首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 15 毫秒
1.
Promoting fuel cells has been one of China's ambitious hydrogen policies in the past few years. Currently, several hydrogen fueling stations (HRSs) are under construction in China to fuel hydrogen-driven vehicles. In this regard, it is necessary to assess the risks of hydrogen leakage in HRSs. Aiming at conducting a comprehensive consequence assessment of liquid hydrogen (LH2) leakage on China's first liquid hydrogen refueling station (LHRS) in Pinghu, a pseudo-source model is established in the present study to simulate the LH2 leakage using a commercial CFD tool, FLACS. The effects of the layout of the LHRS, leakage parameters, and local meteorological conditions on the LH2 leakage consequence has been assessed from the perspectives of low-temperature hazards and explosion hazards. The obtained results reveal that considering the prevailing southeast wind in Pinghu city, the farthest low-temperature hazard distance and lower flammable limit (LFL) -distance occurs in the leakage scenario along the north direction. It is found that the trailer parking location in the current layout of the LHRS will worsen the explosion consequences of the LH2 leakage. Moreover, the explosion will completely destroy the control room and endanger people on the adjacent road when the leakage equivalent diameter is 25.4 mm. The performed analyses reveal that as the wind speed increases, the explosion hazard decreases.  相似文献   

2.
Due to its unique advantages, such as clean and pollution-free, hydrogen energy has gradually improved its energy transition position. Constructing nuclear hydrogen production systems is a necessary means to achieve large-scale hydrogen production, and the study of hydrogen leakage and diffusion behavior is critical to commercializing hydrogen production systems. In engineering practice, the distance between the hydrogen storage device and the nuclear power plant is an important indicator to measure the safety of nuclear hydrogen production. To study the influence of gas storage tank's own conditions and external environmental conditions on leakage diffusion, influencing factors such as wind speed, leakage direction, leakage diameter, leakage height, and leakage angle are discussed in the present study. By calculating severe working conditions combined with the above multiple factors, the longest distance of hydrogen diffusion is determined. Finally, peak overpressure impact generated by hydrogen explosion was evaluated, and the minimum separation distance required to avoid safety risks was predicted. The results demonstrate that when the wind direction is consistent with the leakage direction, and the leakage angle is 0°, the higher the wind speed, the larger the leakage diameter and the lower the leakage height, resulting in a longer diffusion distance. Under more extreme and severe working conditions, the diffusion distance of combustible hydrogen cloud can reach as far as 237 m. Once hydrogen diffusion explodes, the minimum separation distance required is about 338 m. This research provides an effective method for safety risk assessment of a nuclear hydrogen production system.  相似文献   

3.
In order for fuel cell vehicles to develop a widespread role in society, it is essential that hydrogen refuelling stations become established. For this to happen, there is a need to demonstrate the safety of the refuelling stations. The work described in this paper was carried out to provide experimental information on hydrogen outflow, dispersion and explosion behaviour. In the first phase, homogeneous hydrogen–air mixtures of a known concentration were introduced into an explosion chamber and the resulting flame speed and overpressures were measured. Hydrogen concentration was the dominant factor influencing the flame speed and overpressure. Secondly, high-pressure hydrogen releases were initiated in a storage room to study the accumulation of hydrogen. For a steady release with a constant driving pressure, the hydrogen concentration varied as the inlet airflow changed, depending on the ventilation area of the room, the external wind conditions and also the buoyancy induced flows generated by the accumulating hydrogen. Having obtained this basic data, the realistic dispersion and explosion experiments were executed at full-scale in the hydrogen station model. High-pressure hydrogen was released from 0.8 to 8.0 mm nozzle at the dispenser position and inside the storage room in the full-scale model of the refuelling station. Also the hydrogen releases were ignited to study the overpressures that can be generated by such releases. The results showed that overpressures that were generated following releases at the dispenser location had a clear correlation with the time of ignition, distance from ignition point.  相似文献   

4.
The transport sector is considered as one of the sectors producing high carbon emissions worldwide due to the use of fossil fuels. Hydrogen is a non-toxic energy carrier that could serve as a good alternative to fossil fuels. The use of hydrogen vehicles could help reduce carbon emissions thereby cutting down on greenhouse gases and environmental pollution. This could largely be achieved when hydrogen is produced from renewable energy sources and is easily accessible through a widespread network of hydrogen refuelling stations. In this study, the techno-economic assessment was performed for a wind-powered hydrogen refuelling station in seven cities of South Africa. The aim is to determine the optimum configuration of a hydrogen refuelling station powered by wind energy resources for each of the cities as well as to determine their economic viability and carbon emission reduction capability. The stations were designed to cater for 25 hydrogen vehicles every day, each with a 5 kg tank capacity. The results show that a wind-powered hydrogen refuelling station is viable in South Africa with the cost of hydrogen production ranging from 6.34 $/kg to 8.97 $/kg. These costs are competitive when compared to other costs of hydrogen production around the world. The cities located in the coastal region of South Africa are more promising for siting wind powered-hydrogen refuelling station compared to the cities located on the mainland. The hydrogen refuelling stations could reduce the CO2 and CO emissions by 73.95 tons and 0.133 tons per annum, respectively.  相似文献   

5.
Hydrogen fuelling station is an infrastructure for the commercialisation of hydrogen energy utilising fuel cells, particularly, in the automotive sector. Hydrogen fuel produced by renewable sources such as the solar and wind energy can be an alternative fuel to depress the use of fuels based on fossil sources in the transport sector for sustainable clean energy strategy in future. By replacing the primary fuel with hydrogen fuel produced using renewable sources in road transport sector, environmental benefits can be achieved. In the present study, techno-economic analysis of hydrogen refuelling station powered by wind-photovoltaics (PV) hybrid power system to be installed in ?zmir-Çe?me, Turkey is performed. This analysis is carried out to a design of hydrogen refuelling station which is refuelling 25 fuel cell electric vehicles on a daily basis using hybrid optimisation model for electric renewable (HOMER) software. In this study, National Aeronautics and Space Administration (NASA) surface meteorology and solar energy database were used. Therefore, the average wind speed during the year was assessed to be 5.72 m/s and the annual average solar irradiation was used to be 5.08 kW h/m2/day for the considered site. According to optimisation results obtained for the proposed configuration, the levelised cost of hydrogen production was found to be US $7.526–7.866/kg in different system configurations. These results show that hydrogen refuelling station powered by renewable energy is economically appropriate for the considered site. It is expected that this study is the pre-feasibility study and obtained results encougare the hydrogen refuelling station to be established in Turkey by inventors or public institutions.  相似文献   

6.
Constructing hydrogen refueling stations will be popular for hydrogen energy use in the future, and investigating the diffusion characteristics of hydrogen in a leakage incident is quite significant. The instantaneous evolution of flammable hydrogen clouds arising from liquid hydrogen leakage in a hydrogen refueling station is predicted using Ansys Fluent, and parametric analyses are conducted to reveal the effects of storage pressure, source height, and leakage direction on the distributions of the flammable regions. In addition, the feasibilities of heating the ceiling or the ground of the station after the leakage of liquid hydrogen to accelerate the hydrogen dilution are examined. The results show that the flammable region is stabilized at 90 s, the corresponding flammable hydrogen cloud volume is about 333 m3, and the extensions of downwind and vertical directions reach 10 m and 9.3 m. Storage pressure has a finite effect on the downwind diffusion distance of the flammable cloud. A lower source height tends to format the high-concentration hydrogen cloud near the ground while a higher source height helps separate the flammable clouds from the ground. The upward leakage direction leads to the maximum downwind diffusion distance of about 10.2 m while the downward leakage direction makes the high hydrogen concentration region confined below the ceiling. Just maintaining the ceiling at the initial temperature of 300 K is effective for accelerating the hydrogen dilution in the upward leakage. The maximum hydrogen concentration and the flammable volume can be reduced at rates of 0.35 vol % and 8% for every 50 K increase in heating temperature. For the downward leakage, keeping the ground at the initial temperature just works for the first 40 s in reducing the maximum hydrogen concentration, while increasing the heating temperature receives a gradually declined effect on reducing the flammable volume.  相似文献   

7.
If the general public is to use hydrogen as a vehicle fuel, customers must be able to handle hydrogen with the same degree of confidence, and with comparable risk, as conventional liquid and gaseous fuels. The hazards associated with jet releases from leaks in a vehicle-refuelling environment must be considered if hydrogen is stored and used as a high-pressure gas since a jet release in a confined or congested area can create an explosion hazard. As there was insufficient knowledge of the explosion hazards, a study was initiated to gain a better understanding of the potential explosion hazard consequences associated with high-pressure leaks from hydrogen vehicle refuelling systems. This paper describes the experiments with a dummy vehicle and dispenser units to represent refuelling station congestion. Experiments with ignition of premixed 5.4 m × 6.0 m × 2.5 m hydrogen–air clouds and hydrogen jet releases up to 40 MPa (400 bar) pressure are described. The results are discussed in terms of the conditions leading to the greatest overpressures and overall conclusions are made from these.  相似文献   

8.
Nowadays, the development of hydrogen economy in the transportation sector is hindered by the principal barriers arising from the lack of adequate infrastructure and the small fleet of hydrogen-based road vehicles.This study investigates the potential of small-scale autonomous hydrogen refuelling stations with onsite production via an alkaline electrolysis apparatus powered by a small wind turbine. In this context, an urban area with promising wind resources has been selected. Based on the wind conditions and an indicative hydrogen demand for refuelling light-duty fuel cell electric vehicles such as bicycles, the sizing of the wind turbine and the electrolyser has been theoretically calculated. For supporting the daily hydrogen refuelling demand of the fuel cell electric bicycles, which is estimated at approximately 6 kg, it is calculated that a 50 kW wind turbine should be installed in order to power a 70 kW alkaline electrolyser for producing hydrogen. The capital cost of the hydrogen station is calculated at €248,130, while the retail price of the produced hydrogen is estimated to be more than 50.2 €/kgH2 in order to achieve a positive internal rate of return.Ultimately, the present paper aims at delivering a feasibility study of a small-scale H2 refuelling station for fuel cell bicycles in order to provide investors with initiatives to implement such schemes in urban environments where problems of low air quality and high traffic are intense.  相似文献   

9.
Most inhabitants of rural communities in Africa lack access to clean and reliable electricity. This has deprived the rural dwellers access to modern healthcare delivery. In this paper, an off-grid renewable energy system consisting of solar PV and wind turbine with hydrogen storage scheme has been explored to meet the electrical energy demands of a health clinic. The health clinic proposed is a group II with 10 beds located in a typical village in South Africa. First, the wind and solar energy resources of the village were analysed. Thereafter, the microgrid architecture that would meet the energy demand of the clinic (18.67 kWh/day) was determined. Some of the key results reveal that the average annual wind speed at 60 m anemometer height and solar irradiation of the village are 7.9 m/s and 4.779 kWh/m2/day, respectively. The required architecture for the clinic composes of 40 kW solar PV system, 3 numbers of 10 kW wind turbines, 8.6 kW fuel cell, 25 kW electrolyser and 40 kg hydrogen tank capacity. The capital cost of the microgrid was found to be $177,600 with a net present cost of $206,323. The levelised cost of energy of the system was determined to be 2.34 $/kWh. The project has a breakeven grid extension distance of 8.81 km. Since this distance is less than the nearest grid extension distance of 21.35 km, it is established that the proposed renewable energy microgrid with a hydrogen storage system is a viable option for the rural community health clinic.  相似文献   

10.
Hydrogen refuelling stations are important for achieving sustainable hydrogen economy in low carbon transport and fuel cell electric vehicles. The solution presented in this paper provides us with a technology for producing carbon dioxide free hydrogen, which is an approach that goes beyond the existing large-scale hydrogen production technologies that use fossil fuel reforming. Hence, the main goal of this work was to design a hydrogen refuelling station to secure the autonomy of a hydrogen powered bicycle. The bicycle hydrogen system is equipped with a proton exchange membrane fuel cell stack of 300 W, a DC/DC converter, and a metal hydride storage tank of 350 NL of hydrogen. The hydrogen power system was made of readily available commercial components. The hydrogen station was designed as an off-grid system in which the installed proton exchange membrane electrolyzer is supplied with electric energy by direct conversion using photovoltaic cells. With the hydrogen flow rate of 2000 cc min−1 the hydrogen station is expected to supply at least 5 bicycles to be used in 20 km long city tourist routes.  相似文献   

11.
It appears to be the most economical means of transporting large quantities of hydrogen over great distances by the existing natural gas pipeline network. However, the leakage and diffusion behavior of urban hydrogen blended natural gas and the evolution law of explosion characteristics are still unclear. In this work, a Computational Fluid Dynamics three-dimensional simulation model of semi-confined space in urban streets is developed to study the diffusion process and explosion characteristics of hydrogen-blended natural gas. The influence mechanism of hydrogen blending ratio and ambient wind speed on the consequences of explosion accident is analyzed. And the dangerous area with different environmental wind effects is determined through comparative analysis based on the most dangerous scenarios. Results indicate that the traffic flow changes the diffusion path of the jet, the flammable gas cloud forms a complex profile in many obstacles, high congestion level lead to more serious explosion accidents. Wind effect keeps the flammable gas cloud near the vehicle flow, the narrow gaps between the vehicles aggravate the expansion of the flammable gas cloud. When the wind direction is consistent with the leakage direction, hydrogen blended natural gas is gathered in the recirculation zone due to the vortex effect, which results in more serious accident consequences. With the increase in hydrogen blending ratio, the higher content of H and OH in the gas mixture significantly increases the premixed burning rate, the maximum overpressure rises rapidly when the hydrogen blend level increases beyond 40%. The results can provide a basis for construction safety design, risk assessment of leakage and explosion hazards, and emergency response in hydrogen blended natural gas distribution systems.  相似文献   

12.
If the general public is to use hydrogen as a vehicle fuel, customers must be able to handle hydrogen with the same degree of confidence, and with comparable risk, as conventional liquid and gaseous fuels. Since hydrogen is stored and used as a high-pressure gas, a jet release in a confined or congested area can create an explosion hazard. Therefore, hazards associated with jet releases from leaks in a vehicle-refuelling environment must be considered. As there was insufficient knowledge of the explosion hazards, a study was initiated to gain a better understanding of the potential explosion hazard consequences associated with high-pressure leaks from hydrogen vehicle refuelling systems. Our first paper [1] describes the release and subsequent ignition of a high-pressure hydrogen jet in a simulated dispensing area of a hydrogen vehicle refuelling station. In the present paper, an array of dummy storage cylinders with confining walls (to represent isolation from the forecourt area) was used to represent high-pressure hydrogen cylinder storage congestion. Experiments with ignition of premixed 5.4 m × 6.0 m × 2.5 m hydrogen-air clouds and hydrogen jet releases up to 40 MPa pressures were performed. The results are presented and discussed in relation to the conditions giving the highest overpressures. We concluded from the study that the ignition of a jet release gives much higher local overpressure than in the case of ignition of a homogeneous mixture inside the cylinder storage congestion area. The modelling of these results will be presented in Part 2 of this paper.  相似文献   

13.
Ningbo's seaport hydrogen refueling station was used as the research object. The effects of different leakage angles, wind direction, roof shape, leakage hole diameters, temperature, and humidity on the diffusion of hydrogen leakage were studied by numerical simulation. The influence of leakage angle on hydrogen leakage is mainly reflected in the presence or absence of obstacles. The volume of the flammable hydrogen cloud was reduced by 31.16%, and the volume of the hazardous hydrogen cloud was reduced by 63.22% when there was no obstacle. The wind direction can significantly impact hydrogen leakage, with downwind and sidewind accelerating hydrogen discharge and reducing the risk. At the same time, headwind significantly increases the volume of the flammable hydrogen cloud. Compared with no wind, the volume of the flammable hydrogen cloud increased by 71.73% when headwind, but the volume of the hazardous hydrogen cloud decreased by 24.00%. If hydrogen shows signs of accumulation under the roof, the sloping roof can effectively reduce the hydrogen concentration under the roof and accelerate the hydrogen discharge. When the leakage angle θ = 90°, the sloping roof reduced the volume of the flammable hydrogen cloud by 11.74%. The leakage process was similar for different leak hole diameters in the no wind condition. The inverse of the molar fraction of hydrogen on the jet centerline was linearly related to the dimensionless axial distance of the jet in different cases. Using a least squares fit, the decay rate was obtained as 0.0039. In contrast, temperature and humidity have almost no effect on hydrogen diffusion. Hydrogen tends to accumulate on the lower surface of the roof, near the roof pillars and the hydrogen dispenser. In this paper, a set of hydrogen detector layout schemes was developed, and the alarm success rate was verified to be 83.33%.  相似文献   

14.
A comparison study is conducted to reveal the differences of hazard distances and accident durations between hydrogen vehicles and CNG vehicles during a representative accident in an open environment, i.e gas release from thermally-activated pressure relief device (TPRD). The analysis is performed for the scenario of impinging jet fires released from 4.2 mm TPRD diameter, with release inventory assumption on the basis of similar driving range: 4 kg hydrogen storage at 35 MPa and 20 kg methane storage at 25 MPa. Results show that the release duration for CNG vehicle is over two times longer than that for hydrogen vehicle, indicating that CNG vehicle jet fire accident is more time-consuming and firefighters have to wait a longer time before they can safely approach the vehicle. For both hydrogen vehicle and CNG vehicle, the longest hazard distance near the ground occur at a few seconds after the initiation of the TPRD. Afterwards the flames will shrink and the hazard distances will decrease. For firefighters with bunker gear, they must stand at least 6 m and 14 m away from the hydrogen vehicle and CNG vehicle, respectively. For general public, a perimeter of 12 m and 29 m should be set around the accident scene for hydrogen vehicle and CNG vehicle, respectively.  相似文献   

15.
The transition to low- or zero-emission vehicles in the transportation sector is a challenging task toward meeting the greenhouse gas emission targets set by the majority of countries. One way of achieving this goal is to utilise hydrogen gas via fuel cell electric vehicles. This paper investigates the operation, driving range and refuelling process of a fuel cell electric bicycle. The methodology applied includes an estimation of the bike's range under different routes and riders, the riders' opinions and a financial evaluation of the hydrogen fuel cost compared to other urban vehicle alternatives. The results showed a minimum median range-to-energy consumption ratio of 20.5 km/kWh, while the maximum hydrogen cost was found to reach 0.025 €/km when refuelling the hydrogen bicycle in an autonomous hydrogen station. The outcome of this study indicates that the introduction of light-duty hydrogen vehicles in urban transportation may adequately meet the average daily driving distance of city residents.  相似文献   

16.
To handle a hydrogen fuel cell vehicle (HFCV) safely after its involvement in an accident, it is necessary to provide appropriate emergency response information to the first responder. In the present study a forced wind of 10 m/s or faster with and without a duct was applied to a vehicle leaking hydrogen gas at a rate of 2000 NL/min. Then, hydrogen concentrations were measured around the vehicle and an ignition test was conducted to evaluate the effectiveness of forced winds and the safety of emergency response under forced wind conditions. The results: 1) Forced winds of 10 m/s or faster caused the hydrogen concentrations in the vicinity of the vehicle to decline to less than the lower flammability limit, and the hydrogen gas in the various sections of the vehicles were so diluted that even if ignition occurred the blast-wave pressure was moderate. 2) When the first responder had located the hydrogen leakage point in the vehicle, it was possible to lower the hydrogen concentrations around the vehicle by aiming the wind duct towards the leakage point and blowing winds at 10 m/s from the duct exit.  相似文献   

17.
The controversial and highly emotional discussion about biofuels in recent years has shown that greenhouse gas2 (GHG) emissions can only be evaluated in an acceptable way by carrying out a full life cycle assessment (LCA) taking the overall life cycle including all necessary pre-chains into consideration. Against this background, the goal of this paper is it to analyse the overall life cycle of a hydrogen production and provision. A state of the art hydrogen refuelling station in Hamburg/Germany opened in February 2012 is therefore taken into consideration. Here at least 50% hydrogen from renewable sources of energy is produced on-site by water electrolysis based on surplus electricity from wind (mainly offshore wind parks) and water. The remaining other 50% of hydrogen to be sold by this station mainly to hydrogen-fuelled buses is provided by trucks from a large-scale production plant where hydrogen is produced from methane or glycerol as a by-product of the biodiesel production. These two pathways are compared within the following explanations with hydrogen production from biomass and from coal. The results show that – with the goal of reducing GHG emissions on a life cycle perspective – hydrogen production based on a water electrolysis fed by electricity from the German electricity mix should be avoided. Steam methane reforming is more promising in terms of GHG reduction but it is still based on a finite fossil fuel. For a climatic sound provision of hydrogen as a fuel electricity from renewable sources of energy like wind or biomass should be used.  相似文献   

18.
A quantitative risk assessment of human life during the operation of a hydrogen refueling station (HRS) is conducted. We calculate the risks for three accident scenarios: a hydrogen leak from the external piping surrounding a dispenser, a hydrogen leak from an accumulator connection piping and a hydrogen leak from a compressor/connection piping in the HRS. We first calculate the probability of accident by multiplying the estimated leak frequency with the incident occurrence probability considering the ignition probability and failure probability of the safety barrier systems obtained through event tree analysis for each scenario. We next simulate the blast and flame effects of the ignition of concentration fields formed by hydrogen leakage. We then use existing probit functions to estimate the consequences of eardrum rupture, fatalities due to displacement by the blast wave, fatalities due to head injuries, first-degree burns, second-degree burns, and fatal burn injuries by accident scenario, leak size, and incident event, and we estimate the risk distribution in 1-m cells. We finally assess the risk reduction effects of barrier placement and the distance to the dispenser and quantify the risk level that HRSs can achieve under existing law. Quantitative risk assessment reveals that the risk for a leak near the dispenser is less than 10−6 per year outside a distance of 6 m to the dispenser. The risk for a leak near the accumulators and compressors exceeds 10−4 per year within a distance of 10 m from the ignition point. A separation of 6 m to the dispenser and a barrier height of 3 m keep the fatal risk from burns to the workers, consumers and residents and passersby below the acceptable level of risk. Our results therefore show that current laws sufficiently mitigate the risks posed by HRSs and open up the possibility for a regulatory review.  相似文献   

19.
The accidental releases of hydrogen from liquid storage and the subsequent consequences are studied from a harm perspective rather than a standpoint of risk. The cold, thermal and overpressure effects from hydrogen cold cloud, fireball, jet fire, flash fire, and vapor cloud explosion are evaluated in terms of two kinds of effect distances based on lethal and harmful criteria. Results show that for instantaneous release, the sequence of effect distances is vapor cloud explosion > flash fire > cold cloud > fireball, and for continuous release, the sequence is vapor cloud explosion > flash fire > jet fire > cold cloud. An overall comparison between instantaneous and continuous release reveals that the catastrophic rupture, rather than leakages, is the dominant event. Besides, the effect distances of liquid hydrogen tank are compared with those of 70 MPa gaseous storage with equivalent mass. Compared with 70 MPa gaseous storage, the liquid hydrogen storage may be safer under leak scenarios but more dangerous under catastrophic rupture scenario.  相似文献   

20.
Studies focused on the behavior of the hydrogen leakage and diffusion are of great importance for facilitating the large scale application of the hydrogen energy. In this paper, the hydrogen leakage and diffusion in six scenarios which including comparison of different leakage position and different wind effect are analyzed numerically. The studied geometry is derived from the hydrogen refueling station in China. Due to the high pressure in hydrogen storage take, the hydrogen leakage is momentum dominated. The hydrogen volume concentration with the variation of the leakage time in different scenarios is plotted. More importantly, profiles of the flammable gas cloud at the end of the leakage are quantitatively studied. Results indicate that a more narrow space between the leakage hole and the obstacle and a smaller contact area with the obstacle make the profile of the flammable gas cloud more irregular and unpredictable. In addition, results highlight the wind effect on the hydrogen leakage and diffusion. Comparing with scenario which the wind direction consistent with the leakage direction, the opposite wind direction may result in a larger profile of the flammable gas cloud. With wind velocity increasing, the profile of the flammable gas cloud is confined in a smaller range. However, the presence of the wind facilitates the form of the recirculation zone near the obstacle. With an increase of the wind velocity, the recirculation zone moves downward along the obstacle. Thus, the hydrogen accumulation is more prominent near the obstacle.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号