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异佛尔酮二异氰酸酯(IPDI)、聚己内酯二醇(PCL)为主要原料合成聚氨酯预聚体,甲基丙烯酸甲酯和丙烯酸丁酯合成端羟基共聚物,两者共聚并在水中分散,得到丙烯酸酯改性水性聚氨酯(PUA)。PUA乳液形貌表征结果表明,当聚丙烯酸酯数均分子量达到9 041时,复合乳液的稳定性变差;复合乳液平均粒径随聚丙烯酸酯(PA)分子量增大而增加,但都小于150 nm,并呈现典型的核壳结构。FTIR测试表明,随着PA链段分子量增大,其氢键相互作用相对减弱。DSC测试显示在PA分子量较低时,PA和PU链段是相容的。TG和拉伸测试结果显示,PUA的热稳定性及力学性能都得到明显改善。 相似文献
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M. Azam Ali Mubarak A. Khan K. M. Idriss Ali 《Polymer-Plastics Technology and Engineering》2013,52(4):603-620
Forty different formulations were developed with urethane diacrylate (M1200) oligomers (containing an aliphatic backbone chain) in the presence of eight different functional monomer diluents additives and five co monomers (co additives). Thin films, prepared with these formulations under ultraviolet (UV) and electron beam (EB) radiations, were characterized. The theological properties were correlated with glass transition temperature (T g) of the co monomer diluents. Results obtained with M1200 under UV and EB radiations are discussed and compared with those of aromatic urethane (M1100) films, previously reported. 相似文献
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以2-氨基-6-氯嘌呤(2)为原料,在相转移催化剂四丁基溴化铵催化下与3-溴丙烷-1,1,1-三甲酸乙酯(3)缩合,得2-氨基-6-氯-9-(2,2-二乙氧羰基丁酸乙酯-4-基)嘌呤(4)。4用乙醇钠溶液脱羧得2-氨基-6-氯-9-(2-乙氧羰基丁酸乙酯-4-基)嘌呤(5)。5在AlCl3催化下,用NaBH4作还原剂还原得2-氨基-6-氯-9-(4-羟基-3-羟甲基丁基)嘌呤(6)。6在4-二甲基氨基吡啶(DMAP)催化下,与醋酐反应得2-氨基-6-氯-9-(4-乙酰氧基-3-乙酰氧基甲基丁基)嘌呤(7)。7在Pd-C催化下,氢化脱氯得泛昔洛韦(1)。以2-氨基-6-氯嘌呤(2)计总收率为55%。 相似文献
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目的探讨中药联合胰岛素治疗2型糖尿病(T2DM)减低HbA1c的水平。方法对23例初诊T2DM患者作为联合组,采用中药联合胰岛素强化治疗,20例空腹血糖值相同者(对照组)单纯胰岛素治疗作为对照组,疗程3个月,采用SPSS16.0进行统计分析,比较2组在患病结局、血糖控制、糖化血红蛋白(HbA1c)水平之间的差异。结果治疗前2组空腹血糖和餐后2h血糖水平差异无统计学意义(P>0.05),治疗2周后差异有统计学意义(P<0.05)。治疗前2组HbA1c水平差异无统计学意义(P>0.05),治疗3个月后2组差异有统计学意义(P<0.05)。结论中药胰岛素治疗T2DM相比于单纯胰岛素治疗可获得更好血糖控制。 相似文献
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F. R. Hartley 《Coloration Technology》1969,85(2):66-71
The chemistry of chrome mordanting is discussed under the headings: reaction of wool with chromium(VI) anions; reaction of wool with chromium(III) cations; reduction of chromium(VI) to chromium(IlI); interaction between chromium(Vl) and dye; interaction between chromium(III) and dye; and interaction between chromium(III), dye and wool. 相似文献
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Contact angles were measured for a series of compression-molded polypropene films blended with acrylic acid (AA) or maleic anhydride (MAH)/polyethylene oxide (PEO) (1 : 1) additives. The influence of different molding conditions concerning time and temperature as well as a coating of the aluminium foils used for the processing with polyethylene oxide (PEO) or polyvinyl pyrrolidone (PVP) were investigated. Films processed with uncoated aluminium foils showed, with one exception, no influence on contact angles with increasing molding temperatures and longer processing times. Upon coating the aluminium foils with hydrophilic substances the receding contact angles decrease by up to 60° with constant contact angle hysteresis. This behaviour corresponding to a permanent hydrophilization is attributed to chemical reactions of the coating with the functional groups of the additives. 相似文献
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Batu Can Yaman Ekim Onur Orhan Bekir Karabucak Fusun Ozer Markus B. Blatz 《Journal of Adhesion Science and Technology》2013,27(1):71-81
Objective: This study investigated the effect of saliva contamination and cleansing effect of a self-etching primer (SEP), phosphoric acid (PA), chlorhexidine (CHX), and ethanol (EtOH) on the microtensile bond strength (μTBS) of a fiber post cemented with a self-adhesive resin cement (SAC) to root canal dentin.Material and methods: Sixty human lower premolar roots were randomly divided into 10 groups: (1) no saliva contamination, no cleansing (Control); (2) no saliva contamination, cleansing with SEP (NC-SEP); (3) no saliva contamination, cleansing with PA (NC-PA); (4) no saliva contamination, cleansing with CHX (NC-CHX); (5) no saliva contamination, cleansing with EtOH (NC-EtOH); (6) with saliva contamination, no cleansing (SC-NC); (7) with saliva contamination, cleansing with SEP (SC-SEP); (8) with saliva contamination, cleansing with PA (SC-PA); (9) with saliva contamination, cleansing with CHX (SC-CHX); (10) with saliva contamination, cleansing with EtOH (SC-EtOH). After cementation of posts, the roots were transversally sectioned to obtain six slices (n = 36) followed by μTBS test. Data were analyzed with ANOVA and Tukey HSD tests (p = 0.05).Results: Saliva contamination and cleansing methods had a significant effect on μTBS values (p < 0.0001). All cleansing agents improved bond strengths when compared with Control and SC-NC. Cleansing with CHX and ethanol showed lower μTBS values than phosphoric acid and SEP, regardless of saliva contamination (p < 0.05).Conclusions: Saliva contamination negatively affected bonding performance of SAC to root dentin. However; SEP, PA, CHX and EtOH can be used on contaminated dentin surfaces to optimize bonding performance of self-adhesive cements. 相似文献
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Carbon fiber (CF), PU(polyurethane)-coated carbon fiber (CF-PU) and Ni-coated fiber (NCF) treated with a coupling agent (CA) were used to prepare composites for high impact polystyrene (HIPS) by melt blending. The optimum concentration of the titanate CA is 1.5 phf (per hundred parts of filler) when coupled with the carbon fibers. A composite prepared by adding a CA directly into the matrix which was then reinforced with fibers was investigated for comparison. These composites were evaluated for electromagnetic interference shielding effectiveness, dispersion, and adhesion between the polymer and the filler by means of scanning electron microscopy (SEM). The addition of CA generally improved the shielding effectiveness; this is especially apparent when the matrix was pretreated with CA before compounding with the fibers. The tensile properties were also improved upon CA addition. 相似文献
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Vineta Srebrenkoska Gordana Bogoeva Gaceva Maurizio Avella Maria Emanuela Ericco Gennaro Gentile 《Polymer-Plastics Technology and Engineering》2013,52(11):1113-1120
Renewable raw materials and recyclable thermoplastic polymers provide attractive eco-friendly quality as well as environmental sustainability to the resulting natural fiber reinforced composites. We studied the possibility of using the recycled polypropylene (PP) for production of composites based on kenaf fibers (KF) and rice hulls (RH) as reinforcements. Polypropylene/rice-hulls (PP/RH/CA) and polypropylene/kenaf (PP/K/CA) composites with 30% fiber (filler) content and appropriate compatibilizing agent (CA)—a maleic anhydride grafted PP (MAPP), have been prepared by two steps procedure: melt mixing and compression molding. Flexural strength and thermal stability of the composites with recycled PP were similar to those with neat PP. The composites reinforced with kenaf fibers have shown better properties than those based on rice hulls. The flexural strength of the composite sample with recycled PP is 51.3 MPa in comparison with 51.1 MPa for the composite with neat PP. Degradation temperatures of neat and composite with recycled PP at residual weight 90% are 344.4°C and 343.5°C, respectively. The results obtained report the possibility of utilization of recycled PP for the production of natural reinforcements based composites with good mechanical characteristics for using as construction building materials in housing systems. 相似文献
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The antioxidative effects of rosemary and grape-seed extracts spiked in human plasma were examined using the thiobarbituric acid (TBA) method. The TBA values of plasma spiked with reagents to generate reactive oxygen species, such as singlet oxygen ((1)O(2)), hydroxyl radicals ((·)OH), peroxynitrite (ONOO(-)), and superoxide anions (O(2)(·-)), were measured by a flow injection analysis method with fluorescence (FL) detection. TBA values obtained by the addition of 50 mg/mL of rosemary extracts for (1)O(2), (·)OH, ONOO(-), and O(2)(·-) increased to 964 ± 65%, 1063 ± 61%, 758 ± 78%, and 698 ± 41%, respectively (n = 3, P < 0.01), whereas the values with 1 mg/mL of grape-seed extracts or tocopherol decreased (40.2 - 66.3%). Furthermore, the antioxidative effects of rosemary extract in rat plasma, spiked with reagents to generate (·)OH, were examined by high-performance liquid chromatography with FL detection. No peak, other than TBA-malondialdehyde, could be detected using wavelengths of 532 (λ(ex)) and 553 nm (λ(em)). 相似文献
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Petr Vl?ek Miroslav Janata Petra Látalová Jaroslav Krí? Eva ?adová Luděk Toman 《Polymer》2006,47(8):2587-2595
Cellulose diacetate (CDA) was acylated with 2-bromoisobutyryl bromide (BriBr) or with dichloroacetyl chloride (ClAcCl) giving polyfunctional macroinitiators for ATRP grafting of styrene (St), MMA and butyl acrylate (BuA). Under various reaction conditions, macroinitiators with variable degrees of functionalisation could be prepared. The macroinitiators with 2-bromoisobutyryl (BriB) groups were grafted with St or BuA, those with dichloroacetyl (ClAc) functions were used for graft copolymerization of MMA. Graft copolymers with chemically different grafts as well as tunable lengths and densities of grafts were synthesized in this way. Poly(CDA-g-St) and poly(CDA-g-MMA) were further used as macroinitiators of BuA polymerization, giving poly[CDA-g-(St-b-BuA)] and poly[CDA-g-(MMA-b-BuA)] graft copolymers with diblock grafts. 相似文献
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Oligomers of various polyacrylates and polymethacrylates and a chlorinated paraffin (as an analogue for PVC) were studied in order to give information relevant to the miscibility of the respective polymers. The heats of mixing of the oligomers with the chlorinated paraffin were measured and showed that those oligomers with the lowest and highest ester group concentration (poly(methyl acrylate) and poly(octadecyl methacrylate)) had unfavourable (positive) heats of mixing whereas oligomers with intermediate ester group concentrations had favourable (negative) heats of mixing. This was consistent with the miscibility of the respective polymers in most cases. The results were interpreted in terms of the summation of the effects of the specific interactions and the dispersive forces. A high concentration of interacting groups leads to a high contribution from the specific interaction, but in the case of poly(methyl acrylate) with the highest concentration of interacting groups this is outweighed by a large unfavourable contribution from the dispersive forces. 相似文献
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采用热模压成型的方法,在热塑性聚酰亚胺(TPI)中添加玻璃微珠(GB)、玻璃纤维粉(GFP)和短切玻璃纤维(SGF)进行复合增强,研究了3种不同形态填充材料及其含量对复合材料力学、摩擦磨损及热性能的影响。结果表明,随着填充物填充量的增加,所制得复合材料的刚性明显提高;并且填充物长径比越大,其作用效果越明显,由此制得的复合材料同时具有较低的体积磨损率及线膨胀系数。采用SGF增强复合材料的力学强度也随其填充量的增加显著增大,而采用GB及GFP填充的材料则呈下降趋势。采用SEM观察了复合材料断裂面的结构形貌,初步分析了其增强机理。 相似文献