共查询到19条相似文献,搜索用时 62 毫秒
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聚醚改性硅油,是在硅氧烷链段上引入聚醚链段,使分子结构中含有疏水基团和亲水基团的一种特殊结构的聚硅氧烷化合物。其中聚硅氧烷部分赋予表面活性剂以耐候、低表面张力、抗静电、生理惰性等特点。通过调节聚醚的氧化乙烯(E沪)、氧化丙烯(PO-)的聚合度及其之比和不同封端,可以获得不同性能、不同用途的表面活性剂。在涂料工业、聚氨酯、农药、日化工业、纺织行业、消泡剂等有很重要的应用,是改性有机硅油中应用最广、品种最多的一类产品。 相似文献
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介绍了聚醚改性聚硅氧烷的合成方法,例举了其作为乳化剂在日化个人护理品、消泡剂及光亮剂中的应用。 相似文献
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以高碳醇、植物油脂和消泡颗粒为主消泡成分,聚醚改性聚硅氧烷为增效助剂,磺化油脂、斯潘-80和吐温-80为复合乳化剂体系,制得聚醚改性聚硅氧烷消泡剂。同时探讨了在不同温度下,该消泡剂应用于抄纸白水中的消泡效果。通过与国内外产品对比,自制产品具有更优越的消泡/抑泡和快速消除细微泡沫的能力。 相似文献
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以低含氢硅油和烯丙基聚醚为原料、氯铂酸为催化剂,在无溶剂条件下合成了聚醚改性聚硅氧烷;并将其与硅膏、白炭黑、乳化剂、增稠剂等复配,制成有机硅消泡剂。探讨了加料分式及加料时间、物料配比、催化剂用量、反应温度、反应时间等对反应的影响,以及消泡剂在水性涂料中的应用性能。结果表明,合成聚醚改性聚硅氧烷的最佳工艺为:Si—H与C=C的量之比为1∶1.1、铂的加入量占物料总质量的5×10-6,聚醚滴加时间3 h、反应温度130℃、反应时间6 h,在此条件下活性氢的转化率可达82.8%。由此聚醚改性聚硅氧烷配成的有机硅消泡剂用于水性涂料中,具有优异的消/抑泡性能及良好的体系相容性。 相似文献
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低黄变和亲水性氨基聚硅氧烷的开发 总被引:8,自引:1,他引:8
概述了氨基聚硅氧烷的发展历程、特点及发展趋势,着重介绍了氨基聚硅氧烷的黄变机理,低黄变氨基聚硅氧烷、亲水性氨基聚硅氧烷的开发,以及氨基聚硅氧烷的生态环保性。 相似文献
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The morphology and fracture toughness of epoxy resins modified with amino-terminated polydimethylsiloxane (ATPDMS), differing in their molecular weight, and the degree of the preliminary reaction in the melt state were investigated. Tetramethyl biphenol diglycidyl ether (TMBPDGE) was used as the base epoxy resin. The degree of preliminary reaction between epoxy and polysiloxane increased with the decrease of the molecular weight of polysiloxane in the melt state. When the low molecular weight polysiloxane (AT900) was mixed with high molecular weight polysiloxane in the preliminary reaction, the low molecular weight polysiloxane enhanced the compatibility between the epoxy resin and the high molecular weight polysiloxane and produced smaller size and narrow distribution of polysiloxane particles. The small and highly concentrated polysiloxane particles, as determined by scanning electron microscopy improved the fracture toughness of the epoxy resin. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 64: 941–955, 1997 相似文献
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A higher-ordered polysiloxane was prepared by the sol-gel reaction of (3-(2-aminoethylamino)propyl)trimethoxysilane in a hydrochloric acid aqueous solution without using any surfactants. The X-ray diffraction profile of the resulting polysiloxane showed three peaks with the d-value ratio of 1:1/√3:1/2, indicating that this polysiloxane has a hexagonal phase. The peaks shifted by changing the humidity. Therefore, we estimated that this hexagonal phase came from the stacking of a rodlike polymer with a Si-O-Si framework at the core and ammonium groups extruding outside. The TEM image of the polysiloxane showed a stripe pattern indicating an ordered arrangement. Because one repeating unit of the present polysiloxane has two ammonium groups, the ion-exchange capacity of this polysiloxane and viscosity of its aqueous solution were larger than those of the previous polysiloxane with single-ammonium group. 相似文献
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以107、甲基二甲氧基封端107和三甲氧基封端107为基础聚合物,以二甲基甲氧基单边封端聚二甲基硅氧烷为新型增塑剂,以碳酸钙为补强填料,制备研究贮存稳定、对石材无污染醇型硅酮密封胶。探讨了聚合物类型、增塑剂添加量以及碳酸钙与基础聚合物配比对密封胶性能的影响。 相似文献
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多苯基聚硅氧烷对硅橡胶阻尼性能的影响 总被引:1,自引:0,他引:1
以低苯基硅橡胶为基胶,通过添加多苯基聚硅氧烷,制备出阻尼硅橡胶,并对其性能进行了研究。结果表明,加入铂催化的多苯基聚硅氧烷能显著提高硅橡胶在-50-150℃温度区域内的阻尼系数;多苯基聚硅氧烷中侧基数量越多,阻尼系数峰值出现的温度越高。加入铂催化的多苯基聚硅氧烷能够显著提高硅橡胶的撕裂强度和断裂伸长率,对硅橡胶的拉伸强度和热稳定性影响不大。两种催化体系合成的多苯基聚硅氧烷对硅橡胶阻尼系数的影响不同,Ph3SiO-接枝率较低时,加入锡催化剂多苯基聚硅氧烷的硅橡胶的阻尼峰值较高;接枝率进一步增加时,加入铂催化多苯基聚硅氧烷的硅橡胶的阻尼系数曲线出现尖峰,而加入锡催化剂多苯基聚硅氧烷的硅橡胶的阻尼峰仍呈现宽峰。 相似文献
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重防腐涂装工程中三种高档面漆的比较——聚氨酯/氟碳/聚硅氧烷 总被引:1,自引:0,他引:1
介绍了当前重防腐涂装工程中聚氨酯、氟碳、聚硅氧烷3种面漆,并从涂料成膜机理、性能、施工等方面作了对比,对环氧聚硅氧烷和丙烯酸聚硅氧烷2种面漆进行了分折。 相似文献
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J. O. Iroh Deepika Rajamani 《Journal of Inorganic and Organometallic Polymers and Materials》2012,22(3):595-603
Environmentally friendly polysiloxane and clay/polysiloxane composite coatings were synthesized on aerospace-grade aluminum
alloy AA2024-T3 substrates from mildly acidified aqueous solution. The polysiloxane coatings were synthesized by acid-catalyzed
hydrolysis and condensation of organosilane coupling agents such as glycidoxypropyltrimethoxysilane (GPTMS) and tetramethoxysilane
(TMOS) followed by solution drop-casting onto the substrate to form self assembled nanoparticles, coating. The epoxy polysiloxane
coating formed by condensation reaction of hydrolyzed TMOS and GPTMS was subsequently cured with aminosilane coupling agent
to form cross-linked polysiloxane coating. Clay/polysiloxane coating was formed by dispersing about 0.1–0.3wt% of clay in
the hydrolyzed TMOS/GPTMS solution followed by solution casting and the resulting clay/polysiloxane composite coating was
subsequently cured with aminosilane coupling agent. The structure and composition of organosilane coupling agents and hybrid
polysiloxane coatings were determined by reflection–absorption infrared spectroscopy (RAIR) and X-ray diffraction spectrometry
(XRD). The hydrolysis, condensation and curing reactions of TMOS and the organosilane coupling agents were studied by analyzing
thin films cast on aluminum alloy substrate after a predetermined reaction time by using RAIR. The XRD results show that the
resulting polysiloxanes are semi-crystalline polymers. Wide angle XRD analysis indicated that clay dispersed in clay/polysiloxane
composite coating is either highly intercalated or partially exfoliated. This inference was drawn from the disappearance of
d001 diffraction peak for clay from the XRD spectrum of clay/polysiloxane coatings cured at 100 °C for 2.5 h. 相似文献