Solution‐Processed All‐Ceramic Plasmonic Metamaterials for Efficient Solar–Thermal Conversion over 100–727 °C

Low‐cost and large‐area solar–thermal absorbers with superior spectral selectivity and excellent thermal stability are vital for efficient and large‐scale solar–thermal conversion applications, such as space heating, desalination, ice mitigation, photothermal catalysis, and concentrating solar power. Few state‐of‐the‐art selective absorbers are qualified for both low‐ ( < 200  ° C) and high‐temperature ( > 600  ° C) applications due to insufficient spectral selectivity or thermal stability over a wide temperature range. Here, a high‐performance plasmonic metamaterial selective absorber is developed by facile solution‐based processes via assembling an ultrathin ( ≈ 120 nm) titanium nitride (TiN) nanoparticle film on a TiN mirror. Enabled by the synergetic in‐plane plasmon and out‐of‐plane Fabry–Pérot resonances, the all‐ceramic plasmonic metamaterial simultaneously achieves high, full‐spectrum solar absorption (95%), low mid‐IR emission (3% at 100  ° C), and excellent stability over a temperature range of 100–727  ° C, even outperforming most vacuum‐deposited absorbers at their specific operating temperatures. The competitive performance of the solution‐processed absorber is accompanied by a significant cost reduction compared with vacuum‐deposited absorbers. All these merits render it a cost‐effective, universal solution to offering high efficiency (89–93%) for both low‐ and high‐temperature solar–thermal applications.     

Solar cooling with water–ammonia absorption chillers and concentrating solar collector – Operational experience

Concentrating solar collectors provide high efficiency at high driving temperatures favourable for thermally driven chillers. Therefore, they offer applications for hot climates and industrial process integration, especially in combination with NH₃–H₂O chillers that provide refrigeration temperatures below 0 °C. The presented solar cooling installation comprises a linear concentrating Fresnel collector that provides the driving heat for two NH₃–H₂O absorption chillers at temperatures up to 200 °C. Chilled water temperatures are produced in the range between −12 °C and 0 °C. Collector capacities reached up to 70 kW at peak times and the total cooling capacity of both chillers showed peak values up to 25 kW. For good operating conditions, the thermal system EER was 0.8 and an electrical system EER of 12 was easily achieved. The system showed a sound operating behaviour. The performance of different operation and control strategies was analysed, evaluated and enhanced within the two year operation phase.     

Predicting the Effect of Temperature on the Shock Absorption Properties of Polyethylene Foam

Polyethylene (PE) foam is a material used commonly in protective packaging for its shock absorption properties. When developing a package design intended to mitigate shock to the product, decisions are typically made based on established cushion evaluation procedures performed at standard laboratory conditions. Distribution environment temperatures, however, can vary greatly from the condition at which these materials are assessed. The research presented in this paper utilizes the stress–energy method of cushion evaluation and highlights trends in the stress–energy equations of PE foam tested at 12 different temperatures, ranging from ?20°C to 50°C. A quadratic polynomial is used to describe the variation in the stress–energy equation coefficients over the temperature range evaluated. The model developed enables cushion curve prediction for any static stress, drop height, material thickness and temperature expected over the intended range of use of the material. This model is validated by performing additional impact testing of samples at various temperatures and comparing experimentally obtained acceleration values to those predicted by the model. Further model analysis is performed to estimate the optimal static stress for the material at any temperature within the range tested and to study the variation with temperature of this optimal point. Results reveal that the model developed is capable of predicting the shock absorption properties of the material within the range of parameters tested and that the optimal static stress of the material decreases as temperature increases from ?20°C to 50°C. Application to cushion design is made to recommend an approach to designing a PE cushion system for use over a range of temperatures. Copyright © 2016 John Wiley & Sons, Ltd.     

Experimental evaluation of thermophysical properties of oil-based titania nanofluids for medium temperature solar collectors

Thermal oils are widely used as working fluids in the medium temperature heat transfer applications including concentrating solar thermal collectors. However, the weak thermal characteristics of these oils are major drawbacks in their successful application in the medium-high temperature solar collectors. Fortunately, the emergence of nanotechnology has provided the opportunity to alter thermo-physical properties of base fluids by adding small amount of sub-micron size solid particles possessing better properties. This paper presents an experimental investigation of thermophysical properties of an oil-based nanofluid to be used in the medium temperature solar collector for enhanced thermal energy transport. The colloidal suspensions were prepared by dispersing different weight fractions (0.25 wt.%, 0.5 wt.%, 0.75 wt.% and 1.0 wt.%) of Titania nanoparticles in Therminol-55 oil using two-step method. Shear mixing and high energy ultrasonication was employed to achieve uniform mixing and de-agglomeration of the nanoparticles in order to enhance the stability of the colloidal suspensions. Thermophysical properties of the nanofluids were determined as a function of nanoparticles concentrations in the temperature range of 25 °C–130 °C. The experimental results demonstrated substantial improvement in thermal conductivity of the nano-oils with an increase in nanoparticles loading which further enhanced at higher temperatures. Dynamic viscosity and effective density displayed a decreasing trend against rising temperature which indicate the effectiveness of these nanofluids for medium temperature heat supply. Nano-oils with superior thermal properties can improve the performance of medium temperature solar thermal collectors.     

Thermal treatment of the precipitated solid material (PSM) from the waste black liquor (WBL)

Preciptated solid materials (PSM) from waste black liquor (WBL), at pH 8·5–9·0, produced from cooking of rice straw in paper mill factories were thermally treated. The cooking process led to decrease in organic material and partial substitution in silica structure. During this cooking process, three probable stages of mass loss comprise removal of moisture, volatile release, and combustion. The chemical analysis depicts the cooking effect on leaching either the high percentage elements (Ca, Na, and K) or some metallic cations (Mn, Cd, Zn and Cu) in the parent rice straw. Silica hydrate, amorphous silica and crystalline silica were obtained at <600°C, 600–700°C and at>800°C, respectively. The infrared spectra show gradual removal of the hydrocarbon bond (C–H), molecular H₂O, and sianol group (Si-OH) with temperature. TG, DTA, XRD and SEM were used in this study.     

Static coarsening behaviour of lamellar microstructure in selective laser melted Ti–6Al–4V

Static coarsening mechanism of selective laser melted (SLMed) Ti–6Al–4V with a lamellar microstructure was established at temperatures from 700 °C to 950 °C. Microstructure evolution revealed that high heat treatment temperature facilitated martensite decomposition and promoted lamellae growth. At each temperature, the growth rate decreased with increasing holding time. The static coarsening behaviour of SLMed Ti–6Al–4V can be interpreted by Lifshitz, Slyozov, and Wagner (LSW) theory. The coarsening coefficient were 0.33, 0.33–0.4, 0.4–0.5 for 700–800 °C, 900 °C and 950 °C, respectively. This indicated the coarsening mechanism was bulk diffusion at 700–800 °C, and a combination of bulk diffusion and interface reaction at 900 °C and 950 °C conditions.     

Realization of Fe–C Eutectic Point Using an Alumina Crucible

As another crucible material for metal–carbon eutectic points, alumina ceramic was used in the first trial to make an Fe–C eutectic point for the calibration of a thermocouple. Its melting and freezing behavior was tested 26 times with a type S thermocouple at various melting offset temperatures, namely, +4 °C, +9 °C, and +19 °C, and at a fixed freezing offset temperature of ?11 °C. The melting emf is reproducible independent of the melting offset temperatures, and the standard deviation of the 26 melting temperatures is 0.02 °C without breakage of the cell. The difference of melting emf between alumina Fe–C and graphite Fe–C fixed points is only 25 mK within an uncertainty of 0.39 °C (k = 2). The melting behaviors of an alumina cell are quite similar to a common graphite cell. Thus, alumina can be used as a crucible material in an Fe–C eutectic system without breakage, and it can be used at a higher temperature range. As possible application systems using alumina crucibles, Pd–C and Si–SiC eutectic points are suggested.     

Kinetics of precipitation in 17–4 PH stainless steel

Abstract

The sequence of precipitation and its kinetics in 17–4 PH (precipitation hardening) stainless steel were studied by observing the electrical resistivity and microstructure of the alloy during isothermal aging at various temperatures in the range 320–600°C. By the absence of an incubation period for the onset of precipitation it is shown that there is no free energy barrier to nucleation. The electrical resistivity of the specimen decreased on prolonged aging approaching a steady value asymptotically with time. The alloys aged above 550°C were found to have higher final resistivity values than those aged at lower temperatures. By transmission electron microscopy, local reversion of the martensite to austenite, attributed to enhanced diffusion and concentration of copper atoms at the lath boundaries, was revealed in the specimens aged at temperatures above 550°C. The kinetics of precipitation in the system obeyed the Johnson–Mehl equation. The activation energy Q of the precipitation process was estimated to be 112·2 ± 3·6 kJ mol^?l from the resistivity measurements. This may be understood in terms of an enhanced diffusion of copper atoms in the supersaturated matrix caused by a higher dislocation density and a higher concentration of quenched-in vacancies.

MST/826     

有机朗肯循环模拟及涡旋式膨胀机的性能研究

近些年来,太阳能作为一种可再生能源受到了广泛的关注。其中利用太阳能集热器实现100℃以下高效的热量回收,是一种普遍且有效的太阳能利用方式。采用有机朗肯循环与100℃的低温热源相结合进行发电,目前也逐渐受到了研究人员的关注。考虑到膨胀机是有机朗肯循环的核心部件,本文选择了R600制冷剂作为ORC系统的工质,对其进行了计算以及热力学性能分析。同时搭建了利用压缩空气来驱动的涡旋式膨胀机性能研究的实验台。从ORC的理论分析得,当热源温度为78~97℃,环境温度为30℃,可以获得0.7~1kW的电量,效率为0.84~0.89。利用压缩空气模拟R600,当温度从75℃变化到95℃,对应的压力从0.8MPa变化到1.2MPa,膨胀机出口压力控制在0.28MPa,等熵效率维持在0.7左右。膨胀机的功电转化效率随着膨胀机理想输出功的增加而降低。     

Air-stable,earth-abundant molten chlorides and corrosion-resistant containment for chemically-robust,high-temperature thermal energy storage for concentrated solar power

A dramatic reduction in man-made CO₂ emissions could be achieved if the cost of electricity generated from concentrated solar power (CSP) plants could become competitive with fossil-fuel-derived electricity. The solar heat-to-electricity conversion efficiency of CSP plants may be significantly increased (and the associated electricity cost decreased) by operating CSP turbines with inlet temperatures ≥750 °C instead of ≤550 °C, and by using thermal energy storage (TES) at ≥750 °C to allow for rapidly dispatchable and/or continuous electricity production. Unfortunately, earth-abundant MgCl₂–KCl-based liquids currently being considered as low-cost media for large-scale, high-temperature TES are susceptible to oxidation in ambient air, with associated undesired changes in liquid composition and enhanced corrosion of metal alloys in pipes and tanks containing such liquids. In this paper, alternative high-temperature, earth-abundant molten chlorides that are resistant to oxidation in ambient air are identified via thermodynamic calculations. The oxidation resistance, and corrosion-resistant containment, of such molten chlorides at 750 °C are then demonstrated. Such an air-tolerant strategy, involving chemically-robust, low-cost TES media paired with effective containment materials, provides a critical advance towards the higher-temperature operation of, and lower-cost electricity generation from, CSP plants.     

Low temperature deposition of hexagonal BN films by chemical vapour deposition

Transparent hexagonal BN films were deposited onto copper substrates from the reactant gas BCl₃-NH₃-H₂ at temperatures in the range 250–700°C. The lowest deposition temperature of the films was about 250°C. The films deposited at temperatures below 450°C were unstable in moist atmosphere and devitrified; a 20%–30% decrease in weight was observed when these films were heated above 600°C in an argon atmosphere. In contrast, the films deposited at temperatures above 600°C were very stable, decreased in weight by 1%–2% on heating and were stable in air at temperatures below 750°C.     

Facile synthesis of rice shaped CuO nanostructures for battery application

The oxides of transition metals are an important class of semiconductors, which have applications in electronics, magnetic storage media, solar applications and catalysis. Among them, CuO has attracted much attention due to its widespread applications. In this paper, a facile synthesis of rice shaped CuO nanostructures have been prepared by reflux method for battery application using Copper nitrate and ammonia as precursors. Samples were prepared at three different reaction timings namely 6, 12 and 24 h. The as-prepared samples were calcinated at 400 °C to ensure the formation of copper oxide. The final products were subjected to X-ray diffraction, scanning electron microscopy, FT-IR and UV–Vis spectroscopy in order to study the effect of reaction time on the properties of the prepared copper oxide nanostructures. It is found that at controlled reaction time rice shaped CuO nanostructures are obtained. Cyclic voltammogram was recorded to understand the electrocatalytic behaviors of the rice shaped CuO sample prepared under optimized condition.     

Microstructure,grain growth,and hardness during annealing of nanocrystalline Cu powders synthesized via high energy mechanical milling

In this paper, the microstructure and hardness evolutions of commercially pure Cu subjected to high energy mechanical milling and subsequent annealing treatments in the temperature range of 400–700 °C are investigated. The results demonstrated the simultaneous occurrence of recovery, recrystallization, and grain growth during annealing of the nanocrystalline Cu. The volume fraction of the recrystallized grains estimated using the grain orientation spread exhibits lower values as a result of its dynamic recovery at higher temperatures. The normal grain growth in the range of 400–600 °C and significant abnormal grain growth at higher temperatures are observed during annealing. As a result of the abnormal grain growth, the microhardness value rapidly decreases for the sample annealed at 700 °C. An analysis of the grain growth kinetics using the parabolic equation in the temperature range of 400–600 °C reveals a time exponent of n ≈ 2.7 and an activation energy of 72.93 kJ/mol. The calculated activation energy for the grain growth in the nanocrystalline Cu is slightly less than the activation energy required for the lattice diffusion. This low activation energy results from the high microstrain as well as the Zener-pinning mechanism that arises from the finely dispersed impurities drag effect.     

Flexural properties of z-pinned composite laminates in seawater environment

Unidirectional carbon-fibre reinforced composite laminates with and without z-pins were immersed in artificial seawater and exposed to two different temperature levels (?1.75 and 50 °C), as well as thaw–freeze cycles (+20/?20 °C). The investigation described is focused on the question to which degree seawater absorption, as well as bending properties are influenced by z-pin reinforcement. The results indicate an increasing influence of the z-pin reinforcement on the water sorption rate, while the sorption rate of unpinned laminates is lower. This is a result of the additional diffusion pathways of the moisture ingress into the laminate caused by the inserted z-pins which in turn change the micro-structure. Furthermore, the sorption rate depends on the immersion temperature. Laminates immersed into seawater with higher temperatures (50 °C) display a significantly higher diffusion rate than those immersed in colder seawater (?1.75 °C) or those immersed under thaw–freeze conditions (+20/?20 °C). Z-pin reinforced laminates with a unidirectional fibre orientation show a reduced bending strength by about 31 %, as well as a reduced flexural modulus by about 11 % in comparison to unpinned samples. Unpinned and z-pinned samples that were exposed to a seawater environment for 1344 h show a reduced flexural modulus depending on the immersion temperatures. As opposed to flexural modulus, flexural strength is not affected by immersion time or temperature. The overall bending strain energy that is necessary for a complete fracture of the unpinned samples under 4-point bending loads can be described with the value of the elastic bending strain energy. In contrast to this the overall bending strain energy of the z-pinned laminates is composed of two different components –the elastic bending strain energy and the post-fracture strain energy. The post-fracture strain energy occurs after exceeding the flexural strength. The overall bending strain energy of z-pinned and unpinned samples without immersion into seawater is around 7.2 J, while the percentage of the post-fracture energy of the pinned samples is 40 % with respect to the overall bending strain energy. The duration of the immersion into water and higher water temperatures increases the overall bending strain energy for both unpinned and pinned samples. The increase is higher for z-pinned samples and is mainly caused by the increase of the post-fracture energy.     

Spray-pyrolysed cobalt black as a high temperature selective absorber

Cobalt oxide coatings with an integrated solar absorptance of 0.93 and a hemispherical emittance at 100°C of 0.14 were prepared by spray pyrolysis on stainless steel substrates kept at 300°C. The coatings are strongly adherent and stable up to temperatures of about 600°C. Auger electron spectroscopy, X-ray photoelectron spectroscopy and X-ray and electron diffraction investigations revealed the coatings to be composed of an upper layer of Co₃O₄ and subsequent layers of CoO down to the substrate. The absorption mechanism is primarily intrinsic. Lower substrate temperatures (about 150°C) can be used for preparing coatings from equimolar aqueous solutions of cobaltous acetate and thiourea. Such coatings, containing both cobalt oxide and cobalt sulphide, have a comparable absorptance but a higher emittance and are stable only up to about 300°C.     

Formation and properties of cadmium sulfide buffer layer for CIGS solar cells grown using hot plate bath deposition

In the present study, cadmium sulfide (CdS) thin films were deposited on different substrates [soda glass, fluoride doped tin oxide, and tin doped indium oxide (ITO) coated glass] by a hot plate method. To control the thickness and the reproducibility of the sample production, the thin films were coated at different temperatures and deposition times. The CdS thin films were heated at 400 °C in air and forming gas (FG) atmosphere to investigate the effect of the annealing temperatures. The thickness of the samples, measured by ellipsometry, could be controlled by the deposition time and temperature of the hot plate. The phase formation and structural properties of CdS thin films were studied by X-ray diffraction and scanning electron microscopy, whereas the optical properties were obtained by UV–vis spectroscopy. A hexagonal crystal structure was observed for CdS thin films and the crystallinity improved upon annealing. The structural and optical properties of CdS thin films were also enhanced by annealing at 400 °C in FG atmosphere (95 % N₂, 5 % H₂). The optical band gap was changed from 2.25 to 2.40 eV at different annealing temperatures and gas atmospheres. A higher electrical conductivity, for the sample annealed at FG, was noticed. The samples deposited on ITO and annealed in FG atmosphere showed the best structural and electrical properties compared to the other samples. CdS thin films can be widely used for application as a buffer layer for copper–indium–gallium–selenide solar cells.     

Rutile TiO<Subscript>2</Subscript> films as electron transport layer in inverted organic solar cell

Titanium dioxide (TiO₂) thin films were prepared by sol–gel spin coating method and deposited on ITO-coated glass substrates. The effects of different heat treatment annealing temperatures on the phase composition of TiO₂ films and its effect on the optical band gap, morphological, structural as well as using these layers in P3HT:PCBM-based organic solar cell were examined. The results show the presence of rutile phases in the TiO₂ films which were heat-treated for 2 h at different temperatures (200, 300, 400, 500 and 600 °C). The optical properties of the TiO₂ films have altered by temperature with a slight decrease in the transmittance intensity in the visible region with increasing the temperature. The optical band gap values were found to be in the range of 3.28–3.59 eV for the forbidden direct electronic transition and 3.40–3.79 eV for the allowed direct transition. TiO₂ layers were used as electron transport layer in inverted organic solar cells and resulted in a power conversion efficiency of 1.59% with short circuit current density of 6.64 mA cm^?2 for TiO₂ layer heat-treated at 600 °C.     

The aggregative effect of acid dyestuff (orange II) on the activation energy of wool dyeing

Abstract

In dye liquor, the hydrophobic group of acid dyestuff molecules often interacts with one another to form aggregates. For the purpose of investigating the aggregative effect of acid dyestuff on the activation energy of wool dyeing, this study derives a rate equation based on the theory of Langmuir chemisorption and deals with the activation energy of wool dyeing under different dyeing temperatures and dyestuff concentrations.

The Arrhenius plot from the rate of different dyeing temperatures clearly indicates two straight lines which intersect at 60°C. It is clear that the activation energy found at temperatures below 60°C is higher than that at temperatures above 60°C. It is suggested that when temperatures are below 60°C, the acid dyestuff molecules are in an aggregated state, so that the activation energy below 60°C is higher than that above 60°C. It is also suggested that the higher the concentration, the higher will be the activation energy.     

The thermal stability of nonalloyed ohmic contacts to AlGaN/GaN heterostructures

Degradation of nonalloyed ohmic contacts with heavily doped GaN epitaxially grown to the heterostructures with two-dimensional electron gas has been investigated. The change in the relative contact resistivity at temperatures of up to 600°C for the Ti/Pd/Au, Cr/Au, and Cr/Pd/Au metallization compositions has been studied. It is demonstrated that the Cr/Pd/Au metallization composition, the resistivity of which decreases at working temperatures of 400°C, is the most resistant to the effect of temperature. It is shown for the first time that the largest contribution to the increase in the contact resistivity to two-dimensional electron gas upon heating above 400°C is made by the resistivity of the Cr/Pd/Au–n⁺-GaN metal–dielectric structure, while, at temperatures of 400°C and higher, the resistance between heavily doped GaN and two-dimensional electron gas decreases.

     

A Lithium–Air Battery Stably Working at High Temperature with High Rate Performance

Driven by the increasing requirements for energy supply in both modern life and the automobile industry, the lithium–air battery serves as a promising candidate due to its high energy density. However, organic solvents in electrolytes are likely to rapidly vaporize and form flammable gases under increasing temperatures. In this case, serious safety problems may occur and cause great harm to people. Therefore, a kind of lithium–air that can work stably under high temperature is desirable. Herein, through the use of an ionic liquid and aligned carbon nanotubes, and a fiber shaped design, a new type of lithium–air battery that can effectively work at high temperatures up to 140 °C is developed. Ionic liquids can offer wide electrochemical windows and low vapor pressures, as well as provide high thermal stability for lithium–air batteries. The aligned carbon nanotubes have good electric and heat conductivity. Meanwhile, the fiber format can offer both flexibility and weavability, and realize rapid heat conduction and uniform heat distribution of the battery. In addition, the high temperature has also largely improved the specific powers by increasing the ionic conductivity and catalytic activity of the cathode. Consequently, the lithium–air battery can work stably at 140 °C with a high specific current of 10 A g^‐1 for 380 cycles, indicating high stability and good rate performance at high temperatures. This work may provide an effective paradigm for the development of high‐performance energy storage devices.