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用电导、表面张力和折光指数法估算了十二烷基硫酸钠(SLS)、十二烷基苯磺酸钠(SDBS)和辛基酚聚氧乙烯基醚(OP)复合乳化剂的临界胶束浓度(CMC)。发现,SLS/OP和SDBS/OP的CMS值约为10^-3g/ml数量级,数据与乳化剂纯度有关,但与复合乳化剂中两者的比例无关。同时对三种测定方法作了评价。 相似文献
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电导法测定表面活性剂溶液的临界胶束浓度 总被引:2,自引:0,他引:2
本文用电导法测定了十二烷基磺酸钠在40℃和60℃时的临界胶束浓度(CMC),根据“相分离模型”计算了40℃时十二烷基硝酸钠溶液的胶束形成标准焓变(△Hm),标准吉布斯自由能变化(△Gm)和标准熵变(△Sm)。 相似文献
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以中性红为探针,用吸伏安法测定了十六烷基三甲基溴化铵的临界胶速浓度,基本原理为:存在于表面活性剂溶液中的微量中性红在悬汞电极上的吸附伏安峰电流对表面活性剂浓度的曲线在临界胶束浓度处有一拐点,此点即为阳离子表面活性剂的临界胶束浓度。 相似文献
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低聚型表面活性剂临界胶束浓度的分光光度法测定 总被引:1,自引:0,他引:1
本文在前人的基础上提出了一种采用紫外分光光度法测定聚型表面活性剂的临界胶束浓度的新方法,探讨了不同条件对测定结果的影响,并确立了优化条件。通过对增溶机理的讨论,进一步说明了低聚型表面活性水溶液的特征。 相似文献
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聚酯型高分子表面活性剂临界胶束浓度的测定:紫外分光光度法 总被引:1,自引:0,他引:1
本文通过实验选出了适用于测定聚酯型表面活性剂临界胶束浓度的添加物二甲基偶氮苯,确定了最佳浓度区间,建立了简单,快速的测定方法。 相似文献
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碘光谱法测定非离子表面活性剂的临界胶束浓度 总被引:6,自引:0,他引:6
考察了碘光谱法测定非离子表面活性剂在水溶液中的临界胶束浓度(cmc)的影响因素。欲得正确结果,须将碘-胶束溶液(不同浓度)放置,待碘的分配达到平衡(例如24h)后再进行测定,这样测得TritonX-100、TritonX-305和单分散的纯化合物C12H25O(C2H4O)6H的cmc分别为2.4×10-4、3.5×10-4和8.4×10-5mol·dm-3,与文献中用表面张力法测得的结果一致。若按Ross和Oliver将预先配好的溶液稀释后1小时内测定的方法,则所得结果偏低。只要测定时碘-胶束溶液已达平衡,则碘浓度在4~12mg/100ml范围内对cmc的测定结果无明显的影响。文献中提到的碘浓度对cmc测定值的影响可能是由于碘的分配未达平衡所致。 相似文献
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采用电导法测定一定温度下不同浓度的十四烷基三甲基氯化铵(TTAC),十六烷基三甲基氯化铵(CTAC),十八烷基三甲基氯化铵(STAC)溶液的电导率值,计算摩尔电导率,研究碳链上碳原子数对表面活性剂临界胶束浓度(CMC)的影响。结果表明:CMC(TTAC)=0.00580 mol/L,CMC(CTAC)=0.0041mol/L,CMC(STAC)=0.0039 mol/L,可知随着碳链上碳原子个数的增多,相应的临界胶束浓度(CMC)呈减小趋势。 相似文献
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A technique for determining low critical micelle concentrations (CMC) by means of a hydrophobic fluorescence probe has been
developed. The amount of the fluorescent probe at the CMC is so small that the effect of the probe on micelle formation is
negligible. The fluorescence intensity was measured at fixed dye/surfactant ratios, and it decreased with concentration. A
quantity proportional to fluorescent quantum yield was calculated and found to be high for concentrations of surfactant above
the CMC and almost zero below the CMC, giving a distinct break in the quantum yield vs. the concentration curve. 相似文献
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A homologous series of anionic surfactants, namely, sodium-N-(alkyloxycarbonyl) alanine (where alkyl=octyl-, dodecyl-, hexadecyl-, and octadecyl-) were synthesized having the formula:
R-OCO-CH2NH-CH2-CH2-COONa. Surface properties of their solutions, including surface tension, critical micelle concentration, effectiveness, maximum
surface excess, and minimum surface area, were investigated for different concentrations at 25°C. The effects of these surfactants
on the solubilization of a polar and a nonpolar solute were studied. Standard free energies of micellization and adsorption
were calculated for the prepared surfactants in aqueous solution. 相似文献
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用电导法对十二烷基硫酸钠(SDS)的临界胶团浓度(CMC)进行了研究,考虑了温度、pH值、金属离子(Cd2+、Zn2+、Pb2+)浓度变化以及SDS和3种非离子表面活性剂(Brij35、TritonX-100、APG)的复配对溶液CMC值的影响。结果表明,随温度升高,pH值上升,金属离子浓度增加以及Brij35/SDS、TritonX-100/SDS、APG/SDS混合体系配比的增加,溶液CMC值减小。特别当复配比在0.13~1时,CMC值的下降趋势非常明显。这一结果为采用胶团强化超滤技术处理电解锌废水时SDS最佳添加量的确定提供了有效的依据。 相似文献
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J. Coret A. Shiloach P. Berger D. Blankschtein 《Journal of surfactants and detergents》1999,2(1):51-58
We studied the behavior of an aqueous ternary surfactant mixture composed of a nonionic surfactant and two anionic surfactants
which differ in both surfactant hydrophobic tail length and surfactant hydrophilic head structure. We used an experimental
design program to calculate the critical micelle concentrations (CMCs) of this ternary surfactant mixture over the entire
range of solution compositions. As inputs, the experimental design methodology requires the values of the ternary surfactant
mixture CMCs for a limited subset of solution compositions which is determined by the experimental design program. We showed
that this subset of ternary surfactant mixture CMC values can either be measured experimentally or predicted theoretically.
The theoretical CMCs were predicted by a series of userfriendly computer programs which are based on molecular-ther-modynamic
theories describing single and mixed micelle formation. The experimental design program generated two surfaces describing
the ternary surfactant mixture CMCs over the entire solution composition range—one based on the experimentally measured subset
of CMC values, and the other based on the theoretically predicted CMC values for the same subset of solution compositions.
We found that these two CMC surfaces agree very well, thus demonstrating the utility of the computerassisted molecular-thermodynamic
modeling as a predictive tool in surfactant mixture characterization and design. 相似文献
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Youssef Barakat Tahany S. Gendy Attia I. Mohamad Abdel-Fattah M. Youssef 《Polymer International》1989,21(5):383-389
Four low molecular weight nonionic polymeric surfactants were prepared by condensing octyl-, dodecyl-, tetradecyl- and hexadecylphenol with para-formaldehyde, and then reacting the resulting resins with ethylene oxide to obtain products with the desired degree of ethoxylation. The molecular weights of the prepared alkylphenol-formaldehyde resins (prior to ethoxylation) were determined by vapour pressure osmometry. The surface tensions of aqueous solutions of these nonionic polymeric surfactants were determined by using the spinning drop method. Plotting the surface tensions obtained versus the logarithm of concentrations resulted in two lines: the pre-CMC (CMC = critical micelle concentration) line (the linear portion below the CMC value) and the post-CMC line (the linear portion above the CMC value). Least squares regression analysis was performed to get the best equation for each of the two lines. Solving these two equations simultaneously resulted in the value of the CMC and the corresponding surface tension (γCMC) for each surfactant of the four polymeric nonionic groups. The CMC values obtained for these polymeric surfactants are of the same order of magnitude obtained for monomeric and other polymeric nonionic surfactants. 相似文献
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