PE纤维掺量对水泥基复合材料力学性能的影响

针对PE纤维掺量对水泥基复合材料力学性能的影响,开展不同PE纤维掺量下水泥基复合材料的抗压强度、抗折强度、弯曲韧性、直接拉伸性能的试验研究,分析PE纤维水泥基复合材料的开裂模式,通过环境扫描电镜观察和分析薄板弯曲试验中PE纤维的破坏模式。研究表明,不大于2%的PE纤维掺量对水泥基复合材料的抗压强度没有明显改变;当PE纤维掺量大于1%后,PE纤维水泥基复合材料薄板在弯曲荷载作用下表现出极强的韧性特征和变形能力;当纤维掺量大于1.5%时,在直接拉伸荷载作用下PE纤维水泥基复合材料表现出显著的应变硬化特征,并且呈现多缝开裂的稳态破坏模式.     

亚高温作用下国产ECC早期力学性能研究

为研究不同亚高温作用下国产高延性水泥基复合材料（ECC）的早期力学特性,通过抗压试验、单轴拉伸试验、四点弯曲试验和断裂性能试验,分析了50℃、100℃、150℃、200℃4种不同亚高温作用下国产ECC早期抗压性能、拉伸性能、弯曲性能及断裂性能的变化规律。试验结果表明：亚高温有利于国产ECC早期抗压强度及断裂韧度的提升,其抗压强度和断裂韧度均随温度的升高逐渐增强;50℃的亚高温作用可提高国产ECC早期拉伸性能与弯曲性能;100℃温度作用下,国产ECC部分力学特性已经劣化,但仍具有优异的抗变形能力;在温度继续升高后,国产ECC早期抗变形能力明显减弱,但强度性能得到显著提升;国产ECC经不同亚高温作用后仍可保持良好的早期力学性能。     

纳米纸/聚合物基复合材料加热过程数值模拟分析

为了研究加热过程中纳米纸加热片的埋入方式及加热功率等因素对纳米纸/聚合物基复合材料温度分布的影响,采用FLUENT软件分析了矩形弯曲及平板形纳米纸/聚合物基复合材料达到稳态时的温度分布规律。模拟结果表明:相同加热功率作用下,平板形纳米纸/聚合物基复合材料达到稳态时典型温度相对较高,但是温度分布也更不均匀。加热过程中平板形及矩形弯曲纳米纸/聚合物基复合材料的典型温度均随加热功率的增大成线性增长。和矩形弯曲纳米纸/聚合物基复合材料相比,平板形纳米纸/聚合物基复合材料温度升高的速率相对更快。分析认为,纳米纸加热片的单位体积内热源越大,其升温速率越快,纳米纸/聚合物基复合材料达到稳态时温度越高,同时温度分布均匀性越差。     

功能无纺布插层复合材料的结构阻尼性能

以负载定量聚偏二氟乙烯的尼龙无纺布为功能插层,采用共固化工艺制备碳纤维增强环氧树脂基结构阻尼复合材料.测试复合材料的弯曲强度、弯曲模量和层间剪切强度等静态力学性能和储能模量和损耗因子的温度谱.此外,通过单悬臂梁振动实验评价阻尼减振性能.通过光学显微镜和扫描电镜分析共固化复合材料的微观结构,研究了阻尼机理.结果表明,在复合材料层间插入改性的尼龙无纺布能在不引起力学性能明显下降的前提下,显著提高复合材料的阻尼性能.其中插入7层改性的PNF插层的复合材料损耗因子达到0.008 3,比无插层复合材料提高了72.9%,弯曲模量下降了16.3%.     

复合材料波纹夹层结构弯曲性能研究

为研究不同芯层结构弯曲性能,对芯板结构为矩形、梯形、三角形和余弦形的复合材料波纹板进行三点弯曲试验,利用ABAQUS仿真软件对复合材料夹层结构进行试验仿真.仿真结果表明在相同尺寸、厚度和晶格数目条件下,夹层结构芯层和下面板首先发生破坏.通过对不同芯层弯曲刚度计算可知,矩形芯板弯曲刚度较高.     

膨润土/环氧树脂复合材料的制备与性能研究

以钙基膨润土和环氧树脂为原料,制备膨润土/环氧树脂复合材料.对其结构和性能进行研究,通过X射线衍射(XRD)、红外光谱(FT-IR)等对制备的复合材料进行表征.结果表明:膨润土/环氧树脂复合材料的力学性能与环氧树脂相比有明显提高,当复合材料中膨润土的质量分数为1.5%时,复合材料的弯曲性能、拉伸性能和冲击性能最强.     

养护温度对高延性水泥基材料力学性能的影响

研究养护温度对高延性水泥基复合材料性能的影响,分析养护温度在20、40、60和80℃时水泥基复合材料的抗弯性能、抗压强度、抗折强度及裂缝分布特点.结果表明,养护温度越高,高延性水泥基复合材料的早期跨中挠度越小;养护温度高于40℃时,试件的跨中挠度和韧性指数随龄期延长无明显变化;高养护温度能显著提高高延性水泥基复合材料的早期抗压强度和抗折强度,龄期对高温养护条件下高延性水泥基复合材料的抗压、抗折强度影响不大;粉煤灰掺量相同时,常温养护下高延性水泥基复合材料的裂缝更加细密均匀;养护温度为60℃时,粉煤灰掺量提高至80%,高延性水泥基复合材料的韧性显著提高,28d抗压强度可达70MPa.     

FLUENT模拟分析巴基纸基复合材料的温度场分布

为了研究加热过程中加热功率及聚合物基体导热系数等因素对巴基纸基复合材料达到稳态所需时间及温度场分布的影响规律,采用有限元软件FLUENT分别模拟了不同工况条件下矩形弯曲、正弦形及平板形巴基纸增强聚合物基复合材料的热传导性能。计算结果表明:三种形状巴基纸基复合材料加热达到稳态后整体温度水平均随加热功率的增大呈线性增长,且巴基纸基复合材料达到稳态时所需时间也随加热功率的增大而延长。随着聚合物基体材料导热系数的增大,巴基纸基复合材料温度分布更加均匀,且巴基纸基复合材料达到稳态所需要的时间越短。分析认为,加热功率对巴基纸基复合材料温度分布规律的影响主要通过巴基纸加热片的单位体积热源起作用;聚合物基体导热系数增大利于巴基纸加热片热量的散出,因此缩短了巴基纸基复合材料达到稳态的所需时间。     

Re2O3弥散强化Ag基复合材料的制备与性能

目的 采用稀土氧化物(Re2O3)进行弥散强化,探讨稀土氧化物种类及掺量对复合材料的性能影响,提高Ag基复合材料的熔化温度和力学性能.方法 通过化学共沉积制取了Re2O3/Ag复合粉体,并在35 MPa下压制成型,进而在氩气保护下850℃高温烧结.制备出稀土氧化物弥散分布的银基复合材料样品,并对其熔化温度、力学性能等指标进行测试.结果 Y2O3掺量为4%时可获得最大的溶化温度为975℃,掺量为1%时可获得最大的抗拉强度.延伸率随Re2O3质量分数的增加而下降.结论 Re2O3弥散强化Ag基复合材料的熔化温度、力学 性能较纯Ag有所提高,可作为OPIT工艺的包套材料.     

超高性能水泥基材料的力学行为及机理分析

研究安防系统对超高性能水泥基复合材料工作性及超高力学性能的特殊要求,以大掺量超细工业废渣取代水泥,掺加超高硬度细集料,采用高温干热养护制度,成功制备出一种超高性能水泥基复合材料.对其工作性及不同养护温度和养护时间下的力学性能进行测试,结果表明,制备的材料具有较好的工作特性及超高力学性能,可满足安保产品要求,其抗压强度最高可达240 MPa.采用X射线衍射技术、差热-热重分析方法及扫描电镜对其微观结构形成进行分析,结果显示,超高硬度细集料与胶凝材料的强物理结合使其在复合材料中起增强相的作用,高温养护加速了水泥的水化及矿物惨合料的火山灰反应,降低了材料中Ca(OH)2的含量,增加了C-S-H凝胶的含量,提高了材料的密实度,改善了界面微观结构,提高了超高性能水泥基复合材料的宏观力学性能.     

固化剂用量对SF/UF共混复合材料力学性能的影响

剑麻纤维(SF)经碱处理后与自制的低毒改性脲醛树脂(UF)、固化剂等原料进行捏合、模压成型,制成SF/UF共混复合材料,研究了不同固化剂用量对复合材料力学性能的影响:并用DSC对树脂进行了固化分析,采用扫描电镜(SEM)对材料的微观形貌进行了观察.结果表明,固化剂用量对复合材料的力学性能有较大影响:用量为1.0%时,复合材料的冲击强度达到12.39 kJ/m2,磨损体积仅为1.47×10 mm3,弯曲强度达到了55.24 MPa.     

Physical and Mechanical Properties of PP Composites based on Different Types of Lignocellulosic Fillers

The presents preparation and characterization of different types of lignocellulosic fillers (pine wood sawdust/ walnut shell flour/ black rice husk powder) reinforced polypropylene composites were presented. The effect of MAPP as coupling agent (4wt%) on the physical and mechanical properties was also investigated. Polypropylene composites were prepared at different rates of filler/matrix (wt%) by using extrusion (for melt blending) and hot compression molding process. Maximum values of tensile and flexural strength were obtained as 26.1 and 43.4 MPa, respectively, whereas the elongation at break value was 4.11% at 10% pine wood sawdust reinforced PP. Tensile and flexural modulus of composites reached the maximum values as 3855 and 3633 MPa with the composite of 30% walnut shell flour reinforced PP. Characterization of composites was carried out by using tensile test, flexural test, FT-IR, and SEM.     

包覆工艺制备C—SiC—B4C—TiB2复合材料的组织与性能

以鳞片石墨,B4C,SiC,TiO2为原料,利用包覆工艺在不同热压温度下制备了W（C）=50％的C—SiC—B4C—TiB2复合材料,并详细研究了热压温度对复合材料显微组织和性能的影响规律．结果表明,当热压温度高于1850℃时,复合材料由C,SiC,B4C和TiB2这四相组成;复合材料的体积密度、抗折强度和断裂韧性均随着热压温度的升高而增加．2000oC热压时,复合材料的体积密度、气孔率、抗折强度和断裂韧性分别达到2．41g／cm^3,3．42％,176MPa和6．1MPa·m^1/2;热压温度升高,复合材料的碳相和陶瓷相逐渐致密,碳相最终形成了在陶瓷基体上镶嵌的直径为40μm橄榄球状和条状这两种形貌．碳／陶瓷相的弱界面分层诱导韧化和第二相TiB2与陶瓷基体之间热膨胀系数不匹配所致的残余应力使变形过程中微裂纹的扩展路径发展变化,使复合材料的韧性提高．     

Property of three-dimensional silica composites

Silica fibers-reinforced, fused silica composites were fabricated with repeated vacuum-assisted liquid-phase infiltration. The mechanical properties, thermal properties, and ablative properties of the samples were evaluated. The effect of the silica fiber content and treatment temperature on the flexural strength of the three-dimensional SiO2 （3-D SiO2） composites also was investigated. The SiO2 composites show good mechanical properties and excellent ablative performance. The flexural strength increases with an increase in silica fiber content, and decreases with an increase in treatment temperature. When the volume fraction of the silica fiber is 50vo1% and the treatment temperature is 700℃ the flexural strength of the composites reaches a maximum value of 78 MPa. By adding cyclohexanone surfactant, the infiltration property can be largely improved, resulting in the density of SiO2 composites increasing up to 1.65 g/cm^3. The fracture surfaces of the flexural specimens observed using SEM, show that the pseudoplasticity and the toughening mechanisms of the composites are caused by absorption of a lot of energy by interface debonding and fiber pulling out.     

填料对木塑复合材料弯曲性能的影响

大掺量添加填料可以大幅度地降低生产成本,但同时也会对材料性能产生一定影响.试验研究了木粉、碳酸钙、粉煤灰的掺量对木塑复合材料弯曲性能的影响.结果表明：随着木粉掺量的增加,木塑材料的弯曲强度先增加后降低,当木粉掺量达到60%时,弯曲强度达到最大值.随着碳酸钙掺量的增加,木塑材料的弯曲强度先增加后降低,当其掺量达到30%时,弯曲强度达到最大值,掺加粉煤灰也呈现相同规律.     

Analysis of Mechanical Characteristics of Fly Ash Cenospheres Reinforced Epoxy Composites

Fly ash cenospheres(FACs) as a recycling material of industrial waste has become a competitor for other inorganic particle fillers. Epoxy resin(EP) composites reinforced with different content of FACs as well as different size grading ratio were prepared. The surface modification of FACs particles was conducted before incorporating into EP matrix. The impact and flexural strengths and the flexural modulus were investigated, and the fracture surfaces of the testing samples were analyzed using SEM. Results showed that FACs had an obvious effect on the mechanical characteristics of the FACs/EP composites. With increasing weight fraction of FACs, the impact and flexural strengths and the flexural modulus of EP composite samples increased, and reached the highest values when the weight fraction of FACs reached 15 wt%. The mechanical characteristics of the FACs/EP composites however deteriorated with further increasing of FACs content. For the EP composites reinforced with different size grading ratio of FACs, the larger proportion of small FACs particles, the better mechanical properties of the EP composites. The results were analyzed from the aspect of the plastic deformation, new surface formation and fracture absorption energy. The synergistic effect of the size grading ratio of FACs was not obvious, which would be further investigated.     

Preparation and properties of C/C-SiC brake composites fabricated by warm compacted-in situ reaction

Carbon fibre reinforced carbon and silicon carbide dual matrix composites(C/C-SiC) were fabricated by the warm compacted-in situ reaction.The microstructure,mechanical properties,tribological properties,and wear mechanism of C/C-SiC composites at different brake speeds were investigated.The results indicate that the composites are composed of 58wt%C,37wt%SiC,and 5wt%Si.The density and open porosity are 2.0 g.cm~(-3) and 10%,respectively.The C/C-SiC brake composites exhibit good mechanical properties.The ...     

Mechanical behavior and microstructure characterization of 3D stitched quartz fibers-reinforced silica composites

The mechanical properties of silica material in the monolithic form are ;far from acceptable levels. In this paper, 3D stitched quartz preform was used for the fiber reinforcement, and quartz fibers- reinforced silica composites were prepared by the silica sol-infiltration-sintering method. The density of the composite was up to 1.71 g/cm3 after 10 infiltration-sintering cycles. The flexural strength and the in-plane shear strength were 61.7 MPa and 20.3 MPa, respectively. The flexural stress-deflection curve exhibited mostly nonlinear behavior, which was different from that of monolithic ceramics. Because of the existence of the fiber in Z axis direction, shearing property between the different layers of 3D stitched composites were greatly enhanced. Toughness effect of the 3D stitched quartz preform was conspicuous. The as-fabricated composites showed non-catastronhic failure behavior resulting from weak fiber/matrix interface.     

Influence of an Optimized Fibre Coating on Interfacial and Mechanical Properties of Glass Fibre／Polypropylene Composites

The influence of pretreatment of fibre on interfacial and mechanical properties of glass fibre/polypropylene composites was investigated.Firstly,the glass fibres were coated with the blends of m-IPP(maleic anhydride grafting isotatic polypropylene)and m-APP(maleic anhydride grafting amorphous polypropylene)in different ratios.Secondly,the interfacial reaction of the coated composites was analysed by FTIR，which shows that the interfacial chemical reaction reaction between m-IPP/m-APP in the fibre coating and the fibre suface-bound coupling agent is in existence.Thirdly,the microstructure of the coated composites was studied by SEM.The results indicate that the coating treatment if effective on improving interfacial adhesion of the fibre-matrix and the right amount of m-APP added to the coat impels the plastic deformation surrounding the point of cracks,which makes cracks turn to region and prevents from further interface debonding.Lastly,the mechanical properties were evaluated by measurement of the flexural strength and impact strength of the composites.It was fond that the flexural strength and impact strength of the composites with coating fibre are higher than those of uncoating fibre composite.The results of these investigations draw the conclusion that the pretreatment of fibre with m-IPP/m-APP blends can form an optimize interlayer between the fibre and the PP matrix,which improves both the strength and toughness of the composites.