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《Polymer-Plastics Technology and Engineering》2013,52(5):1403-1424
Abstract A simple and inexpensive technique for preparation of membranes by chemically induced graft copolymerization of methacrylic acid (MAA) onto low-density polyethylene (PE) films using sodium bisulfite (SBS) initiator was developed. Several parameters affecting the grafting rate and yield, such as the concentration of aqueous monomer solutions (4–20%) and initiator (0.025–0.2 M/L), reaction temperature (50–70°C), and within reaction times ranging from 1 to 6 h were studied. The results show that grafted films with 20% up to 500% graft were obtained under the synthesis conditions mentioned. Some selective properties of the grafted films (membranes), such as swelling behavior and mechanical properties were investigated. Also, the films were characterized by infrared (IR) spectroscopy, thermal gravimetric analysis (TGA), and scanning electron microscopy (SEM). Such prepared graft copolymers may be of great interest in some practical uses such as dialysis and ultrafiltration membranes and also for wastewater treatment from heavy and toxic metals. 相似文献
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Modification of chitin by grafting with itaconic acid (IA) was carried out using potassium persulfate as redox initiator. In complimentary experiments, grafting was performed using γ‐radiation. Grafting was confirmed by FTIR spectroscopy. The effect of monomer concentration, initiator concentration and copolymerization temperature on the percentage of grafting were studied. The effect of radiation dose was also investigated. Values for percentages of grafting of up to 300 % were reached. It was observed that the percentage of grafting increased with increasing monomer concentration and showed a tendency to level off at IA concentration of 0.1 mol l?1. The percentage of grafting increased with temperature up to 60 °C and then decreased. The solubility of the grafted chitin was studied in organic and inorganic solvents. The complexation of the grafted chitin with some cations, namely copper, nickel, cobalt, zinc and lead, was also investigated. The metal uptake was measured by UV spectroscopy. Thermogravimetric analysis of the grafted chitin was also studied. Copyright © 2004 Society of Chemical Industry 相似文献
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Graft copolymerization of acrylonitrile (AN) on chemically modified sisal fibers was studied using a combination of NaIO4 and CuSO4 as initiator in an aqueous medium in the temperature range of 50–70°C. Effects of reaction medium, variation of time and temperature, concentration of CuSO4, NaIO4 and AN, and the amount of sisal fiber on the percentage of graft yield have been investigated. Water absorption (%) and tensile properties such as tensile strength, Young's modulus and extension at break of untreated, chemically modified and AN‐grafted sisal fibers were evaluated and compared. FTIR spectroscopy and scanning electron microscopy (SEM) of the chemically modified and AN‐grafted sisal fibers have been carried out. 相似文献
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超细纤维素与丙烯酸接枝共聚反应规律的研究 总被引:5,自引:2,他引:5
用过硫酸盐氧化法使超细纤维素与丙烯酸接枝共聚。当反应温度 88℃ ,反应时间 5h ,单体用量 3 .75mol/L ,引发剂浓度 3 .5mmol/L ,接枝率可达 70 %以上。文章同时对其接枝反应的机理进行了探讨。 相似文献
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剑麻纤维蒸汽爆破处理研究 总被引:23,自引:2,他引:23
采用蒸汽爆破处理技术处理剑麻纤维,分析阐述了蒸汽爆破处理过程及原理。通过化学分析方法及扫描电镜、红外光谱、X—射线衍射等现代分析手段分析蒸汽爆破处理前后剑麻纤维化学组分和形态结构的变化。结果表明,蒸汽爆破处理技术能够实现剑麻纤维各组分的有效分离,减少杂质成分,提高纤维素含量;同时,蒸汽爆破处理能改善剑麻纤维的形态结构,提高化学试剂的可及度,改善化学反应性能。 相似文献
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Polypropylene (PP) films were grafted with N-phenylmaleimide using γ-radiation. The effect of both monomer concentration and dose rate on the degree of grafting was measured. Characterization of the grafted PP films included IR spectroscopy, X-ray spectroscopy, electrical conductivity, mechanical properties and thermal stability has been studied. © of SCI. 相似文献
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壳聚糖和丙烯酰胺基甲基丙磺酸接枝共聚及表征 总被引:7,自引:0,他引:7
以硫酸铈铵为引发剂,醋酸为溶剂,用2 丙烯酰胺基 2 甲基丙磺酸(AMPS)与壳聚糖(CTS)制备CTS-AMPS接枝改性产品。正交实验优化出较佳的工艺条件为:反应时间3h,反应温度40℃,m(CTS)∶m(AMPS)=1∶5,引发剂用量5g(相对于1g壳聚糖)。用IR和X射线衍射对产物进行了表征。 相似文献
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Graft copolymers of sodium alginate (NaAlg) with itaconic acid (IA) were prepared in aqueous solution using ceric ammonium nitrate (CAN) as the redox initiator under N2 atmosphere. The carboxylic acid groups of IA were neutralized with sodium hydroxide before grafting process. Grafted copolymers as sodium salts (NaAlg‐g‐PIA) were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, intrinsic viscosity measurement, differential scanning calorimetry, and thermogravimetric analysis. The graft yield (GY %) of the graft copolymer and the grafting efficiency (GE %) of the reaction were evaluated comparatively. The effects of the reaction variables such as the reaction time, temperature, percentage of NaAlg, monomer and initiator concentrations on these parameters were studied. It was observed that GY% and GE% increased and then decreased with increasing concentrations of IA and polymerization temperature. The optimum grafting conditions for maximum GY were obtained with a reaction time of 5 h, reaction temperature of 30°C, IA concentration of 0.23 M, CAN concentration of 9.12 × 10?2 M and percentage of NaAlg 0.5 g/dL. The overall activation energy for the grafting was also calculated to be 1135 cal/mol. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
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以过硫酸钾/硫酸为引发剂,使尼龙66纤维与衣康酸进行接枝共聚反应。研究了尼龙66纤维接枝率与硫酸浓度、过硫酸钾浓度、衣康酸(IA)浓度、反应温度、时间和预处理时间之间的关系。实验结果表明:在硫酸浓度0.5mol/L、反应温度55℃、反应时间40h时,接枝率较高;尼龙66纤维的预处理时间对接枝率也有较大影响。同时,用FTIR、1HNMR、WAXD等手段对接枝共聚物的结构进行了研究。 相似文献
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聚乳酸是目前最具竞争力的生物降解高分子材料,但也存在脆性过大、亲水性差、售价太高等明显缺点。本文综述了近年来以聚乳酸为主链进行的接枝聚合反应。聚乳酸接枝物的合成,能够明显改善聚乳酸的表面性能。而且可以在聚乳酸与其他高分子材料的共混体系中发挥明显的增容作用,为新型聚乳酸共混物的制备提供了可能性。 相似文献
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以过氧化二异丙苯(DCP)为引发剂,在双螺杆挤出机中制备了衣康酸(IA)熔融接枝低密度聚乙烯(LDPE)。考察了引发剂用量、单体用量、螺杆转速对接枝反应的影响,并探讨了苯乙烯(St)作共聚单体对接枝反应的影响。结果表明:St共聚单体可显著提高接枝率。 相似文献
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衣康酸的开发利用与市场前景 总被引:6,自引:0,他引:6
衣康酸是聚合物生产中的一种重要中间体,具有广泛的用途和优良的性能,其应用范围不断扩大,需求日益递增。文章重点介绍国内外衣康酸的生产、应用现状与发展趋势;产品的市场前景与需求分析;生产工艺技术以及我省近年来的研制成果。 相似文献
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