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复合型氢氧化镁阻燃剂的改性研究 总被引:1,自引:0,他引:1
采用石灰乳法制备氢氧化镁阻燃剂,对混合碱用量、溶剂总量、水/醇比和反应时间进行考察,并采用三种典型的改性剂———磷酸三苯酯、双咪唑啉、双子磺酸钠对氢氧化镁阻燃剂进行改性。结果表明,Mg(OH)2的最佳制备条件为:氯化镁与混合碱的摩尔比为1∶2.2,溶剂的总量为2 100 mL,水/醇的体积比为4∶1,反应时间为30 min。采用晶须改性剂磷酸三苯酯时,温度在80℃,改性时间4 h,添加量2%(质量百分比)时,活化指数较好;采用双咪唑啉、双子磺酸钠时,温度在40℃,改性时间2 h,添加量4%(质量百分比)时,活化指数较好。 相似文献
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氢氧化镁阻燃剂的现状及展望 总被引:8,自引:0,他引:8
分析了氢氧化镁作为阻燃剂的性能及优点,并根据其作为阻燃剂产品的要求,对其制备方法进行了概述。总结了目前国内外镁资源的利用、研究、生产和使用状况,结合国内的实际情况,对阻燃剂氢氧化镁发展提出了建议,同时指出应加强对阻燃型氢氧化镁产品行业标准的制定工作,以促进该行业的进一步发展。 相似文献
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A novel phosphorus‐silicon‐containing flame retardant, spirocyclic pentaerythritol bisphosphorate disphosphoryl chloride/9, 10‐dihydro‐9‐oxa‐10‐phosphaphanthrene‐10‐oxide/vinyl methyl dimethoxysilane (SPDV), was synthesized successfully and used for optimizing the flame retardancy of ethylene‐vinyl acetate copolymer (EVM) rubber/magnesium hydroxide (MDH) composites. The microstructure of SPDV was characterized and determined by Fourier transform infrared (FTIR) and nuclear magnetic resonance (NMR) spectroscopy. Thermogravimetric analysis (TGA) showed that SPDV had good charring effect in air even at high temperature (800°C). The flame retardancy of the optimized EVM/MDH composites by SPDV was investigated by limiting oxygen index (LOI), cone calorimeter, and UL‐94 vertical burning tests. A higher LOI value (29.4%) and better UL‐94 rating (V‐0) can be achieved for the optimized EVM/MDH composite (EVM‐7) than EVM/MDH composite without SPDV (EVM‐3) with the total loading of additives. The HRR decreased and residual mass increased gradually as the loading of SPDV increased for the optimized EVM/MDH composites. There existed distinct synergistic intumescent flame‐retardant effect between SPDV and MDH in EVM matrix. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
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氢氧化镁阻燃剂的表面改性及其在聚丙烯中的应用 总被引:4,自引:0,他引:4
采用不同改性剂对氢氧化镁进行表面改性处理,通过实验发现采用4%的硬脂酸钠处理后的氢氧化镁阻燃剂在聚丙烯体系中分散均匀,当氢氧化镁在聚丙烯体系中的添加量达65%时,达到了理想的阻燃效果。 相似文献
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Halogen‐free flame‐retarded polyethylene materials have been prepared by using magnesium hydroxide (MH) as a flame retardant combined with red phosphorous (RP) and expandable graphite (EG) as synergists. The effects of these additives on the combustion behavior of the filled linear low density polyethylene (LLDPE), such as a limiting oxygen index (LOI), the rate of heat release (RHR), the specific extinction area (SEA), etc., have been studied by the LOI determination and the cone calorimeter test. The results show that RP and EG are good synergists for improving the flame retardancy of LLDPE/MH formulations. In addition, a suitable amount of ethylene and vinyl acetate copolymer (EVA) added in the formulations can increase the LOI values while promoting the char formation and showing almost no effect on the RHR and SEA values. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 206–214, 2001 相似文献
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Poly(trimethylene terephthalate)/magnesium hydroxide composites with on‐demand thickening at high temperatures 下载免费PDF全文
Magnesium hydroxide, when melt extruded with poly(trimethylene terephthalate) (PTT) at low concentrations (1–3 wt.%), can be melt processed during extrusion and injection molding. When the polymer is heated in the melt to 295°C, the viscosity of the composite behaves similarly to control samples and the viscosity decreases as a function of temperature. When the temperature of the composite is raised above 295°C (above the normal processing conditions for PTT), a significant change in the melt rheology of the composite is observed relative to unfilled compositions. This change in melt rheology coincides with the decomposition temperature of magnesium hydroxide and formation of magnesium oxide, a common thickening agent employed in unsaturated polyester resins. Lower processing temperature polyesters, including PTT, enable processing of the polymer in the presence of magnesium hydroxide under normal conditions. The viscosity modifier ‘turns on’ when the composite sees elevated temperature where magnesium oxide is known to form. The magnesium oxide is hypothesized to interact with PTT carboxyl end groups, providing the observed increase in viscosity. The rheological response observed in the composites is dependent on the concentration of magnesium hydroxide. During burning, the viscosity modifier results in a non‐dripping formulation of PTT. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
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In this paper, a new bio-based flame retardant MHPA was prepared by the reaction of magnesium hydroxide (MH) and phytic acid (PA). Then the crosslinked high-density polyethylene (HDPE) flame-retardant composite was prepared by adding it and silicone rubber (SR) into HDPE and using electron beam irradiation. The test results of limiting oxygen index (LOI) and cone calorimeter test (CCT) show that the combination of MHPA and SR can increase the flame retardancy and smoke suppression performance of HDPE. The LOI of HDPE composite with 10 parts of SR is 28.3%, and its pHRR, THR and TSP values are reduced to 454.1 kW/m2, 99.7 MJ/m2 and 8.3 m2, respectively, which is because MHPA and SR jointly promote the formation of continuous and high-density carbon slag in the combustion process of HDPE and inhibit the penetration of flame. In addition, the HDPE composite with 10 parts of SR has significant tensile strength, elongation breaking strength and tear strength, because SR can produce continuous stable structure with HDPE after irradiation and crosslinking. Therefore, this study verified that MHPA and SR together can effectively improve the flame retardancy, smoke suppression and mechanical properties of HDPE composite. 相似文献
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阻燃型氢氧化镁的制备及其应用 总被引:1,自引:1,他引:1
为制备高分散性氢氧化镁阻燃剂,以氯化镁为原料,氢氧化钠为沉淀剂,采用直接水热法制备了超细氢氧化镁微晶。采用扫描电子显微镜和X射线衍射仪对其形貌和晶体结构进行了表征;同时将其填充到乙烯-醋酸乙烯酯共聚物(EVA)树脂中,采用转矩流变仪、拉力试验机和氧指数仪对EVA/氢氧化镁混合物的流变性能、力学性能和阻燃性能进行了研究。结果显示,所制备的氢氧化镁产品为六方晶型,分散性高,与EVA树脂的相容性好。氢氧化镁填充量为60%(质量分数)的EVA混合物的转矩流变性能、力学性能和阻燃性能均优秀,平衡扭矩为13.8 N.m,拉伸强度为9.1 MPa,断裂伸长率达到1 200%,氧指数达到45。 相似文献
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氢氧化镁阻燃剂在聚合物改性中的应用研究进展 总被引:2,自引:0,他引:2
综述了氢氧化镁(MH)的阻燃机理及超细化、表面改性处理和与其他阻燃剂协同阻燃在聚合物改性中的应用。展望了氢氧化镁阻燃研究的发展前景。 相似文献
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不同氢氧化镁对LLDPE性能的影响 总被引:1,自引:0,他引:1
采用气泡液膜法制备了疏松型纳米氢氧化镁(LN-MH),将其和不同氢氧化镁分别填充到线型低密度聚乙烯(LLDPE)中制得复合材料。通过常规力学性能测试、TG、极限氧指数(LOI)和锥形量热仪(CONE)研究了疏松型氢氧化镁(LN-MH)和普通氢氧化镁(C-MH)对LI。DPE性能的影响。结果表明:LN-MH/LLDPE复合材料的拉伸强度、弯曲强度和氧指数均比C-MH/LLDPE有显著的提高;与C-MH相比,LN-MH对LLDPE有更好的阻燃效果和成炭作用,但热稳定性稍差。 相似文献
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The flammability characterization and synergistic flame retardant effect of cerium oxide (CeO2) in the ethylene‐vinyl acetate/aluminum hydroxide blends were studied using limiting oxygen index (LOI), UL‐94 test, and cone calorimeter test (CCT). The results showed that the addition of a given amount of CeO2 apparently increased the LOI value and UL‐94 rating. The data obtained from the CCT indicated that the addition of CeO2 greatly decreased the heat release rate and prolonged the combustion time. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献