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本文叙述了一种新的测量方法—同位素X萤光背射法,用低能光子源激发稀土矿浆样品,使之产生特征X射线峰和反散射峰。反散射峰的强度与矿浆浓度存在单值对应的非线性关系。浓度越低反散射峰强度越高,由此可直接测量矿浆浓度。它解决了选矿过程中高原子序数介质的矿浆浓度的在线测量问题。这种新的放射性同位素应用技术,与同位素射线吸收法测量矿浆浓度在原理上有着根本不同。目前,此方法未见公开报导。 相似文献
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河北汉诺坝玄武岩稀土元素特征 总被引:1,自引:0,他引:1
本文主要对河北汉诺坝碱性玄武岩和拉斑玄武岩十七个样品的稀土元素含量进行了测定。两种玄武岩在球粒陨石标准化模式图上有明显富集轻稀土的特征,且均具有正的微弱Eu异常,稀土元素丰度变化受岩性变化的控制。 相似文献
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随着稀土在冶金中应用的发展,要求有相应的稀土总量与轻重稀土分量的测定方法。 我国稀土资源丰富,矿源轻重比例各不相同,这就反映到加入钢铁中的稀土元素轻重比例也各不相同。尽管以前测定稀土总量的灵敏显色剂很多,但大多数对轻稀土的发色能力强、摩尔吸光系数较大;而对重稀土含量高的样品,测其总量就存在着因轻重稀土比例不同而检量线不同的问题。 相似文献
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《四川有色金属》2016,(3)
轻稀土铈替代稀土永磁材料钕铁硼中的钕是降低生产成本、平衡稀土资源利用比较有效的方式。本文首先通过调节合金成分研究了制备Nd_2Fe_(14)B单相的工艺,其次以轻稀土铈部分替代钕的方式通过X射线衍射仪、扫描电镜及振动样品磁强计分别研究了(Nd_(1-x)Ce_x)_(11.76)Fe_(81.39)B_(6.85)(x=0.0,0.1,0.2)物相的晶体结构、微观组织及磁性能。研究结果表明替代后的物相均为Nd_2Fe_(14)B型的四方相。通过在600℃下烧结2小时,随着铈添加的含量增多合金的内禀矫顽力以及剩磁虽然有所下降,但当铈含量添加到20%(x=0.2)时,合金的内禀矫顽力和剩磁仍然可达到9.31kOe和98.80emu/g。 相似文献
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稀土标准分析方法中稀土元素分析谱线的述评 总被引:1,自引:0,他引:1
针对ICP-AES法测定稀土样品中稀土元素时,一些元素的分析谱线难以选择的问题,总结了稀土标准分析方法中利用电感耦合等离子体发射光谱法测定单一稀土金属及其氧化物中稀土杂质量,稀土矿石、稀土精矿、离子型稀土矿、氯化稀土、碳酸轻稀土及钐铕钆中的稀土配分量,氧化钇铕中的稀土杂质及氧化铕量,镝铁合金、钆镁合金中的稀土杂质量,稀土硅铁及镁硅铁合金中的稀土总量、镨钕合金及其化合物、钕铁硼废料中的配分量时,所选用的分析谱线。为分析检测类似样品时选择分析谱线方面起到一定的参考作用。 相似文献
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稀土资源中轻稀土镧、铈、镨、钕比重很大 ,光学玻璃、储氢材料、抛光粉、催化剂、颜料、永磁体等都使用大量的轻稀土。因此 ,氟碳铈镧矿、独居石的轻稀土分离更显重要〔1,2〕。在湿法冶金生产过程中 ,分析方法异常丰富 ,随着电感耦合等离子体发射光谱、X射线荧光等仪器分析的迅速发展 ,常规分析和产品分析日臻完善 ,形成了许多国家和行业标准〔3,4〕。快速、准确的仪器分析可随时掌握生产工艺的运行状态 ,从而保障产品质量的合格和稳定 ,但昂贵的大型仪器又制约中控分析的普及 ,较高的使用和维护费非一般规模项目所能承受。本文提出的经典… 相似文献
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M. L P. REDDY T. R. RAMAMOHAN C. CHANDRA SHEKARA BHAT P. B. SHANTHI A. D. DAMODARAN 《Mineral Processing and Extractive Metallurgy Review》2013,34(1-4):273-282
Abstract An empirical mathematical model has been developed for the simulation of an integrated solvent extraction circuit consisting of an extractor, scrubber and a stripper. This model is designed to simulate the separation of any lanthanide from a mixed lanthanide feed. The Kremser equation is used to calculate the separation occurring in each section of the circuit. The inputs required for the simulation are the feed composition, separation factors, equilibrium data of the key element under a wide range of conditions, the number of stages and flow rates of the aqueous and organic streams in the circuit. This model has been validated with the experimental data for the separation of Nd from a mixed lanthanide chloride feed with 2-ethylhexyl phosphonic acid mono 2-ethyl-hexyl ester (EHPNA) as an extractant. 相似文献
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YanLu-Ming;(严六明);ZhanQian-Bao;(詹千宝);QinPei;(钦佩);ChenNian-Yi;(陈念贻)(ShanghaiInstituteofMetallurgy,AcademiaSinica,Shanghai200050... 相似文献
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Sincerareearthchelateswerefoundtoemitlaserinthebeginningof 1 96 0s ,thefluo rescenceproperties ,efficiencyandlifetimeforrareearthorganicchelateswereextensivelystudied .Thechelateswereprovednottobesuitableforlasermaterialsintheendof1 970s .Soinisuggestedtousera… 相似文献
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The enthalpies of solution in water of complexes of RE(NO3)3(RE = La - Nd, Sm- Lu, Y) with L-α-Histidine (His) were measured at 298.15 K. The standard enthalpies of formation of RE(His)^3 (aq) were calculated. The “tetrad effect” regularity was observed from the curve, which is the enthalpies of solution plotted against the atomic numbers of the elements in lanthanide series. 相似文献
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New Opportunities for Lanthanide Luminescence 总被引:1,自引:0,他引:1
Jean-Claude G. Bünzli 《中国稀土学报(英文版)》2007,25(3):257-274
Trivalent lanthanide ions display fascinating optical properties. The discovery of the corresponding elements and their first industrial uses were intimately linked to their optical properties. This relationship has been kept alive until today when many high-technology applications of lanthanide-containing materials such as energy-saving lighting devices, displays, optical fibers and amplifiers, lasers, responsive luminescent stains for biomedical analyses and in cellulo sensing and imaging, heavily rely on the brilliant and pure-color emission of lanthanide ions. In this review we first outlined the basics of lanthanide luminescence with emphasis on f-f transitions, the sensitization mechanisms, and the assessment of the luminescence efficiency of lanthanide-containing emissive molecular edifices. Emphasis was then put on two fast developing aspects of lanthanide luminescence: materials for telecommunications and light emitting diodes, and biomedical imaging and sensing. Recent advances in NIR-emitting materials for plastic amplifiers and waveguides were described, together with the main solutions brought by researchers to minimize non-radiative deactivation of excited states. The demonstration in 1999 that erbium tris(8-hydroxyquinolinate) displayed a bright green emission suitable for organic light emitting diodes (OLEDs) was followed by realizing that in OLEDs, 25% of the excitation energy leads to singlet states and 75% to triplet states. Since lanthanide ions are good triplet quenchers, they now also play a key role in the development of these lighting devices. Luminescence analyses of biological molecules are among the most sensitive analytical techniques known. The long lifetime of the lanthanide excited states allows time-resolved spectroscopy to be used, suppressing the sample autofluorescence and reaching very low detection limits. Not only visible lanthanide sensors are now ubiquitously provided in medical diagnosis and in cell imaging, but the feasibility of using NIR emission of ions such as YbⅢ is now being tested because of deeper penetration in biological tissues. 相似文献
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Abstract Solvent extraction is a powerful method for lanthanide and actinide intra- and inter-group separations. Apart of the general parameters governing the extraction.f-electron elements exhibit several peculiarities of the process. Two of them are described in the paper: double-double (tetrad) effect in the lanthanide and actinide series and itinerant properties of the actinides (III) in respect to the lanthanide series, as well as the effects of inner- and outer-sphere hydration of the extracted species. Extraction chromatography is presented as the most powerful technique of the extractive separation. 相似文献
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The kinetic behaviours of the substitution reaction of rare earth-PHA with CyDTA were studied systemati-cally.The relationship between the rate constant and atomic number was discussed.The rate differentiation val-ue R_d(R_d=lgk_(z n)-lgk_z)was proposed to evaluate the possibility of differential kinetic analysis.The R_d valuebetween the neighbouring lanthanide ions first increases and then decreases along with increasing atomic number,so that the middle and heavy rare earth mixture(such as Sm-Gd and Gd-Y)are ideal systems for thedifferential rate kinetic analysis. 相似文献
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The solid oxide fuel cell (SOFC) is a high-efficient and environmentally friendly power generation system.The rare earth oxide materials are used extensively in the manufacturing of SOFC components.In particular, the CeO2doped with Gd2O3 or Sm2O3, lanthanide perovskite oxides are indispensable and key materials for developing the intermediate temperature SOFC.The research and development status of application of high purity rare earth oxides in SOFC was overviewed.The rare earth oxide-based and -doped materials were discussed for the SOFC components.Concerning the rare earth oxides applicable to SOFC, several topics were also pointed out for further researching and developing. 相似文献
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HalinaHubicka 《中国稀土学报(英文版)》2002,20(1):31-35
The rare earth complexes with EDTA, Ln(edta), show an unusual sequence of affinity for the anion-ex-changers. The sorption and chromatographic separation of y3 for Nd3 complexes with EDTA was studied by using the strongly basic gel and macroporous polyacrylate anion-exchangers, Amberlite IRA 458 and Amberlite 958, and the weakly basic gel polyacrylate anion-exchanger, Amherlite IRA-68. The investigations on sorption and separation of rare earth complexes with EDTA on the polyacrylate anion-exchangers applied mainly in the environment protection so far indicate that they can he applied in anionexchange separation of lanthanide complexes with aminopolycarboxylic acids. It was shown that the weakly basic polyacrylate gel anion-exchanger Amberlite IRA-68 is the most effective in purification of y3 from Nd3 in comparison with the strongly basic anion-exchangers of this type. 相似文献