Indoor/outdoor relationships for PM2.5 and associated carbonaceous pollutants at residential homes in Hong Kong - case study

Six residences were selected (two roadside, two urban, and two rural) to evaluate the indoor-outdoor characteristics of PM(2.5) (aerodynamic diameter <2.5 microm) carbonaceous species in Hong Kong during March and April 2004. Twenty-minute-averaged indoor and outdoor PM(2.5) concentrations were recorded by DustTrak samplers simultaneously at each site for 3 days to examine diurnal variability of PM(2.5) mass concentrations and their indoor-to-outdoor (I/O) ratios. Daily (24-h average) indoor/outdoor PM(2.5) samples were collected on pre-fired quartz-fiber filters with battery-powered portable mini-volume samplers and analyzed for organic and elemental carbon (OC, EC) by thermal/optical reflectance (TOR) following the Interagency Monitoring of Protected Visual Environments (IMPROVE) protocol. The average indoor and outdoor concentrations of 24 h PM(2.5) were 56.7 and 43.8 microg/m(3), respectively. The short-term PM(2.5) profiles indicated that the penetration of outdoor particles was an important contributor to indoor PM(2.5), and a household survey indicated that daily activities were also sources of episodic peaks in indoor PM(2.5). The average indoor OC and EC concentrations of 17.1 and 2.8 microg/m(3), respectively, accounted for an average of 29.5 and 5.2%, respectively, of indoor PM(2.5) mass. The average indoor OC/EC ratios were 5.8, 9.1, and 5.0 in roadside, urban, and rural areas, respectively; while average outdoor OC/EC ratios were 4.0, 4.3, and 4.0, respectively. The average I/O ratios of 24 h PM(2.5), OC, and EC were 1.4, 1.8, and 1.2, respectively. High indoor-outdoor correlations (r(2)) were found for PM(2.5) EC (0.96) and mass (0.81), and low correlations were found for OC (0.55), indicative of different organic carbon sources indoors. A simple model implied that about two-thirds of carbonaceous particles in indoor air are originated from outdoor sources. PRACTICAL IMPLICATIONS: Indoor particulate pollution has received more attentions in Asia. This study presents a case study regarding the fine particulate matter and its carbonaceous compositions at six residential homes in Hong Kong. The characteristics and relationship of atmospheric organic and elemental carbon were discussed indoors and outdoors. The distribution of eight carbon fractions was first reported in indoor samples to interpret potential sources of indoor carbonaceous particles. The data set can provide significant scientific basis for indoor air quality and epidemiology study in Hong Kong and China.     

The spatial and temporal variations in PM10 mass from six UK homes

People spend the majority of their time indoors mostly in the domestic environment, where their health may be effected by significant airborne particulate pollution. The indoor/outdoor air quality at six homes in Wales and Cornwall was investigated, based on different locations (urban, suburban, rural) and household characteristics (smokers, non-smokers). The spatial and temporal variations in PM10 mass were monitored for a calendar year, including ambient weather conditions. The activities of individuals within a household were also recorded. Monitoring of PM10 took place inside (kitchen, living room, bedroom) homes, along with concomitant collections outdoors. Samples were subjected to gravimetric analysis to determine PM10 concentrations and examined by scanning electron microscopy to identify the types of particles present on the filters. The results of the study show there are greater masses of PM10 indoors, and that the composition of the indoor PM10 is controlled by outdoor sources, and to a lesser extent by indoor anthropogenic activities, except in the presence of tobacco smokers. The indoor and outdoor PM10 collected was characterised as being a heterogeneous mixture of particles (soot, fibres, sea salt, smelter, gypsum, pollen and fungal spores).     

Relation between Indoor and Outdoor Exposure to Fine Particles near a Busy Arterial Road

Abstract Various studies on indoor and outdoor particulate matter in the urban environment in the vicinity of busy arterial roads in the centre of the subtropical city of Brisbane have indicated that the revised United States Environmental Protection Agency National Ambient Air Quality Standards (US EPA NAAQS) for Particulate matter PM_2.5 could be exceeded not only outdoors but also indoors. The aim of this work was to investigate outdoor exposure to submicrometer particles and their relationship with indoor exposure in a hypothetical office building located in the vicinity of a busy arterial road. The outdoor exposure values and trends were measured in terms of particle number in the submicrometer size range and were then recalculated to represent mass concentration trends. The results of this study indicate that exposure to PM_0.7 particles in ambient air close to a busy road often exceeds the levels of the annual and 24-hour US EPA NAAQS PM_2.5 standards. It is likely that exposure to PM_2.5 is even higher, and may significantly exceed these standards.     

Functional group characterization of indoor, outdoor, and personal PM: results from RIOPA

Fourier transform infrared (FTIR) spectra of outdoor, indoor, and personal fine particulate matter (PM(2.5)) samples were collected during the Relationship of Indoor, Outdoor, and Personal Air (RIOPA) study. FTIR spectroscopy provides functional group information about the entire PM(2.5) sample without any chemical preparation. It is particularly important to characterizing the poorly understood organic fraction of PM(2.5). To our knowledge this is the first time that FTIR spectroscopy has been applied to a PM(2.5) exposure study. The results were used to chemically characterize indoor air and personal exposure. Sulfate was strongest in outdoor samples, which is consistent with the generally accepted understanding that sulfate is of outdoor origin. Absorbances attributed to soil dust were also seen in many outdoor and some indoor and personal samples. Inorganic nitrate absorbances were a common feature of many California and some New Jersey samples. Carbonyl absorbances showed substantial variation in strength, number of peaks, and wave number shift between samples, indicating variability in composition and sources. Absorbances attributed to aliphatic hydrocarbon and amide functional groups were enhanced in many personal and indoor samples, which suggested the influence of indoor sources in these homes. We speculate that meat cooking is one possible source of particulate amides. PRACTICAL IMPLICATIONS: To our knowledge this is the first time that FTIR spectroscopy has been used to characterize the composition of indoor and personal PM(2.5). The presence of sulfate, nitrate, ammonium, soil dust and a number of organic functional groups are all detected in one analysis on filter samples without extraction or other sample preparation. Differences between indoor and outdoor spectra are used to identify spectral features due to indoor-generated PM(2.5). Particularly interesting are the much larger aliphatic absorbances, shifts in carbonyl absorbances, and occasional small amide absorbances found in indoor and personal spectra but rarely in outdoor spectra. These observations are important because organics make up a large portion of PM(2.5) mass and their composition and properties are poorly characterized. The properties and behavior of organic compounds in airborne particles are often predicted based on their functional group composition. This analysis begins the development of a better understanding of the functional group composition of indoor and personal PM(2.5) and how it differs from that of outdoor PM(2.5). Eventually this will lead to an improved understanding of the properties, behavior and effects of PM(2.5) of indoor and outdoor origin.     

Penetration of nitrogen oxides and particles from outdoor into indoor air and removal of the pollutants through filtration of incoming air

We studied the effect of ventilation and air filtration systems on indoor air quality in a children's day-care center in Finland. Ambient air nitrogen oxides (NO, NO2) and particles (TSP, PM10) were simultaneously measured outdoors and indoors with automatic nitrogen oxide analyzers and dust monitoring. Without filtration nitrogen oxides and particulate matter generated by nearby motor traffic penetrated readily indoors. With chemical filtration 50-70% of nitrogen oxides could be removed. Mechanical ventilation and filtration also reduced indoor particle levels. During holidays and weekends when there was no opening of doors and windows and no particle-generating activity indoors, the indoor particle level was reduced to less than 10% of the outdoor level. At times when outdoor particle concentrations were high during weekdays, the indoor level was about 25% of the outdoor level. Thus, the possible adverse health effects of nitrogen oxides and particles indoors could be countered by efficient filtration. We also showed that inclusion of heat recovery equipment can make new ventilation installations economical.     

Real-time characterization of aerosol particle composition,sources and influences of increased ventilation and humidity in an office

Most of human exposure to atmospheric pollutants occurs indoors, and the components of outdoor aerosols may have been changed in the way before reaching indoor spaces. Here we conducted real-time online measurements of mass concentrations and chemical composition of black carbon and the non-refractory species in PM_2.5 in an occupied office for approximately one month. The open-close windows and controlled dampness experiments were also performed. Our results show that indoor aerosol species primarily originate from outdoors with indoor/outdoor ratio of these species typically less than unity except for certain organic aerosol (OA) factors. All aerosol species went through filtration upon transport indoors. Ammonium nitrate and fossil fuel OA underwent evaporation or particle-to-gas partitioning, while less oxidized secondary OA (SOA) underwent secondary formation and cooking OA might have indoor sources. With higher particulate matter (PM) mass concentration outdoors than in the office, elevated natural ventilation increased PM exposure indoors and this increased exposure was prolonged when outdoor PM was scavenged. We found that increasing humidity in the office led to higher indoor PM mass concentration particularly more oxidized SOA. Overall, our results highlight that indoor exposure of occupants is substantially different from outdoor in terms of mass concentrations and chemical species.     

Toxicity and elemental composition of particulate matter from outdoor and indoor air of elementary schools in Munich, Germany

Outdoor particulate matter (PM(10)) is associated with detrimental health effects. However, individual PM(10) exposure occurs mostly indoors. We therefore compared the toxic effects of classroom, outdoor, and residential PM(10). Indoor and outdoor PM(10) was collected from six schools in Munich during teaching hours and in six homes. Particles were analyzed by scanning electron microscopy and X-ray spectroscopy (EDX). Toxicity was evaluated in human primary keratinocytes, lung epithelial cells and after metabolic activation by several human cytochromes P450. We found that PM(10) concentrations during teaching hours were 5.6-times higher than outdoors (117 ± 48 μg/m(3) vs. 21 ± 15 μg/m(3), P < 0.001). Compared to outdoors, indoor PM contained more silicate (36% of particle number), organic (29%, probably originating from human skin), and Ca-carbonate particles (12%, probably originating from paper). Outdoor PM contained more Ca-sulfate particles (38%). Indoor PM at 6 μg/cm(2) (10 μg/ml) caused toxicity in keratinocytes and in cells expressing CYP2B6 and CYP3A4. Toxicity by CYP2B6 was abolished with the reactive oxygen species scavenger N-acetylcysteine. We concluded that outdoor PM(10) and indoor PM(10) from homes were devoid of toxicity. Indoor PM(10) was elevated, chemically different and toxicologically more active than outdoor PM(10). Whether the effects translate into a significant health risk needs to be determined. Until then, we suggest better ventilation as a sensible option. PRACTICAL IMPLICATIONS: Indoor air PM(10) on an equal weight base is toxicologically more active than outdoor PM(10). In addition, indoor PM(10) concentrations are about six times higher than outdoor air. Thus, ventilation of classrooms with outdoor air will improve air quality and is likely to provide a health benefit. It is also easier than cleaning PM(10) from indoor air, which has proven to be tedious.     

Size-resolved dynamics of indoor and outdoor fluorescent biological aerosol particles in a bedroom: A one-month case study in Singapore

This study evaluated the interrelations between indoor and outdoor bioaerosols in a bedroom under a living condition. Two wideband integrated bioaerosol sensors were utilized to measure indoor and outdoor particulate matter (PM) and fluorescent biological airborne particles (FBAPs), which were within a size range of 0.5-20 μm. Throughout this one-month case study, the median proportion of FBAPs in PM by number was 19% (5%; the interquartile range, hereafter) and 17% (3%) for indoors and outdoors, respectively, and those by mass were 78% (12%) and 55% (9%). According to the size-resolved data, FBAPs dominated above 2 and 3.5 μm indoors and outdoors, respectively. Comparing indoor upon outdoor ratios among occupancy and window conditions, the indoor FBAPs larger than 3.16 μm were dominated by indoor sources, while non-FBAPs were mainly from outdoors. The occupant dominated the indoor source of both FBAPs and non-FBAPs. Under awake and asleep, count- and mass-based mean emission rates were 45.9 and 18.7 × 10⁶ #/h and 5.02 and 2.83 mg/h, respectively. Based on indoor activities and local outdoor air quality in Singapore, this study recommended opening the window when awake and closing it during sleep to lower indoor bioaerosol exposure.     

Applying indoor and outdoor modeling techniques to estimate individual exposure to PM2.5 from personal GPS profiles and diaries: A pilot study

Impacts of individual behavior on personal exposure to particulate matter (PM) and the associated individual health effects are still not well understood. As outdoor PM concentrations exhibit highly temporal and spatial variations, personal PM exposure depends strongly on individual trajectories and activities. Furthermore, indoor environments deserve special attention due to the large fraction of the day people spend indoors. The indoor PM concentration in turn depends on infiltrated outdoor PM and indoor particle sources, partially caused by the activities of people indoor.We present an approach to estimate PM2.5 exposure levels for individuals based upon existing data sources and models. For this pilot study, six persons kept 24-hour diaries and GPS tracks for at least one working day and one weekend day, providing their daily activity profiles and the associated geographical locations. The survey took place in the city of Münster, Germany in the winter period between October 2006 and January 2007. Environmental PM2.5 exposure was estimated by using two different models for outdoor and indoor concentrations, respectively. For the outdoor distribution, a dispersion model was used and extended by actual ambient fixed site measurements. Indoor concentrations were modeled using a simple mass balance model with the estimated outdoor concentration fraction infiltrated and indoor activities estimated from the diaries. A limited number of three 24-hour indoor measurements series for PM were performed to test the model performance.The resulting average daily exposure of the 14 collected profiles ranged from 21 to 198 µg m^− 3 and showed a high variability over the day as affected by personal behavior. Due to the large contribution of indoor particle sources, the mean 24-hour exposure was in most cases higher than the daily means of the respective outdoor fixed site monitors.This feasibility study is a first step towards a more comprehensive modeling approach for personal exposure, and therefore restricted to limited data resources. In future, this model framework not only could be of use for epidemiological research, but also of public interest. Any individual operating a GPS capable device may become able to obtain an estimate of its personal exposure along its trajectory in time and space. This could provide individuals a new insight into the influence of personal habits on their exposure to air pollution and may result in the adaptation of personal behavior to minimize risks.     

Reduction of fine airborne particulates (PM3) in a small city centre office, by altering electrostatic forces

A two stage intervention study was carried out to establish the degree to which a newly developed, electrostatic air cleaning (EAC) system can improve indoor air quality (IAQ) by reducing the number of airborne fine particles. The IAQ and how employees in a city centre office (49 m2) perceived it, was monitored from May until November 1998. The number of fine particles, PM3 (0.3-3.0 microm); number of coarse particles, PM7 (3.0-7.0 microm); number of small positive and negative air ions; relative humidity and temperature were recorded in and out of doors. To assess the employees' perception of any changes in their work environment, a questionnaire was completed. Number of particles, relative humidity and temperature were also recorded in a nearby office, equipped with an identical air processor, where no interventions were made. The results from the first intervention (Stage 1), comparing number of airborne particles outdoors to indoors, gave a 19% reduction for PM3 and a 67% reduction for PM7 (P < 0.001). The reduction in PM3 was inconsistent and not statistically significant (P = 0.3). The reduction in PM7 from outdoors and the removal of PM7 created indoors was achieved by optimizing the existing air moving equipment. The results from the second intervention (Stage 2--with EAC units installed) comparing indoor to outdoor values, gave a further reduction in PM3 of 21% (P < 0.001) and a further 3% reduction for PM7 (P > 0.05). Therefore, at the end of Stage 2, the total reductions in particles from outdoors to indoors were 40% for PM3 and 70% for PM7 (P < 0.001). The Stage 2 results strongly suggest that electrostatic forces, created by the EAC unit(s) improved the removal of PM3, with no further significant improvement in the reduction of PM7. The questionnaire indicated an improvement in the IAQ, as perceived by the employees. The results suggest that the EAC system is effective in reducing PM3 and thereby improving IAQ in an urban office.     

Hospital indoor respirable particles and carbonaceous composition

Indoor air PM2.5 and PM10 samples were collected at the different types of indoor enviornment in the four hospitals and their adjacent outdoor environments in Guangzhou, China, during the summertime. The objectives of this study were (1) to characterize the indoor PM concentrations and associated carbonaceous species in hospitals, (2) to investigate the potential indoor sources and (3) to reconstruct carbonaceous composition in PM. Additionally, regression analysis was made to evaluate effect of outdoor sources to indoor PM levels and comparison was made between I/O levels in different types of indoor environment to evaluate effects of human activities and ventilation types to indoor PM levels.     

Reduction potential of urban PM2.5 mortality risk using modern ventilation systems in buildings

Urban PM2.5 (particulate matter with aerodynamic diameter smaller than 2.5 microm) is associated with excess mortality and other health effects. Stationary sources are regulated and considerable effort is being put into developing low-pollution vehicles and environment-friendly transportation systems. While waiting for technological breakthroughs in emission controls, the current work assesses the exposure reductions achievable by a complementary means: efficient filtration of supply air in buildings. For this purpose infiltration factors for buildings of different ages are quantified using Exposures of Adult Urban Populations in Europe Study (EXPOLIS) measurements of indoor and outdoor concentrations in a population-based probability sample of residential and occupational buildings in Helsinki, Finland. These are entered as inputs into an evaluated simulation model to compare exposures in the current scenario with an alternative scenario, where the distribution of ambient PM2.5 infiltration factors in all residential and occupational buildings are assumed to be similar to the subset of existing occupational buildings using supply air filters. In the alternative scenario exposures to ambient PM2.5 were reduced by 27%. Compared with source controls, a significant additional benefit is that infiltration affects particles from all outdoor sources. The large fraction of time spent indoors makes the reduction larger than what probably can be achieved by local transport policies or other emission controls in the near future. PRACTICAL IMPLICATIONS: It has been suggested that indoor concentrations of ambient particles and the associated health risks can be reduced by using mechanical ventilation systems with supply air filtering in buildings. The current work quantifies the effects of these concentration reductions on population exposures using population-based data from Helsinki and an exposure model. The estimated exposure reductions suggest that correctly defined building codes may reduce annual premature mortality by hundreds in Finland and by tens of thousands in the developed world altogether.     

Organic compound characterization and source apportionment of indoor and outdoor quasi-ultrafine particulate matter in retirement homes of the Los Angeles Basin

Abstract Quasi‐ultrafine (quasi‐UF) particulate matter (PM_0.25) and its components were measured in indoor and outdoor environments at four retirement communities in Los Angeles Basin, California, as part of the Cardiovascular Health and Air Pollution Study (CHAPS). The present paper focuses on the characterization of the sources, organic constituents and indoor and outdoor relationships of quasi‐UF PM. The average indoor/outdoor ratios of most of the measured polycyclic aromatic hydrocarbons (PAHs), hopanes, and steranes were close to or slightly lower than 1, and the corresponding indoor–outdoor correlation coefficients (R) were always positive and, for the most part, moderately strong (median R was 0.60 for PAHs and 0.74 for hopanes and steranes). This may reflect the possible impact of outdoor sources on indoor PAHs, hopanes, and steranes. Conversely, indoor n‐alkanes and n‐alkanoic acids were likely to be influenced by indoor sources. A chemical mass balance model was applied to both indoor and outdoor speciated chemical measurements of quasi‐UF PM. Among all apportioned sources of both indoor and outdoor particles, vehicular emissions was the one contributing the most to the PM_0.25 mass concentration measured at all sites (24–47% on average).

Practical Implications

Although people (particularly the elderly retirees of our study) generally spend most of their time indoors, a major portion of the PM_0.25 particles they are exposed to comes from outdoor mobile sources. This is important because, an earlier investigation, also conducted within the Cardiovascular Health and Air Pollution Study (CHAPS), showed that indoor‐infiltrated particles from mobile sources are more strongly correlated with adverse health effects observed in the elderly subjects living in the studied retirement communities compared with other particles found indoors ( Delfino et al., 2008 ).     

The analysis of PM2.5 and associated elements and their indoor/outdoor pollution status in an urban area

In this study, elemental composition of PM2.5 and the status of indoor/outdoor pollution were investigated in a commercial building near a roadside area in Daejeon, Korea. A total of 60 parallel PM2.5 samples were collected both on the roof (outdoor) and in an indoor office of a building near a highly congested road during the spring and fall of 2008. The concentrations of 23 elements were analysed from these PM2.5 samples using instrumental neutron activation analysis. PM2.5 levels in indoor environment (47.6 ± 16.5 μg/m(3)) were noticeably higher than the outdoor levels (37.7 ± 17.2 μg/m(3)) with the I/O concentration ratio of 1.37 ± 0.33 [correlation coefficient (r) = 0.89, P < 0.001]. Principal component analysis results coincidently showed the predominance of sources such as soil dust, traffic, oil/coal combustion and road dust for both indoor and outdoor microenvironments. An isolated source in the indoor environment was assigned to environmental tobacco smoke (ETS) with high factor loading of Ce, Cl, I, K, La and Zn. The overall results of our study indicate that the sources of indoor constituents were strongly dependent on outdoor processes except for the ones affected by independent sources such as ETS. PRACTICAL IMPLICATIONS: An improved understanding of the factors affecting the indoor PM2.5 concentration levels can lead to the development of an efficient management strategy to control health risks from exposure to indoor PM2.5 and related toxic components. A comparison of our comprehensive data sets indicated that most indoor PM2.5 and associated elemental species were strongly enriched by indoor source activities along with infiltration of ambient outdoor air for a naturally ventilated building.     

Measurements of children's exposures to particles and nitrogen dioxide in Santiago, Chile

An exposure study of children (aged 10-12 years) living in Santiago, Chile, was conducted. Personal, indoor and outdoor fine and inhalable particulate matter (< 2.5 .m in diameter, PM2.5 and < 10 microm in diameter, PM10, respectively), and nitrogen dioxide (NO2) were measured during pilot (N = 8) and main (N = 20) studies, which were conducted during the winters of 1998 and 1999, respectively. For the main study, personal, indoor and outdoor 24-h samples were collected for five consecutive days. Similar mean personal, indoor and outdoor PM2.5 concentrations (69.5, 68.5 and 68.1 microg/m3, respectively) were found. However, for coarse particles (calculated as the difference between measured PM10 and PM2.5, PM2.5-10), indoor and outdoor levels (35.4 and 47.4 microg/m3) were lower than their corresponding personal exposures (76.3 microg/m3). Indoor and outdoor NO2 concentrations were comparable (35.8 and 36.9 ppb) and higher than personal exposures (25.9 ppb). Very low ambient indoor and personal O3 levels were found, which were mostly below the method's limit of detection (LOD). Outdoor particles contributed significantly to indoor concentrations, with effective penetration efficiencies of 0.61 and 0.30 for PM2.5 and PM2.5-10, respectively. Personal exposures were strongly associated with indoor and outdoor concentrations for PM2.5, but weakly associated for PM2.5-10. For NO2, weak associations were obtained for indoor-outdoor and personal-outdoor relationships. This is probably a result of the presence of gas cooking stoves in all the homes. Median I/O, P/I and P/O ratios for PM2.5 were close to unity, and for NO2 they ranged between 0.64 and 0.95. These ratios were probably due to high ambient PM2.5 and NO2 levels in Santiago, which diminished the relative contribution of indoor sources and subjects' activities to indoor and personal PM2.5 and NO2 levels.     

Characterization of indoor air quality in primary schools in Antwerp, Belgium

The indoor air quality of 27 primary schools located in the city centre and suburbs of Antwerp, Belgium, was assessed. The primary aim was to obtain correlations between the various pollutant levels. Indoor:outdoor ratios and the building and classroom characteristics of each school were investigated. This paper presents results on indoor and local outdoor PM2.5 mass concentrations, its elemental composition in terms of K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Br, Pb, Al, Si, S, and Cl, and its black smoke content. In addition, indoor and local outdoor levels of the gases NO2, SO2, O3, and BTEX (benzene, toluene, ethyl benzene, and xylene isomers) were determined. Black smoke, NO2, SO2 and O3, occurred at indoor:outdoor ratios below unity, indicating their significant outdoor sources. No linear correlation was established between indoor and outdoor levels for PM2.5 mass concentrations and BTEX; their indoor:outdoor ratios exceeded unity except for benzene. Classroom PM2.5 occurred with a different elemental composition than local outdoor PM2.5. The re-suspension of dust because of room occupation is probably the main contributor for the I/O ratios higher than 1 reported for elements typically constituting dust particles. Finally, increased benzene concentrations were reported for classrooms located at the lower levels. PRACTICAL IMPLICATIONS: The elevated indoor PM2.5, and BTEX concentrations in primary school classrooms, exceeding the ambient concentrations, raise concerns about possible adverse health effects on susceptible children. This is aggravated by the presence of carpets and in the case of classrooms at lower levels. Analysis of PM2.5's elemental composition indicated a considerable contribution of soil dust to indoor PM2.5 mass. In order to set adequate threshold values and guidelines, detailed information on the health impact of specific PM2.5 composites is needed. The results suggest that local outdoor air concentrations measurements do not provide an accurate estimation of children's personal exposures to the identified air pollutants inside classrooms.     

Source apportionment of indoor residential fine particulate matter using land use regression and constrained factor analysis

Source contributions to urban fine particulate matter (PM(2.5) ) have been modelled using land use regression (LUR) and factor analysis (FA). However, people spend more time indoors, where these methods are less explored. We collected 3-4- day samples of nitrogen dioxide and PM(2.5) inside and outside of 43 homes in summer and winter, 2003-2005, in and around Boston, Massachusetts. Particle filters were analysed for black carbon and trace element concentrations using reflectometry, X-ray fluorescence (XRF), and high-resolution inductively coupled mass spectrometry (ICP-MS). We regressed indoor against outdoor concentrations modified by ventilation, isolating the indoor-attributable fraction, and then applied constrained FA to identify source factors in indoor concentrations and residuals. Finally, we developed LUR predictive models using GIS-based outdoor source indicators and questionnaire data on indoor sources. FA using concentrations and residuals reasonably separated outdoor (long-range transport/meteorology, fuel oil/diesel, road dust) from indoor sources (combustion, smoking, cleaning). Multivariate LUR regression models for factors from concentrations and indoor residuals showed limited predictive power, but corroborated some indoor and outdoor factor interpretations. Our approach to validating source interpretations using LUR methods provides direction for studies characterizing indoor and outdoor source contributions to indoor cocentrations. PRACTICAL IMPLICATIONS: By merging indoor-outdoor modeling, factor analysis, and LUR-style predictive regression modeling, we have added to previous source apportionment studies by attempting to corroborate factor interpretations. Our methods and results support the possibility that indoor exposures may be modeled for epidemiologic studies, provided adequate sample size and variability to identify indoor and outdoor source contributions. Using these techniques, epidemiologic studies can more clearly examine exposures to indoor sources and indoor penetration of source-specific components, reduce exposure misclassification, and improve the characterization of the relationship between particle constituents and health effects.     

室内颗粒污染的源辨识与源解析

辨识室内颗粒物来源与分析室内颗粒物元素特征称为源辨识与源解析,是进行室内空气污染控制与净化的理论依据与前提条件。本文通过对室内空气品质（IAQ）模型进行理论分析,阐明了室内外污染源与室内颗粒物浓度之间的关系。指出室内颗粒污染物研究应根据污染源已知与未知两种情况进行讨论,并针对不同的情况分别采用源辨识与源解析技术。     

Particle size distribution and composition in a mechanically ventilated school building during air pollution episodes

Particle count-based size distribution and PM(2.5) mass were monitored inside and outside an elementary school in Salt Lake City (UT, USA) during the winter atmospheric inversion season. The site is influenced by urban traffic and the airshed is subject to periods of high PM(2.5) concentration that is mainly submicron ammonium and nitrate. The school building has mechanical ventilation with filtration and variable-volume makeup air. Comparison of the indoor and outdoor particle size distribution on the five cleanest and five most polluted school days during the study showed that the ambient submicron particulate matter (PM) penetrated the building, but indoor concentrations were about one-eighth of outdoor levels. The indoor:outdoor PM(2.5) mass ratio averaged 0.12 and particle number ratio for sizes smaller than 1 microm averaged 0.13. The indoor submicron particle count and indoor PM(2.5) mass increased slightly during pollution episodes but remained well below outdoor levels. When the building was occupied the indoor coarse particle count was much higher than ambient levels. These results contribute to understanding the relationship between ambient monitoring station data and the actual human exposure inside institutional buildings. The study confirms that staying inside a mechanically ventilated building reduces exposure to outdoor submicron particles. PRACTICAL IMPLICATIONS: This study supports the premise that remaining inside buildings during particulate matter (PM) pollution episodes reduces exposure to submicron PM. New data on a mechanically ventilated institutional building supplements similar studies made in residences.     

上海地区冬季住宅室内外颗粒物浓度的相关性

对上海市某住宅建筑室内外PM10、PM2.5、PM1的浓度进行了测量,研究了最小通风量(外门窗关闭)条件下3种天气时颗粒浓度随时间变化的规律以及相关性,分析了颗粒物浓度与环境温湿度参数之间的关系。研究结果显示,测试期间,室内外空气中细颗粒(PM 2.5)占可吸入颗粒(PM 10)浓度比例分别达65%和87%以上;无明显室内源时,I/O比值小于1且随粒径减小而减小;室内外颗粒浓度相关性与粒径大小有关系,PM1、PM2.5的浓度相关性大于PM10。研究还表明,颗粒物浓度的关联性与天气状况有关系,多云、雨天和阴天时浓度关联性有显著差别;颗粒物的浓度受到室内外温湿度的影响,且受天气状况影响而呈现复杂性。