共查询到18条相似文献,搜索用时 484 毫秒
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高容量储氢材料的研究进展 总被引:6,自引:0,他引:6
氢能是一种理想的二次能源.氢能开发和利用需要解决氢的制取、储存和利用3个问题,而氢的规模储运是现阶段氢能应用的瓶颈.氢的储存方法有高压气态储存、低温液态储存和固态储存等3种.固态储氢材料储氢是通过化学反应或物理吸附将氢气储存于固态材料中,其能量密度高且安全性好,被认为是最有发展前景的一种氖气储存方式.由轻元素构成的轻质高容量储氢材料,如硼氢化物、铝氢化物、氨摹氢化物等,理论储氢容量均达到5%(质量分数)以上,这为固态储氢材料与技术的突破带来了希望.新型储氢材料未来研究的重点将集中于高储氢容量、近室温操作、可控吸/放氢、长寿命的轻金属基氢化物材料与体系. 相似文献
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高密度储氢材料研究进展 总被引:2,自引:0,他引:2
氢是一种清洁的燃料,氢能是未来有发展前景的新型能源之一.氢的储存是氢能现阶段开发和利用的瓶颈.氢的储存方法有高压气态储存、低温液态储存和固态储存等3种,其中高压气态储存或低温液态储存不能满足将来的储氢目标.固态储氢是通过化学或物理吸附将氢气储存于固态材料中,其能量密度高且安全性好,被认为是最有发展前景的一种氢气储存方式.高密度储氢材料由轻元素构成,包括铝氢化物、硼氢化物、氨基氢化物、氨硼烷等,理论储氢质量分数均达到5%以上.综述了高密度储氢材料的研究进展,认为高储氢容量、近室温操作、可控吸/放氢、长寿命的轻质氢化物材料有希望达到燃料电池和移动氢源应用的目标. 相似文献
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氢气的检测具有重要的学术意义和广阔的应用前景.氢敏传感器发展的关键在于高品质氢敏材料的研制.本文根据氢敏材料工作原理的不同,分别介绍了电化学型、半导体型、热导型和光学型四类氢敏传感器及相应氢敏材料的国内外研究最新进展,着重描述了各类氢敏材料的作用机制和改性途径,并展望了氢敏材料及氢敏传感器的发展方向. 相似文献
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Jun Yang Yifan Cao Shuyu Zhang Qingwen Shi Siyu Chen Shengcai Zhu Yunsong Li Jianfeng Huang 《Small (Weinheim an der Bergstrasse, Germany)》2023,19(29):2207295
Tungsten oxide (WO3) is an appealing electrocatalyst for the hydrogen evolution reaction (HER) owing to its cost-effectiveness and structural adjustability. However, the WO3 electrocatalyst displays undesirable intrinsic activity for the HER, which originates from the strong hydrogen adsorption energy. Herein, for effective defect engineering, a hydrogen atom inserted into the interstitial lattice site of tungsten oxide (H0.23WO3) is proposed to enhance the catalytic activity by adjusting the surface electronic structure and weakening the hydrogen adsorption energy. Experimentally, the H0.23WO3 electrocatalyst is successfully prepared on reduced graphene oxide. It exhibits significantly improved electrocatalytic activity for HER, with a low overpotential of 33 mV to drive a current density of 10 mA cm−2 and ultra-long catalytic stability at high-throughput hydrogen output (200 000 s, 90 mA cm−2) in acidic media. Theoretically, density functional theory calculations indicate that strong interactions between interstitial hydrogen and lattice oxygen lower the electron density distributions of the d-orbitals of the active tungsten (W) centers to weaken the adsorption of hydrogen intermediates on W-sites, thereby sufficiently promoting fast desorption from the catalyst surface. This work enriches defect engineering to modulate the electron structure and provides a new pathway for the rational design of efficient catalysts for HER. 相似文献
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In power plants, several major components such as steam generator tubes, boilers, steam/water pipe lines, water box of condensers
and the other auxiliary components like bolts, nuts, screws fasteners and supporting assemblies are commonly fabricated from
plain carbon steels, as well as low and high alloy steels. These components often fail catastrophically due to hydrogen embrittlement.
A brief overview of our current understanding of the phenomenon of such hydrogen damage in steels is presented in this paper.
Case histories of failures of steel components due to hydrogen embrittlement, which are reported in literature, are briefly
discussed. A phenomenological assessment of overall process of hydrogen embrittlement and classification of the various damage
modes are summarized. Influence of several physical and metallurgical variables on the susceptibility of steels to hydrogen
embrittlement, mechanisms of hydrogen embrittlement and current approaches to combat this problem are also presented. 相似文献
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用核反应分析方法,对等离子体基脉冲偏压沉积DLC膜的氢分布和氢含量进行了较系统的研究.结果表明,用等离子体基脉冲偏压沉积技术可获得较低氢含量的DLC膜;其氢含量范围约为6at%~17at%,且氢沿膜厚是均匀分布的,随等离子体密度及离化率降低,DLC膜的氢含量增加,荷能离子对生长表面的轰击具有较强的析氢作用,工作气体中引入氢气促进DLC膜中氢的析出. 相似文献
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Hiroaki Wakayama 《Fullerenes, Nanotubes and Carbon Nanostructures》2020,28(10):841-845
AbstractCarbon materials were prepared by plasma chemical vapor deposition at different pressures without catalyst, and the structure and hydrogen storage characteristics of milled and unmilled samples of the materials were evaluated. Using this approach, we were able to fabricate graphite microcrystals with a crystallite size of several nanometers, and the crystallite size and surface area could be controlled by changing the pressure during plasma chemical vapor deposition. The hydrogen storage capacity of the unmilled materials was 0.3?wt%, but milling increased this value to 1.0?wt% by reducing the crystallite size and increasing the crystallite surface area. 相似文献
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Yuichiro Watanabe Daisuke Yokoyama Tomoyuki Koganezawa Hiroshi Katagiri Takashi Ito Satoru Ohisa Takayuki Chiba Hisahiro Sasabe Junji Kido 《Advanced materials (Deerfield Beach, Fla.)》2019,31(18)
Use of the intrinsic optoelectronic functions of organic semiconductor films has not yet reached its full potential, mainly because of the primitive methodology used to control the molecular aggregation state in amorphous films during vapor deposition. Here, a universal molecular engineering methodology is presented to control molecular orientation; this methodology strategically uses noncovalent, intermolecular weak hydrogen bonds in a series of oligopyridine derivatives. A key is to use two bipyridin‐3‐ylphenyl moieties, which form self‐complementary intermolecular weak hydrogen bonds, and which do not induce unfavorable crystallization. Another key is to incorporate a planar anisotropic molecular shape by reducing the steric hindrance of the core structure for inducing π–π interactions. These synergetic effects enhance horizontal orientation in amorphous organic semiconductor films and significantly increasing electron mobility. Through this evaluation process, an oligopyridine derivative is selected as an electron‐transporter, and successfully develops highly efficient and stable deep‐red organic light‐emitting devices as a proof‐of‐concept. 相似文献
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XueguiQI ZeshaoCHEN GuanzhongWANG 《材料科学技术学报》2003,19(3):235-239
In this paper we focus on diamond film hot-filament chemical vapor deposition reactors where the only reactant is hydrogen so as to study the formation and transport of hydrogen atoms. Analysis of dimensionless numbers for heat and mass transfer reveals that thermal conduction and diffusion are the dominant mechanisms for gas-phase heat and mass transfer, respectively. A simplified model has been established to simulate gas-phase temperature and H concentration distributions between the filament and the substrate. Examination of the relative importance of homogeneous and heterogeneous production of H atoms indicates that filament-surface decomposition of molecular hydrogen is the dominant source of H and gas-phase reaction plays a negligible role. The filament-surface dissociation rates of H2 for various filament temperatures were calculated to match H-atom concentrations observed in the literature or derived from power consumption by filaments. Arrhenius plots of the filament-surface hydrogen dissociation rates suggest that dissociation of H2 at refractory filament surface is a catalytic process, which has a rather lower effective activation energy than homogeneous thermal dissociation. Atomic hydrogen, acting as an important heat transfer medium to heat the substrate, can freely diffuse from the filament to the substrate without recombination. 相似文献