海洋环境防腐蚀玻璃鳞片涂料的研制

用中碱玻璃鳞片为主要防腐蚀颜料,制备了一种适用于海洋气候的高固含厚浆型环氧玻璃鳞片涂料,并且考察了不同玻璃鳞片及其用量、粒径对涂层耐介质性能的影响。结果发现选用偶联剂包覆较好的玻璃鳞片,粒径为300目,用量为20%~25%,最能发挥其阻隔屏蔽效应。并且针对海洋环境的特殊性,对比测试了环氧玻璃鳞片涂料和普通环氧涂料的耐阴极剥离性能。     

耐化学品涂料对硫酸、盐酸、硝酸和乙酸的耐受性研究

介绍了硫酸、盐酸、硝酸、乙酸的腐蚀概况及常用的防腐方法。考察了6种涂料对不同浓度酸液的耐受性。研究发现环氧涂料对酸耐受性较差,3种酚醛涂料对不同酸的耐受性有所差别,聚环胺固化的环氧酚醛涂料比环氧及其他环氧酚醛涂料可耐更高浓度的硫酸和盐酸。乙烯基酯玻璃鳞片涂料和酚醛乙烯基酯玻璃鳞片涂料对酸的耐受性较好。同时,随着酸液浓度增大,涂料最高耐受温度有所降低。高交联密度环氧酚醛涂料比环氧酚醛涂料对酸液有更优异的耐温性能,酚醛乙烯基酯玻璃鳞片涂料比乙烯基酯玻璃鳞片涂料对酸液有更优异的耐温性能。同时介绍了一个98%浓硫酸地坪的案例和一个37%浓盐酸碳钢储罐的案例。     

低温快干环氧煤沥青玻璃鳞片涂料的研制

通过对比实验,确定了能在-5～5℃的温度条件固化成膜的环氧煤沥青玻璃鳞片涂料的配比,讨论了玻璃鳞片对涂膜防腐性能的影响及助剂对涂膜的影响。克服了环氧类涂料在低温条件下固化时间长甚至不能固化的缺点,使环氧煤沥青玻璃鳞片涂料在低温条件下能正常施工。     

玻璃鳞片导电涂料的研究

以自制的化学镀银鳞片石墨对传统的无溶剂型环氧玻璃鳞片涂料进行改性,制得了玻璃鳞片导电涂料。研究了含不同质量分数化学镀银鳞片石墨的玻璃鳞片导电涂层的电阻、表干/实干时间、厚度、硬度、耐蚀性及其BSE照片。结果表明,含有化学镀银石墨的玻璃鳞片涂料其表干/实干时间缩短、厚度增加、硬度和耐蚀性均有所提高。确定了化学镀银鳞片石墨在涂料中的最佳质量分数为30%。所得玻璃鳞片导电涂料的电阻率为252.75Ω·cm。     

环氧煤沥青玻璃鳞片防腐涂料

以环氧煤 青树脂作为成膜物,配用玻璃鳞片、颜料、填料及助剂,研制成厚浆型环氧煤沥青玻璃鳞片重防腐涂料。介绍了该涂料的用途、配方、生产工艺、性能指标和施工注意事项。     

石墨烯-玻璃鳞片环氧复合涂料在油气储运防腐中的应用研究

探究油气储运防腐中使用石墨烯-玻璃鳞片环氧复合涂料的效果.选取40目玻璃鳞片与石墨烯结合起来,制备出加入不同含量玻璃鳞片的防腐蚀涂料.重点分析所制备的涂料附着力、表面形貌等指标情况.研究结果表明,在不同含量玻璃鳞片下,涂层和基体之间可以相互结合,涂层具有良好的附着力;通过720 h中性盐雾腐蚀后,涂层结构比较紧密、完整...     

环氧玻璃鳞片重防腐蚀涂料

研制出一种环氧玻璃鳞片重防腐蚀涂料,并介绍了该涂料的基本配方、生产工艺和性能指标。     

环氧树脂及其涂料

持久防腐的环氧树脂涂料及其涂覆的金属材料,环氧树脂涂料的水溶性改性,在地板表面能形成不平整图案的耐磨环氧涂料添加剂组合物,低温快干环氧煤沥青玻璃鳞片涂料的研制     

船舶涂料演绎精彩明天

船舶涂料主要起到防腐和美化船体的作用,为了满足船主对船舶涂装的越来越高的要求,涂料厂商纷纷开发质量更高、性能更好的涂料品种。超厚膜型环氧、焦油环氧涂料、环氧玻璃鳞片涂料、高耐侯性的氟涂料、有机硅醇酸涂料、有机硅丙烯酸树脂涂料等都是发展方向。     

防腐蚀涂料综述（上）

介绍了我国防腐蚀涂料的品种、生产状况、存在问题及解决对策，并提出水性环氧涂料、粉末涂料、玻璃鳞片涂料的开发应用前景。     

钛纳米聚合物涂料在NaCl溶液中的电化学阻抗谱

采用电化学阻抗谱方法对钛纳米聚合物涂料的防腐性能进行了研究,并通过与环氧树脂清漆、环氧玻璃鳞片涂料的对比,说明钛纳米聚合物涂料的防腐性能显著优于上述两种涂料的防腐性能。     

环氧玻璃鳞片长效防腐涂料的制备

研制了一种环氧玻璃鳞片长效防腐涂料,玻璃鳞片经复合硅烷处理剂处理后,其用量在20％～30％时,涂层的防护效果最佳。盐雾试验4000h,湿热试验3000h,涂层无变化,具有优异的防腐性能,可用于海洋平台、石油化工等重防腐领域。     

环氧玻璃鳞片重防腐涂料

以环氧树脂作为成膜物,玻璃鳞片作为骨料,配用各种助剂,研制成厚浆型环氧玻璃鳞片重防腐涂料,适用于苛刻环境的防腐。介绍了该涂料的配方、生产工艺、性能指标和施工方法。     

The effect of morphology on the corrosion inhibition and mechanical properties of hybrid polymer coatings

The durability and mechanical properties of epoxy ester coatings and films has been improved by blending with rigid aromatic polyurea (PU). The interaction of PU and epoxy ester was enhanced by coupling the polymers with polymethylhydrosiloxane. The reactions between various entities are analyzed by Fourier transform infrared spectroscopy and the change in physical and mechanical properties are studied by a dynamic mechanical analyzer. The corrosion resistance of the hybrid coatings was measured by direct current polarization method, direct current polarization (DCP). The addition of polymethylhydrosiloxane enhances the corrosion properties in the hybrid coatings. The surface morphology was analyzed by scanning electron microscopy. The glass transition temperature of the films increases with increasing PU concentration and a wide glass rubber transition range for hybrid coatings was achieved which confirms the higher impact strength of the hybrid coatings and films. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013     

湿热历史对环氧粉末涂料固化时间及热特性的影响

环氧粉末的固化时间及热特性是三层结构聚乙烯防腐层（ 3PE）涂敷时工艺设置的重要参数,准确的固化时间数据是确保各层之间形成最佳结合的关键。本研究选取了 6种典型环氧粉末样品,研究了固化后涂层不同存放环境及后处理方式对环氧粉末涂层固化时间及固化后热特性的影响。研究发现固化时间测试时涂层用水淬冷后,放置周期及存放环境对固化涂层热特性测试结果会产生一定的影响,甚至可能会得出错误的结果,从而影响对粉末涂料固化时间的准确判断。通过对各样品不同放置周期、不同干燥处理方式的对比测试,发现随着涂层在潮湿环境下放置时间的增加,玻璃化温度的变化值（ ΔTg）在逐渐增大,但将涂层在一定温度下进行加热除湿处理后,又可以得到与淬冷后立即进行测试时相当的结果。由此可见,固化涂层样品长时间放置过程中水分子由表面扩散至涂层内部引起涂层塑化,进而导致涂层玻璃化转变温度降低,可能是影响固化时间及热特性测试的关键因素。     

The influence of ultra-fine glass fibers on the mechanical and anticorrosion properties of epoxy coatings

The effects of different contents of ultra-fine glass fiber on mechanical and anticorrosion properties of epoxy coatings have been investigated. The FTIR and SEM have been used to analyze the surface nature and microstructure of the coatings. Electrochemical impedance spectroscopy (EIS) and a salt spray test have also been used to characterize the contents of ultra-fine glass fibers on the impedance of the coatings. When 10%, 20%, 30% of ultra-fine glass fibers are added to the coatings, their hardness and adhesion increases by 67%, 67%, 200% and 21.6%, 39%, 40%, respectively, compared with the properties of the pure coating. But the anticorrosion properties of the coatings containing high ultra-fine glass fiber content decreased with respect to the pure coatings properties.     

高性能玻璃鳞片防腐涂料的研制

采用偶联剂处理玻璃鳞片等方法,研制了高固体分环氧改性聚氨酯玻璃鳞片防腐涂料,优于普通防腐涂料,适用于油气田、化工设备等苛刻腐蚀环境的防腐,尤其适用于输油管道和原油贮罐的内壁防腐。介绍了该高性能防腐涂料所用的原料、制备工艺和性能指标。讨论了涂料的溶剂体系、玻璃鳞片片径、偶联剂、颜填料、助剂等的选用。     

Evaluation of surface treatments for glass fibers in composite materials

The thermomechanical stability of a number of organosilane surface treatments for glass fibers was evaluated for use in a fiber reinforced epoxy resin. All of the silane coatings were found to improve the tensile strength of E-glass filaments, particularly at large gauge lengths. A phenylamino silane and an amino silane were particularly effective in this regard. The fiber/matrix interface was evaluated as a function of temperature and after exposure to boiling water using a single-fiber composite test. All silane coatings transmitted a higher interfacial shear stress than obtained in composites with no coatings, and in all cases the shear stress transmission was considerably higher than would be expected from the yield properties of the resin. Measurements of the glass transition temperature of the epoxy resin, as well as Fourier-Transform Infra-Red analysis, indicated modification of resin properties in a zone around the glass fibers. Each of the silane coatings provided more stable thermomechanical properties than those obtained with uncoated glass, at least until the silanes were irreversibly degraded by boiling water. A phenylamino silane provided the most thermally stable properties. Finally, unidirectional E-glass fiber reinforced laminae were fabricated and the measured values of longitudinal strength were compared favorably to theoretical predictions.     

水性重防腐涂料的研究进展

概括了几种水性重防腐涂料所用的树脂及其研究进展,重点综述了水性环氧重防腐涂料和水性无机硅酸锌涂料的发展状况。其次,讨论了几种应用于水性重防腐涂料的防锈颜料和鳞片状填料,特别是对于玻璃鳞片进行了比较详细和深入的分析。最后,对于水性重防腐涂料未来的发展方向提出了展望。