共查询到19条相似文献,搜索用时 897 毫秒
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综述了聚丙烯用阻燃剂的3种阻燃作用机理,包括气相阻燃、凝聚相阻燃、中断热交换阻燃机理。重点介绍了聚丙烯用阻燃剂的研究开发进展,包括水合金属化合物阻燃剂、磷系阻燃剂、膨胀型阻燃剂、硅系阻燃剂、纳米阻燃剂等。最后,指出纳米无机阻燃剂、膨胀型阻燃剂以及具有高效阻燃、低烟、无毒的复配阻燃剂是聚丙烯用阻燃剂未来的发展趋势。 相似文献
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膨胀型阻燃剂在阻燃聚丙烯中的应用 总被引:3,自引:0,他引:3
简述了阻燃聚丙烯的发展概况,重点阐述了膨胀型阻燃剂的阻燃机理及其在阻燃聚丙烯中的应用现状,叙述了一些典型的膨胀阻燃体系及特点,并概述了膨胀型阻燃剂的发展方向。 相似文献
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膨胀型阻燃剂在聚丙烯中的应用研究进展 总被引:1,自引:0,他引:1
综述了近年来聚丙烯(PP)阻燃用膨胀型阻燃剂的研究应用现状,简要概述了膨胀型阻燃剂的阻燃机理,分析了膨胀型阻燃存在的不足,指出了膨胀型阻燃剂发展方向。 相似文献
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概述了聚丙烯阻燃剂的作用机理,介绍了水合金属化合物、磷系阻燃剂、膨胀型阻燃剂等在聚丙烯(PP)阻燃应用中的研究进展。采用表面改性及微细化等措施对水合金属化合物和磷系阻燃剂进行改性,可以克服常规无机阻燃剂添加量大、对制品加工性能和物理性能有较大影响的不足。膨胀型阻燃剂、复合阻燃剂、多功能阻燃协效剂都是今后值得关注的方向。 相似文献
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The flame retardant polypropylene containing the micro-envelope core-shell structure flame retardant, which encapsulated ammonium polyphosphate into melamine-formaldehyde resin and sodium silicate through in situ polymerization was prepared with polyamide 6, added as a carbon-forming agent. The composition of ammonium polyphosphate, encapsulated ammonium polyphosphate with melamine-formaldehyde resin and the micro-envelope core-shell structure flame retardant were characterized. The fire safety and thermal stability were investigated and showed an improvement including limiting oxygen index, thermogravimetric analysis, vertical burning tests, and microscale combustion calorimeter. The burned compounds were also studied to confirm the burning mechanism. The results showed the flame retardant performance had been greatly improved, while polyamide 6 had better char-forming effect. Besides, the water solubility of flame retardants and their influence on the mechanical properties of polypropylene were also investigated. The results on the effects of additives demonstrated a high efficiency flame retardant to polypropylene. A core-shell flame retardant that sodium silicate and melamine-formaldehyde resin-coated ammonium polyphosphate had been constructed. The effect of the built flame retardant system on the combustion performance of polypropylene was studied from the mechanism and performance. The LOI of the most flame retardant polypropylene reached 28.6%, and UL-94 reached the V-0 level. 相似文献
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Dehong Chen Qiukai Zheng Feiyue Liu Linli Xu Kai Xu 《Polymer-Plastics Technology and Engineering》2013,52(4):432-439
Rod-like morphological magnesium hydroxide nanoparticles were synthesized via coprecipitation with copper ions. Flame retardant composites were prepared by these particles and polypropylene. The microstructure, flame retardation, mechanical property, thermal oxidative degradation behavior and mechanism of these composites were discussed. The results demonstrated that these composites containing copper compound increased the flame retardation, but decreased the initial oxidative decomposition temperatures and mechanical properties. Thermogravimetric and infrared analysis showed that the decomposition procedure was divided into three stages. In addition, the degradation kinetics was analyzed by Flynn-Wall-Ozawa method, and it showed that polypropylene composites containing copper compound exhibited a different decomposition mechanism. 相似文献
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严淑芬 《现代塑料加工应用》2007,19(6):61-64
综述了近年来聚丙烯(PP)主要阻燃体系的研究进展,并叙述各类PP用复合阻燃体系如Sb203/卤系阻燃体系、磷系阻燃体系、膨胀型阻燃体系、有机硅复合体系等的研究应用状况,指出了PP阻燃的发展方向。 相似文献
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