共查询到20条相似文献,搜索用时 171 毫秒
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日常生活中人们一般都知道在微波炉中不能使用金属器皿进行加热 ,因为金属会反射微波辐射从而影响到烹饪效果。但美国科学家一项新的研究发现表明 ,金属处于粉末状态时对微波辐射会有很强的啄性 ,利用这一特性可为汽车等行业加工出高性能的金属部件。美国宾夕法尼亚州立大学材料研究实验室的科学家在最新一期英国《自然》杂志上介绍说 ,他们在研究中采用 2 45kHz的微波场来对铁、镍、钴、钼、铜、铝和锡等金属的粉末进行加热试验 ,并利用微波加热烧结法成功地用金属粉末制成小型齿轮及其它环状、管状的机械零件。与利用普通高温加热烧结… 相似文献
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为了提高钛铁矿回收效率,对钛铁矿在脉冲微波条件下的升温行为进行了研究,采用自制的脉冲微波设备,对钛铁矿进行脉冲微波预处理。研究了不同辐照时间、脉冲微波功率、矿样质量和不同矿样粒度对钛铁矿升温性能的影响。采用X射线衍射仪对矿样组成进行分析,利用激光粒度仪对样品粒度进行检测。研究结果表明:物料在微波场中的升温行为,既决定于矿物本身的性质,又与微波加热设备的功率密切相关。当矿样粒度为25 mm、质量为40 g、辐照时间为30 s、微波平均功率为3 kW时,样品的升温性能最好。该研究对脉冲微波在助磨领域的应用具有重要意义。 相似文献
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研究了利用微波配碳还原焙烧分解铁酸锌的工艺及机理。利用碳气化控制、化学控制及扩散控制模型研究了样品中铁酸锌分解的动力学行为,并考察了微波功率、反应温度、配碳比和粒度对铁酸锌分解率的影响。结果表明,样品的微波加热碳热还原试验的控制步骤为碳气化控制,活化能为39.21kJ/mol,在微波加热温度850℃、C/ZnFe2O4质量比为1∶4、粒径74~89μm、微波功率1.8kW、加热时间60min的条件下,铁酸锌的分解率达到90%。 相似文献
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红土矿的微波浸出研究 总被引:4,自引:0,他引:4
本文研究了红土矿的微波加热浸出,采用X射线衍射分析和原子吸收分光光度法研究了红土矿物相和组成,主要物质为二氧化硅、蛇纹石和针铁矿,镍主要存在于蛇纹石及针铁矿中.研究了微波辐射加热条件下,红土矿的浸出过程.考察了微波辐射功率、H2SO4浓度、液固比、加热时间、铜离子浓度等因素对氧化镍矿浸出的影响,结果表明,镍、铁浸出率和反应体系的温度随着微波辐射功率的提高而增加;在微波功率为955W,H2SO4浓度为0.90mol/L,液固比为6∶1,反应时间40 min的条件下,镍的浸出率为99%,实验证明矿浆中少量的铜离子,即可起到较强的催化作用.以收缩未反应核模型为基础,建立了红土矿的微波浸出的动力学模型.对实验数据进行多相反应动力学处理,用1-2α/3-(1-α)2/3~t作图得到近似直线. 相似文献
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Recent studies have shown that metal powder compacts can be heated to high temperatures using microwaves. While microwave
heating of ceramics is well understood and modeled, there is still uncertainty about the exact mechanism and mode of microwave
heating of particulate metals. The current study describes an approach for modeling the microwave heating of metal powder
compacts using an electromagnetic-thermal model. The model predicts the variation in temperature with time during sintering.
The effect of powder size, emissivity, and susceptor heating on the heating rate has also been assessed. These predictions
have been validated by the experimental observations of the thermal profiles of Sn-, Cu-, and W-alloy compacts, using a 2.45
GHz multimode microwave furnace. 相似文献
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传统加热直接还原具有热效率低、球团"冷中心"和废热废气量大等问题,造成还原时间长、能耗高和污染大。试验利用微波的选择加热、快速加热、体积加热和清洁干净等优点,以及铁矿球团和无烟煤强的吸波特性,开发了铁矿球团煤基微波竖炉直接还原这一新工艺。研究表明,铁矿球团外配煤粉在1 050℃的微波加热条件下还原焙烧65min,可以获得95.25%的金属化率,同时具有1718.88N/个的抗压强度。与常规加热相比,微波加热还原焙烧的时间可以缩短27.78%,抗压强度增加近1倍,而且还原过程产生的废热废气量很少。 相似文献
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在微波辐射加热条件下考察了微波辐射功率、浸出用液的Na2Oc质量浓度、液固比等对高炉铝酸钙渣的浸出过程的影响,并与传统加热浸出进行了比较。结果表明,氧化铝浸出率和反应体系的温度随着微波辐射功率的提高而增加。在温度未达到溶液沸点之前,反应体系为非恒温反应过程。微波辐射浸出与传统加热浸出相比较,微波辐射加热下炉渣中氧化铝浸出速率较传统加热方式浸出快得多,微波浸出可降低浸出用液的Na2Oc质量浓度,缩短浸出时间。 相似文献
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The interfacial tension between the molten metal and the surrounding plasma environment affects the circulation of molten
metal in the weld pool, heat transfer, and the eventual structure and properties of the weld metal. Since the effect of plasma
on the interfacial tension of molten metals is not known, interfacial tension values between low pressure argon plasma and
pure copper and iron were measured. The variables studied were temperature and the intensity of plasma emission. 相似文献
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An experimental investigation of the rates of oxygen solution in molten cobalt, copper, iron and nickel was carried out using
pure oxygen and a constant-volume Sieverts’ method. It was found that the volume of gaseous oxygen which initially reacted
with the inductively stirred metals was strongly dependent on the physical nature of the oxide film which formed during the
first stage of reaction. The initial temperature of the molten iron, cobalt, and nickel was 1600°C, and for copper was 1250°C.
For initial oxygen pressures above the melt of about one atmosphere both molten iron and copper, which formed liquid surface
oxides, initially absorbed nearly 20 cm3 (STP) O2/cm2 of melt surface area, while molten cobalt and nickel, which formed solid oxides, absorbed about 6 cm3 (STP) O2/cm2 under the same experimental conditions. For approximately 30 s after the initial reaction between these liquid metals and
gaseous oxygen, the oxygen absorption rate was proportional to the square root of the oxygen pressure above the melt, and
proportional to the melt surface area, but independent of melt volume. The rate-limiting step for oxygen absorption by liquid
iron, cobalt and copper can be described by dissociative adsorption of oxygen molecules at the gas/oxide interface. After
30 s of reaction, the rate of oxygen absorption became less dependent on the oxygen pressure above the melt. This indicated
that the rate-controlling step was changing from a surface reaction to growth of the oxide layer by cationic diffusion in
the bulk oxide. The oxidation rate of liquid nickel appears to be too complex to be described by models for dissociative adsorption
of oxygen molecules at the gas/oxide interface and parabolic growth of the oxide layer. The formation of a thin layer of nickel
oxide which allows oxygen to migrate through cracks or grain boundaries may be responsible for the relatively high oxygen
absorption rate compared to that of liquid cobalt.
R. H. RADZILOWSKI, formerly a Graduate Studient at The University of Michigan 相似文献
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An experimental investigation of the rates of oxygen solution in molten cobalt, copper, iron and nickel was carried out using
pure oxygen and a constant-volume Sieverts' method. It was found that the volume of gaseous oxygen which initially reacted
with the inductively stirred metals was strongly dependent on the physical nature of the oxide film which formed during the
first stage of reaction. The initial temperature of the molten iron, cobalt, and nickel was 1600‡C, and for copper was 1250‡C.
For initial oxygen pres-sures above the melt of about one atmosphere both molten iron and copper, which formed liquid surface
oxides, initially absorbed nearly 20 cm3 (STP) O2/cm2 of melt surface area, while molten cobalt and nickel, which formed solid oxides, absorbed about 6 cm3 (STP) 02/cm2 under the same experimental conditions. For approximately 30 s after the initial reaction between these liquid metals and
gaseous oxygen, the oxygen absorption rate was proportional to the square root of the oxygen pressure above the melt, and
pro-portional to the melt surface area, but independent of melt volume. The rate-limiting step for oxygen absorption by liquid
iron, cobalt and copper can be described by dissocia-tive adsorption of oxygen molecules at the gasJoxide interface. After
30 s of reaction, the rate of oxygen absorption became less dependent on the oxygen pressure above the melt. This indicated
that the rate-controlling step was changing from a surface reaction to growth of the oxide layer by cationic diffusion in
the bulk oxide. The oxidation rate of liquid nickel appears to be too complex to be described by models for dissociative ad-sorption
of oxygen molecules at the gasJoxide interface and parabolic growth of the oxide layer. The formation of a thin layer of nickel
oxide which allows oxygen to migrate through cracks or grain boundaries may be responsible for the relatively high oxygen
ab-sorption rate compared to that of liquid cobalt.
Formerly a Graduate Student at The University of Michigan 相似文献
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Effect of conventional and microwave sintering on the properties of yttria alumina garnet-dispersed austenitic stainless steel 总被引:3,自引:0,他引:3
S. S. Panda A. Upadhyaya D. Agrawal 《Metallurgical and Materials Transactions A》2006,37(7):2253-2264
The current study examines the effect of heating mode, temperature, and varying yttria alumina garnet (YAG) addition (5 and
10 wt pct) on the densification and properties of austenitic (316L) stainless steel. The straight 316L stainless steel and
316L-YAG composites were heated in a radiatively heated (conventional) and 2.45 GHz microwave sintering furnace. The compacts
were consolidated through solid state as well as supersolidus sintering at 1200 °C and 1400 °C, respectively. Both 316L and
316L-YAG compacts couple with microwaves and heat to the sintering temperature rapidly (∼45 °C/min). The overall processing
time was reduced by about 90 pct through microwave sintering. As compared to conventional sintering, compacts sintered in
microwaves exhibit higher densification and finer microstructure but no corresponding improvement in mechanical properties
and wear resistance. This has been correlated to elongated, irregular pore structure in microwave-sintered compacts. 相似文献
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Influence of microwave heating on the microstructures of iron ore pellets with coal during reduction
Iron ore oxidised pellets as the burden of blast furnace present many advantages, such as uniform size, high iron grade and high physical strength. A comparison of the iron ore oxidised pellets with coal (out-proportioning) by conventional heating and microwave heating was carried out in this paper. Microstructure transformations during reduction process were investigated by optical microscopy and scanning electron microscope with energy dispersive spectrometry analysis. Micro-hardness of metallic iron phase formed in the reduction was tested with digital micro-hardness tester. The influences of microwave heating on reduction degree, morphology, iron phase and gangues were investigated, respectively. The results show that reduction time can be greatly shortened by microwave heating even at lower temperatures. The fine cracks generated, as the pellets were heated by microwave, were irradiated due to the selectivity of microwave heating. Densification of the metallic iron phase and the separation of the iron and gangues were both found to be enhanced by microwave heating. 相似文献