Probabilistic evaluation of initiation time of chloride-induced corrosion

The paper presents a model for chloride ingress into concrete. The model accounts for two mechanisms which control the chloride ingress—diffusion and convection. Using one-dimensional (1-D) formulation of the model, the influence of chloride binding and ambient humidity on chloride ingress into concrete has been investigated. Based on results of this investigation parameters for probabilistic analysis have been selected. Probabilistic evaluation of the time to corrosion initiation has then been carried out for a reinforced concrete (RC) wall (1-D problem) and a RC column (2-D problem) in a marine environment. Results of the analysis show that for the same thickness of the concrete cover the probability of corrosion initiation in the corner reinforcing bars of the RC column is much higher than in reinforcing bars in the middle part of the RC wall. The results demonstrate the importance of 2-D modelling for correct prediction of corrosion initiation in such RC elements as columns and beams.     

Structural concrete with incorporation of coarse recycled concrete and ceramic aggregates: durability performance

The growing difficulty in obtaining natural coarse aggregates (NCA) for the production of concrete, associated to the environmental issues and social costs that the uncontrolled extraction of natural aggregates creates, led to a search for feasible alternatives. One of the possible paths is to reuse construction and demolition waste (CDW) as aggregates to incorporate into the production of new concrete. Therefore, a vast and detailed experimental campaign was implemented at Instituto Superior Técnico (IST), which aimed at determining the viability of incorporating coarse aggregates from concrete and ceramic brick wall debris, in the production of a new concrete, with properties acceptable for its use in new reinforced and pre-stressed structures. In the experimental campaign different compositions were studied by incorporating pre-determined percentages of recycled coarse concrete aggregates and recycled coarse ceramic plus mortar particles, and the main mechanical, deformability and durability properties were quantified, by comparison with a conventional reference concrete (RC). In this article, these results are presented in terms of the durability performance of concrete, namely water absorption, carbonation and chlorides penetration resistance.     

Laboratory studies on influence of transverse cracking on chloride-induced corrosion rate in concrete

To clarify the corrosion mechanism of steel induced by transverse crack, a study on the influence of crack widths and epoxy coating on corrosion of steel bars in cracked concrete is presented here. Microcell and macrocell corrosions of bars were investigated on single crack specimens with crack widths of 0.08, 0.26, 0.38 and 0.94 mm. The entire study was carried out in an artificially created chloride ion-induced corrosion environment. The results show that the steel in cracks was activated once the transverse crack occurred on concrete element, and the macrocell corrosion must co-exist with microcell corrosion of reinforcements in test specimens with transverse crack. The macrocell current of steel elements were separated from the crack width, and the wider the transverse crack is, the higher corroded area and the greater microcell current of the rebar is. Oxygen and water go into concrete through crack instead of through concrete cover. The epoxy coating cannot prevent the occurrence and propagation of crack, so it was not effective to prevent corrosion of steel bars in cracked concrete.     

The influence of corrosion on bond properties between concrete and reinforcement in concrete structures

The rebar corrosion in reinforced concrete is one of the most extensive pathologies affecting the performance of concrete structures. Chloride-induced rebar corrosion damage results mainly from the use of de-icing salts in cold climates and/or exposure to marine environments. Carbonation damage is a further important degradation mechanism. The internal consequences of corrosion are the modification of the steel behavior and degradation of the steel–concrete bond. This work is devoted to the influence of the controlled corrosion on the adherence between steel and concrete. A new geometry of specimen has been designed to: (i) avoid the lateral confining stresses that appear during the classical pullout tests and (ii) permit to impose a known confinement for the study of its influence on the behavior of the interface. Five specimens with different levels of corrosion have been tested in this contribution. Reinforcing bars embedded in concrete were submitted to accelerated corrosion using an external current source. The magnitude of corrosion was measured using both Faraday’s law and the weight loss method. The level of corrosion varied from 0% to 0.76%. The geometry of the specimens allowed us to take series of digital pictures during the tests, which were analyzed using a digital image correlation, the procedure named CORRELI^LMT. The results of pullout tests proposed in this contribution indicate that: (i) levels of corrosion that are less than 0.4% of weight loss improves the bond stress and (ii) levels of corrosion resulting in more than 0.4% of weight loss lead to a reduction of the bond stress value.     

Lattice modelling of corrosion induced cracking and bond in reinforced concrete

A lattice approach is used to describe the mechanical interaction of a corroding reinforcement bar, the surrounding concrete and the interface between steel reinforcement and concrete. The cross-section of the ribbed reinforcement bar is taken to be circular, assuming that the interaction of the ribs and the surrounding concrete can be captured by a cap-plasticity interface model. The expansive corrosion process is represented by an Eigenstrain in the lattice elements forming the interface between concrete and reinforcement. Several pull-out tests with varying degree of corrosion are analysed. The numerical results are compared with experiments reported in the literature. The influence of the properties of concrete are studied. The proposed lattice approach offers insight into corrosion induced cracking and its influence on bond strength.     

Efficacy of surface hydrophobic agents in reducing water and chloride ion penetration in concrete

Hydrophobic agents are surface protection materials capable of increasing the angle of contact between the water and the concrete surface. For this reason, hydrophobic agents reduce water (in liquid form) penetration in concrete. Therefore, many European construction regulating agencies recommend this treatment in their maintenance policy. Nonetheless, there continues to be a gap in the understanding about which transport mechanisms of the concrete are modified by the hidrophobic agents. The aim of this study was to fill this gap in regards to reinforced concrete structures inserted in a marine environment. To this end, certain tests were used: Two involving permeability mechanism, one determining capillary absorption, and the last, a migration test used to estimate the chloride diffusion coefficient in saturated condition. Results indicated the efficacy of the hydrophobic agents in cases where capillary suction is the mechanism of water penetration (reduced by 2.12 and 7.0 times, depending of the product). However, when the transport mechanism is permeability this product is not advisable. Moreover, it was demonstrated that the chloride diffusion coefficient (in saturated condition) is reduced by the hydrophobic agents, however, the magnitude of this reduction is minor (reduced by 11% and 17%, depending on the product).      

Assessment of mechanical properties of concrete incorporating carbonated recycled concrete aggregates

An accelerated carbonation technique was employed to strengthen the quality of recycled concrete aggregates (RCAs) in this study. The properties of the carbonated RCAs and their influence on the mechanical properties of new concrete were then evaluated. Two types of RCAs, an old type of RCAs sourced from demolished old buildings and a new type of RCAs derived from a designed concrete mixture, were used. The chosen RCAs were firstly carbonated for 24 h in a carbonation chamber with a 100% CO₂ concentration at a pressure level of 0.1 Bar and 5.0 Bar, respectively. The experimental results showed that the properties of RCAs were improved after the carbonation treatment. This resulted in performance enhancement of the new concrete prepared with the carbonated RCAs, especially an obvious increase of the mechanical strengths for the concrete prepared with the 100% carbonated new RCAs. Moreover, the replacement percentage of natural aggregates by the carbonated RCAs can be increased to 60% with an insignificant reduction in the mechanical properties of the new concrete.     

Carbonation behaviour of recycled aggregate concrete

This paper reviews the effect of incorporating recycled aggregates, sourced from construction and demolition waste, on the carbonation behaviour of concrete. It identifies various influencing aspects related to the use of recycled aggregates, such as replacement level, size and origin, as well as the influence of curing conditions, use of chemical admixtures and additions, on carbonation over a long period of time. A statistical analysis on the effect of introducing increasing amounts of recycled aggregates on the carbonation depth and coefficient of accelerated carbonation is presented. This paper also presents the use of existing methodologies to estimate the required accelerated carbonation resistance of a reinforced recycled aggregate concrete exposed to natural carbonation conditions with the use of accelerated carbonation tests. Results show clear increasing carbonation depths with increasing replacement levels when recycled aggregate concrete mixes are made with a similar mix design to that of the control natural aggregate concrete. The relationship between the compressive strength and coefficients of accelerated carbonation is similar between the control concrete and the recycled aggregate concrete mixes.     

Influence of corrosion inhibitors on concrete transport properties

The effect on transport properties of admixing corrosion inhibitor in Portland cement based concrete is studied experimentally in this paper. Two commonly available types of corrosion inhibitor have been evaluated: an organic corrosion inhibitor and a nitrite based inhibitor. The gas permeability, water permeability and chloride migration of the resulting concrete were evaluated by means of standard test methods. In some cases, 1% sodium chloride was added to the concrete. It is found that both types of corrosion inhibitor lead to higher transport coefficients. The increment caused by the nitrite based inhibitor is higher than for the amine-ester based inhibitor. The influence of sodium chloride addition during mixing is not prominent. The obtained transport properties are analysed and discussed by means of BSE experiments and image analysis.     

Durability of recycled aggregate concrete prepared with carbonated recycled concrete aggregates

The mechanical properties of recycled aggregate concrete (RAC) incorporating carbonated recycled concrete aggregates (RCAs) have previously been reported. However, the durability of RAC prepared with carbonated RCAs remains to be accessed. In this study, the durability properties of RAC prepared with non-carbonated RCAs and carbonated RCAs, in terms of deformation (drying shrinkage), water absorption and permeability (bulk electrical conductivity, gas and chloride ion permeability), are presented. The experimental results indicated that: (i) the incorporation of the carbonated RCAs in RAC not only helped to reduce the water absorption of RAC, but also reduced its permeability; (ii) when 100% carbonated NRCAs was used, the improvement extent of impermeability was 15.1%, 36.4% and 42.4% for bulk electrical conductivity, chloride ion permeability and gas permeability, respectively. Comparing the results of the mechanical and durability properties, the CO₂ curing treatment of RCAs had a greater beneficial impact on the durability properties of the RAC; and (iii) there was a good correlation between the water absorption of RAC and its permeability indicators. The water absorption value of RAC may be used as a criterion of the durability of RAC.     

Stochastic multiscale modeling and simulation framework for concrete

In this paper we present a computational framework for generating a realistic representative volume element of concrete, which reflects its inherent structural randomness. Computed tomography (CT) images are employed to provide the necessary information for the geometric statistical characterization of aggregate and defect (voids, pores, and micro-cracks) distributions. A Monte-Carlo simulation is used to generate 1000 realizations of statistically equivalent representative volume element (SERVE) and finite element predictions of SERVEs elastic and inelastic response are compared with experiments.     

Effect of ground granulate blast-furnace slag on corrosion performance of steel embedded in concrete

Corrosion of steel in concrete is one of the major causes of premature deterioration of reinforced concrete structures, leading to structural failure. To prevent the failure of concrete structures because of corrosion, impermeable and high performance concretes should be produced various mineral admixtures. In this study, plain and reinforced concrete members are produced with mineral admixtures replacing cement. Ground granulated blast-furnace slag (GGBFS) has replaced cement as mineral admixture at the ratios of 0%, 25% and 50%. The related tests have been conducted at the ages of 28 and 90, after exposing these produced plain and reinforced concrete members to two different curing conditions. The unit weight, ultrasonic pulse velocity, splitting tensile and compressive strength tests are conducted on plain concrete members. Half-cell potential and accelerated corrosion tests are also conducted on reinforced concrete members. According to the test results, it is concluded that the curing age and type are important and corrosion resistant concrete can be produced by using GGBFS mineral admixture at the ratio of 25%.     

Probabilistic modeling of chloride-induced corrosion in concrete structures using first- and second-order reliability methods

Concrete structures are subjected to chloride-induced corrosion that can lead to shortened service life. Reliable predictions of life cycle performance of concrete structures are critical to the optimization of their life cycle design and maintenance to minimize their life cycle costs. This paper presents two simplified semi-analytical probabilistic models based on the first- and second-order reliability methods to model the uncertainty of the key parameters including surface chloride concentration, chloride threshold, cover depth and diffusion coefficient, which govern the chloride ingress into concrete and corrosion of reinforcing steel. A case study of a reinforced concrete highway bridge deck is used to illustrate the capability and efficiency of these simplified probabilistic models in modeling the uncertainty and predicting the time-dependent probability of corrosion. The models enable to quantify the impact of the different governing parameters on probability of corrosion and service life, which can be used to develop cost-effective management strategies.     

Factors influencing chloride-induced corrosion of reinforcement in concrete

The paper presents the results of a corrosion investigation on rebar electrodes embedded in concrete prism specimens which were exposed to cycles of sea-water spray for up to about 600 days (1200 marine cycles). The w/c ratio of the matrix was varied between 0.45 and 0.76 and the cement content ranged between 330 and 530 kg m^?3. Corrosion potential and polarization resistance of the electrodes were monitored at regular intervals by means of electrochemical procedures using a potentiostat apparatus. The Cl^? and OH^? concentrations in the matrix were also determined at the level of rebar electrodes. The results show that cement content has an insignificant influence on rebar corrosion, w/c ratio being the dominant factor which controls corrosion. The Cl^? and OH^? concentrations of the pore fluid are of secondary importance relative to w/c ratio. Acceptable corrosion rates are achieved at a w/c of 0.45, with the pore fluid Cl^?/OH^? ratio reaching a value of 11.     

Modeling of chloride-induced corrosion in reinforced concrete structures

A numerical procedure is presented in this paper for the prediction of chloride induced steel corrosion in reinforced concrete structures. Finite element analysis is introduced for the mechanical analysis of crack initiation and propagation due to the accumulation of corrosion products around the reinforcement, while the alternating direction implicit method is used to solve the transport equations of temperature, humidity, chloride ions and oxygen in concrete. Based on the assumption of a uniform distribution of corrosion products, a self-adaptation process for the variation of boundary conditions is proposed through a series of diffusion analyses together with crack propagation in concrete. Therefore, the interaction between the corrosion rate and the propagation of cracks in concrete is taken into account. Furthermore, a numerical program is developed and a case study involving bridge deck exposed to a marine environment in Hong Kong is investigated. The results show that interactive behavior has a significant effect on the corrosion rate of the reinforcement, and the non-cracking model significantly overestimates the service life of structures.     

Meso-scale numerical investigation on cracking of cover concrete induced by corrosion of reinforcing steel

Concrete cover cracking induced by corrosion of steel reinforcement is a major influencing factor for durability and serviceability of reinforced concrete structures. Here in this study, the influence of concrete meso-structure on the failure pattern of concrete cover is accounted for. The concrete is assumed to be a three-phase composite composed of aggregate, mortar matrix and the interfacial transition zone (ITZ). And a concrete random aggregate structure is established for the study on the mechanical behavior of radial corrosion expansion. In the present simulations, the plasticity damaged model is used to describe the mechanical behavior of the mortar matrix and the ITZ, and it is assumed that the corrosion of steel reinforcement is uniform. The cracking of concrete cover due to steel reinforcement corrosion is numerically simulated. The simulation results have a good agreement with the available test data and they are between the two analytical results. The failure patterns obtained from the macro-scale homogeneous model and the meso-scale heterogeneous model are compared. Furthermore, the influences of ratio of cover thickness and reinforcement diameter (i.e. c/d), the location of the steel reinforcement (i.e., placed at the middle and corner zones) and the concrete tensile strength on the steel corrosion rate when the concrete cover cracks are investigated. Finally, some useful conclusions are drawn.     

Cyclic modeling of FRP-confined concrete with improved ductility

Confinement by fiber reinforced polymer (FRP) wraps can significantly enhance strength and ductility of concrete columns. Behavior of FRP-confined concrete in uniaxial compression can be characterized by its bilinear stress–strain and unique dilation properties. A number of models have in recent years been developed to capture these characteristics under monotonic loading. None, however, have addressed the cyclic response of FRP-confined concrete. A total of 24 FRP-confined concrete stub specimens were tested in uniaxial compression under different levels of loading and unloading, with different fiber type, wrap thickness, and loading patterns. Based on a regression analysis of test results, a constitutive model is developed that includes cyclic rules for loading and unloading, plastic strains, and stiffness and strength degradations. The proposed model is validated by comparing analytical predictions with experimental results of an independent test series. Good agreement was shown between the analysis and experiments, confirming the ability of the model to predict the cyclic behavior of FRP-confined concrete. The model could be easily implemented in a fiber element model for flexural analysis of cyclic loaded beam-columns in conjunction with a strain gradient approach.     

Effect of curing parameters on CO2 curing of concrete blocks containing recycled aggregates

In this study, a CO₂ curing process was adopted in order to promote rapid strength development of concrete blocks containing recycled aggregates. The influence of several factors associated with the curing conditions on the curing degree and compressive strength of the concrete blocks were investigated, including curing time, temperature, relative humidity, pressure and post-water curing after the pressurized CO₂ curing (PCC) process. In addition a flow-through CO₂ curing (FCC) method at ambient pressure was also used. The results of the PCC experiments showed that, considerable curing degree and compressive strength were attained during the first 2 h of CO₂ curing, and a prolonged curing time yielded slower gains. The variations of temperature from 20 °C to 80 °C and relative humidity from 50% to 80% had limited impacts on PCC; but the effects of CO₂ gas pressure on the curing degree and compressive strength were more pronounced. The post-water curing after pressurized CO₂ curing allowed the concrete blocks to attain further strength gain but its effectiveness was inversely proportional to the CO₂ curing degree already attained. The FCC experimental results indicated that although a lower curing degree and slower strength development at the early age were observed, after 24 h of curing duration, they were comparable to those obtained by the PCC method. To assess the thermal stability of the concrete blocks, the optimum CO₂ curing regime was adopted for preparing the concrete blocks with recycled aggregates, and the CO₂ cured specimens exhibited better fire resistance than the water-cured ones at 800 °C.     

Performance updating of concrete bridges using proactive health monitoring methods

Uncertainties associated with modelling of deteriorating bridges strongly affect management decisions, such as inspection, maintenance and repair actions. These uncertainties can be reduced by the effective use of health monitoring systems, through which information regarding in situ performance can be incorporated in the management of bridges.The objectives of this paper are twofold; first, an improved chloride induced deterioration model for concrete bridges is proposed that can quantify degradation in performance soon after chlorides are deposited on the bridge, rather than when initiation of corrosion at the reinforcement level takes place. As a result, the implications of introducing proactive health monitoring can be assessed using probabilistic durability criteria. Thus, the second objective of the paper is to present a methodology for performance updating of deteriorating concrete bridges fitted with a proactive health monitoring system.This methodology is illustrated via a simple example of a typical bridge element, such as a beam or a part of a slab. The results highlight the benefits from introducing ‘smart’ technology in managing bridges subject to deterioration, and quantify the reduction in uncertainties and their subsequent effect on predictions of future bridge performance.     

Effects of phosphate on the chloride-induced corrosion behavior of reinforcing steel in mortars

The influence of phosphate as a corrosion inhibitor on the corrosion behavior of as-received and pre-rusted reinforcing steels in mortar specimens was investigated after 360 days exposure in 3.5% NaCl solution. This involved the use of electrochemical techniques for studying the steel surface reactions and microscopic observations of the steel–mortar interface. The electrochemical methods, including electrochemical impedance spectroscopy (EIS) and measurements of corrosion potential (E_corr) and linear polarization resistance (LPR), were employed to evaluate the corrosion tendency and general corrosion rate of steel. In addition, the pitting corrosion resistance of steel was also determined by cyclic polarization (CP) measurements. The results indicate that different from nitrite, which is generally accepted as an anodic inhibitor, phosphate may be a cathodic inhibitor according to its reduced corrosion rate and more negative E_corr at the same dosage as nitrite in mortar specimens. The study also reveals that the inhibiting efficiency of phosphate against general corrosion of both as-received and pre-rusted specimens is lower than 10%, which is inferior to nitrite in some respects. However, as indicated by cyclic polarization measurements, the presence of phosphate provides slightly higher pitting corrosion resistance in comparison to nitrite. Furthermore, it suggests that the corrosion inhibition mechanism of phosphate in mortars mainly depends on a dual effect occurring at the steel–mortar interface. Furthermore, it is confirmed that phosphate has little effect on the long-term mechanical properties of mortars.