共查询到18条相似文献,搜索用时 93 毫秒
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稀土长余辉发光材料的开发应用与改性处理 总被引:12,自引:0,他引:12
介绍了以铝酸盐为基质以铝酸盐为基质稀土为激活剂或主激活剂的新型光致长余辉的特点、开发现状、应用领域及蓄光机理。重点综述了将蓄光体制成性能优良的发光树脂、发光陶瓷、着色蓄光性复合体及用作灯粉时的改性处理工艺、产品特点和用途。 相似文献
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长余辉发光材料是属于光致发光材料的一种,是指经日光和长波紫外线等光源的短时间照射,关闭光源后,仍能在很长一段时间内持续发光的材料。由于稀土长余辉发光材料的储光-发光的特性,它们可作为发光涂料、发光薄膜、发光油墨、发光纤维、发光纸等,在建筑装潢、军事设施、交通运输、消防应急等领域得到了广泛应用。 相似文献
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稀土离子掺杂对长余辉发光玻璃发光性能的影响 总被引:2,自引:0,他引:2
选择制备了系列Eu^2+,Dy^3+共掺杂的硼铝酸锶长余辉发光玻璃。利用发光光谱、余辉衰减曲线、热释光谱系统研究了稀土离子掺杂对长余辉玻璃发光性能的影响。研究结果表明,不同掺量组合的Eu^2+及Dy^3+对长余辉玻璃发光性能有不同影响,在Eu^2+及Dy^3+掺量比为l:l(摩尔比)的情形下,随Eu^2+离子掺量的增多,发光性能下降;在Eu^2+及Dy^3+掺量比为1:2的情形下,随Eu^2+离子掺量的增多,发光性能增强。在此实验基础上,围绕缺陷形态及其与稀土离子间的能量传递,提出了可能的长余辉机制。 相似文献
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硅酸镁锶(Sr2MgSi2O7)作为目前常用的一种长余辉发光材料基质,性能稳定,耐酸碱性能良好。本文介绍了长余辉发光材料的发光原理,综述了近年来Sr2MgSi2O7长余辉发光材料的主要制备方法以及稀土掺杂Sr2MgSi2O7材料的研究进展,并对该材料的发展做出了展望。制备Sr2MgSi2O7长余辉发光材料的方法主要包括高温固相法,溶胶-凝胶法,化学沉淀法和燃烧合成法,其中最常用的为高温固相法。通过掺杂稀土离子可以形成具有不同发光特性的长余辉发光材料。稀土掺杂Sr2MgSi2O7材料作为一种储能、节能的长余辉发光材料,展现出了广阔的发展和应用前景。 相似文献
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Progress of studies on various multi-color long afterglow luminescence materials was reviewed.Two luminescent mechanism of long afterglow behavior were discussed.Further research and development prospects about the materials were proposed. 相似文献
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Y1.94-xMgxO2S:0.06Ti (0≤x≤0.10) phosphors with long afterglow were synthesized by solid state reaction route. The photoluminescence spectra, decay curves, thermoluminescent spectra and chromaticity coordinate curves were investigated. The results show that the luminescence intensity of Y1.94-xMgxO2S:0.06Ti (0≤x≤0.10) phosphors decrease gradually with increasing Mg2 ion content, and the shape of luminescence spectra and chromaticity coordinate change as well. Furthermore, two thermoluminescent peaks in single Ti-doped Y2O2S sample are found at 91.8 and 221.5 ℃, respectively. Nevertheless, significant different spectra were found for the Mg, Ti co-doped Y2O2S samples that three thermoluminescence peaks appear at 52.3, 141.7 and 226.8 ℃, respectively. These results indicate that the co-doped Mg ion changes the inherent trap depth of single Ti-doped Y2O2S:Ti phosphor, and induces simultaneously a new trap level in the Y1.94-xMgxO2S:0.06Ti phosphor. Based on the analysis of thermoluminescent spectra, photoluminescent spectra, decay curve and crystal structure defect, it was proposed that the varied structure defect and introduced new trap level by the doped Mg2 ions should be responsible for reducing luminescence intensity and varying color in the Y1.94-xMgxO2S:0.06Ti phosphor. 相似文献
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Synthesis of Long Afterglow Photoluminescent Materials Sr_2MgSi_2O_7∶Eu~(2 ), Dy~(3 ) by Sol-Gel Method 总被引:1,自引:0,他引:1
Withtheprogressofsocialcivilizationanddevel opmentofmodernscienceandtechnology ,thedemandforluminescentmaterialskeepsincreasingduetoitsgreatsocialandeconomicbenefits .Therefore ,prepa rationofluminescentmaterialswasregardedbypeopleveryearly .Asanembellish… 相似文献
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SrAl2O4 :Eu2+, Dy3+ Long Afterglow Phosphors Prepared by Chemical Coprecipitation Method 总被引:1,自引:0,他引:1
SrAl2 O4: Eu2 , Dy3 long afterglow phosphors were prepared by chemical coprecipitation method. Ammonium carbonate and ammonium hydrogen carbonate were used as the precipitants. The preparation of the SrAl2 O4: Eu2 ,Dy3 precursor was completed at room temperature by controlling the concentration of the metal-salt solution, pH value of the system, etc. The phosphors were prepared by sintering the precursor at 1000 ~ 1200 ℃ in a weak reducing atmosphere for 2 h. The XRD, SEM, excitation spectra, emission spectra and afterglow decay of the samples were tested and the optimal synthesis conditions of the SrAl2O4: Eu2 , Dy3 long afterglow phosphors prepared by precipitation method were determined. The phosphor which had good luminescent properties is prepared and its persistent time can reach more than 1600 min. In the coprecipitation process, a small amount of glucose operates to refe the luminescent powders. The particle size of the phosphor can be less than 1 μm. The sintering temperature of the sample prepared by the coprecipitation method is much lower than that of the one prepared by the high temperature solid state method.Compared with the high temperature solid state method, a clear blue shift occurs in the excitation and emission spectra of the samples. 相似文献
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燃烧法合成新型蓝色硅酸盐长余辉材料及其发光性能的研究 总被引:17,自引:0,他引:17
采用燃烧法快速合成了Sr2MgSi2O7:Eu^2 ,Dy^3 新型蓝色长余辉材料,用x射线粉末衍射表征材料的相组成和晶体结构,用激发和发光光谱、余辉亮度对材料的发光性质进行表征并对该体系发光机制进行了讨论。结果表明,燃烧法和高温固相法合成的这种长余辉材料具有相同组成和结构,燃烧法可以快速制备出细粉体。合成材料的激发带峰值位于356nm,发射光谱峰值在475nm,是典型的Eu^2 的4f-5d跃迁所产生,余辉时间5h以上。 相似文献