有效能分析在环境评价中的应用

讨论了有效能分析的概念及有效能分析与环境损害间的联系,并阐述了废物排放有效能分析的几个问题,介绍了大气排放环境费用的计算方法。     

ON EXERGY AND ENVIRONMENTAL IMPACT

Environmental problems span a continuously growing range of pollutants, hazards and eco-system degradation factors that affect areas ranging from local through regional to global. Some of these problems may arise from observable, chronic effects on, for instance, human health, while others may stem from the perceived risk of a possible accidental release of hazardous materials. A significant number of these environmental issues are caused by or relate to the production, transformation and end use of energy. In this regard, energy and environment studies which lead to increased energy efficiency can reduce environmental impact by reducing energy losses. Within the scope of exergy methods, such activities lead to increased exergy efficiency, which is of great importance for practical applications. In this study, the main relationships between energy and environmental impact are identified. Historical and modern examples are used to illustrate some of the concepts. The relationships introduced are: order-destruction/chaos-creation, resource degradation and waste exergy emissions. Some examples are given demonstrating the use of exergy analysis in addressing and solving environmental problems. © 1997 by John Wiley & Sons, Ltd.     

应用(火用)方法分析PFBC-CC系统的环境影响

采用火用方法建立了系统排放的废弃物和废热分析模型,从火用的概念出发分析排放物对环境的影响,并对一个增压流化床联合循环(PFBC-CC)发电系统的环境影响进行分析.结果表明,系统排放的CO2和热量对环境的影响是不可忽视的,S元素从SO2转移到CaSO4可大大降低系统的环境影响.为了用火用方法建立更全面的环境影响分析,还需要对参考环境模型进行更深入的研究.     

Application of the exergy method to the environmental impact estimation: The nitric acid production as a case study

In this work the exergy method is used to compare various methods for removal of NO_x from waste (tail) gas released into the atmosphere from nitric acid production plants with respect to their overall environmental impact. Three basic methods for NO_x abatement are analysed: selective catalytic reduction (SCR), non-selective catalytic reduction (NSCR) and extended absorption. The positive and negative effects and the net effect from the NO_x abatement are calculated. The following exergy-based indicators are used for comparing the energy efficiency and the environmental impact of different treatment processes as a result from pollutants removal: reduction of the exergy of the emissions from the whole process route (ammonia and nitric acid production units); exergy of the additional emissions, arising as a result of the treatment process; total net reduction of the exergy consumption, Cumulative Energy Consumption (CEnC) and Cumulative Exergy Consumption (CExC) of natural resources as a result of the waste flows treatment.     

Exergy-based assessment for waste gas emissions from Chinese transportation

As an effective measure for environmental impact associated with the waste emissions, exergy is used to unify the assessment of the waste gases of CO, NO_x, and SO₂ emitted from fossil fuel consumption by the transportation system in China. An index of emission exergy intensity defined as the ratio of the total chemical exergy of the emissions and the total converted turnover of the transportation is proposed to quantify the environmental impact per unit of traffic service. Time series analyses are presented for the emission exergy and emission exergy intensity of the whole Chinese transportation as well as for its four sectors of highways, railways, waterways and civil aviation from 1978 to 2004. For the increasing emission exergy with CO taking the largest share, the highways sector was the major contributor, while the railways sector initially standing as the second main contributor developed into the least after 1995. The temporal and structural variations of the emissions are illustrated against the transition of the transportation system in a socio-economic perspective, with emphasis on policy-making implications.     

A longitudinal analysis of the UK transport sector, 1970–2010

This paper presents an overview of the resource consumption and environmental impact of the United Kingdom's transport system for the period between 1970 and 2010. For the purpose of this analysis the concept of exergy has been employed both to quantify and aggregate the energy used and the atmospheric emissions arising from the sector. Our analysis illustrates and elucidates the disproportionate increase of the overall exergy consumed by the transport sector when compared to that of other UK economic sectors. Furthermore, its environmental impact and, in particular, the trends in the emission of the main ambient air pollutants and greenhouse gases is discussed. Exergy efficiency and intensity time series are also calculated and recommendations are made in order to minimize the sector's environmental impact and to facilitate a shift towards a more sustainable transport system.     

Exergy, exergoeconomic and environmental analyses and evolutionary algorithm based multi-objective optimization of combined cycle power plants

A comprehensive exergy, exergoeconomic and environmental impact analysis and optimization is reported of several combined cycle power plants (CCPPs). In the first part, thermodynamic analyses based on energy and exergy of the CCPPs are performed, and the effect of supplementary firing on the natural gas-fired CCPP is investigated. The latter step includes the effect of supplementary firing on the performance of bottoming cycle and CO₂ emissions, and utilizes the first and second laws of thermodynamics. In the second part, a multi-objective optimization is performed to determine the “best” design parameters, accounting for exergetic, economic and environmental factors. The optimization considers three objective functions: CCPP exergy efficiency, total cost rate of the system products and CO₂ emissions of the overall plant. The environmental impact in terms of CO₂ emissions is integrated with the exergoeconomic objective function as a new objective function. The results of both exergy and exergoeconomic analyses show that the largest exergy destructions occur in the CCPP combustion chamber, and that increasing the gas turbine inlet temperature decreases the CCPP cost of exergy destruction. The optimization results demonstrates that CO₂ emissions are reduced by selecting the best components and using a low fuel injection rate into the combustion chamber.     

Exergetic environmental assessment of life cycle emissions for various automobiles and fuels

This paper examines material emissions produced during thirteen fuel life cycles for automobiles, on mass and exergy bases. The masses of fuel life cycle emissions are compared with the chemical exergies of these emissions. For the emissions data used, the chemical exergy results suggest that compressed natural gas use in motor vehicles produces emissions that are the most out of equilibrium with the natural environment, relative to all other fuel life cycle paths considered. It is also shown that diesel use in grid-independent hybrid electric vehicles has the lowest chemical exergies of emissions of all thirteen fuel-vehicle combinations under consideration, suggesting a lower degree of potential environmental impact. The exergy methodology presented for assessing the potential for environmental impact may help in the development and design of transportation technologies that are more environmentally benign than those presently used.     

Exergetic pollution potential: Estimating the revocability of chemical pollution

The waste exergy approach to quantitative comparison of environmental impacts is considerably improved by proposing a separate accounting of material and energetic waste exergy and the implications are discussed within the context of sustainability. The exergy of mixing of a waste stream is found to be particularly well suited to an exergetic definition of chemical pollution and a correlative relationship with environmental pollutant cost (EPC) is suggested. A comprehensive measure of chemical environmental impact called pollution potential is defined as temperature multiplied by the change in configurational entropy per mole of pollutant in the environment. The result is related to the ideal thermodynamic work of chemical separation per mole required to instantaneously revoke a chemical pollutant, thereby returning the environment to a pristine reference condition. The current pollution potentials and total exergy of revocation of several notable atmospheric pollutants are estimated. Carbon dioxide is found to have low pollution potential in comparison to most halogenated hydrocarbons, but the vast quantities of anthropogenic carbon dioxide in the atmosphere would require much more total exergy of separation to revoke.     

Exergy,waste accounting,and life-cycle analysis

The authors argue that thermodynamics offers a means of accounting for both resource inputs and waste outputs in a systematic and uniform way. The new feature of the present work is to extend the applications of exergy analysis to resource and waste accounting and to present the results in an integrated analytical framework, namely, life-cycle analysis (LCA). We conclude that exergy is appropriate for general statistical use, both as a measure of resource stocks and flows and as a measure of waste emissions and potential for causing environmental harm.     

Engineering sustainability: thermodynamics,energy systems,and the environment

Thermodynamic concepts have been utilized by practitioners in a variety of disciplines with interests in environmental sustainability, including ecology, economics and engineering. Widespread concern about resource depletion and environmental degradation are common to them all. It has been argued that these consequences of human development are reflected in thermodynamic parameters and methods of analysis; they are said to mirror energy transformations within society. ‘Exergy’, a quantity which follows from the First and Second Laws of Thermodynamics, has been viewed as providing the basis of a tool for resource and/or emissions accounting. It is also seen as indicating natural limits on the attainment of sustainability. The more traditional use of the exergy method is illustrated by a number of cases drawn from the United Kingdom energy sector: electricity generation, combined heat and power schemes, and energy productivity in industry. This indicates the scope for increasing energy efficiency, and the extent of exergetic ‘improvement potential’, in each of these areas. Poor thermodynamic performance is principally the result of exergy losses in combustion and heat transfer processes. However, the application of such thermodynamic ideas outside the sphere of engineering has its critics. The link between the efficiency of resource utilization, pollutant emissions, and ‘exergy consumption’ is only indirect, and generally provides an insufficient basis for environmental appraisal. Methods of energy and exergy analysis are, therefore, evaluated as appropriate measures of sustainability in and beyond the energy sector. Copyright © 2004 John Wiley & Sons, Ltd.     

Application of the exergy method to environmental impact estimation: The ammonium nitrate production as a case study

The exergy method is used to compare different production processes and various methods for emission abatement with respect to their overall environmental impact. Some ammonium nitrate production processes are studied as examples, because the pollutants (ammonia and ammonium nitrate), emitted from these processes into the air and/or into the water, are really a feedstock and a product from the production process. Therefore, the essential result of the waste flows treatment is the recycling of the pollutants (ammonia and ammonium nitrate) back into the production process, decreasing simultaneously the exergy input and cumulative exergy consumption     

Comparative assessment of hydrogen production methods from renewable and non-renewable sources

In this study, we present a comparative environmental impact assessment of possible hydrogen production methods from renewable and non-renewable sources with a special emphasis on their application in Turkey. It is aimed to study and compare the performances of hydrogen production methods and assess their economic, social and environmental impacts, The methods considered in this study are natural gas steam reforming, coal gasification, water electrolysis via wind and solar energies, biomass gasification, thermochemical water splitting with a Cu–Cl and S–I cycles, and high temperature electrolysis. Environmental impacts (global warming potential, GWP and acidification potential, AP), production costs, energy and exergy efficiencies of these eight methods are compared. Furthermore, the relationship between plant capacity and hydrogen production capital cost is studied. The social cost of carbon concept is used to present the relations between environmental impacts and economic factors. The results indicate that thermochemical water splitting with the Cu–Cl and S–I cycles become more environmentally benign than the other traditional methods in terms of emissions. The options with wind, solar and high temperature electrolysis also provide environmentally attractive results. Electrolysis methods are found to be least attractive when production costs are considered. Therefore, increasing the efficiencies and hence decreasing the costs of hydrogen production from solar and wind electrolysis bring them forefront as potential options. The energy and exergy efficiency comparison study indicates the advantages of biomass gasification over other methods. Overall rankings show that thermochemical Cu–Cl and S–I cycles are primarily promising candidates to produce hydrogen in an environmentally benign and cost-effective way.     

Exergy as the confluence of energy,environment and sustainable development

The exergy of an energy form or a substance is a measure of its usefulness or quality or potential to cause change. A thorough understanding of exergy and the insights it can provide into the efficiency, environmental impact and sustainability of energy systems, are required for the engineer or scientist working in the area of energy systems and the environment. Further, as energy policies play an increasingly important role in addressing sustainability issues and a broad range of local, regional and global environmental concerns, policy makers also need to appreciate the exergy concept and its ties to these concerns. During the past decade, the need to understand the connections between exergy and energy, sustainable development and environmental impact has become increasingly significant. In this paper, a study of these connections is presented in order to provide to those involved in energy and environment studies, useful insights and direction for analyzing and solving environmental problems of varying complexity using the exergy concept. The results suggest that exergy provides the basis for an effective measure of the potential of a substance or energy form to impact the environment and appears to be a critical consideration in achieving sustainable development.     

Performance analysis of a waste‐heat‐powered thermodynamic cycle for multieffect refrigeration

A multieffect refrigeration system that is based on a waste‐heat‐driven organic Rankine cycle that could produce refrigeration output of different magnitudes at different levels of temperature is presented. The proposed system is integration of combined ejector–absorption refrigeration cycle and ejector expansion Joule–Thomson (EJT) cooling cycle that can meet the requirements of air‐conditioning, refrigeration, and cryogenic cooling simultaneously at the expense of industrial waste heat. The variation of the parameters that affect the system performance such as industrial waste heat temperature, refrigerant turbine inlet pressure, and the evaporator temperature of ejector refrigeration cycle (ERC) and EJT cycles was examined, respectively. It was found that refrigeration output and thermal efficiency of the multieffect cycle decrease considerably with the increase in industrial waste heat temperature, while its exergy efficiency varies marginally. A thermal efficiency value of 22.5% and exergy efficiency value of 8.6% were obtained at an industrial waste heat temperature of 210°C, a turbine inlet pressure of 1.3 MPa, and ejector evaporator temperature of 268 K. Both refrigeration output and thermal efficiency increase with the increase in turbine inlet pressure and ERC evaporator temperature. Change in EJT cycle evaporator temperature shows a little impact on both thermal and exergy efficiency values of the multieffect cycle. Analysis of the results clearly shows that the proposed cycle has an effective potential for cooling production through exploitation of lost energy from the industry. Copyright © 2014 John Wiley & Sons, Ltd.     

Exergetic life cycle assessment of a hydrogen production process

Exergetic life cycle assessment (ExLCA) is applied with life cycle assessment (LCA) to a hydrogen production process. This comparative environmental study examines a nuclear-based hydrogen production via thermochemical water splitting using a copper–chlorine cycle. LCA, which is an analytical tool to identify, quantify and decrease the overall environmental impact of a system or a product, is extended to ExLCA. Exergy efficiencies and air pollution emissions are evaluated for all process steps, including the uranium processing, nuclear and hydrogen production plants. LCA results are presented in four categories: acidification potential, eutrophication potential, global warming potential and ozone depletion potential. A parametric study is performed for various plant lifetimes. The ExLCA results indicate that the greatest irreversibility is caused by uranium processing. The primary contributor of the life cycle irreversibility of the nuclear-based hydrogen production process is fuel (uranium) processing, for which the exergy efficiency is 26.7% and the exergy destruction is 2916.3 MJ. The lowest global warming potential per megajoule exergy of hydrogen is 5.65 g CO₂-eq achieved a plant capacity of 125,000 kg H₂/day. The corresponding value for a plant capacity of 62,500 kg H₂/day is 5.75 g CO₂-eq.     

Methodology for inventorying greenhouse gas emissions from global cities

This paper describes the methodology and data used to determine greenhouse gas (GHG) emissions attributable to ten cities or city-regions: Los Angeles County, Denver City and County, Greater Toronto, New York City, Greater London, Geneva Canton, Greater Prague, Barcelona, Cape Town and Bangkok. Equations for determining emissions are developed for contributions from: electricity; heating and industrial fuels; ground transportation fuels; air and marine fuels; industrial processes; and waste. Gasoline consumption is estimated using three approaches: from local fuel sales; by scaling from regional fuel sales; and from counts of vehicle kilometres travelled. A simplified version of an intergovernmental panel on climate change (IPCC) method for estimating the GHG emissions from landfill waste is applied. Three measures of overall emissions are suggested: (i) actual emissions within the boundary of the city; (ii) single process emissions (from a life-cycle perspective) associated with the city's metabolism; and (iii) life-cycle emissions associated with the city's metabolism. The results and analysis of the study will be published in a second paper.     

Energy and exergy performance of residential heating systems with separate mechanical ventilation

The paper brings new evidence on the impact of separate mechanical ventilation system on the annual energy and exergy performance of several design alternatives of residential heating systems, when they are designed for a house in Montreal. Mathematical models of residential heating, ventilation and domestic hot water (HVAC–DHW) systems, which are needed for this purpose, are developed and furthermore implemented in the Engineering Equation Solver (EES) environment. The Coefficient of Performance and the exergy efficiency are estimated as well as the entropy generation and exergy destruction of the overall system. The equivalent greenhouse gas emissions due to the on-site and off-site use of primary energy sources are also estimated. The addition of a mechanical ventilation system with heat recovery to any HVAC–DHW system discussed in the paper increases the energy efficiency; however, it decreases the exergy efficiency, which indicates a potential long-term damaging impact on the natural environment. Therefore, the use of a separate mechanical ventilation system in a house should be considered with caution, and recommended only when other means for controlling the indoor air quality cannot be applied.     

Exergoeconomic analysis of hydrogen production using a standalone high-temperature electrolyzer

The conventional hydrogen production methods, primarily steam methane reforming and coal gasification, produce massive amounts of greenhouse gas emissions which significantly cause impacts on the environment. An alternative hydrogen production method is high-temperature electrolysis using Solid Oxide Electrolyzer that combines both high conversion efficiency and saleable high purity hydrogen production. The produced hydrogen can feed the various industrial processes at different scales in addition to offering an environmentally friendly storage option. The scope of this paper is to examine the economic feasibility of this technology through the utilization of the exergoeconomic concept, which traces the flow of exergy through the system and price both waste and products. Therefore, a standalone solid oxide electrolyzer of a 1MWe is considered for hydrogen production using renewably generated electricity. Having the detailed exergy analysis conducted in earlier studies, the focus of this article is on the costing of each exergy stream to determine the exergy cost and the potential changes outcomes as a result of the system operating or design parameters optimization. It is found that the cost of hydrogen production through the modular high-temperature electrolyzer varies between $3-$9/kg with an average of about $5.7/kg, respectively.     

The effects of hydrogen fuel usage on the exergetic performance of a turbojet engine

In this study, the hydrogen fuel effect on the exergetic performance of a turbojet engine used in a military trainer aircraft is investigated. For the first step, the performance assessments of the exergetic performance are conducted according to jet fuel usage and the actual test cell data of the engine. For the second step, an exergetic evaluation is parametrically estimated to use the hydrogen fuel in the engine. Finally, the performance results of the engine run by jet fuel are compared with the performance results of the engine run by hydrogen fuel. Regarding the results of this study, by using hydrogen fuel in the engine, the exergy efficiency of the engine decreases from 15.40% to 14.33%, while the waste exergy rate increases from 6196.51 kW to 6669.4 kW. At the same time, the exergy rate of the fuel rises from 7324.87 kW to 7785.25 kW, hence the specific fuel exergy of the hydrogen fuel is higher than that of the jet fuel. The waste exergy flow cost of the engine rises from 16.52 × 10^?3 US$/kW to 17.79 × 10^?3 US$/kW. The environmental effect factor of the engine escalates from 5.49 to 5.98 and the ecological effect factor increases from 6.49 to 6.98. On the other hand, the exergetic sustainability index of the engine reduces from 0.182 to 0.167 when the sustainable efficiency factor of the engine goes down from 1.182 to 1.167. Between the components, for both jet fuel and hydrogen fuel, the CC has the highest values of the fuel exergy waste ratio, the relative waste exergy ratio, the product exergy waste ratio, the fuel ratio indicator, the product ratio indicator, the waste exergy cost flow, the environmental effect factor, the ecological effect factor, and the exergetic improvement potential when the CC has the lowest values of the exergy efficiency, exergetic sustainability index, and sustainable efficiency factor, respectively. The reason for this result is that the combustion process contains high irreversibities. The obtained results indicate that the hydrogen fuel usage in the turbojet engine badly affects the exergetic performance of the engine and its components (especially the combustion chamber) hence the specific exergy of the hydrogen fuel is higher than the jet fuel's. On the other hand, the exhaust emissions emitted to the environment decrease from 0.509 kg/s to 0.0045 kg/s with the hydrogen fuel usage.