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Co(CH(3)CO(2))(2)4H(2)O reacts with benzene-1,2-dioxyacetic acid (bdoaH(2)) to give the Co(2+) complexes [Co(bdoa)(H(2)O)(3)]H(2)O (1a) and [Co(bdoa)(H(2)O)(3)] 3.5H(2)O (1b). Subsequent reaction of 1a with 1,10- phenanthroline produces [CO(phen)(3)] bdoa10H(2)O (2a) and {[CO(phen)(3)](bdoa)}(2)24H(2)O (2b). Molecular structures of 1b and 2b were determined crystallographically. In 1b the bdoa(2-)- ligates the metal by two carboxylate oxygens and two ethereal oxygens, whereas in 2b the bdoa(2-) is uncoordinated. The Mn(2+) and Cu(2+) complexes [Mn(bdoa)(phen)(2)]H(2)O (3) and [Cu(pdoa)(imid)(2)] (4) were also synthesised, 1a-4 and other metal complexes of bdoa H(2) (metal = Mn(2+), Co(2+) ,Cu(2+), Cu(+) ) were screened for their ability to inhibit the growth ofhe yeast Candida albicans. Complexes incorporating the 1,10-phenanthroline ligand were the most active. 相似文献
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The interaction of binuclear rhodium(II) complexes [Rh(2)(OOCCH(3))(4)(H(2)O)(2)], [Rh(2){OOCCH(OH)Ph}(2)(phen)(2)(H(2)O)(2)] {OOCCH(OH)Ph}(2), [Rh(2)(OOCCH(3))(2)(bpy)(2)(H(2)O)(2)](OOCCH(3))(2) and [Rh(2)Cl(2)(OOCMe)(2)(bpy)(2)](3H(2)O) with ceruloplasmin, cysteine, glutathione and coenzyme A have been investigated using. UV-Vis and CD spectroscopies. The complexes containing phen or bpy at pH = 7.4 and 4.0 are readily reduced with sulfhydryl compounds, while rhodium(II) acetate is relatively stable in these conditions. Complex [Rh(2){OOCCH(OH)Ph}(2)(phen)(2)(H(2)O)(2)] strongly changes structure of ceruloplasmin leading to the decrease of of alpha-helix content and loss of oxidase activity. 相似文献
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Zhang Tonglai Lu Chunhua Zhang Jianguo Yu Kaibei 《Propellants, Explosives, Pyrotechnics》2003,28(5):271-276
The title compound {[Ca(CHZ)2(H2O)](NTO)2⋅3.5H2O}n was synthesized by using an aqueous solution of calcium 3‐nitro‐1,2,4‐triazol‐5‐onate and carbohydrazide (CHZ, NH2NHCONHNH2). Its molecular structure was determined by X‐ray diffraction and its crystals have monoclinic form, with space group C2/c, where a=2.4483(4) nm, b=1.2581(2) nm, c =1.6269(3) nm, β=121.168(12)°, V=4.2879(13) nm3, Z=8, dc=1.727 g⋅cm−3, μ (Mo Kα)=3.9 cm−1, M=557.47, F(000)=2312. The coordination polyhedron is a tricapped trigonal prism in a tetradecahedron with a coordination number of nine. The whole molecule has many long chains formed through the carbohydrazide bridges, and every long chain is unlimited along the c axis. The long chains are linked by hydrogen bonds to form the crystal structure. 相似文献
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合成了稀土高氯酸盐与咪唑、DL α 丙氨酸的4种配合物晶体。经傅里叶变换红外光谱(FTIR)、元素分析和化学分析测定后确定其组成为[Ln(C3H7NO2)x(C3H4N2)(H2O)](ClO4)3(Ln=La,x=3;Ln=Pr,Nd,Sm,x=2)。用差示扫描量热法(DSC)测定了4种配合物的热分解数据,4个配合物开始熔化分解的温度分别为502 5K,532 4K,495 7K,516 7K,配合物有较高的热稳定性。 相似文献
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The reaction between mer-[RuNO(NH3)3(NO2)(OH)]Cl·0.5H2O and an excess of 16 M HNO3 leads to the protonation of the starting complex and crystallization of the complex with a coordinated water molecule and nitrite anion. The crystal structure of the product has been determined. The coordinated water molecule tends to be a weak acid with a measured pKa of 2.4. 相似文献
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《Inorganic chemistry communications》2001,4(1):33-35
The reaction between [RuNO(NH3)4OH]Cl2 and an excess of 2 M H2SO4 leads to the protonation of the starting complex and crystallisation of the title complex with sulphate and hydrosulphate anions. The crystal structure of the product has been determined. The linear nitroso group and water molecule are coordinated in trans positions. 相似文献
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Howard M. Colquhoun Simon M. Doughty John M. Maud J. Fraser Stoddart David J. Wllliams John B. Wolstenholme 《Israel journal of chemistry》1985,25(1):15-26
In addition to hydrogen bonding and Coulombic forces, charge transfer interactions stabilise the 1:1 adducts formed between [Pt(bipy)(NH3)2] 2+ and a series of dibenzo-3n-crown-n (n = 6–12) ethers as evidenced by 1H NMR and UV-visible spectra in solution and by X-ray crystal structures (for n = 8 and 10) in the solid state. Mutual diamagnetic (ring current) shielding by the aromatic systems of host and guest results in dramatic upfield shifts of certain aromatic proton resonances on adduct formation, especially when n = 10 or 11. A broad charge-transfer absorption band at 350 nm attains its maximum intensity at n = 11 though stability constant measurements indicate optimum binding when n = 10. X-ray diffraction studies reveal that, when n = 8, only one of the crown ether benzo-rings interacts with the bipyridyl ligand in a charge-transfer sense. However, when n = 10, the macrocycle is sufficiently large and flexible to allow both benzo-rings to enter into stabilising interactions with the bipyridyl ligand such that the platinum complex is encapsulated by the host in a U-shaped cavity. 相似文献
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在水醇溶液中合成了标题配位聚合物[Cu(bipy)(H2O)2]SO4(bipy=2,2-′bipyridine),进行了元素分析、X射线衍射等表征。X射线衍射结果表明,此配合物属单斜晶系,空间群为Cc,晶胞参数为:a=1.5138(2)nm,b=1.2455(8)nm,c=0.7001(8)nm,β=106.013(3)°,V=1.2690(0)nm3,Z=4,Dc=1.841 g/cm3,μ=1.913 mm-1,F(000)=716。配合物中的金属铜离子与一个2,2′-联吡啶、2个水分子配位,形成一个变形的四边形结构。配合物通过O-H…O氢键构建为三维超分子。 相似文献
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《Inorganic chemistry communications》2007,10(9):1067-1069
A novel 3D [La2(C2O4)2(NO3) (OH)(H2O)] · 3H2O 1 has been synthesized under hydrothermal conditions and characterized by elemental analyses, IR, TGA, X-ray powder diffraction, X-ray single crystal diffraction and photoluminescence. The bridging modes of both nitrates and oxalates in compound 1 are uncommon. We have unexpectedly generated an unusual compound by using the simplest ligands, oxalates and nitrates in the presence of nicotinate (HIN). 相似文献
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A mixed-type of azametallacrown based on a flexible pentadentate N-propionyl ligand was reported, which exhibits not only the completely different arrangement of the metal centers but also diversely geometric configurations of the N-terminal ligands, and this complex can further assemble into a novel 3-D supramolecular structure using two different aza18-MC-6 as secondary building units (SBUs) via the intermolecular C–H?π, π–π and C–H?O interactions. Temperature-dependent magnetic susceptibility measurements of the title complex indicate that the complex presents significantly antiferromagnetic coupling among metal centers. 相似文献
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《化学世界》2015,(12)
用3d金属离子锰与2-羟基-3-吡啶羧酸配体合成出新的水杨酸式螯合具有三维网络结构的Mn(H_2O)_2(HNic)_2配合物。均三苯甲酸苯环上一、三、五位置上的羧基都有脱质子化进行各种不同的结合,利用这点水溶液合成氢键配合物Mn(H_2O)_2(HNic)。我们采用常规分析方法即元素分析谱等,对配合物进行了表征.利用X-射线衍射晶体结构分析,结果显示该配合物属于单斜晶系,空间群为P2(1)/c,每一各晶胞包含两个Mn(H_2O)_2(HNic)_2分子,一个2-羟基-3-吡啶羧酸分子,通过N原子质子化的H原子与临近2-羟基-3-吡啶羧酸分子上的羟基上O原子又形成了一个八元环的氢键结构,该配合物具有复杂的氢键结构。 相似文献
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The dinuclear CoII coordination compound with empirical formula [Co2(2,4-pydc)2(bpa)(H2O)6](H2O)2 (1); bpa = 1,2-bis(2,4-pyridyl)ethane, 2,4-pydc = 2,4-pyridinedicarboxylate anion, has been synthesized and õcharacterized by elemental analysis, single crystal X-ray diffraction, IR and UV–vis spectra, TGA and XRPD. Compound 1 is a symmetry-related dinuclear compound consisting of two six coordinated cobalt atoms, one bpa ligand, two 2,4-pydc ligands and two lattice water molecules. Each CoII ion is coordinated by one oxygen atom and one nitrogen atom from 2,4-pydc bidentate chelate ligand, one nitrogen atom of bpa bidentate bridging ligand and three water molecules, giving a distorted octahedral geometry with CoN2O4 chromophore. The crystal packing of this compound reveals a novel 3D supramolecular network, formed by hydrogen-bonding and C–H⋯π interactions. Investigations of the dynamic structural transformation behavior demonstrate that the title compound exhibits a solvent-induced reversible crystal-to-amorphous transformation with chromotropism when exposed to water vapor. This indicates that the dehydrated amorphous form, Co2(2,4-pydc)2(bpa)(H2O)2 (1A), may be utilized as an indicator for humidity. 相似文献
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《Inorganic chemistry communications》2007,10(9):975-978
A novel Cd(II)/4-pya coordination polymer {[Cd(μ-Cl)(4-pya)(H2O)]2 · 4H2O}∞ (1) (4-pya = trans-4-pyridylacrylate) was synthesized and structurally characterized. Single-crystal X-ray diffraction revealed that 1 consists of a 2D (4, 4) network constructed from the 4-pya bridging ligand and the dimeric [Cd(μ-Cl)]2 cores, in which each six-coordinated Cd(II) ion adopts an octahedral coordination geometry. Each 2D layer is further stacked along the a axis through hydrogen bonding interactions to afford a 3D hydrogen-bound network. An infinite water chain is generated via hydrogen bonds into each resulting 1D channel. The luminescent properties of 1 in the solid state were investigated. 相似文献