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聚合物/蒙脱土纳米复合材料的研究进展 总被引:1,自引:0,他引:1
综述了蒙脱土(MMT)的结构特征、蒙脱土的有机化改性、聚合物/蒙脱土纳米复合材料(PMN)的制备方法以及聚合物/蒙脱土纳米复合材料的结构特性及性能特点。 相似文献
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选用硅烷偶联剂(KH560)对钠基蒙脱土进行改性。采用熔融共混法制备了不同类型的蒙脱土/聚对苯二甲酸丁二醇酯(PBT)纳米复合材料,通过X射线衍射、透射电镜、动态热力学测试等手段考察了不同类型的蒙脱土对复合材料结构和性能的影响。硅烷偶联剂接枝改性蒙脱土后,蒙脱土/PBT复合材料中蒙脱土层间距从1.26 nm增加到1.42 nm,且蒙脱土在聚合物基体中的团聚现象明显改善。与未改性蒙脱土和商品化有机改性蒙脱土相比较,硅烷偶联剂改性蒙脱土/PBT复合材料的拉伸强度和缺口冲击强度提高。 相似文献
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聚乙烯(PE)/OMMT纳米复合材料的结构、形态和性能 总被引:7,自引:0,他引:7
选择一种新型的有机改性蒙脱土(OMMT),在不加任何相容剂的条件下,利用熔融挤出法分别制备出了剥离型高密度聚乙烯/蒙脱土纳米复合材料、插层型线型低密度聚乙烯/蒙脱土和低密度聚乙烯/蒙脱土纳米复合材料。利用透射电子显微镜观察制备的复合材料的亚微观分散形态,确定了制备出的纳米复合材料的类型,并对不同亚微观结构形态进行了分析讨论,得出了不同分子结构影响纳米复合材料形成不同分散形态的结论;对于3种纳米复合材料的物理性能测试结果表明,不同亚微观分散形态的纳米复合材料的纳米效应不同,对物理性能的影响各有不同,对于聚合物/蒙脱土纳米复合材料的深入研究具有重大意义,同时分散均匀的纳米复合材料结构对于进一步研究聚乙烯纳米膜的气体阻隔性等性能奠定了良好的基础。 相似文献
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聚氯乙烯/蒙脱土纳米复合发泡材料的研究 总被引:1,自引:0,他引:1
制备了季磷盐改性有机蒙脱土并研究其对聚氯乙烯/蒙脱土纳米复合发泡材料结构和力学性能的影响,XRD、FT-IR、表面接触角等分析测试表明季膦盐改性剂有效实现了对蒙脱土的有机改性。季磷盐改性的钙基蒙脱土能有效改善复合材料的泡孔质量,提高复合材料的力学性能。 相似文献
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采用熔融插层和不同链长的改性荆改性蒙脱土的方法制备了三元乙丙橡胶(EPDM)/蒙脱土(MMT)纳米复合材料。X-射线衍射(XRD)和透射电镜(TEM)的测试结果表明:采用分子中亚甲基的数量小于16的改性剂改性MMT获得的有机蒙脱土与EPDM复合所得到的复合材料为传统型复合材料。而采用分子中亚甲基的数量大于16的改性剂改性MMT获得的有机蒙脱土与EPDM复合所得到的纳米复合材料为插层型。同时,笔者还探讨了EPDM接枝马来酸酐增容剂时复合材料形态的影响以及获得剥离型纳米复合材料的增容剂中马来酸酐的临界接枝率和增容剂最佳含量。此外,时该纳米复合材料的物理机械性能进行了评价。 相似文献
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聚氨酯/蒙脱土纳米复合材料研究进展 总被引:4,自引:0,他引:4
综述聚氨酯/蒙脱土纳米复合材料的国内外研究进展,重点阐述蒙脱土的有机化改性,聚氨酯/蒙脱土纳米复合材料的结构分析表征、制备方法及性能研究,最后介绍聚氨酯/蒙脱土纳米复合材料的最新应用情况。 相似文献
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分别从制备方法,力学性能,流变性能,微观形态和其他性能5个方面综述了近年来有机改性黏土填充PP/PA6复合材料的研究概况,从而得出结论:要提高有机改性黏土填充PP/PA6纳米复合材料的宏观性能,关键在于微观相容性的提高。 相似文献
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将三种不同插层剂改性的蒙脱土与聚酰胺6和聚酰胺66通过熔融共混分别制得纳米复合材料,对其热性能和力学性能进行了研究,对不同插层剂的改性效果和聚酰胺6、聚酰胺66两类纳米复合材料的性能进行了比较。结果显示,所有复合材料的热变形温度、拉伸模量、屈服强度、弯曲模量和弯曲强度均比纯树脂的要高,而断裂伸长率和缺口冲击强度则有所下降;蒙脱士对聚酰胺6的改性效果明显好于对聚酰胺66;三种插层剂中,含羟基的季铵盐改性效果最好,含两个长链烃基的铵盐改性效果最差。 相似文献
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聚合物/蒙脱土纳米复合材料研究进展 总被引:1,自引:0,他引:1
文章简要介绍了蒙脱土的结构,概述了聚合物/蒙脱土纳米蒙脱土材料的结构及性能,详细介绍了聚丙烯(PP)/蒙脱土、聚乙烯(PE)/蒙脱土、环氧树脂(EP)/蒙脱土纳米复合材料国内外最新的研究进展,叙述了聚合物/蒙脱土纳米复合材料优良的力学性能和热学性能。最后对聚合物/蒙脱土纳米复合材料的未来发展做了预测。 相似文献
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F. Chouli A. Benyoucef A. Yahiaoui C. Quijada E. Morallon 《Journal of Polymer Research》2012,19(11):1-9
Polymer/montmorillonite nanocomposites were prepared. Intercalation of 2-methylaniline with aniline monomers into montmorillonite modified by cation was followed by subsequent oxidative polymerization of the monomers in the interlayer spacing. The clay was prepared by cation exchange process between sodium cation in (M-Na) and copper cation (M-Cu). We prepared a series of polymer/clay nanocomposite materials that consisted of an emeraldine base of poly(2-MA), poly(2-MA-co-ANI) and PANI by layered copper montmorillonite. All organic monomers used were first intercalated into the interlayer regions of clay hosts followed by a one-step in situ oxidative polymerization. The unique properties of the as-synthesized nanocomposites materials are investigated by electronic conductivity measurements, X-ray diffraction, FTIR spectroscopy, UV-vis spectroscopy, thermogravimetric analysis and SEM, were also studied by cyclic voltammetry which indicates the electroactive effect of nanocomposite gradually increased with aniline in the polymer chain. 相似文献
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This article focuses on structural, thermal, and mechanical properties of nanocomposites in dependence of preparation method and poly(methyl mathacrylate) (PMMA)/organically modified montmorillonite (OMMT) ratio. PMMA/OMMT nanocomposites were prepared by bulk polymerization and by melt compounding. Properties of nanocomposites of the same composition prepared by the two methods were compared. It was observed that nanocomposites prepared via melt compounding at 200°C had a highly oriented structure with lower interlayer spacing values than nanocomposites prepared via bulk polymerization. Two reasons for the observed smaller interlayer spacing obtained by melt compounding were identified. The first is enhanced PMMA penetration and/or formation between layers in the case of bulk polymerization, which was confirmed by determination of stronger interactions between OMMT and PMMA by Soxhlet extraction, infrared spectroscopy, and differential dynamic calorimery. The second reason for smaller interlayer spacing for nanocomposites prepared by melt compounding is organic modifier degradation during melt compounding process, which was confirmed by thermogravimetric analysis. Both reasons lead to the fracture of melt compounded nanocomposites on the OMMT‐polymer interface, which was observed by scanning electron microscopy. For nanocomposites with disoriented structure and larger interlayer spacing prepared via bulk polymerization the fracture occurred in the polymer matrix. POLYM. COMPOS., 2009. © 2008 Society of Plastics Engineers 相似文献
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Phenolic resin/clay nanocomposites were prepared using a suspension condensation polymerization method that was suitable to both novolac and resole. Natural montmorillonite and two kinds of organic modified montmorillonite were adopted to investigate the effect of modification on the final morphology of the nanocomposites. X-ray diffraction (XRD) measurements and Transmission Electron Microscope (TEM) observations showed that clay platelets were easier to be exfoliated or intercalated in novolac than in resole because novolac usually has a linear structure. The modifier with a phenyl ring was more compatible with novolac (or resole) than the aliphatic type modifier. The influence of curing on the morphology was studied as well. An exfoliation-adsorption and in situ condensation mechanism was proposed on the formation of the nanocomposites. 相似文献