The ternary powder blends based on low-density polyethylene (LDPE) and two polymers of natural origin poly(lactic acid) (PLA) and starch are obtained in a rotor disperser under conditions of shear deformations. The dependence of the final powder dispersity on the composition is explored. A comparative analysis of the mechanical properties of the ternary blends with those of the LDPE–PLA and PLA–starch binary blends previously obtained has revealed that the presence of two rigid polymers PLA and starch leads to an increase in the elastic modulus and a decrease in the tensile strength and elongation at break. In the study of the blend biodegradability, it is found that the presence of two polymers of natural origin in the system with a total mass fraction of 60% promotes intensive biodegradation. 相似文献
A series of LDPE blends with plasticized (PLST) and granular starch (FILST) were prepared. Ethylene/vinyl acetate (EVA) copolymer was used as a compatibilizer in three different amounts: 10, 25 and 50 wt% based on starch. The blends were studied by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). Second derivative IR spectra showed peak shifts similar to those observed in V-type starch complexes with ethylene/vinyl alcohol copolymers. The possibility for V-type complex formation is supported by the lower biodegradation rates of the blends containing higher amounts of EVA. Mechanical properties of the blends, especially elongation at break, were satisfactory even for blends containing high amounts of starch (20–30 wt%). 相似文献
In this study, thermoplastic starch (TPS) was mixed with low density polyethylene with different melt
flow indexes in a one-step extrusion process to produce LDPE/TPS blends varied from 32% to 62% by weight
of TPS. The influence of starch content and LDPE viscosity on morphology, biodegradation and tensile properties
of LDPE/TPS blends were evaluated. Starch continuity and biodegradability were studied by hydrolytic, enzymatic
and bacterial degradation. The LDPE viscosity had a considerable effect on the morphology and the connectivity
of the starch particles. Evaluation of hydrolytic extraction showed that blends having TPS content above
50 wt% possessed a full connectivity. Studies of biodegradation indicated that the bacterial attack on
starch resulted in weight loss of TPS of 92%, 39% and 22%, for PE1/TPS having 62% and 32% TPS, and PE2/TPS
(31% TPS), respectively. Comparatively, the weight loss was more significant at 100%, 66% and 31% by hydrolytic
extraction. Differences between these two techniques were discussed in terms of the accessibility of starch
domains to microorganisms. Tensile properties (εb and E) decreased with increasing
exposure time to activated sludge. Changes in tensile properties were highly dependent on the biodegradation
rate. PE1/TPS blends having 32% starch remained ductile after 45 days of exposure to bacterial attack. 相似文献
Thermoplastic starch/poly(butylene succinate) (TPS/PBS), an entirely biodegradable polymer blend, was prepared by a two-step extrusion method. Maleic anhydride grafted PBS (rPBS) was successfully synthesised as an interfacial compatibiliser. The miscibility, morphology, thermal behaviour and mechanical properties of the TPS/PBS blends were investigated. The results demonstrated that the strength and elongation at break of TPS/PBS blends were greatly increased with the addition of rPBS in PBS blends due to improved interfacial miscibility. Better distribution and smaller phase domain were observed in the blends with higher content of compatibilisers. The water resistance was also enhanced by incorporation of rPBS. It was indicated that compatibilised TPS/PBS blends possessed a combination of good biodegradability, improved strength and high water resistance. TPS/PBS blend was expected to serve as a promising packing material. 相似文献
Summary: In the previous study, we observed compatibilizing effects of low density polyethylene (LDPE)/polystyrene (PS) with polystyrene‐block‐poly(ethylene‐co‐butylene)‐block‐polystyrene (SEBS), a triblock copolymer. Blends consisting of 70 wt.‐% LDPE and 30 wt.‐% PS were prepared with a SEBS concentration of up to 10 wt.‐%. This study examined the electrical properties such as the electrical breakdown, water tree length, permittivity and tan δ in the blends. The possibility of using these blends as insulating material substitutes for LDPE was investigated. The electrical breakdown strength reached a maximum of 66.67 kV/mm, which is superior to 50.27 kV/mm of the LDPE used as electrical insulators for cables. In addition, the water tree length decreased with increasing SEBS concentration. The water tree lengths of the blends containing SEBS were shorter than that of the LDPE. The permittivity of the blends was 2.28–2.48 F/m, and decreased with increasing SEBS concentration with the exception of S‐0. Tan δ of the blends increased smoothly with increasing SEBS content.
Breakdown strength , water tree length, permittivity and tan δ of the LDPE/PS/SEBS blends and raw materials. 相似文献
Low-density polyethylene, (LDPE) was mixed with two grades of tapioca starch–low-grade and high-grade. Various compositions were prepared and mechanical and thermal studies performed. The biodegradability of these samples was checked using a culture medium containing Vibrios (an amylase-producing bacteria), which was isolated from a marine benthic environment. The soil burial test and reprocessability of these samples were checked. The studies on biodegradability show that these blends are partially biodegradable. These low-density polyethylene-starch blends are reprocessable without sacrificing much of their mechanical properties. 相似文献