Life cycle assessment of three types of hydrogen production methods using solar energy

A comprehensive life cycle assessment (LCA) is carried out for three methods of hydrogen production by solar energy: hydrogen production by PEM water electrolysis coupling photothermal power generation, hydrogen production by PEM water electrolysis coupling photovoltaic power generation, and hydrogen production by thermochemical water splitting method using S–I cycle coupling solar photothermal technology. The assessment also contains an evaluation of four environmental factors which are global warming potential, acidification potential, ozone depletion potential, and nutrient enrichment potential. After conducting a quantitative analysis of all three methods with environmental factors being considered, a conclusion has been drawn: The global warming potential and the acidification potential of the thermochemical water splitting by S–I cycle coupling solar photothermal technology are 1.02 kg CO₂-eq and 6.56E-3 kg SO₂-eq. And this method has significant advantages in the environmental impact of the whole ecosystem.     

The cost analysis of hydrogen life cycle in China

Currently, the increasing price of oil and the possibility of global energy crisis demand for substitutive energy to replace fossil energy. Many kinds of renewable energy have been considered, such as hydrogen, solar energy, and wind energy. Many countries including China have their own plan to support the research of hydrogen, because of its premier features. But, at present, the cost of hydrogen energy production, storage and transportation process is higher than that of fossil energy and its commercialization progress is slow. Life cycle cost analysis (LCCA) was used in this paper to evaluate the cost of hydrogen energy throughout the life cycle focused on the stratagem selection, to demonstrate the costs of every step and to discuss their relationship. Finally, the minimum cost program is as follows: natural gas steam reforming – high-pressure hydrogen bottles transported by car to hydrogen filling stations – hydrogen internal-combustion engines.     

Life cycle analysis of processes for hydrogen production

Hydrogen is considered to be an ideal energy carrier in the foreseeable future and can play a very important role in the energy system. A variety of technologies can be used to produce hydrogen. One of the most remarkable methods for large-scale hydrogen production is thermo-chemical water decomposition using heat energy from nuclear, solar and other sources. Detailed simulations of the two most promising water splitting thermo-chemical cycles (the Westinghouse cycle and the Sulphur-Iodine cycle) were performed in Aspen Plus code and obtained results were used for life cycle analysis. They were compared with two different processes for hydrogen production (coal gasification and coal pyrolysis). Some of the results obtained from LCA are also reported in the paper.     

Life cycle assessment of hydrogen-based electricity generation in place of conventional fuels for residential buildings

In the current study, environmental impact evaluation of electricity generation from hydrogen instead of conventional fuels is investigated with a life cycle impact assessment for residential usage. For this purpose, lignite, natural gas, and hydrogen are utilized to a power plant to generate electricity in Istanbul, Turkey throughout the year. The utilized method for life cycle analysis is the CML 2001 which considers the impacts of global warming, acidification, abiotic fossil depletion, photochemical ozone creation, ionising radiation, human toxicity potential, land use, eutrophication potential, ozone layer depletion, freshwater aquatic ecotoxicity, ecotoxicity of marine aquatic, ecotoxicity of marine sediment, and terrestrial ecotoxicity. The results of the present study illustrate that the generation with hydrogen is the best option for the environment in terms of all impact category. The global warming potentials with the 500 years time horizon for each option of electricity generation are found as 1.4 × 10⁶ ton CO₂ eq, 6 × 10⁵ ton CO₂ eq and 4.6 × 10⁴ ton CO₂ eq, respectively in the month of January.     

Life cycle assessment of hydrogen fuel cell and gasoline vehicles

A life cycle assessment of hydrogen and gasoline vehicles, including fuel production and utilization in vehicles powered by fuel cells and internal combustion engines, is conducted to evaluate and compare their efficiencies and environmental impacts. Fossil fuel and renewable technologies are investigated, and the assessment is divided into various stages.     

Life cycle assessment and evaluation of energy payback time on high-concentration photovoltaic power generation system

In this study, the environmental load of photovoltaic power generation system (PV) during its life cycle and energy payback time (EPT) are evaluated by LCA scheme. Two hypothetical case studies in Toyohashi, Japan and Gobi dessert in China have been carried out to investigate the influence of installation location and PV type on environmental load and EPT. The environmental load and EPT of a high-concentration photovoltaic power generation system (hcpV) and a multi-crystalline silicon photovoltaic power generation system (mc-Si PV) are studied. The study shows for a PV of 100 MW size, the total impacts of the hcpV installed in Toyohashi is larger than that of the hcpV installed in Gobi desert by 5% without consideration of recycling stage. The EPT of the hcpV assumed to be installed in Gobi desert is shorter than EPT of the hcpV assumed to be installed in Toyohashi by 0.64 year. From these results, the superiority to install PV in Gobi desert is certificated. Comparing with hcpV and mc-Si PV, the ratio of the total impacts of mc-Si PV to that of hcpV is 0.34 without consideration of recycling stage. The EPT of hcpV is longer than EPT of mc-Si PV by 0.27 year. The amount of global solar radiation contributing to the amount of power generation of mc-Si PV is larger than the amount of direct solar radiation contributing to the amount of power generation of hcpV by about 188 kW h/(m² year) in Gobi desert. Consequently, it appears that using mc-Si PV in Gobi desert is the best option.     

太阳能热力发电的生命周期分析

应用生命周期分析法(LCA)，对塔式太阳能热力电站所用设备材料的生产、运输、电站基本建设等3个过程进行了分析，分别计算出3个过程中的能耗及其对环境的影响，并与燃煤发电进行了比较。结果表明．太阳能热力电站每发电10MWh，即可节省能源3．78t标准煤，少向大气排放粉尘、CO2、NOx、SO2分别为498．7，9 933，49．94，78．75kg。太阳能热力发电具有显著的节能和环保效益。     

Life cycle assessment of high temperature electrolysis for hydrogen production via nuclear energy

A life cycle assessment (LCA) of one proposed method of hydrogen production—the high temperature electrolysis of water vapor—is presented in this paper. High temperature electrolysis offers an advantage of higher energy efficiency over the conventional low-temperature alkaline electrolysis due to reduced cell potential and consequent electrical energy requirements. The primary energy source for the electrolysis will be advanced nuclear reactors operating at temperatures corresponding to those required for the high temperature electrolysis. The LCA examines the environmental impact of the combined advanced nuclear-high temperature electrolysis plant, focusing upon quantifying the emissions of carbon dioxide, sulfur dioxide, and nitrogen oxides per kilogram of hydrogen produced. The results are presented in terms of the global warming potential (GWP) and the acidification potential (AP) of the system. The GWP for the system is 2000 g carbon dioxide equivalent and the AP, 0.15 g equivalents of hydrogen ion equivalent per kilogram of hydrogen produced. The GWP and AP of this process are one-sixth and one-third, respectively, of those for the hydrogen production by steam reforming of natural gas, and are comparable to producing hydrogen from wind- or hydro-electricity powered conventional electrolysis.     

Direct coupling photovoltaic power regulator for stand-alone power systems with hydrogen generation

This paper describes a photovoltaic power regulator aimed for photovoltaic stand-alone hydrogen-backup power systems. The main characteristics of the regulator are the following; it employs a modular approach where each power cell has three ports, one input and two outputs, the input port is connected to a photovoltaic source while the two output ports are connected to a battery and to an electrolyser, respectively. A second characteristic is that the proposed regulator is driven sequentially, minimising the regulator losses. The operation and features of the photovoltaic regulator are presented and analyzed. Design guidelines are suggested and experimental validation is also given for a 2 kW prototype.     

Environmental and energy life cycle analyses of passenger vehicle systems using fossil fuel-derived hydrogen

Hydrogen energy utilization is expected due to its environmental and energy efficiencies. However, many issues remain to be solved in the social implementation of hydrogen energy through water electrolysis. This analyzes and compares the energy consumption and GHG emissions of fossil fuel-derived hydrogen and gasoline energy systems over their entire life cycle. The results demonstrate that for similar vehicle weights, the hydrogen energy system consumes 1.8 MJ/km less energy and emits 0.15 kg-CO 2 eq./km fewer GHG emissions than those of the gasoline energy system. Hydrogen derived from fossil fuels may contribute to future energy systems due to its stable energy supply and economic efficiency. Lowering the power source carbon content also improved the environmental and energy efficiencies of hydrogen energy derived from fossil fuels.     

Life cycle energy consumption and GHG emissions of hydrogen production from underground coal gasification in comparison with surface coal gasification

Developing underground coal gasification (UCG)-based hydrogen production (UCG-H₂) is expected to alleviate hydrogen supply and demand contradiction, but its energy consumption and environmental impact need to be clarified. In this paper, comparative study of energy consumption and greenhouse gas (GHG) emissions between UCG-H₂ and typical surface coal gasification (SCG)-based hydrogen production (SCG-H₂) is carried out using life cycle assessment method. Result shows energy consumption of UCG-H₂ is only 61.2% of that of SCG-H₂, which is 1,327,261 and 2,170,263 MJ respectively, reflecting its obvious energy saving advantage. 80% capture rate can achieve an appropriate balance between energy consumption and emissions. Under this capture rate, emissions of UCG-H₂ and SCG-H₂ are roughly equivalent, which are 207,582 and 197,419 kg CO₂-eq respectively. Scenario analysis indicates energy consumption in hydrogen industry can reduce by 38.8% when hydrogen production is substituted by UCG with CCS to fully meet demand of 21 Mt in 2030.     

Life cycle assessment of hydrogen production by methane decomposition using carbonaceous catalysts

Methane decomposition to yield hydrogen and carbon (CH₄ ? 2H₂ + C) is one of the cleanest alternatives, free of CO₂ emissions, for producing hydrogen from fossil fuels. This reaction can be catalyzed by metals, although they suffer a fast deactivation process, or by carbonaceous materials, which present the advantage of producing the catalyst from the carbon obtained in the reaction. In this work, the environmental performance of methane decomposition catalyzed by carbonaceous catalysts has been evaluated through Life Cycle Assessment tools, comparing it to other decomposition processes and steam methane reforming coupled to carbon capture systems. The results obtained showed that the decomposition using the autogenerated carbonaceous as catalyst is the best option when reaction conversions higher than 65% are attained. These were confirmed by 2015 and 2030 forecastings. Moreover, its environmental performance is highly increased when the produced carbon is used in other commercial applications. Thus, for a methane conversion of 70%, the application of 50% of the produced carbon would lead to a virtually zero-emissions process.     

Optimum energy evaluation and life cycle cost assessment of a hydrogen liquefaction system assisted by geothermal energy

In this study, analyses of the thermodynamic performance and life cycle cost of a geothermal energy-assisted hydrogen liquefaction system were performed in a computer environment. Geothermal water at a temperature of 200 °C and a flow rate of 100 kg/s was used to produce electricity. The produced electricity was used as a work input to liquefy the hydrogen in the advanced liquefaction cycle. The net work requirement for the liquefaction cycle was calculated as 8.6 kWh/kg LH₂. The geothermal power plant was considered as the work input in the liquefaction cycle. The hydrogen could be liquefied at a mass flow rate of 0.2334 kg/s as the produced electricity was used directly to produce liquid hydrogen in the liquefaction cycle. The unit costs of electricity and liquefied hydrogen were calculated as 0.012 $/kWh and 1.44 $/kg LH₂. As a result of the life cycle cost analysis of the system, the net present value (NPV) and levelized annual cost (LAC) were calculated as 123,100,000 and 14,450,000 $/yr. The simple payback period (N_spp) and discount payback period (N_dpp) of the system were calculated as 2.9 and 3.6 years, respectively.     

Life cycle energy and greenhouse emissions analysis of wind turbines and the effect of size on energy yield

Wind turbines, used to generate renewable energy, are typically considered to take only a number of months to produce as much energy as is required in their manufacture and operation. With a life expectancy of upwards of 20 years, the energy produced by wind turbines over their life can be many times greater than that embodied in their production. Many previous life cycle energy studies of wind turbines are based on methods of assessment now known to be incomplete. These studies may underestimate the energy embodied in wind turbines by more than 50%, potentially overestimating the energy yield of those systems and possibly affecting the comparison of energy generation options. With the increasing trend towards larger scale wind turbines, comes a respective increase in the energy required for their manufacture. It is important to consider whether or not these increases in wind turbine size, and thus embodied energy, can be adequately justified by equivalent increases in the energy yield of such systems. This paper presents the results of a life cycle energy and greenhouse emissions analysis of two wind turbines and considers the effect of wind turbine size on energy yield. The issue of incompleteness associated with many past life cycle energy studies is also addressed. Energy yield ratios of 21 and 23 were found for a small and large scale wind turbine, respectively. The embodied energy component was found to be more significant than in previous studies, emphasised here due to the innovative use of a hybrid embodied energy analysis approach. The life cycle energy requirements were shown to be offset by the energy produced within the first 12 months of operation. The size of wind turbines appears to not be an important factor in optimising their life cycle energy performance.     

Life cycle GHG emissions from Malaysian oil palm bioenergy development: The impact on transportation sector's energy security

Malaysia's transportation sector accounts for 41% of the country's total energy use. The country is expected to become a net oil importer by the year 2011. To encourage renewable energy development and relieve the country's emerging oil dependence, in 2006 the government mandated blending 5% palm-oil biodiesel in petroleum diesel. Malaysia produced 16 million tonnes of palm oil in 2007, mainly for food use. This paper addresses maximizing bioenergy use from oil-palm to support Malaysia's energy initiative while minimizing greenhouse-gas emissions from land-use change. When converting primary and secondary forests to oil-palm plantations between 270–530 and 120–190 g CO₂-equivalent per MJ of biodiesel produced, respectively, is released. However, converting degraded lands results in the capture of between 23 and 85 g CO₂-equivalent per MJ of biodiesel produced. Using various combinations of land types, Malaysia could meet the 5% biodiesel target with a net GHG savings of about 1.03 million tonnes (4.9% of the transportation sector's diesel emissions) when accounting for the emissions savings from the diesel fuel displaced. These findings are used to recommend policies for mitigating GHG emissions impacts from the growth of palm oil use in the transportation sector.     

Life cycle energy and environmental analysis of a microgrid power pavilion

Microgrids—generating systems incorporating multiple distributed generator sets linked together to provide local electricity and heat—are one possible alterative to the existing centralized energy system. Potential advantages of microgrids include flexibility in fuel supply options, the ability to limit emissions of greenhouse gases, and energy efficiency improvements through combined heat and power (CHP) applications. As a case study in microgrid performance, this analysis uses a life cycle assessment approach to evaluate the energy and emissions performance of the NextEnergy microgrid Power Pavilion in Detroit, Michigan and a reference conventional system. The microgrid includes generator sets fueled by solar energy, hydrogen, and natural gas. Hydrogen fuel is sourced from both a natural gas steam reforming operation and as a by‐product of a chlorine production operation. The chlorine plant receives electricity exclusively from a hydropower generating station. Results indicate that the use of this microgrid offers a total energy reduction potential of up to 38%, while reductions in non‐renewable energy use could reach 51%. Similarly, emissions of CO₂, a key global warming gas, can be reduced by as much as 60% relative to conventional heat and power systems. Hydrogen fuels are shown to provide a net energy and emissions benefit relative to natural gas only when sourced primarily from the chlorine plant. Copyright © 2006 John Wiley & Sons, Ltd.     

Life cycle assessment of hydrogen production from biomass gasification. Evaluation of different Spanish feedstocks

Gasification of biomass can be used for obtaining hydrogen reducing the total greenhouse gases emissions due the fixation of CO₂ during photosynthetic processes. The kind of raw materials is an important variable since has a great influence on the energy balance and environmental impacts. Wastes from forestry are considered as the most appropriate raw materials since they do not compete for land. The aim of this work is to determine the environmental feasibility of four Spanish lignocellulosic wastes (vine and almond pruning and forest waste coming from pine and eucalyptus plantation) for the production of hydrogen through gasification. LCA methodology was applied using global warming potential, acidification, eutrophication and the gross energy necessary for the production of 1 Nm³ of hydrogen as impact categories. As expected, the use of biomass instead of natural gas leads to the reduction of CO₂ emissions. Regarding to the different feedstocks, biomass coming from forestry is more environmental-friendly since does not need cropping procedures. Finally, the distribution of environmental charges between pruning wastes and fruits (grape and almond) and the use of obtained by-products have a great influence, reducing the environmental impacts.     

Life cycle assessment of various hydrogen production methods

A comprehensive life cycle assessment (LCA) is reported for five methods of hydrogen production, namely steam reforming of natural gas, coal gasification, water electrolysis via wind and solar electrolysis, and thermochemical water splitting with a Cu–Cl cycle. Carbon dioxide equivalent emissions and energy equivalents of each method are quantified and compared. A case study is presented for a hydrogen fueling station in Toronto, Canada, and nearby hydrogen resources close to the fueling station. In terms of carbon dioxide equivalent emissions, thermochemical water splitting with the Cu–Cl cycle is found to be advantageous over the other methods, followed by wind and solar electrolysis. In terms of hydrogen production capacities, natural gas steam reforming, coal gasification and thermochemical water splitting with the Cu–Cl cycle methods are found to be advantageous over the renewable energy methods.     

Life cycle assessment of hydrogen supply chain with special attention on hydrogen refuelling stations

The controversial and highly emotional discussion about biofuels in recent years has shown that greenhouse gas² (GHG) emissions can only be evaluated in an acceptable way by carrying out a full life cycle assessment (LCA) taking the overall life cycle including all necessary pre-chains into consideration. Against this background, the goal of this paper is it to analyse the overall life cycle of a hydrogen production and provision. A state of the art hydrogen refuelling station in Hamburg/Germany opened in February 2012 is therefore taken into consideration. Here at least 50% hydrogen from renewable sources of energy is produced on-site by water electrolysis based on surplus electricity from wind (mainly offshore wind parks) and water. The remaining other 50% of hydrogen to be sold by this station mainly to hydrogen-fuelled buses is provided by trucks from a large-scale production plant where hydrogen is produced from methane or glycerol as a by-product of the biodiesel production. These two pathways are compared within the following explanations with hydrogen production from biomass and from coal. The results show that – with the goal of reducing GHG emissions on a life cycle perspective – hydrogen production based on a water electrolysis fed by electricity from the German electricity mix should be avoided. Steam methane reforming is more promising in terms of GHG reduction but it is still based on a finite fossil fuel. For a climatic sound provision of hydrogen as a fuel electricity from renewable sources of energy like wind or biomass should be used.     

Life cycle environmental and economic analyses of a hydrogen station with wind energy

This study aimed to identify the environmental and economic aspects of the wind-hydrogen system using life cycle assessment (LCA) and life cycle costing (LCC) methodologies. The target H₂ pathways are the H₂ pathway of water electrolysis (WE) with wind power (WE[Wind]) and the H₂ pathway of WE by Korean electricity mix (WE[KEM]). Conventional fuels (gasoline and diesel) are also included as target fuel pathways to identify the fuel pathways with economic and environmental advantages over conventional fuels. The key environmental issues in the transportation sector are analyzed in terms of fossil fuel consumption (FFC), regulated air pollutants (RAPs), abiotic resource depletion (ARD), and global warming (GW). The life cycle costs of the target fuel pathways consist of the well-to-tank (WTT) costs and the tank-to-wheel (TTW) costs. Moreover, two scenarios are analyzed to predict potential economic and environmental improvements offered by wind energy-powered hydrogen stations.