortho‐, meta‐ and para‐ positions, synthesised in our previous study, were applied to PLA and PET fibres to examine their dyeing performance, and colour fastness and dye exhaustion properties. Different shades of yellow, orange, reddish brown and brown were obtained. Most of the synthesised novel heterocyclic disazo disperse dyes exhibited good build‐up properties with high K/S levels on both fibres. Para‐ bonding substituent provided higher K/S values than meta‐ and ortho‐ positions for –NO2 and –Cl substituents for both fibres. Overall, the most synthesised novel heterocyclic disazo disperse dyes in this study exhibited good build‐up properties with high K/S, exhaustion and wet fastness levels on both PLA and PET fibres. 相似文献
20.
F R Latham 《Coloration Technology》1992,108(3):120-122
In the exhaust-dyeing sector, the established trend towards short liquors will continue, and even become more pronounced. This trend makes it necessary to pay attention to the changed requirements with regard to the pretreatment, solubility of the dyes and auxiliaries used, and to fabric-running properties, etc. Process control and product selection must also be checked to ensure their suitability for the different requirements. In this way, the disadvantages of the short-liquor technique can be overcome and full advantage taken of it. Either hot-dyeing or warm-dyeing types offer certain advantages, depending on the fastness requirements, the equipment available and the processing techniques employed. 相似文献