边界润滑抗磨与降噪的机理分析

采用特殊配制的润滑油实现边界润滑,可以降低高达125dB(A)以上的钢轨矫直噪声和110dB(A)以上的车削噪 声,可以极大地延长恶劣接触状态下矫直辊模拟试件的使用寿命,由此提出表面微凸体油膜弹性支承物理模型。分析该 模型抗磨与降噪机理,并指出今后开展这一新概念研究的方向与意义。     

Influence of different surface modification technologies on friction of conformal tribopair in mixed and boundary lubrication regimes

Moving machine assemblies are generally designed to operate in full film lubrication regime to ensure high efficiency and durability of components. However, it is not always possible to ensure this owing to changes in operating conditions such as load, speed, and temperature. The overall frictional losses in machines are dependent on the operating lubrication regimes (boundary, mixed or full-film). The present work is thus aimed at investigating the role of different surface modification technologies on friction of a sliding bearing/roller tribopair both in boundary and mixed lubrication regimes. A special test rig comprising of two bearings was built for the experimental studies. Tribological tests were conducted in a wide speed range to enable studies in boundary and mixed lubrication regimes. The influence of application of different surface modification technologies on both the sliding bearing and the roller surfaces on friction has been studied. The rollers used in these studies were provided with five different coatings (hard DLCs and a soft self-lubricating coating). Additionally, two uncoated rollers having different surface roughness were also studied. Uncoated bearings were used in all tribopairs except two. These two bearings were coated with DLC and phosphate coatings respectively and uncoated rollers were the mating counterparts. Friction measurements were made on the new as well as the previously run-in surfaces. It was found that the rollers with self-lubricating coating resulted in lowest boundary friction closely followed by the rollers with the hardest DLC coatings. The DLC coating applied on to the bearing showed lower boundary friction after running-in. Mixed friction has been found to be mainly dependent on the surface topography characteristics of both the original and the run-in surfaces of bearings and rollers. The harder DLC coatings and the phosphated bearing showed the lowest mixed friction due to an efficient running-in of the bearing surface.     

Friction reduction in low-load hydrodynamic lubrication with a hydrophobic surface

A novel tribometer capable of measuring low friction forces and low loads at high speeds has been employed to measure the friction coefficient in a pure sliding, ball-on-flat contact in hydrodynamic lubrication conditions. The tribometer was custom-built for measuring friction at low loads, to allow the authors to investigate the feasibility of using the liquid-slip phenomenon for the lubrication of high-sliding MEMS. The theory behind lubrication with liquid slip and its effect on friction is briefly discussed. Contacting surfaces were treated to create hydrophobic/hydrophilic or hydrophilic/hydrophilic pairs. Hydrophobic surfaces were made by coating mica with a self-assembled silane monolayer while the hydrophilic surfaces used were freshly cleaved mica and plasma-cleaned steel. Experiments were conducted at sliding speeds of up to 2 m/s and loads below 0.2 N. An aqueous glycerol solution was used as lubricant. Results obtained with hydrophilic/hydrophilic surfaces were in accord with hydrodynamic lubrication theory. Tests with hydrophobic/hydrophilic surfaces revealed a reduction in friction, which may be attributed to lubricant slip against the hydrophobic surface.     

Comparative study of the tribological properties of various modified mild steels under boundary lubrication condition

AISI1045 steel was modified by laser heat-treatment and conventional heat treatment. The friction and wear behaviors of the steel specimens after various surface modifications sliding against SAE52100 steel under the lubrication of liquid paraffin containing sulphurized olefin were comparatively investigated on an Optimol SRV oscillating friction and wear tester. The worn surface morphologies of the modified steel specimens were analyzed using a scanning electron microscope. The elemental compositions and chemical states of some typical elements on the worn surfaces of the modified steel specimens were analyzed with an energy dispersive X-ray analyzer and X-ray photoelectron spectroscope, respectively. It was found that the laser heat-treated specimen showed the highest hardness and best wear-resistance. The laser heat-treated and conventionally heat treated AISI1045 steel specimens sliding against SAE52100 steel under the lubrication of liquid paraffin containing sulphurized olefin registered smaller friction coefficients than under the lubrication of liquid paraffin alone. This was partly attributed to the increased hardness of the modified specimens. The tribochemical reaction between the steel and the active elements in the additive was involved in the sliding of the modified steel specimens against SAE52100 steel ball under the boundary lubricating condition, with the formation of a surface protective film composed of various tribochemical products. This also contributed to improve the friction and wear behavior of the modified steel specimens. The steel specimens subject to different surface modifications showed differences in the wear mechanisms under the boundary lubricating condition as well. Namely, the tempered steel specimen was mainly characterized by plastic deformation and pitting, the quenched specimen by grooves and delaminating, and the laser heat-treated one by polishing and mild adhesion.     

Tribological behavior of PEEK-based materials under mixed and boundary lubrication conditions

In modern industries, more and more mechanical components are exposed to mixed and even boundary lubrication conditions, inducing fast wear and even scuffing of the motion systems. In order to enhance the lifetime and reliability of the motion systems, replacing metal–metal friction pairs by metal–polymer ones can be one of the most effective approaches. The present work focuses on tribological behavior of pure polyetheretherketone (PEEK) and a formulated PEEK composite lubricated with diesel and engine oil. It was demonstrated that in mixed and boundary lubrication regimes the structure of PEEK materials affect significantly the tribological performance. Formation of a tribofilm on the surface of metallic counterbody plays an important role on the tribological behavior of the PEEK-based materials.     

Molecular orbital indexes criteria for friction modifiers in boundary lubrication

Friction modifiers, due to their adsorption onto metal surfaces, play an important role in boundary lubrication. The molecular orbital indexes were used as the criteria to study the interaction between lubricant polar end groups and metal surfaces. By comparing the net electric charge of bonding atoms, the highest occupied molecular orbital energy (E_HOMO) and the lowest unoccupied molecular orbital energy (E_LUMO) of interactive molecules, one could find that the hydrogen bond strength between alcohol and oxide metal surface which is hydroxylated was stronger than that between a hydroxylated oxide metal surface and ester. On the other hand, the interaction between naked aluminium atoms and ester is stronger than that between naked aluminium atoms and alcohol. Thus, lubricants consisting of alcohol and ester show a combination friction-reducing effect because each of the two components has its own advantages in interaction with the hydroxylated aluminium oxide and naked aluminium atoms on the lubricated interface.     

Effect of high-pressure rheology of lubricating oils on boundary lubrication

High-pressure rheology of lubricating oil was determined using different experiments, and the phase diagram was drawn. The four-ball wear tests were used to evaluate anti-wear characteristics of oils in boundary lubrication condition. The bridged ring compound oils showed the minimum wear scar in the four-ball wear tests. The diameter of wear scar decreases with increasing the elastohydrodynamic film-forming capability. Next, we considered the molecular packing parameter T_VE−T at the four-ball wear test. The T_VE−T values of bridged ring compound oils were in the range 250-360 and oils were elastic-plastic solid. It is concluded that the solidified oil film under boundary lubrication conditions has the anti-wear action.     

Measurements of friction in strip drawing under thin film lubrication

Strip drawing is used to investigate the friction behaviour under thin film lubrication in metal forming with plastic deformation. Friction coefficients are measured under a wide range of tribological conditions. The surface roughness is measured on an interferometric profilometer. The results show that the friction coefficient decreases with increasing oil film thickness h_w, as estimated using a formula appropriate for smooth tool and workpiece. Measurements of the surface topography show that change in friction is associated with a change in contact ratio between the tool and strip. The effect of strip reduction, strip roughness and die roughness on the friction coefficient is also investigated.     

Reduction of Friction by Functionalised Viscosity Index Improvers

A range of functionalised polymethacrylate copolymers have been synthesised with different functionalities, polymer architecture and molecular weight. It is shown that appropriately functionalised block copolymers give enhanced film thickness and greatly reduced friction under low entrainment speed conditions, even with polymer concentration as low as 1% wt. This behaviour almost certainly results from the formation of an adsorbed brush-like film of thickness ca 20 nm on each polar surface. These films provide a highly viscous inlet that promotes fluid entrainment and thus maintains a separating film down to very low entrainment speed. The adsorbed polymer films are also able to maintain separation in stationary contact conditions. Randomly distributed copolymers do not show this type of behaviour. The friction reduction observed is more effective in unidirectional, mixed sliding–rolling than in reciprocating, sliding conditions. However, it is found that functionalised polymers and conventional organic and molybdenum-based friction modifiers can be combined to provide effective friction reduction over the whole range of rubbing conditions.     

Tribological behavior of vegetable oil-based lubricants with nanoparticles of oxides in boundary lubrication conditions

This work studied the development of vegetable based lubricants and the addition of oxides nanoparticles (ZnO and CuO) as additive for extreme pressure (EP), exploring the EP and oil base influence in tribological behavior. The results showed that with the addition of nanoparticles to conventional lubricant, the tribological properties can be significantly improved. A smoother and more compact tribofilm has formed on the worn surface, which is responsible for the further reduced friction and wear. Also, lubricants developed from modified vegetable oil can replace mineral oil, improving the tribological and environmental characteristics. However, the addition of nanoparticles in vegetable base lubricants is not beneficial to wear reduction.     

Surface generation and boundary lubrication in bulk forming of aluminium alloy

The electrical contact resistance is measured between the tool and workpiece during plane strain compression of aluminium strip coated with a non-conductive oxide film produced by anodising. Results are correlated with the observed oxide topography after the test. The purpose is to investigate the mechanism of the development of close metal-to-metal contact, the associated material transfer and their effects on the friction coefficient under boundary lubrication conditions. Initially the anodised layer provides electrical insulation between the tool and the strip but, as deformation proceeds, this layer breaks up and fresh metal is extruded through the cracks formed, causing a sharp fall in electrical resistance. Details of this behaviour are explored, showing a dependence not only on strip reduction, but also on the base oil used and the presence of boundary additives. The change in the behaviour is tracked as a transfer layer builds up on the tool.     

Combination of DLC coatings and EP additives for improved tribological behaviour of boundary lubricated surfaces

The aim of the present investigation was to obtain some further understanding of the mechanism responsible for low-friction behaviour of W-containing DLC coatings (W-DLC) when lubricated with EP additivated oil. Boundary lubricated wear and friction tests were performed under reciprocating sliding motion using a high frequency test rig and a contact pressure of 1.5 GPa. Additionally, some of the tests were performed in a load-scanning reciprocating test rig, with the contact pressure being in the range from 2.4 to 5.6 GPa. The influence of concentration of a sulphur-based EP additive on the friction behaviour was investigated.This investigation showed that W-DLC coatings greatly improve the tribological properties of boundary-lubricated surfaces, especially when pairing coated and uncoated steel surfaces. The improved tribological behaviour was found to be governed by the gradual formation of a WS₂ type tribofilm on the steel counter-face or on revealed steel substrate. The friction level depends on the additive concentration.     

Boundary lubrication mechanisms of carbon coatings by MoDTC and ZDDP additives

Fuel economy and reduction of harmful elements in lubricants are becoming important issues in the automotive industry. An approach to respond to these requirements is the potential use of low friction coatings in engine components exposed to boundary lubrication conditions. Diamond-like-carbon (DLC) coatings present a wide range of tribological behavior, including friction coefficients in ultra-high vacuum below 0.02. The engine oil environment which provides similar favourable air free conditions might lead to such low friction levels.In this work, the friction and wear properties of DLC coatings in boundary lubrication conditions have been investigated as a function of the hydrogen content in the carbon coating. Their interaction with ZDDP which is the exclusive antiwear agent in most automotive lubrication blends and friction-modifier additive MoDTC has been studied. Hydrogenated DLC coatings can be better lubricated in the presence of the friction-modifier additive MoDTC through the formation of MoS₂ solid lubricant material than can non-hydrogenated DLC. In contrast, the antiwear additive ZDDP does not significantly affect the wear behavior of DLC coatings. The good tribological performances of the DLC coatings suggest that they can contribute to reduce friction and wear in the engine, and so permit the significant decrease of additive concentration.     

Molecular basis of lubrication

The advent of micro-electromechanical devices (MEMs), sensors, actuators, microsystems, and nanotechnology have called to attention the effect of friction on moving parts in nano/micro devices. To take full advantage of the opportunity to sense, compute, and actuate in real time, fast-moving parts are often necessary or desirable. As the scales of the components shrink, adhesion, stiction, friction, and wear become a significant technological barrier for the successful deployment of durable devices. Most current devices in production avoid such contacts.The nature of the surface contacts, as component scale moves from macro to micro to nano, is dominated by surface forces that normally are dwarfed by mechanical loading. Therefore nanolubrication needs to take into account different factors than conventional lubrication concepts. This paper compares traditional lubrication concepts and those necessary for nanolubrication and proposes various nanometer scale thick lubricating film designs as a means to control the surface properties of surfaces at nano/micro scales.Many of the concepts derive their origin from studies and observations from the magnetic hard disk technology where a “monolayer” of lubricant protects the system and has proven to be robust and safe. Examples from magnetic hard disks will be used to illustrate some of the concepts.     

Ferrocene derivatives in boundary lubrication

Model friction and thermal investigations have been carried out to study the most reactive of the ferrocene derivatives tested so far—1,1′-diethyl-2-thia[3]ferrocenophane. The analysis of the results obtained from model friction investigations points to the reactive character of both sulphur and ferrocene iron in reactions with the surfaces of the samples tested. The presence of ferrocene derivative reaction products on the surface of the metal samples studied has been confirmed by means of instrumental analytical methods     

A microwedge model of sliding contact in boundary/mixed lubrication

A refined friction model of sliding contact in boundary/mixed lubrication regime is developed. In addition to the well-known asperity flattening and roughening effects, significant deformation of asperities can be incited by the elastic microwedges on the tool surface. A model of asperity deformation, which includes the effects of smoothing, roughening, and microwedge, is proposed for processes where smooth tool and rough workpiece are used. A finite element formulation incorporating the microwedge effect in the Reynolds equation for lubricant flow is also derived. Numerical results showed that the inclusion of microwedge in the analysis provides a good agreement with the experimental measurements, especially with many interesting phenomena that can be neither explained nor predicted by the other friction models.     

Alternative and low sulfur fuel options: boundary lubrication performance and potential problems

Studies of alternative fuels at Penn State include biodiesel, dimethyl ether (DME) and low sulfur diesel fuels. The fuel studies include bench tests, laboratory engine tests and vehicle tests. DME was evaluated in a campus shuttle bus operating on its regular campus route. A 25:75 vol% mixture of DME and diesel fuel was used. Laboratory engine tests of oxygenated fuels, including biodiesel, resulted in significant particulate reductions. However, some alternative fuels exhibit low lubricity. Bench tests comparing friction and wear characteristics of the fuels are described.     

On the effort to discriminate the principal function of tribofilm on friction under the boundary lubrication condition

Friction coefficient under boundary lubrication conditions is affected by many factors. In order to study the friction characteristic of tribofilm, friction coefficient of tribofilm formed on steel disk under the boundary lubrication conditions was separately measured under dry condition using a laboratory-made micro-tribometer to eliminate the hydrodynamic lubrication action of fluid. This paper introduces the approaching method to understand the friction characteristic of tribofilm. In this paper, sliding speed dependency of friction exerted by tribofilm was observed that could not be interpreted by the classical boundary lubrication mechanisms. The additives having long alkyl chain showed strong sliding speed dependency of friction.     

Molecular aspects of boundary lubrication

Recent molecular dynamics computer simulations of boundary lubrication, in which the lubricant and sliding solid surfaces are represented at an atomistic level, have given new insights into the mechanism of boundary lubrication. Combined with recent data from experiments on sliding surfaces, these simulations have forced us to modify our traditional view of lubrication in this regime. Stick-slip behaviour at low sliding velocities, discontinuous shear velocity profiles across the gap and lubricant states oscillating between solid-like and liquid-like extremes are some of the phenomena that occur in boundary lubrication. The Eyring model is discussed and directions for improvements proposed that would encompass stick-slip behaviour.     

A computer model of mixed lubrication in point contacts

A numerical model of mixed lubrication is presented in this paper. The idea introduced here is that asperity contact may be viewed as a result of a continuous decrease in film thickness, so that the transition between contact and non-contact is continuous and the same mathematical model should work for both regions. The pressure over the thin films is assumed to obey the Reynolds equation, and the solution of the equation, under the condition of h→0, is expected to be the same as that predicted by the theory of elasticity. To achieve convergent and stable solutions, the left-hand side terms of the Reynolds equation are switched off when the local film thickness approaches zero, leading to a reduced Reynolds equation. Pressure distributions over the entire computation domain are thus obtained through solving a unified equation system without identifying hydrodynamic or asperity contact regions. Computations were conducted for several example cases and results show that convergent solutions are achievable on different types of roughness, over a wide range of λ ratios (0.01 to infinity), and for different slide-to-roll ratios (0.0–2.0).