复合材料RTM成型工艺综述

本文主要是综述RTM成型工艺的基本原理、工艺特点,讨论了适于RTM的增强材料和树脂休系并讨论了工艺参数对RTM模制品质量的影响以及RTM在成型三维复合材料方面的应用。     

先进树脂基复合材料RTM成型工艺研究及应用进展

复合材料的成型工艺是改进并提升先进树脂基复合材料性能的关键,而树脂传递模塑(RTM)成型工艺是一种环保高效、成本低、高精度的闭模成型工艺。概述并分析了传统RTM成型工艺过程及优缺点,并对高压树脂传递模塑成型(HPRTM)、轻质树脂传递模塑成型(LRTM)、真空辅助树脂灌注工艺(VARTM)、西门(Seeman)树脂浸渍技术(SCRIM P)等RTM衍生成型工艺的研究进展与应用进行了介绍分析。     

RTM树脂材料及其辅助成型工艺研究进展

简要介绍RTM工艺的成型原理,详细介绍用于RTM的新型树脂及改性树脂材料的研究进展情况、各种RTM辅助成型的工艺进展情况,并展望RTM技术在航天航空等领域的应用。     

我国树脂基复合材料成型工艺的发展方向

介绍了我国树脂基复合材料成型工艺已陈旧过时、必须更新换代的原因；RTM和辐射固化(主要有EB、UV固化)的优越性；得出的结论是，树脂基复合材料的最佳成型技术是RTM成型 EB(或UV)固化技术。     

先进树脂基复合材料RTM工艺的研究进展

随着复合材料的应用越来越广泛,制件产品复杂性和质量要求越来越高,逐渐衍生出多种复合材料成型工艺.而树脂传递模型(RTM)及其派生工艺是一种高质量、高精度、高效率、低成本和绿色化的闭模成型工艺.本文简要介绍了RTM成型工艺原理、RTM衍生工艺成型过程及特点、RTM工艺应用现状以及RTM用树脂的研究现状,并提出了RTM工艺...     

耐高温结构用复合材料管材及其制造技术的研究

本文应用BMI树脂制造出耐温等级为180℃的碳纤维复合材料结构用管材，并对高性能复合材料材的缠绕及RTM成型工艺，基体BMI树脂的工艺适应性进行了研究。     

树脂传递模塑（RTM）成型工艺及应用

本文概述了树脂传递模塑(RTM)的成型工艺过程及其应用前景。由此可了解 RTM 技术的全貌。通过对 RTM 与其它几种主要的复合材料加工工艺的比较,如SRIM(结构反应注射成型),SMC(片材成型)等,可以清楚地认识到 RTM 作为新一代复合材料加工工艺在航空、航天、航海、汽车和建筑等各个领域的发展潜力。     

酚醛复合材料的RTM熔芯成型

采用酚醛树脂传递模型（RTM）及低熔点合金可熔性型芯复合工艺,成型莆状极其复杂的复合材料发动机机体,对成型温度,树脂粘度及型芯的熔化温度等工艺参数进行实验研究,为优化复合材料发动机机体成型工艺提供了理论和实验基础。     

树脂基复合材料成型工艺的发展

随着复合材料工业的迅速发展,传统的复合材料成型工艺日臻完善,新的成型方法不断涌现。本文通过梳理接触低压成型工艺、拉挤成型工艺、模压成型工艺、缠绕成型工艺、铺放成型工艺、RTM成型工艺这几种先进树脂基复合材料成型工艺的发展历程,分析发展过程中的关键技术,来研究先进复合材料成型工艺的演变,从而探讨未来树脂基复合材料成型工艺的发展方向。     

树脂传递模塑充填过程的数值模拟

树脂传递模塑成型（RTM）工艺是在一定温度及压力下把低黏度的树脂注入预先置有增强纤维的模具中,然后固化成型的一种复合材料液体成型方法。本文建立了RTM工艺充模过程的数学模型,并采用有限元/控制体积法实现了对复杂薄壁构件的充填模式、压力场和速度场的模拟。     

An RTM densification method of manufacturing carbon-carbon composites using Primaset PT-30 resin

This paper presents a development of carbon-carbon (C-C) composite by resin transfer molding (RTM) process. The RTM was used for both manufacturing of the resin matrix composite part as well as impregnation of the carbonized parts. Materials chosen were heat-treated T300 2-D carbon fabric and Primaset PT-30 cyanate ester. The PT-30 resin has a char yield similar to that of phenolics, very low volatiles, low viscosity at processing temperatures, and no by-products during cure, and hence, an excellent choice for RTM process. The process consists of RTM of the composite part, carbonization, RTM impregnation, and re-carbonization. The last two steps were repeated to achieve the desired density. The measured density and mechanical properties of just two times-densified C-C composite panels were superior to or nearly the same as the data in the literature by other processes. The RTM densification is about twice as fast as the resin solution method and it is environment friendly.     

RTM用环氧树脂体系的固化工艺研究

本文研究了以多官能团环氧树脂及液体酸酐为基体,以叔胺及有机酸盐为促进剂组成的RTM用环氧树脂体系,采用DSC和DMA等方法研究了树脂体系的固化工艺及固化物的性能.结果表明:该树脂体系粘度低,适用期长,适用于RTM工艺;该树脂体系的湿热性能较差,需进一步研究改性.     

Properties of poly(butylene terephthatlate) polymerized from cyclic oligomers and its composites

The high viscosity of thermoplastic matrices hampers fiber impregnation. This problem can be overcome by using low viscous polymeric precursors such as cyclic butylene terephthalate (CBT^® resins), which polymerize to form a thermoplastic matrix. This allows thermoset production techniques, like resin transfer molding (RTM), to be used for the production of textile reinforced thermoplastics. Due to the processing route and more specifically the time-temperature profile, inherent to the RTM process, the crystallites of the matrix consist out of well-defined, thick and well-oriented crystal lamellae. Together with a high overall degree of crystallinity and a low density of tie molecules, these large and perfect crystals cause polymer brittleness. Matrix brittleness lowers the transverse strength of unidirectional composites to below the matrix strength, but leaves the mechanical properties in the fiber direction unaffected. Although not a valid option for the RTM production route, crystallization from a truly random melt and at a sufficiently high cooling rate would substantially improve the ductility.     

A novel high performance RTM resin based on benzoxazine

Resin transfer molding (RTM) has the potential to manufacture high quality, geometrically complex composite parts. Benzoxazine is a new kind of high performance composite matrix. It can be polymerized with a ring‐opening reaction without releasing volatiles. In this article, a novel RTM resin made from aromatic diamine, phenol and formaldehyde is reported. The viscosity and curing behavior of the RTM resin as well as the properties of the cured neat resin and fiber reinforced composite were investigated. The resin has a viscosity lower than 0.5 Pa · s after 4 hr at 100°C, and can be cured at 180°C. The tensile strength, modulus, and elongation of the cast resin are 94 MPa, 4.6 GPa, and 2.2%, respectively. The flexural strength and modulus of the cast resin are 160 MPa and 4.9 GPa. The flexural strength and modulus of its glass fiber laminate are 662 MPa and 30 GPa. It is very easy to control the viscosity and curing rate of the RTM resin through the addition of reactive dilute agents and catalysts according to the requirement of RTM processing. POLYM. COMPOS., 26:563–571, 2005. © 2005 Society of Plastics Engineers     

用于树脂压铸（RTM）的树脂基体研究

文中介绍了ＲＴＭ用树脂体系的研究概况，结果表明树脂体系具有低的粘度，较长的贮存期和良好的反应性能，固化树脂和复合材料的力学性能及耐热性能优良，它能满足ＲＴＭ对基体的要求。     

RTM专用混合型树脂体系研究——反应特性与工艺特性研究

本文采用乙烯基酯树脂和环氧树脂体系共混改性的方法。研究和开发具有良好工艺性、耐热性和力学性能的低成本ＲＴＭ用树脂体系。研究表明，乙烯基酯树脂和环氧树脂体系具有良好的共混特性。ＤＳＣ及粘度分析研究表明，混合型树脂体系中的乙烯基酯组份分散了环氧树脂的反应放热，有效降低了７１１环氧树脂的反应速度和改善了树脂的工艺特性。使混合型树脂具有较好的ＲＴＭ工艺低粘度平台工艺性能。所研究的混合型树脂体系可用于ＲＴＭ     

In-situ monitoring of the resin transfer molding impregnation and cure process

Resin transfer molding (RTM) of advanced fiber architecture materials promises to be a cost effective process for obtaining composite parts with exceptional strength. However there are a larger number of material processing parameters that must be observed, known, and/or controlled during the resin transfer molding process. These include the viscosity both during impregnation and cure. In-situ sensors which can observe these processing properties within the RTM tool during the fabrication process are essential. This paper will discuss recent work on the use of frequency dependent electromagnetic sensing (FDMS) techniques to monitor these properties in the RTM tool. Our objective is to use these sensing techniques to address problems of RTM scaleup for large complex parts and to develop a closed loop, intelligent, sensor controlled RTM fabrication process.     

国内树脂传递模塑技术的研究进展

从树脂传递模塑(RTM)的专用树脂、增强材料、理论研究、工艺、仿真技术、模具等方面阐述了当前我国RTM技术的研究进展,指出了当前我国RTM存在研究成果应用于实践的较少,受成本限制,应用领域较窄,成型产品性能低下等问题,并提出了低成本、高性能、易操作和能快速成型的原材料研究方向,以及把理论实验研究与实际生产应用结合起来的解决思路。     

High temperature vacuum assisted resin transfer molding of phenylethynyl terminated imide composites

Vacuum Assisted Resin Transfer Molding (VARTM) has proven to be a cost effective process for manufacturing composite structures compared with prepreg/autoclave and traditional resin transfer molding (RTM) processes. However, VARTM has not been accomplished with high temperature resins (such as polyimides) until recently, primarily because no resins had low melt viscosity and long melt stability that are required by VARTM. With the recent invention of phenylethynyl terminated imides (PETIs), high temperature VARTM has been achieved. Two processing methods, in‐plane and through‐thickness resin flow, were proposed and tested. Both methods are capable of fabricating polyimide matrix composites; and the carbon fiber laminates yield good fiber‐resin interfacial bonding and comparable mechanical properties to those laminates fabricated using RTM. POLYM. COMPOS., 2011. © 2010 Society of Plastics Engineers