共查询到19条相似文献,搜索用时 78 毫秒
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H103树脂吸附废水中苯胺 总被引:10,自引:2,他引:8
1前言生产多亚甲基多芳基异氰酸酯(简称PAPI)时有大量苯胺废水排放,严重污染环境。我们采用国产H103大孔吸附树脂吸附,使排放废水中苯胺浓度达3mg.cm-’以下,吸附效果优于美国AmberlitXAD-4树脂(图互),又以50~60oC稀盐酸或工业酒精脱附,苯胺回收率>90%,回收苯胺可用于PAPI生产中‘’-’1。固定吸附床放大设计的方法有多种:传质模型法I‘]、改良设计法、工作吸附量法和Bob].Adams[5]法。经小试及放大试验装置实测比较,认为溶液在床层内停留时间了Z吸附达到平衡所… 相似文献
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《广东化工》2021,48(4)
本文主要研究以树脂吸附为核心,结合次氯酸钠氧化处理苯胺类含盐废水。通过优化吸附条件,比选出最佳树脂吸附工艺。通过进一步研究发现,在树脂吸附的基础上,通过投加定量次氯酸钠进行脱色及COD再处理,使最终出水COD稳定在500 mg/L左右,苯胺的去除率达100%,出水蒸发回收的盐品质好,蒸馏冷凝水COD500 mg/L,达到园区污水处理厂的接管标准。树脂吸附饱和后采用2.5 BV丙酮再生,可恢复吸附能力,连续运行15批次,出水COD及色度均稳定。树脂吸附耦合氧化处理苯胺类含盐废水,既能有效去除废水中苯胺,也能资源化回收盐,实现环境和经济效益的双丰收,并已实现工业化。 相似文献
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在静态条件下研究了粉煤灰对含苯胺废水的处理。比较了不同条件下粉煤灰对苯胺废水的处理效果,确定了处理废水时间、粉煤灰用量、废水pH值、温度、废水中苯胺浓度对处理结果的影响。结果表明,粉煤灰在时间30min、用量8.0g、温度25℃、pH值2.5左右时,对100ml浓度为200mg/L的含苯胺废水的吸附效果最好,去除率高达97.7%。处理后的苯胺废水达到国家三级排放标准(5.0mg/L)。 相似文献
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采用萃取-H103大孔树脂吸附联合处理苯胺废水,试验了各种条件对废水中COD和苯胺去除率的影响.结果表明,萃取的最佳工艺条件是:甲苯作萃取剂,pH为7.5,萃取剂与废水体积比为1:2,在室温(10℃)下振荡、恒温箱(25℃)中静置各10 min进行二级萃取,废水中COD和苯胺去除率均达到90%以上;以萃取出水作为后续H103大孔树脂吸附柱的进水,当pH为7.5,废水流速以2.5、3.5、4.5 BV·h-1流过吸附柱,出水中COD和苯胺质量浓度降至100 mg·L-1和5 mg·L-1以下,去除率分别达到92%和95%以上. 相似文献
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《煤炭加工与综合利用》2017,(10)
针对当前苯胺类废水处理方法的不足,探讨采用大孔树脂吸附—电解和臭氧再生法处理苯胺废水,研究其吸附及再生机理、不同组合工艺的可行性和稳定性,优化工艺运行条件,为工程实际应用提供设计、操作的基础参数和可行性的依据。 相似文献
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有机化工废水中典型的有机污染物,如苯胺、苯酚等,具有高毒性、易生物富集、难生物降解等特质,不仅对人体健康造成不利影响,还会引起严重的环境污染。因此,从水中高效地去除有机污染物迫在眉睫。超交联树脂对有机污染物具有较高的吸附容量及优异的吸附选择性,开发具有高表面积和丰富官能团的功能化超交联树脂有一定的学术价值和广阔的应用前景。本文以氯甲基化聚苯乙烯为前体,3,5-二甲基苯酚为功能单体,甲缩醛为外加交联剂,通过亲核取代反应和Friedel-Crafts烷基化反应,合成了富氧功能化超交联树脂。结果表明,富氧功能化超交联树脂拥有较高的氧含量[8.67%(质量)]、较大的比表面积(198 m2/g)和丰富的微孔(微孔面积占总比表面积的36.3%),300 K下对苯胺的平衡吸附量达156.4 mg/g。树脂对低浓度的苯胺有优秀的吸附效率,达到国家一级排放标准(<1.0 mg/L),且具有优良的循环使用性能。 相似文献
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文章以粉煤灰为吸附剂,以盐酸和氢氧化钠分别作为酸、碱改性剂,对粉煤灰进行了改性处理,并对不同类型粉煤灰对苯胺废水中苯胺的吸附行为进行了研究。实验结果表明酸改性粉煤灰相比碱性粉煤灰和未改性粉煤灰对苯胺废水有较高的COD去除率和色度去除率。搅拌只能加快吸附到达平衡的时间,对粉煤灰平衡状态下的吸附能力基本没有影响。在pH为9.5,常温条件下,适宜的酸改性粉煤灰投加量为每100mL废水投加5 g,较佳的搅拌速率为200 r/min,在此情况下,苯胺废水的COD去除率和色度去除率分别为34.6%和37.8%。 相似文献
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Treatment of aniline hypersaline wastewater with a combined physical–biological method was investigated in this study. This method consisted of the physical adsorption of aniline from hypersaline effluents by resins and the biodegradation of the adsorbate and the regeneration of the adsorbent in the subsequent stage. The XDA-1 resin, selected from five commercial products, could separate aniline from salt effectively. The adsorption rate increased with the increase of salinity. Biodegradation of the aniline desorbed from the exhausted resin could be realized easily without salt interference. During the repetitive six combined operations, the percentage regeneration (PR) and NaCl separation efficiency (SE) of XDA-1 were 92.3% and 98.3%, respectively. No obvious difference could be found in pore size distribution between virgin XDA-1 and samples repeated six regeneration cycles. The PR of specific surface area and total pore volume of the bio-regenerated XDA-1 resin were 94.5% and 97.2%, respectively. It was indicated that XDA-1 could be bio-regenerated successfully and the regenerated resin could be re-utilized. 相似文献
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醇溶苯胺黑生产过程中产生大量含三氯化铁的苯胺废水,采用中和一过滤一恒沸精馏技术处理该类废水并从中回收苯胺,提出了节能减排的设计方案。将该设计用于苯胺废水处理能力300t/d的生产装置后,解决了三氯化铁污染塔设备的问题,降低了新鲜蒸汽和循环水消耗,提高了苯胺的分离效果,可使蒸汽消耗量降低30%~40%,循环水消耗量降低70%,排放废水中的苯胺质量分数由原来的(1000~3000)×10^-6降低到200×10^-6。 相似文献
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Yanhe Han Xie Quan Shuo Chen Huimin Zhao Chunyue Cui Yazhi Zhao 《Separation and Purification Technology》2006,50(3):365-372
For adsorptive separation processes, the adsorption rate and capacity are two important factors affecting the costs. This study describes the anodic polarization of activated carbon fibers (ACFs), which can enhance the adsorption rate and capacity of aniline. The electrosorption kinetics and the affecting factors (bias potential, electrolyte, and pH) of isotherms for aniline on ACFs were investigated. The adsorption/electrosorption of aniline on ACFs follow pseudo-first-order adsorption kinetics, and the adsorption rate improves with increasing bias potential. The electrosorption isotherms, which exhibit a variety of responses depending on bias potential, electrolyte and pH, follow the two classical models of Langmuir and Freundlich. With electrosorption of aniline from aqueous solution, a two-fold enhancement of adsorption capacity is achievable. The initial and saturated ACFs were characterized using scanning electron micrograph (SEM) and Fourier transform infrared spectroscopy (FT-IR). The SEM micrographs show that the surface of ACFs is not oxidized, which is also verified by cyclic voltammetry results. The FT-IR spectroscopy suggests that the interaction between aniline and ACFs is main weak physisorption instead of chemisorption. These experimental results suggest that the electrochemical polarization of ACFs can effectively improve the adsorption rate and capacity of aniline, which may be due to the enhanced affinity between aniline and ACFs instead of the oxidation on the surface of ACFs or in the solution. 相似文献
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采用微波催化氧化法对苯胺模拟水的处理进行了初步的探讨分析;考察了微波时间、微波功率、pH值、H2O2浓度、高分子负载型催化荆质量对废水中苯胺降解的影响,确定了最佳工艺条件.在最佳工艺条件下,CODcr的去除率达到98%以上. 相似文献
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苯胺生产废水中含有硝基苯等有机物,若直接排放,将对环境造成污染。本文简要介绍了我公司将处理苯胺生产废水的生物法改为合成氨制浆工艺处理的方法。运行结果表明:装置运行平稳;工艺气满足生产需要;废水处理费用减少。 相似文献
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