Performance assessment of a direct steam solar power plant with hydrogen energy storage: An exergoeconomic study

Power generation and its storage using solar energy and hydrogen energy systems is a promising approach to overcome serious challenges associated with fossil fuel-based power plants. In this study, an exergoeconomic model is developed to analyze a direct steam solar tower-hydrogen gas turbine power plant under different operating conditions. An on-grid solar power plant integrated with a hydrogen storage system composed of an electrolyser, hydrogen gas turbine and fuel cell is considered. When solar energy is not available, electrical power is generated by the gas turbine and the fuel cell utilizing the hydrogen produced by the electrolyser. The effects of different working parameters on the cycle performance during charging and discharging processes are investigated using thermodynamic analysis. The results indicate that increasing the solar irradiation by 36%, leads to 13% increase in the exergy efficiency of the cycle. Moreover, the mass flow rate of the heat transfer fluid in solar system has a considerable effect on the exergy cost of output power. Solar tower has the highest exergy destruction and capital investment cost. The highest exergoeconomic factor for the integrated cycle is 60.94%. The steam turbine and PEM electrolyser have the highest share of exergoeconomic factor i.e., 80.4% and 50%, respectively.     

Exergy analyses and parametric optimizations for different cogeneration power plants in cement industry

The cement production is an energy intensive industry with energy typically accounting for 50–60% of the production costs. In order to recover waste heat from the preheater exhaust and clinker cooler exhaust gases in cement plant, single flash steam cycle, dual-pressure steam cycle, organic Rankine cycle (ORC) and the Kalina cycle are used for cogeneration in cement plant. The exergy analysis for each cogeneration system is examined, and a parameter optimization for each cogeneration system is achieved by means of genetic algorithm (GA) to reach the maximum exergy efficiency. The optimum performances for different cogeneration systems are compared under the same condition. The results show that the exergy losses in turbine, condenser, and heat recovery vapor generator are relatively large, and reducing the exergy losses of these components could improve the performance of the cogeneration system. Compared with other systems, the Kalina cycle could achieve the best performance in cement plant.     

Comparative exergoeconomic analyses of the integration of biomass gasification and a gas turbine power plant with and without fogging inlet cooling

Inlet cooling is effective for mitigating the decrease in gas turbine performance during hot and humid summer periods when electrical power demands peak, and steam injection, using steam raised from the turbine exhaust gases in a heat recovery steam generator, is an effective technique for utilizing the hot turbine exhaust gases. Biomass gasification can be integrated with a gas turbine cycle to provide efficient, clean power generation. In the present paper, a gas turbine cycle with fog cooling and steam injection, and integrated with biomass gasification, is proposed and analyzed with energy, exergy and exergoeconomic analyses. The thermodynamic analyses show that increasing the compressor pressure ratio and the gas turbine inlet temperature raises the energy and exergy efficiencies. On the component level, the gas turbine is determined to have the highest exergy efficiency and the combustor the lowest. The exergoeconomic analysis reveals that the proposed cycle has a lower total unit product cost than a similar plant fired by natural gas. However, the relative cost difference and exergoeconomic factor is higher for the proposed cycle than the natural gas fired plant, indicating that the proposed cycle is more costly for producing electricity despite its lower product cost and environmental impact.     

Thermodynamic,exergoeconomic and exergoenvironmental analyses and optimization of a solid oxide fuel cell-based trigeneration system

This study proposes a trigeneration system based on solid oxide fuel cell (SOFC) for generating power, cooling and heating simultaneously. The system mainly contains a SOFC, a gas turbine (GT), an organic Rankine cycle (ORC), a steam ejector refrigerator (SER) and a heat exchanger. The thermodynamic, exergoeconomic and exergoenvironmental models of proposed trigeneration system are developed, and the effects of design parameters on system performances are analyzed. The results indicate that the system average product cost and environmental impact per unit of exergy increase with SOFC inlet temperature and working pressure, the pinch point temperature difference and evaporating pressure of Generator, while decrease with the current density of fuel cell. Finally, optimization is performed to achieve the optimal exergy-based performance. It is revealed that though the system exergy efficiency is decreased by 7.64% after optimization, the system average product cost and environmental impact per unit of exergy are significantly reduced.     

Thermodynamic analysis and performance optimization of organic rankine cycles for the conversion of low‐to‐moderate grade geothermal heat

The present study considers a thermodynamic analysis and performance optimization of geothermal power cycles. The proposed binary‐cycles operate with moderately low temperature and liquid‐dominated geothermal resources in the range of 110°C to 160°C, and cooling air at ambient conditions of 25°C and 101.3 kPa reference temperature and atmospheric pressure, respectively. A thermodynamic optimization process and an irreversibility analysis were performed to maximize the power output while minimizing the overall exergy destruction and improving the First‐law and Second‐law efficiencies of the cycle. Maximum net power output was observed to increase exponentially with the geothermal resource temperature to yield 16–49 kW per unit mass flow rate of the geothermal fluid for the non‐regenerative organic Rankine cycles (ORCs), as compared with 8–34 kW for the regenerative cycles. The cycle First‐law efficiency was determined in the range of 8–15% for the investigated geothermal binary power cycles. Maximum Second‐law efficiency of approximately 56% was achieved by the ORC with an internal heat exchanger. In addition, a performance analysis of selected pure organic fluids such as R123, R152a, isobutane and n‐pentane, with boiling points in the range of ?24°C to 36°C, was conducted under saturation temperature and subcritical pressure operating conditions of the turbine. Organic fluids with higher boiling point temperature, such as n‐pentane, were recommended for non‐regenerative cycles. The regenerative ORCs, however, require organic fluids with lower vapour specific heat capacity (i.e. isobutane) for an optimal operation of the binary‐cycle. Copyright © 2015 John Wiley & Sons, Ltd.     

Heat recovery from Diesel engines: A thermodynamic comparison between Kalina and ORC cycles

In the context of heat recovery for electric power generation, Kalina cycle (a thermodynamic cycle using as working fluid a mixture of water and ammonia) and Organic Rankine Cycle (ORC) represent two different eligible technologies. In this work a comparison between the thermodynamic performances of Kalina cycle and an ORC cycle, using hexamethyldisiloxane as working fluid, was conducted for the case of heat recovery from two Diesel engines, each one with an electrical power of 8900 kWe. The maximum net electric power that can be produced exploiting the heat source constituted by the exhaust gases mass flow (35 kg/s for both engines, at 346 °C) was calculated for the two thermodynamic cycles. Owing to the relatively low useful power, for the Kalina cycle a relatively simple plant layout was assumed. Supposing reasonable design parameters and a logarithmic mean temperature difference in the heat recovery exchanger of 50 °C, a net electric power of 1615 kW and of 1603 kW respectively for the Kalina and for the ORC cycle was calculated.Although the obtained useful powers are actually equal in value, the Kalina cycle requires a very high maximum pressure in order to obtain high thermodynamic performances (in our case, 100 bar against about 10 bar for the ORC cycle). So, the adoption of Kalina cycle, at least for low power level and medium–high temperature thermal sources, seems not to be justified because the gain in performance with respect to a properly optimized ORC is very small and must be obtained with a complicated plant scheme, large surface heat exchangers and particular high pressure resistant and no-corrosion materials.     

Thermo-economic investigation on the hydrogen production through the stored solar energy in a salinity gradient solar pond: A comparative study by employing APC and ORC with zeotropic mixture

In this paper, a salinity gradient solar pond (SGSP) is used to harness the solar energy for hydrogen production through two cycles. The first cycle includes an absorption power cycle (APC), a proton exchange membrane (PEM) electrolyzer, and a thermoelectric generator (TEG) unit; in the second one, an organic Rankine cycle (ORC) with the zeotropic mixture is used instead of APC. The cycles are analyzed through the thermoeconomic vantage point to discover the effect of key decision variables on the cycles’ performance. Finally, NSGA-II is used to optimize both cycles. The results indicate that employing ORC with zeotropic mixture leads to a better performance in comparison to utilizing APC. For the base mode, unit cost product (UCP), exergy, and energy efficiency when APC is employed are 59.9 $/GJ, 23.73%, and 3.84%, respectively. These amounts are 47.27 $/GJ, 29.48%, and 5.86% if ORC with the zeotropic mixture is utilized. The APC and ORC generators have the highest exergy destruction rate which is equal to 6.18 and 10.91 kW. In both cycles, the highest investment cost is related to the turbine and is 0.8275 $/h and 0.976 $/h for the first and second cycles, respectively. In the optimum state the energy efficiency, exergy efficiency, UCP, and H₂ production rate of the system enhances 42.44%, 27.54%,15.95%, and 38.24% when ORC with the zeotropic mixture is used. The maximum H₂ production is 0.47 kg/h, and is obtained when the mass fraction of R142b, LCZ temperature, pumps pressure ratio, generator bubble point temperature are 0.603, 364.35 K, 2.12, 337.67 K, respectively.     

Exergoeconomic analysis of a combined heat and power (CHP) system

This study deals with exergoeconomic analysis of a combined heat and power (CHP) system along its main components installed in Eskisehir City of Turkey. Quantitative exergy cost balance for each component and the whole CHP system is considered, while exergy cost generation within the system is determined. The exergetic efficiency of the CHP system is obtained to be 38.33% with 51 475.90 kW electrical power and the maximum exergy consumption between the components of the CHP system is found to be 51 878.82 kW in the combustion chamber. On the other hand, the exergoeconomic analysis results indicate that the unit exergy cost of electrical power produced by the CHP system accounts for 18.51 US$ GW^?1. This study demonstrates that exergoeconomic analysis can provide extra information than exergy analysis, and the results from exergoeconomic analysis provide cost‐based information, suggesting potential locations for the CHP system improvement. Copyright © 2007 John Wiley & Sons, Ltd.     

The first and second law analysis on an organic Rankine cycle with ejector

In consideration of the low efficiency of the organic Rankine cycle (ORC) with low-grade heat source (LGHS), an organic Rankine cycle with ejector (EORC) and a double organic Rankine cycle (DORC) based on the ORC is introduced in this paper. The thermodynamic first law and second law analysis and comparison on the ORC, EORC and DORC cycles are conducted on the cycle’s power output, thermal efficiency, exergy loss and exergy efficiency. Water is chosen as the LGHS fluid, and the same temperature and mass flow rate of the water is the standard condition for the comparative analysis on the cycles. The emphasis is on the thermodynamic performance at the maximum net power output of the cycles. The results show the power output is higher in the EORC and DORC compared to the ORC. And the cycle’s exergy efficiency could be ranked from high to low: DORC > EORC > ORC.     

A procedure to select working fluids for Solar Organic Rankine Cycles (ORCs)

The selection of working fluid and working conditions of the Organic Rankine Cycle (ORC) has a great effect on the system operation, and its energy efficiency and impact on the environment. The main purpose of this study is to develop a procedure to compare capabilities of working fluids when they are employed in solar Rankine cycles with similar working conditions. The Refprop 8.0 database with 117 organic fluids has been considered as the reference in this study. A procedure to compare ORC working fluids based on their molecular components, temperature–entropy diagram and fluid effects on the thermal efficiency, net power generated, vapor expansion ratio, and exergy efficiency of the Rankine cycle has been proposed. Fluids with the best cycle performance have been recognized in two different temperature levels within two different categories of fluids: refrigerants and non-refrigerants. Based on categories of solar collectors, 11 fluids have been suggested to be employed in solar ORCs that use low or medium temperature solar collectors. Collector efficiency improvement and use of the regenerative ORC instead of the basic cycle reduce irreversibility of a solar ORC. Calculation results show that for selected fluids, the theoretical limits for irreversibility reduction and exergy efficiency enhancement through collector efficiency improvement are 35% and 5% respectively, when the collector efficiency increases from 70% to 100%. The effect of regeneration on the exergy efficiency of the cycle is fluid dependent while the effect of collector efficiency improvement on the exergy efficiency of the cycle is nearly independent of fluid type. At the two temperature levels studied, higher molecular complexity results in more effective regenerative cycles except for Cyclohydrocarbons.     

Exergoeconomic analysis of hydrogen production from biomass gasification

In this study, we investigate biomass-based hydrogen production through exergy and exergoeconomic analyses and evaluate all components and associated streams using an exergy, cost, energy and mass (EXCEM) method. Then, we define the hydrogen unit cost and examine how key system parameters affect the unit hydrogen cost. Also, we present a case study of the gasification process with a circulating fluidized bed gasifier (CFBG) for hydrogen production using the actual data taken from the literature. We first calculate energy and exergy values of all streams associated with the system, exergy efficiencies of all equipment, and determine the costs of equipment along with their thermodynamic loss rates and ratio of thermodynamic loss rate to capital cost. Furthermore, we evaluate the main system components, consisting of gasifier and PSA, from the exergoeconomic point of view. Moreover, we investigate the effects of various parameters on unit hydrogen cost, such as unit biomass and unit power costs and hydrogen content of the syngas before PSA equipment and PSA hydrogen recovery. The results show that the CFBG system, which has energy and exergy efficiencies of 55.11% and 35.74%, respectively, generates unit hydrogen costs between 5.37 $/kg and 1.59 $/kg, according to the internal and external parameters considered.     

Performance investigation in modified and improved augmented power generation Kalina cycle using Python

In the generation of electricity and cogeneration, Kalina cycle is considered as one of the competitors to organic Rankine cycle. With the simplicity and identical components of the binary mixture, Kalina system makes it more prominent to get developed and implemented as well with its environmental friendly associate. This work proposes a new improved Kalina cycle system to convert the natural source from sun to useful work. The proposed system utilizes heat source suitable to medium temperature heat applications. The proposed cycle have 2 units of solar collector, favoring an additional heat recovery and higher performance. Solar hot source temperature and pressure are 190°C and 45 bar with additional flow to the turbine of 1.15 kg/s. Energy and second law analysis have considered in evaluating the performance of the proposed plant. The energy analysis shows minimum value of net power, energy efficiency and plant efficiency as 241 kW, 15.5% and 5.7. The exergy analysis defines that, to the proposed cycle, the exergy efficiency initializes at 77% with more exergy destruction at turbine with 31%. With the parametric analysis, the system is amended to have the maximum values of energy and exergy performances as 18.5%, 7.1% and 85%. The parametric study identifies the optimum value of the inlet temperature and pressure of the pump and turbine.     

Exergy,exergoeconomic and multi-objective optimization of a clean hydrogen and electricity production using geothermal-driven energy systems

In this research paper, comprehensive thermodynamic modeling of an integrated energy system consisting of a multi-effect desalination system, geothermal energy system, and hydrogen production unit is considered and the system performance is investigated. The system's primary fuel is a geothermal two-phase flow. The system consists of a single flash steam-based power system, ORC, double effect water–lithium bromide absorption cooling system, PEM electrolyzer, and MED with six effects. The effect of numerous design parameters such as geothermal temperature and pressure on the net power of steam turbine and ORC cycle, the cooling capacity of an absorption chiller, the amount of produced hydrogen in PEM electrolyzer, the mass flow rate of distillate water from MED and the total cost rate of the system are studied. The simulation is carried out by both EES and Matlab software. The results indicate the key role of geothermal temperature and show that both total exergy efficiency and total cost rate of the system elevate with increasing geothermal temperature. Also, the impact of changing absorption chiller parameters like evaporator and absorber temperatures on the COP and GOR of the system is investigated. Since some of these parameters have various effects on cost and efficiency as objective functions, a multi-objective optimization is applied based on a Genetic algorithm for this system and a Pareto-Frontier diagram is presented. The results show that geothermal main temperature has a significant effect on both system exergy efficiency and cost of the system. An increase in this temperature from 260 C to 300 C can increase the exergy efficiency of the system for an average of 12% at various working pressure and also increase the cost of the system by 13%.     

Energy,exergy and economic analyses and multiobjective optimization of a novel solar multi-generation system for production of green hydrogen and other utilities

Renewable energy based multi-generation systems can help solving energy-related environmental problems. For this purpose, a novel solar tower-based multi-generation system is proposed for the green hydrogen production as the main product. A solar-driven open Brayton cycle with intercooling, regeneration and reheat is coupled with a regenerative Rankine cycle and a Kalina cycle-11 as a unique series of power cycles. Significant portion of the produced electricity is utilized to produce green hydrogen in an electrolyzer. A thermal energy storage, a single-effect absorption refrigeration cycle and two domestic hot water heaters are also integrated. Energy, exergy and economic analyses are performed to examine the performance of the proposed system, and a detailed parametric analysis is conducted. Multiobjective optimization is carried out to determine the optimum performance. Optimum energy and exergy efficiencies, unit exergy product cost and total cost rate are calculated as 39.81%, 34.44%, 0.0798 $/kWh and 182.16 $/h, respectively. Products are 22.48 kg/h hydrogen, 1478 kW power, 225.5 kW cooling and 7.63 kg/s domestic hot water. Electrolyzer power size is found as one of the most critical decision variables. Solar subsystem has the largest exergy destruction. Regenerative Rankine cycle operates at the highest energy and exergy efficiencies among power cycles.     

Thermodynamic analysis of an integrated power generation system driven by solid oxide fuel cell

A new integrated power generation system driven by the solid oxide fuel cell (SOFC) is proposed to improve the conversion efficiency of conventional energy by using a Kalina cycle to recover the waste heat of exhaust from the SOFC-GT. The system using methane as main fuel consists an internal reforming SOFC, an after-burner, a gas turbine, preheaters, compressors and a Kalina cycle. The proposed system is simulated based on the developed mathematical models, and the overall system performance has been evaluated by the first and second law of thermodynamics. Exergy analysis is conducted to indicate the thermodynamic losses in each components. A parametric analysis is also carried out to examine the effects of some key thermodynamic parameters on the system performance. Results indicate that as compressor pressure ratio increases, SOFC electrical efficiency increases and there is an optimal compressor pressure ratio to reach the maximum overall electrical efficiency and exergy efficiency. It is also found that SOFC electrical efficiency, overall electrical efficiency and exergy efficiency can be improved by increasing air flow rate. Also, the largest exergy destruction occurs in the SOFC followed by the after-burner, the waste heat boiler, the gas turbine. The compressor pressure ratio and air flow rate have significant effects on the exergy destruction in some main components of system.     

Exergy, exergoeconomic and environmental analyses and evolutionary algorithm based multi-objective optimization of combined cycle power plants

A comprehensive exergy, exergoeconomic and environmental impact analysis and optimization is reported of several combined cycle power plants (CCPPs). In the first part, thermodynamic analyses based on energy and exergy of the CCPPs are performed, and the effect of supplementary firing on the natural gas-fired CCPP is investigated. The latter step includes the effect of supplementary firing on the performance of bottoming cycle and CO₂ emissions, and utilizes the first and second laws of thermodynamics. In the second part, a multi-objective optimization is performed to determine the “best” design parameters, accounting for exergetic, economic and environmental factors. The optimization considers three objective functions: CCPP exergy efficiency, total cost rate of the system products and CO₂ emissions of the overall plant. The environmental impact in terms of CO₂ emissions is integrated with the exergoeconomic objective function as a new objective function. The results of both exergy and exergoeconomic analyses show that the largest exergy destructions occur in the CCPP combustion chamber, and that increasing the gas turbine inlet temperature decreases the CCPP cost of exergy destruction. The optimization results demonstrates that CO₂ emissions are reduced by selecting the best components and using a low fuel injection rate into the combustion chamber.     

A specific exergy costing assessment of the integrated copper-chlorine cycle for hydrogen production

In this study the specific exergy costing (SPECO) approach is employed on a four-step integrated thermochemical copper-chlorine (Cu Cl) cycle for hydrogen production for a second-law based assessment purposes. The Cu–Cl cycle is considered as one of the most environmentally benign and sustainable options of producing hydrogen and is thus investigated in this study due to its potential of ensuring zero greenhouse gas (GHG) emissions. Several conceptual Cu–Cl cycles have been exergoeconomically examined previously, however this study aims at investigating the four-step integrated Cu–Cl cycle developed at the Clean Energy Research Laboratory (CERL) at the Ontario Tech University thereby contributing to the thermo/exergoeconomic assessments of the thermochemical hydrogen production. In this study, the cycle is first thermodynamically modeled and simulated in a process simulation software (Aspen Plus) through exergy and energy approaches. The basic principles of the SPECO methodology are applied to the system and exergetic cost balances are performed for each cycle component. The exergetic costing of each cycle stream is then performed based on the cost balance equations. The purchased equipment cost and the hourly levelized capital cost rates for each cycle component is also obtained. The exergoeconomic factor, relative cost difference and exergy destruction cost rate for various cycle components are also evaluated. Moreover, the effect of several parameters on the total and hourly levelized capital cost rates is analyzed by performing a comprehensive sensitivity analysis. Based on the analysis, the exergy cost, the unit or specific exergy cost, and the unit costs of hydrogen are evaluated to be 6407.55 $/h, 0.042 $/MJ, and 4.94 $/kg respectively.     

A combined thermodynamic cycle used for waste heat recovery of internal combustion engine

In this paper, we present a steady-state experiment, energy balance and exergy analysis of exhaust gas in order to improve the recovery of the waste heat of an internal combustion engine (ICE). Considering the different characteristics of the waste heat of exhaust gas, cooling water, and lubricant, a combined thermodynamic cycle for waste heat recovery of ICE is proposed. This combined thermodynamic cycle consists of two cycles: the organic Rankine cycle (ORC), for recovering the waste heat of lubricant and high-temperature exhaust gas, and the Kalina cycle, for recovering the waste heat of low-temperature cooling water. Based on Peng–Robinson (PR) equation of state (EOS), the thermodynamic parameters in the high-temperature ORC were calculated and determined via an in-house computer program. Suitable working fluids used in high-temperature ORC are proposed and the performance of this combined thermodynamic cycle is analyzed. Compared with the traditional cycle configuration, more waste heat can be recovered by the combined cycle introduced in this paper.     

Exergetic analysis of various types of geothermal power plants

Based on available surveys, it has been shown that Iran has substantial geothermal potential in the north and north-western provinces, where in some places the temperature reaches 240 °C. In order to better exploit these renewable resources, it is necessary to study this area. Thus, the aim of this paper is a comparative study of the different geothermal power plant concepts, based on the exergy analysis for high-temperature geothermal resources. The considered cycles for this study are a binary geothermal power plant using a simple organic Rankine cycle (ORC), a binary geothermal power plant using an ORC with an internal heat exchanger (IHE), a binary cycle with a regenerative ORC, a binary cycle with a regenerative ORC with an IHE, a single-flash geothermal power plant, a double-flash geothermal power plant and a combined flash-binary power plant. With respect to each cycle, a thermodynamic model had to be developed. Model validation was undertaken using available data from the literature. Based on the exergy analysis, a comparative study was done to clarify the best cycle configuration. The performance of each cycle has been discussed in terms of the second-law efficiency, exergy destruction rate, and first-law efficiency. Comparisons between the different geothermal power plant concepts as well as many approaches to define efficiencies have been presented. The maximum first-law efficiency was found to be related to the ORC with an IHE with R123 as the working fluid and was calculated to be 7.65%. In contrast, the first-law efficiency based on the energy input into the ORC revealed that the binary cycle with the regenerative ORC with an IHE and R123 as the working fluid has the highest efficiency (15.35%). Also, the maximum first-law efficiency was shown to be given by the flash-binary with R123 as the working fluid and was calculated to be 11.81%.     

Nuclear energy-driven Kalina cycle system suitable for Indian climatic conditions

Kalina cycle (KC) has been contemplated as one of the energy-efficient power generation cycles. It is suitable for various waste heat recovery applications. It is one of the competitors to Organic Rankine Cycle, Transcritical Cycle, Supercritical Cycle, and Rankine cycle. Kalina cycle system (KCS) is a binary mixture system that utilizes ammonia-water as working fluid. In this work, a parametric study has been made with a low-temperature Kalina cycle system (LTKCS) and a high-temperature Kalina cycle system (HTKCS). The LTKCS utilized the hot source energy from solar energy, whereas for HTKCS the hot stream of energy was received from a pressurized water nuclear reactor. The output and efficiencies (energy, exergy, and relative) were noted for a range of limits for the parameters considered. Separator temperature and turbine concentration have been considered as common parameters for the two KCSs. For LTKCS and HTKCS, the optimum working conditions for separator temperature and turbine concentration exist in the range 110?150°C, 60?100°C and 0.85–0.97, 0.50–0.80, respectively. The optimized values for LTKCS and HTKCS have been derived. Among the two KCSs, HTKCS produces high specific power (675 KW). The optimum value of exergy efficiency results for LTKCS (74%) pertaining to low exergy losses. Energy is recovered more efficiently in LTKCS. This study suggests that KCS is well suited for low-temperature applications.