Studies on Lower Tropospheric Aerosols over New Delhi,India Using Lidar

This study reports the altitude distribution of physical and optical properties of aerosols in the lower troposphere over the urban tropical region Delhi measured using an UV (355 nm) lidar which is capable of operating in both day and night time. It is observed that there is strong seasonal variation in the altitude (from 0.4 to 4 km) distribution of aerosols during the observation period from July 2009 to May 2010. The aerosol extinction coefficient and depolarization values range from 0.02 to 0.6 km^?1 and 0.02 to 0.05 respectively during the observation period. Relatively high aerosol extinction coefficient values were observed below 1.5 km altitude during the autumn season may be due the festivals and bio-mass burning activities. In all the seasons except winter, the aerosol loading from 0.4 km to 4 km range contributes more than 38% to the atmospheric column optical depth.     

Biomedical research productivity and economic crisis in Greece: a 22-year study

This article aims to study the effect of the current financial crisis (2010–2017) on biomedical productivity and impact of Greece-affiliated investigators. PubMed, Scopus and Web of Science were searched for articles published in biomedical journals with at least one Greek affiliation during the period 1995–2016 (date of last search October 19, 2017). The impact of Greek articles was the citations received by published articles during the first 2 years following the year of publication adjusted to the number of Greek and global articles. A discrepancy in the absolute article productivity between the databases was observed: a mean annual increase before the crisis was observed in all databases, while after the crisis the increase persisted in PubMed, in Scopus a decline was observed and in the Web of Science a smaller increase was observed. The changes in relative productivity were similar for both study periods in all databases (increasing before and decreasing after crisis, p?<?0.001 for trend in both periods). A continuous increase in total citations in both periods was observed (mean 2347?±?1622 before and 2627?±?3374 after the crisis). A continuous increase in the impact indices following adjustment for Greek (mean annual increase 0.27?±?0.30 before to 0.37?±?0.62 during the crisis, p?=?0.58) and global productivity (mean annual increase from 0.0024?±?0.0018 to 0.0007?±?0.004, p?=?0.95) was observed throughout the study period. In conclusion, the decline observed in the relative productivity of Greek affiliated articles during crisis compared to the period before was not reflected in their impact.     

Use of high-resolution measurements for the retrieval of temperature and gas-concentration profiles from outgoing infrared spectra in the presence of cirrus clouds

We explore ways in which high-spectral-resolution measurements can aid in the retrieval of atmospheric temperature and gas-concentration profiles from outgoing infrared spectra when optically thin cirrus clouds are present. Simulated outgoing spectra that contain cirrus are fitted with spectra that do not contain cirrus, and the residuals are examined. For those lines with weighting functions that peak near the same altitude as the thin cirrus, unique features are observed in the residuals. These unique features are highly sensitive to the resolution of the instrumental line shape. For thin cirrus these residual features are narrow (< or = 0.1 cm(-1)), so high spectral resolution is required for unambiguous observation. The magnitudes of these unique features are larger than the noise of modern instruments. The sensitivities of these features to cloud height and cloud optical depth are also discussed. Our sensitivity studies show that, when the errors in the estimation of temperature profiles are not large, the dominant contribution to the residuals is the misinterpretation of cirrus. An analysis that focuses on information content is also presented. An understanding of the magnitude of the effect and of its dependence on spectral resolution as well as on spectral region is important for retrieving spacecraft data and for the design of future infrared instruments for forecasting weather and monitoring greenhouse gases.     

河北地区低云、毛毛雨变化趋势及其气溶胶云物理效应的研究

利用1961—2000年期间河北地区的观测资料,分析了区域低云和毛毛雨的变化趋势。结果表明:低云频率趋于增加,毛毛雨日数趋于减少,特别是在环渤海湾地区和太行山东部平原地区这种变化趋势更为明显。其中渤海湾有关测站的毛毛雨幅度达1～4d,而对应的低云出现频率增加显著。渤海湾地区黄骅站的低云从128d增加到140d,乐亭站的低云从132d增加到159d。同时,利用有关研究结果结合最新观测资料,分析了1980—2000年渤海湾地区的气溶胶变化趋势,在此基础上分析了低云、毛毛雨与气溶胶变化的相互作用。结果表明:它们之间存在着比较好的相关性。最后,对低云、毛毛雨变化可能的气溶胶云物理效应进行了讨论。     

Atmospheric Fine and Coarse Mode Aerosols at Different Environments of India and the Bay of Bengal During Winter-2014: Implications of a Coordinated Campaign

In this paper, we present mass concentrations of particulate matter [PM_2.5, PM₁₀ size fractions and total suspended particulates (TSP)] measured simultaneously over land stations (Kullu, Patiala, Delhi, Ajmer, Agra, Lucknow, Varanasi, Giridih, Kolkata, Darjeeling, Jorhat, Itanagar, Imphal, Bhubaneswar, and Kadapa), mostly distributed across the Indo-Gangetic plain (IGP) of India as well as in the marine atmosphere over Bay of Bengal (BoB) in the period from 20 January to 3 February, 2014. The main objective of this study was to quantify the continental outflow of particulates (PM_2.5, PM₁₀ and TSP) from IGP and associated regions into the BoB along with low level north-east wind flow during winter monsoon period. The present study provides a glimpse of the aerosol loading over the IGP region. During this campaign, the highest average PM_2.5 (187.8 ± 36.5 µg m^?3, range 125.6–256.2 µg m^?3), PM₁₀ (272.6 ± 102.9 µg m^?3, range 147.6–520.1 µg m^?3) and TSP (325.0 ± 71.5 µg m^?3, range 220.4–536.6 µg m^?3) mass concentrations were recorded at Varanasi, Kolkata and Lucknow over middle and lower IGP regions. The PM_2.5 (average 41.3 ± 11.9 µg m^?3; range 15.0–54.4 µg m^?3), PM₁₀ (average 53.9 ± 18.9 µg m^?3; range 30.1–82.1 µg m^?3) and TSP (average 78.8 ± 29.7 µg m^?3; range 49.1–184.5 µg m^?3) loading over BoB were found to be comparable to land stations and suggests possible continental outflow. Over the continental region, the highest PM_2.5/PM₁₀ ratio was recorded at Delhi (0.87). The PM_2.5/PM₁₀ ratio over BoB (0.77) was found to be quite high and comparable to Varanasi (0.80) and Agra (0.79).     

Measurement of Ambient Ammonia over the National Capital Region of Delhi,India

Mixing ratio of ambient ammonia (NH₃) was measured at various locations of the National Capital Region (NCR) of Delhi, India using a NH₃-analyzer during January 2010 to June 2012 in campaign mode. The present study has been carried out on campaign based measurement of mixing ratios of NH₃ and NO _x for short period of time over the NCR of Delhi represent the indicative values over the region. The average mixing ratio of ambient NH₃ was 20.9 ± 1.6 ppb during the period. The maximum average mixing ratio of ambient NH₃ (28.8 ± 3.0 ppb) was recorded in an industrial area surrounded by intensive vehicular traffic followed by an agricultural farm (27.5 ± 2.1 ppb), whereas the minimum (6.4 ± 1.2 ppb) was recorded in the semi-urban area. The diurnal trend of NH₃ depended on the ambient temperature at most of the sites and was affected by wind direction. Ambient NH₃ was correlated with the NO _x mixing ratio suggesting that the vehicular emission may be one of the sources of ambient NH₃ in the NCR of Delhi. However, long-term measurements of ambient NH₃ and their precursors will lead to seasonal variation of source apportionment over the NCR, Delhi, India.     

Performance improvement of terrestrial free-space optical communications by mitigating the focal-spot wandering

Abstract

Focal-spot wandering is the main cause for the major power loss in free-space optical communications. Thus,mitigating it is a primary requirement for the successful performance improvement. In order to prove this prerequisite, an experimental set-up using 155-Mbps data transmission is built for the link range of 0.5 km at an altitude of 15.25 m. In the experiment, the receiver is equiped with a control system to stabilize the received optical propagation at the detector plane which is called as focal-spot wandering mitigation control so as to couple the power in bucket perfectly to the photodetector. The performance improvements due to mitigating focal-spot wandering are regressively investigated in terms of various quality assessment key parameters. Maximum radial distance of 0.25 mm, maximum effective scintillation index of 0.17, optical signal-to-noise ratio of 9 dB, minimum eye-opening of ±0.37 V, minimum eye-height of ±0.51 V, controlled bit-error-rate of 6.45 × 10^?9 to 7.09 × 10^?8 and the link margin of 1.83 dB are attained even during strong turbulence level while mitigating focal-spot wandering.     

Modeling exposure period for solar disinfection (SODIS) under varying turbidity and cloud cover conditions

Solar disinfection (SODIS) is widely practiced all around the world. The process requires variable exposure periods depending upon a number of process parameters (e.g., water turbidity, atmospheric temperature, and cloud cover conditions). This paper describes the development of a mathematical model to estimate required exposure period to achieve Fecal coliforms (FCs) removal for changing process parameters. Daily and hourly solar radiation were estimated and found to be suitable for SODIS application with intensity of 500 W/m² over a period of 3–5 h/day. Randomized SODIS experiments over a period of 3 years were conducted to consider seasonal and weather variations. Six samples each for five levels of turbidity (0, 5, 10, 20, and 30 NTU) were exposed to sunlight under variable cloud cover conditions on different days during the 3-year sampling period. Samples were collected and analyzed for remaining FCs at different intervals in each sampling day. Analysis of variance revealed that turbidity and percent of cloud cover are the most significant process parameters. It was found that FCs die-off in SODIS bottles followed the first-order kinetics. Different data sets were used for the development and calibration of the model. The calibrated model was further verified against the literature. Simple characteristics curves have also been established for practical application at household level to estimate exposure periods. The study revealed a significant difference between the required exposure periods for different turbidity and cloud cover conditions.     

Material cloud method for topology optimization

Material cloud method (MCM), a new approach for topology optimization, is presented. In MCM, an optimal structure can be obtained by manipulating the sizes and positions of material clouds, which are material patches with finite sizes and constant material densities. The optimal distributions of material clouds can be obtained by MCM using fixed background finite element meshes. In the numerical analysis procedure, only active elements, where more than one material cloud is contained, are treated. Optimal material distribution can be element‐wise extracted from the distribution of material clouds. With MCM, an expansion–reduction procedure of design domain can be naturally realized through movements of material clouds, so that a true optimal solution can be found without any significant increase of computational costs. It is also shown that a clear material distribution with narrow region of intermediate density can be obtained with relatively fast convergence. Several numerical examples are shown. Some of the results are compared with those of the traditional density distribution method (DDM). Copyright © 2005 John Wiley & Sons, Ltd.     

Determination by spaceborne backscatter lidar of the structural parameters of atmospheric scattering layers

Spaceborne active lidar systems are under development to give new insight into the vertical distribution of clouds and aerosols in the atmosphere and to provide new information on variables required for improvement of forecast models and for understanding the radiative and dynamic processes that are linked to the dynamics of climate change. However, when they are operated from space, lidar systems are limited by atmospheric backscattered signals that have low signal-to-noise ratios (SNRs) on optically thin targets. Therefore specific methods of analysis have to be developed to ensure accurate determination of the geometric and optical properties of scattering layers in the atmosphere. A first approach to retrieving the geometric properties of semitransparent cloud and aerosol layers is presented as a function of false-alarm and no-detection probabilities for a given SNR. Simulations show that the geometric properties of thin cirrus clouds and the altitude of the top of the unstable atmospheric boundary layer can be retrieved with standard deviations smaller than 150 m for a vertical resolution of the lidar system in the 50-100-m range and a SNR of 3. The altitudes of the top of dense clouds are retrieved with a precision in altitude of better than 50 m, as this retrieval corresponds to a higher SNR value. Such methods have an important potential application to future spaceborne lidar missions.     

Follow-up study: on the working time budget of a university teacher. 45 years self-observation

Results from self-observation of the working time distribution of a university teacher for a period of 45 years (starting from the very beginning of his carrier till two years after retirement) are reported classified in (i) teaching; (ii) scientific; (iii) administrative, organizational, technical; (iv) social/other activities. For the whole period, the teaching take 19 %, scientific work—22 % and various kinds of administrative, organizational and technical activities—52 % of the overall working time. The latter varies within the limits of 6.1–14.5 h per calendar day (mean values for an year) and in average is 10 h per calendar day for the entire 45-years-period. The changes of the working time distribution and the working day duration during the years are shown. The time consumed in fulfillment of obligations as head of research institution and of university units is revealed. The data are accompanied with information for the growth of the scientific production of the observed person. It is appeared that the latter as well as the growth of the citations of his papers can be depicted by the well known exponential law describing the accelerated development of the science.     

Experimental Study of Nucleate Pool Boiling of FC-72 on Smooth Surface under Microgravity

Experiments of highly subcooled nucleate pool boiling of FC-72 with dissolved air were studied both in short-term microgravity condition utilizing the drop tower Beijing and in normal gravity conditions. The bubble behavior and heat transfer of air-dissolved FC-72 on a small scale silicon chip (10 × 10 × 0.5 mm³) were obtained at the bulk liquid subcooling of 41 K and nominal pressure of 102 kPa. The boiling heat transfer performance in low heat flux region in microgravity is similar to that in normal gravity condition, while vapor bubbles increase in size but little coalescence occurs among bubbles, and then forms a large bubble remains attached to the heater surface during the whole microgravity period. Thermocapillary convection may be an important mechanism of boiling heat transfer in this case. With further increasing in heat flux to the fully developed nucleate boiling region, the vapor bubbles number as well as their size significantly increase in microgravity. Rapid coalescence occurs among adjacent bubbles and then the coalesced large bubble can depart from the heating surface during the microgravity period. The reason of the large bubble departure is mainly attributed to the momentum effects caused by the coalescence of small bubbles with the large one. Hence, the steady-state pool boiling can still be obtained in microgravity. In the high heat flux regime near the critical heat flux, significant deterioration of heat transfer was observed, and a large coalesced bubble forms quickly and almost covers the whole heater surface, leading to the occurrence of the critical heat flux in microgravity condition.     

Measurement of Ambient NH<Subscript>3</Subscript>, NO and NO<Subscript>2</Subscript> at an Urban Area of Kolkata,India

Mixing ratios of ambient NH₃, NO and NO₂ were measured in campaign mode at Kolkata a megacity of Indo-Gangetic plain of India to study the diurnal variation and mixing ratios of NH₃, NO and NO₂ during 24–27 February 2012. The present study has been carried out on campaign based measurement of mixing ratios of NH₃, NO and NO₂ for short period of time at Kolkata represent the indicative values over the region. The average mixing ratios of ambient NH₃, NO and NO₂ were recorded as 43.4 ± 7.0 ppb, 46.0 ± 8.7 ppb and 31.9 ± 5.5 ppb at Kolkata. In the present case, significant diurnal variation of NH₃, NO and NO₂ were recorded at Kolkata during study. Mixing ratio of ambient NH₃ reaches its maxima (78.9 ppb) at night and minimum during daytime. Result reveals that the ambient NH₃ mixing ratio is positively correlated with ambient NO (r ² = 0.395) and NO₂ (r ² = 0.404) mixing ratio and significant negatively correlated with ambient temperature (r ² = –0.669). Surface wind direction and wind speed analysis indicates that the local acitivities (livestock, drainage, agriculture, vehicles etc.,) may be the possible sources of ambient NH₃ at the observational site of Kolkata.     

Retrieval of total ozone abundances from the ultraviolet region of spectra recorded with an ultraviolet-visible spectrometer

A method is described for deriving total ozone abundances from zenith-sky intensities measured by an UV-visible spectrometer, known as the System of Analysis of Observations at Zenith (SAOZ). Total ozone abundances are determined by comparison of intensity ratios measured at two wavelengths in the UV region with ratios computed with a radiative transfer model. The wavelength pair 320-307 nm was used in this study. Spectra recorded by the SAOZ spectrometer in Oslo (60 degrees N) from the beginning of May 1995 to the end of August 1995 were analyzed, and the results were compared with total ozone measured with a Brewer instrument. The relative difference in derived ozone abundances for the whole period, including days with thin and medium-thick cloud covers, is -0.18 +/- 1.46%. We study the effects of clouds and varying ground albedo on the derived total ozone. Clouds result in an overestimation of the derived total ozone. The error increases with the optical depth tau of the cloud from approximately 2% for an optically thin cloud (tau = 0.5) to approximately 10% for a thick cloud (tau = 50). The ratio between measured intensities at 550 and 350 nm, the so-called color index, can be used as a measure of the cloud optical depth for thin and medium-thick clouds. The effects of thin and medium-thick clouds on the derived ozone abundances can be compensated for by use of an empirical relationship found between the measured color index and the error in the inferred ozone abundances caused by cloud scattering. We also study the influence of changes in the ground albedo and in the ozone profiles on derived total ozone values.     

Estimation of the amount of tropospheric ozone in a cloudy sky by ground-based Fourier-transform infrared emission spectroscopy

The problem of retrieving minor concentrations of constituents by ground-based Fourier-transform infrared emission spectroscopy is addressed by means of the concept of differential optical emission spectroscopy in analogy to the concept of differential optical absorption spectroscopy. Using the prominent nu(3) ozone feature at 1043 cm(-1), we show that the strength of the spectral signature depends not only on the amount of ozone but also on the atmospheric thermal structure. This dependence can be described by a rather accurate approximation, which was used to construct a simple diagram to estimate the amount of column ozone between the instrument site and a cloud deck as well as to determine the detection limit. The detection limit is shown to depend on cloud base height. For a given thermal lapse rate it was found that the lower the detection limit, the higher the cloud base altitude. However, as shown in a case study with variable cloud base height, the concept fails for semitransparent clouds. Multiple scattering of the emitted radiation within the clouds yielded a path enhancement that simulated an enhanced amount of constituent. The path enhancement was estimated to be 2.4-4 km at 1000 cm(-1) for low-level clouds, equivalent to an enhancement factor of 6-21. The multiple scattering effect has considerable consequences for ground-based as well as for nadir satellite retrieval techniques in cloudy skies.     

Measurements of Particulate (PM2.5), BC and Trace Gases Over the Northwestern Himalayan Region of India

Ambient trace gases (NH₃, NO, NO₂ and SO₂) and black carbon (BC) were measured along with particulate matter (PM_2.5) over the northwestern Himalayan region (Palampur, Kullu, Shimla, Solan and Nahan) of Himachal Pradesh (HP), India in a campaign mode during 12–22 March 2013 to evaluate the ambient air quality of the region. The average mixing ratio of ambient NH₃, NO, NO₂ and SO₂ were recorded as 7.1 ± 2.6, 3.1 ± 1.3, 3.9 ± 1.4 and 1.7 ± 0.7 ppb respectively over the northwestern Himalayan region. The average concentration of BC was estimated as 2.2 ± 0.5 µg m^?3 over the region whereas average concentration of PM_2.5 mass was estimated as 41.8 ± 7.9 µg m^?3. The spatial variation of ambient trace gases (NH₃, NO, NO₂ and SO₂), BC and PM_2.5 over the northwestern Himalayan region, India reveals that the region is mainly influenced by local activities, i.e., tourism activities, agricultural activities, biomass burning and vehicular emission. A significant positive linear correlation of NH₃ and NH₄ ⁺ with SO₄ ^2?, NO₃ ^? and Cl^? (NH₄ ⁺ vs. SO₄ ^2? , r ² = 0.652; NH₄ ⁺ vs. NO₃ ^?, r ² = 0.701; and NH₄ ⁺ vs. Cl^?, r ² = 0.627) of the PM_2.5 indicates the possible formation of (NH₄)₂SO₄, NH₄NO₃ and NH₄Cl aerosols over the region.     

Effects of the El Chichon volcanic cloud in the stratosphere on the polarization of light from the sky

A dense volcanic cloud from the El Chichon volcanic eruption has been observed in the stratosphere over Hawaii since it was first discovered at the Mauna Loa Observatory 9 Apr. 1982. Lidar observations have shown the cloud to have been dense and highly layered in its early stages, but as the cloud matured it became more homogeneous and the top portion underwent considerable enhancement. Measurements of the degree of polarization of skylight at the zenith and across the sky in the sun's vertical show that the polarization field is strongly modified by the effects of the cloud and that the modifications are of a different nature from those produced by high turbidity in the lower layers of the atmosphere. The degree of polarization at the zenith during twilight shows a secondary maximum at a solar depression D = 4.8-5 degrees, a secondary minimum at D = 4 degrees, a primary maximum at D = 1-2 degrees, and a rapid decrease to values generally <10% in the immediate sunrise period. The positions of the neutral points are strongly affected by the cloud, the Arago point being shifted from its normal position by as much as 15-20 degrees and the Babinet point being shifted even farther. Multiple Babinet points were observed on some occasions. The measurements indicate the polarization field to be modified more by the El Chichon cloud than it was by the clouds from previous eruptions which have occurred during this century.     

Simulating coronas in color

Coronas are simulated in color by use of the Mie scattering theory of light by small droplets through clouds of finite optical thickness embedded in a Rayleigh scattering atmosphere. The primary factors that affect color, visibility, and number of rings of coronas are droplet size, width of the size distribution, and cloud optical thickness. The color sequence of coronas and iridescence varies when the droplet radius is smaller than approximately 6-microm. As radius increases to approximately 3.5 microm, new color bands appear at the center of the corona and fade as they move outward. As the radius continues to increase to approximately 6 microm, successively more inner rings become fixed in the manner described by classical diffraction theory, while outer rings continue their outward migration. Wave clouds or rippled cloud segments produce the brightest and most vivid multiple ringed coronas and iridescence because their integrated dropsize distributions along sunbeams are much narrower than in convective or stratiform clouds. The visibility of coronas and the appearance of the background sky vary with cloud optical depth tau. First the corona becomes visible as a white aureole in a blue sky when tau approximately 0.001. Color purity then rapidly increases to an almost flat maximum in the range 0.05 < or = tau < or = 0.5 and then decreases, so coronas are almost completely washed out by a bright gray background when tau > or = 4.     

Comparison of Transfer Standard Industrial Lamps against PTB-assigned Radiance Temperature of Vacuum and Gas Filled Tungsten Strip Lamps

Accurate determination of temperature is one of the prime requirements in almost all the areas of physical metrology as it affects the process of any of the industrial manufacturing products. Planck’s equation serves the best approximation for determining temperature of a thermal radiating source. The ratio of pyrometric output signal due to intensities of two radiating sources can be utilized to measure temperature of an unknown source in terms of the temperature of reference metal freezing point source or a high stability tungsten strip lamp. The present paper provides an assessment of a set of tungsten lamps having strip or ribbon filament when compared against the emission of high stability standard lamps. The temperature measured in terms of electrical current across the lamp terminals has been estimated with an uncertainty reasonably acceptable for accurate determination of radiance temperature by these lamps. The uncertainty of temperature at each comparison point for lamps under assessment has been evaluated and reported. The best uncertainty of temperature was estimated to be ±1.7 K at 1073 K, ±1.5 K at 1273 K and ±3.7 K at 2473 K. The uncertainty at 1,073 K is higher as compared to at 1,273 K, is because of very low value of photocurrent signal produced due to low intensity observed at this temperature. The industrial strip lamps, compared against reference standard lamps serve as accurate sources of radiance temperature for comparing the disappearing filament Opto-spectral pyrometers used as direct temperature measuring instruments in the laboratories and in industries in the range above 1,073 K to as high as 2,500 K.     

A Non-destructive FTIR Method for the Determination of Ammonium and Sulfate in Urban PM<Subscript>2.5</Subscript> Samples

Traditionally, the atmospheric particle composition is analyzed using destructive methods. In general, the destructive methods lead to the destruction of the samples, higher cost of the analysis and larger analysis time. In view of aforesaid, in current work, we present a method for the non-destructive analysis of atmospheric particles using open path-Fourier transform infrared spectroscopy (OP-FTIR). The developed method has been used for the measurement of ammonium and sulfate in atmospheric particles without destroying the samples. Here, we targeted the said species because of their relative importance for air pollution episode formation. Particulate sulfate plays a major role in formation of haze. However; particulate acidity is an important factor in this process, which is governed by particulate ammonium concentration. Therefore, both SO₄^2? and NH₄⁺ are important as far as atmospheric chemistry of haze formation is concerned. In the present study, the qualitative and quantitative estimation of ammonium and sulfate ions in PM_2.5 (particulate matter with aerodynamic diameter less than 2.5 µm) was carried out using OP-FTIR with the developed method. The seasonal average concentration of NH₄⁺ and SO₄^2? were measured to be 12.00 ± 5.80, 31.71 ± 12.71 µg/m³ respectively for winters, 3.00 ± 0.85 and 8.00 ± 2.28 µg/m³ respectively for summers and 2.60 ± 1.90 and 7.00 ± 5.21 µg/m³ respectively for monsoon season. The observed results are found to be in good agreement with that of other studies using destructive methods.