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红外光谱法研究降解PE膜的生物降解引发过程 总被引:1,自引:0,他引:1
利用红外光谱法研究环境降解PE薄膜的光氧降解性,其最终产生羧酸的反应历程表明,红外光谱法是评价此类降解膜生物降解引发过程的一种简便而有效的方法。研究结果还表明,胺烷基二茂铁衍生物和新型烷基二硫代氨基甲酸铁是此类PE膜的两类生物降解有效引发剂;而新型烷基二硫代氨基甲酸镍可有效地控制其生物降解引发过程;含有它们的PE薄膜具有较好的环境降解性。 相似文献
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光—生物降解PE塑料配方设计和评价研究 总被引:6,自引:0,他引:6
研究了光-生物降解PE母料及其薄膜制品复合组分配方体系组成设计,经物性,光降解诱导期,光降解终点,光降解眩和生物降解性等性能指标的试验评价,其结果表明:含光敏剂和淀粉为关键组分的-类光-生物降解PE薄膜比单纯的光或生物降解PE薄膜具有更好的光-生物降解性;另一类含光敏剂,促氧化剂和生物降解增敏剂的物降解PE薄膜,在日光作用后,也具有较优的光一生物降解性。 相似文献
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含淀粉与光敏剂的LDPE膜可控光生物降解 总被引:6,自引:0,他引:6
研究了含超淀粉及硬脂酸铁或N,N-二正丁基二硫代氨基甲酸铁/N,N-二正丁基二硫代氨基甲酸镍光敏剂的低密度聚乙烯膜光氧化降解羰基指数,粘均分子量和真菌侵蚀(级)的变化。结果表明,只需在LDPE膜中添加5%-15%淀粉和0.1%-0.3%FeSt3或0.05%-0.20%FeDBC/NiDBC光敏剂,在自然曝露条件下可控LDPE膜的使用寿命 。 相似文献
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淀粉粒度对可生物降解聚乙烯膜性能的影响 总被引:8,自引:0,他引:8
探讨了淀粉 /聚乙烯共混可生物降解膜的性能受淀粉粒度控制问题以及在环境中降解机理 ,并认为对于各种可生物降解薄膜 ,需要在考虑等同使用寿命条件下来判别其生物降解能力 ,才会更加客观。 相似文献
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M. M. Reddy M. Deighton Rahul K. Gupta S. N. Bhattacharya R. Parthasarathy 《应用聚合物科学杂志》2009,111(3):1426-1432
Biodegradation of polyethylene and oxo‐biodegradable polyethylene films was studied in this work. Abiotic oxidation, which is the first stage of oxo‐biodegradation, was carried out for a period corresponding to 4 years of thermo‐oxidation at composting temperatures. The oxidation was followed by biodegradation, which was achieved by inoculating the microorganism Pseudomonas aeruginosa on polyethylene film in mineral medium and monitoring its degradation. The changes in the molecular weight of polyethylene and the concentration of oxidation products were monitored by size exclusion chromatography and Fourier transform infrared (FTIR) spectroscopy, respectively. It has been found that the initial abiotic oxidation helps to reduce the molecular weight of oxo‐biodegradable polyethylene and form easily biodegradable product fractions. In the microbial degradation stage, P. aeruginosa is found to form biofilm on polymer film indicating its growth. Molecular weight distribution data for biodegraded oxo‐biodegradable polyethylene have shown that P. aeruginosa is able to utilize the low‐molecular weight fractions produced during oxidation. However, it is not able to perturb the whole of the polymer volume as indicated by the narrowing of the polymer molecular weight distribution curve toward higher molecular fractions. The decrease in the carbonyl index, which indicates the concentration of carbonyl compounds, with time also indicates the progress of biodegradation. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
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Yew-Wing Lee 《Polymer International》1986,18(2):79-82
The change of shape patterns of the oxidation peak on differential thermal analysis curves of a series of formulations of polyethylene has been investigated. The unstabilised sample exhibits two oxidation peaks. When a chain-terminating antioxidant and dilaurylthiodipropionate were added to polyethylene, it was found that as the concentration of dilaurylthiodipropionate increases, the second oxidation peak reduces in size. In many instances when the amount of dilaurylthiodipropionate reaches 0.3% (by weight), the second oxidation peak disappears. The influences of processing method and outdoor exposure on the peak shape have also been examined. The effectiveness and consumption of antioxidants during weathering is clearly shown by the shape change of the oxidation peak on the differential thermal analysis curves. 相似文献
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Emilia Otal Dionissios Mantzavinos Maria V. Delgado Rolf Hellenbrand Julian Lebrato Ian S. Metcalfe Andrew G. Livingston 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1997,70(2):147-156
The treatment of a model wastewater containing polyethylene glycol (PEG) of molecular weight 10000 in an integrated wet air oxidation–aerobic oxidation process was investigated. Partial wet air oxidation under mild operating conditions was capable of converting the original polymer to lower molecular weight compounds, such as oligomers and short-chain organic acids. The effect of molecular weight on the aerobic biodegradability of polyethylene glycol was assessed by performing shake flasks experiments with various polyethylene glycols in a molecular weight range from 200–35000 and it was found that biodegradability generally decreased with increasing molecular weight. Aqueous solutions of PEG 10000 were subjected to continuous wet air oxidation at a temperature of 423 K and a residence time of 30 min and the oxidised effluents were then subjected to subsequent continuous aerobic oxidation at residence times varying between 0·5 and 4 days. Simultaneously, continuous aerobic oxidation experiments on solutions of PEG 10000 were performed and used to compare the efficiency of the integrated treatment process with that of the direct biological treatment. Partial pretreatment by wet air oxidation under mild operating conditions resulted in effluents whose biodegradation rates were significantly higher than those of the original, unoxidised wastewater, as assessed by total organic carbon (TOC) removal rates. The original wastewater was practically non-biodegradable at a 0·5-day residence time with direct biological treatment, while an 80% TOC removal was achieved when biological treatment was coupled with a preceding wet air oxidation step. Conversely, with a 4-day residence time for the direct biological treatment the original wastewater was only partially degradable with 60–70% TOC removal recorded; with the integrated treatment process at a 4-day residence time in the bioreactor the overall TOC removal was greater than 90%. © 1997 SCI 相似文献
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TNT生物降解的可能途径 总被引:1,自引:0,他引:1
综述了上前国内外报导 的氧化塘生物降解TNT的几种不同途径 。提出了废水中TNT生物降解的新途径:即TNT首先转变为3-A,2-A,2-DA,2,4-DA,再转变为邻苯二甲酸酯类、酚类,以后转变直链酯类,最后TNT完全初降解。 相似文献
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The diffusion of an antifogging agent, EO/PO (epoxyethane/epoxypropane) copolymer, through a polyethylene PE film was studied using a simple experimental system. It was found that the temperature, concentration of antifogging agent, crystallinity of PE film and film thickness affect the diffusion process. 相似文献
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The diffusion of an antifogging agent, EO/PO (epoxyethane/epoxypropane) copolymer, through a polyethylene PE film was studied using a simple experimental system. It was found that the temperature, concentration of antifogging agent, crystallinity of PE film and film thickness affect the diffusion process. 相似文献
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通过在聚乙烯吹塑加工过程中改变吹胀比、牵引比、霜高线高度等工艺条件,考察其对收缩率的影响;并引人膜泡冷却时间的概念,以量化这些工艺条件的影响。结果表明,薄膜纵、横向拉伸的大小和冷却时间的长短共同决定薄膜的收缩率;拉伸越大,薄膜收缩率越大;膜泡冷却时间越短,薄膜收缩率越大。且膜泡冷却时间为6--10、时,纵、横向收缩率比较适合。 相似文献
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