Integrated fossil fuel and solar thermal systems for hydrogen production and CO2 mitigation

In most current fossil-based hydrogen production methods, the thermal energy required by the endothermic processes of hydrogen production cycles is supplied by the combustion of a portion of the same fossil fuel feedstock. This increases the fossil fuel consumption and greenhouse gas emissions. This paper analyzes the thermodynamics of several typical fossil fuel-based hydrogen production methods such as steam methane reforming, coal gasification, methane dissociation, and off-gas reforming, to quantify the potential savings of fossil fuels and CO₂ emissions associated with the thermal energy requirement. Then matching the heat quality and quantity by solar thermal energy for different processes is examined. It is concluded that steam generation and superheating by solar energy for the supply of gaseous reactants to the hydrogen production cycles is particularly attractive due to the engineering maturity and simplicity. It is also concluded that steam-methane reforming may have fewer engineering challenges because of its single-phase reaction, if the endothermic reaction enthalpy of syngas production step (CO and H₂) of coal gasification and steam methane reforming is provided by solar thermal energy. Various solar thermal energy based reactors are discussed for different types of production cycles as well.     

Hydrogen from solar energy,a clean energy carrier from a sustainable source of energy

Solar energy is going to play a crucial role in the future energy scenario of the world that conducts interests to solar-to-hydrogen as a means of achieving a clean energy carrier. Hydrogen is a sustainable energy carrier, capable of substituting fossil fuels and decreasing carbon dioxide (CO₂) emission to save the world from global warming. Hydrogen production from ubiquitous sustainable solar energy and an abundantly available water is an environmentally friendly solution for globally increasing energy demands and ensures long-term energy security. Among various solar hydrogen production routes, this study concentrates on solar thermolysis, solar thermal hydrogen via electrolysis, thermochemical water splitting, fossil fuels decarbonization, and photovoltaic-based hydrogen production with special focus on the concentrated photovoltaic (CPV) system. Energy management and thermodynamic analysis of CPV-based hydrogen production as the near-term sustainable option are developed. The capability of three electrolysis systems including alkaline water electrolysis (AWE), polymer electrolyte membrane electrolysis, and solid oxide electrolysis for coupling to solar systems for H₂ production is discussed. Since the cost of solar hydrogen has a very large range because of the various employed technologies, the challenges, pros and cons of the different methods, and the commercialization processes are also noticed. Among three electrolysis technologies considered for postulated solar hydrogen economy, AWE is found the most mature to integrate with the CPV system. Although substantial progresses have been made in solar hydrogen production technologies, the review indicates that these systems require further maturation to emulate the produced grid-based hydrogen.     

Life cycle cost analysis: A case study of hydrogen energy application on the Orkney Islands

Hydrogen can compensate for the intermittent nature of some renewable energy sources and encompass the options of supplying renewables to offset the use of fossil fuels. The integrating of hydrogen application into the energy system will change the current energy market. Therefore, this paper deploys the life cycle cost analysis of hydrogen production by polymer electrolyte membrane (PEM) electrolysis and applications for electricity and mobility purposes. The hydrogen production process includes electricity generated from wind turbines, PEM electrolyser, hydrogen compression, storage, and distribution by H₂ truck and tube trailer. The hydrogen application process includes PEM fuel cell stacks generating electricity, a H₂ refuelling station supplying hydrogen, and range extender fuel cell electric vehicles (RE-FCEVs). The cost analysis is conducted from a demonstration project of green hydrogen on a remote archipelago. The methodology of life cycle cost is employed to conduct the cost of hydrogen production and application. Five scenarios are developed to compare the cost of hydrogen applications with the conventional energy sources considering CO₂ emission cost. The comparisons show the cost of using hydrogen for energy purposes is still higher than the cost of using fossil fuels. The largest contributor of the cost is the electricity consumption. In the sensitivity analysis, policy supports such as feed-in tariff (FITs) could bring completive of hydrogen with fossil fuels in current energy market.     

Nature inspired artificial photosynthesis technologies for hydrogen production: Barriers and challenges

Hydrogen drives the big wheel of nature. Hydrogen nuclear fusion in the sun produces light and heat. Solar flux reaching the earth's surface in an hour is far more than global annual energy demand. Photosynthesis traps 100-TW solar energy annually into biomass on land at 0.1% efficiency that is about six times more than global yearly energy demand. All photosynthetic organisms (photoautotroph) annually convert 100-billion tons of carbon in the atmosphere into biomass. The rampant rise in energy demand requires to replicate natural photosynthesis process artificially to convert solar energy and Carbon dioxide (CO₂) in liquid and burnable gaseous fuels. Chemists, physicists and biologists are collaborating to develop suitable catalysts for artificial photosynthesis. There is a consensus the sun can fuel transport sector by hydrogen and power grid by photo-electricity. It is well in time to develop a full spectrum of solar technologies instead of keeping ourselves plugged to hydrocarbon honey. Photocathodes and catalysts can mediate water splitting using nature-inspired artificial photosynthesis. Economic hydrogen production can accomplish the grand energy transition from fossil fuels to sustainable and renewable energy sources. This paper reviews the recent advances in artificial photosynthesis technologies and presents our work on the microbial fuel cell for hydrogen production and points out technical barriers and operational challenges.     

Renewable energy harvesting with the application of nanotechnology: A review

It is believed that fossil fuel sources are exhaustible and also the major cause of greenhouse gas emission. Therefore, it is required to increase the portion of renewable energy sources in supplying the primary energy of the world. In this study, it is focused on application of nanotechnology in exploitation of renewable energy sources and the related technologies such as hydrogen production, solar cell, geothermal, and biofuel. Here, nanotechnologies influence on providing an alternative energy sources, which are environmentally benign, are comprehensively discussed and reviewed. Based on the literature, employing nanotechnology enhances the heat transfer rate in photovoltaic/thermal (PV/T) systems and modifies PV structures, which can improve its performance, making fuel cells much cost‐effective and improving the performance of biofuel industry through utilization of nanocatalysts, manufacturing materials with high durability and lower weight for wind energy industry.     

Reducing cycling costs in coal fired power plants through power to hydrogen

The increase of renewable share in the energy generation mix makes necessary to increase the flexibility of the electricity market. Thus, fossil fuel thermal power plants have to adapt their electricity production to compensate these fluctuations. Operation at partial load means a significant loss of efficiency and important reduction of incomes from electricity sales in the fossil power plant. Among the energy storage technologies proposed to overcome these problems, Power to Gas (PtG) allows for the massive storage of surplus electricity in form of hydrogen or synthetic natural gas. In this work, the integration of a Power to Gas system (50 MWe) with fossil fuel thermal power plants (500 MWe) is proposed to reduce the minimum complaint load and avoid shutdowns. This concept allows a continuous operation of power plants during periods with low demand, avoiding the penalty cost of shutdown. The operation of the hybrid system has been modelled to calculate efficiencies, hydrogen and electricity production as a function of the load of the fossil fuel power plant. Results show that the utilisation of PtG diminishes the specific cost of producing electricity between a 20% and 50%, depending on the framework considered (hot, warm and cold start-up). The main contribution is the reduction of the shutdown penalties rather than the incomes from the sale of the hydrogen. At the light of the obtained results, the hybrid system may be implemented to increase the cost-effectiveness of existing fossil fuel power plants while adapting the energy mix to high shares of variable renewable electricity sources.     

H2 Optimization and Fuel Cells Application on Electrical Distribution System and Its Commercial Viability in Australia

Conventional energy technologies are not environmentally friendly, are not renewable, and also the cost of using fossil and nuclear fuels will go higher and higher (anecdotal evidence suggests that consumers will be paying three times their current bill 5 years from now). Therefore, renewable energy sources will play important roles in electricity generation. This paper highlights the advantages of renewable technologies, like future prospects for the poor population, being environmentally friendly, and also available in abundance. This paper points outs the factors seeking hydrogen energy and fuel cell technology to eradicate environmental disasters. This paper is significant as it looks into optimal utilization of renewable energy sources with major emphasis on H₂ optimization and fuel cells application utilizing cogeneration technology. This paper discusses the multiple hydrogen production pathways from different sources, including renewable and nonrenewable sources, H₂ safety, and also barriers to use of hydrogen energy. This paper recommends different types of quantitative and qualitative methods for optimal energy planning, and different types of fuel cells are also discussed. This paper explains a hybrid system inclusive of renewable energy, with its types and benefits. Finally, this paper concludes that Australia could switch from conventional fossil fuel technology to hybrid energy inclusive of renewable energy.     

Integration and economic viability of fueling the future with green hydrogen: An integration of its determinants from renewable economics

The volatility of fossil fuel and their increased consumption have exacerbated the socio-economic dilemma along with electricity expenses in third world countries around the world, Pakistan in particular. In this research, we study the output of renewable hydrogen from natural sources like wind, solar, biomass, and geothermal power. It also provides rules and procedures in an attempt to determine the current situation of Pakistan regarding the workability of upcoming renewable energy plans. To achieve this, four main criteria were assessed and they are economic, commercial, environmental, and social adoption. The method used in this research is the Fuzzy Analytical Hierarchical Process (FAHP), where we used first-order engineering equations, and Levelized cost electricity to produce renewable hydrogen. The value of renewable hydrogen is also evaluated. The results of the study indicate that wind is the best option in Pakistan for manufacturing renewable based on four criteria. Biomass is found to be the most viable raw material for the establishment of the hydrogen supply network in Pakistan, which can generate 6.6 million tons of hydrogen per year, next is photovoltaic solar energy, which has the capability of generating 2.8 million tons. Another significant finding is that solar energy is the second-best candidate for hydrogen production taking into consideration its low-cost installation and production. The study shows that the cost of using hydrogen in Pakistan ranges from $5.30/kg to $5.80/kg, making it a competitive fuel for electric machines. Such projects for producing renewable power must be highlighted and carried out in Pakistan and this will lead to more energy security for Pakistan, less use of fossil fuels, and effective reduction of greenhouse gas emissions.     

Long-term perspective on the development of solar energy

We use dynamic optimization methods to analyze the development of solar technologies in light of the increasing scarcity and environmental pollution associated with fossil fuel combustion. Learning from solar R&D efforts accumulates in the form of knowledge to gradually reduce the cost of solar energy, while the scarcity and pollution externalities associated with fossil fuel combustion come into effect through shadow prices that must be included in the effective cost of fossil energy. Accounting for these processes, we characterize the optimal time profiles of fossil and solar energy supply rates and the optimal investment in solar R&D. We find that the optimal rate of fossil energy supply should decrease over time and vanish continuously upon depletion of the fossil fuel reserves, while the optimal supply of solar energy should gradually increase and eventually take over the entire energy demand. The optimal solar R&D investment should initially be set at the highest feasible rate, calling for early engagement in solar R&D programs, long before large scale solar energy production becomes competitive.     

A review on biomass based hydrogen production technologies

Hydrogen is a renewable energy carrier that is one of the most competent fuel options for the future. The majority of hydrogen is currently produced from fossil fuels and their derivatives. These technologies have a negative impact on the environment. Furthermore, these resources are rapidly diminishing. Recent research has focused on environmentally friendly and pollution-free alternatives to fossil fuels. The advancement of bio-hydrogen technology as a development of new sustainable and environmentally friendly energy technologies was examined in this paper. Key chemical derivatives of biomass such as alcohols, glycerol, methane-based reforming for hydrogen generation was briefly addressed. Biological techniques for producing hydrogen are an appealing and viable alternative. For bio-hydrogen production, these key biological processes, including fermentative, enzymatic, and biocatalyst, were also explored. This paper also looks at current developments in the generation of hydrogen from biomass. Pretreatment, reactor configuration, and elements of genetic engineering were also briefly covered. Bio-H₂ production has two major challenges: a poor yield of hydrogen and a high manufacturing cost. The cost, benefits, and drawbacks of different hydrogen generation techniques were depicted. Finally, this article discussed the promise of biohydrogen as a clean alternative, as well as the areas in which additional study is needed to make the hydrogen economy a reality.     

Synthesis of carbon-doped SnO2 nanostructures for visible-light-driven photocatalytic hydrogen production from water splitting

Environmental issues: global warming, organic pollution, CO₂ emission, energy shortage, and fossil fuel depletion have become severe threats to the future development of humans. In this context, hydrogen production from water using solar light by photocatalytic/photoelectrochemical technologies, which results in zero CO₂ emission, has received considerable attention due to the abundance of solar radiation and water. Herein, a single-step thermal decomposition procedure to produce carbon-doped SnO₂ nanostructures (C–SnO₂) for photocatalytic applications is proposed. The visible-light-driven photocatalytic performance of the as-prepared materials is evaluated by photocatalytic hydrogen generation experiments. The bandgaps of the photocatalysts are determined by ultraviolet–visible diffused reflectance spectroscopy. The crystallinity, morphological features (size and shape), and chemical composition and elemental oxidation states of the samples are investigated by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy. The proposed simple thermal decomposition method has significant potential for producing nanostructures for metal-free photocatalysis.     

The role of hydrogen in high wind energy penetration electricity systems: The Irish case

The deployment of wind energy is constrained by wind uncontrollability, which poses operational problems on the electricity supply system at high penetration levels, lessening the value of wind-generated electricity to a significant extent. This paper studies the viability of hydrogen production via electrolysis using wind power that cannot be easily accommodated on the system. The potential benefits of hydrogen and its role in enabling a large penetration of wind energy are assessed, within the context of the enormous wind energy resource in Ireland. The exploitation of this wind resource may in the future give rise to significant amounts of surplus wind electricity, which could be used to produce hydrogen, the zero-emissions fuel that many experts believe will eventually replace fossil fuels in the transport sector. In this paper the operation of a wind powered hydrogen production system is simulated and optimised. The results reveal that, even allowing for significant cost-reductions in electrolyser and associated balance-of-plant equipment, low average surplus wind electricity cost and a high hydrogen market price are also necessary to achieve the economic viability of the technology. These conditions would facilitate the installation of electrolysis units of sufficient capacity to allow an appreciable increase in installed wind power in Ireland. The simulation model was also used to determine the CO₂ abatement potential associated with the wind energy/hydrogen production.     

Impact of hydrogen on the environment

The present work considers the impact of hydrogen fuel on the environment within the cycles of its generation and combustion. Hydrogen has been portrayed by the media as a fuel that is environmentally clean because its combustion results in the formation of harmless water. However, hydrogen first must be generated. The effect of hydrogen generation on the environment depends on the production process and the related by-products. Hydrogen available on the market at present is mainly generated by using steam reforming of natural gas, which is a fossil fuel. Its by-product is CO₂, which is a greenhouse gas and its emission results in global warming and climate change. Therefore, hydrogen generated from fossil fuels is contributing to global warming to the similar extent as direct combustion of the fossil fuels. On the other hand hydrogen obtained from renewable energy, such solar energy, is environmentally clean during the cycles of its generation and combustion. Consequently, the introduction of hydrogen economy must be accompanied by the development of hydrogen that is environmentally friendly. The present work considers several aspects related to the generation and utilisation of hydrogen obtained by steam reforming and solar energy conversion (solar-hydrogen).     

Large-vscale hydrogen production and storage technologies: Current status and future directions

Over the past years, hydrogen has been identified as the most promising carrier of clean energy. In a world that aims to replace fossil fuels to mitigate greenhouse emissions and address other environmental concerns, hydrogen generation technologies have become a main player in the energy mix. Since hydrogen is the main working medium in fuel cells and hydrogen-based energy storage systems, integrating these systems with other renewable energy systems is becoming very feasible. For example, the coupling of wind or solar systems hydrogen fuel cells as secondary energy sources is proven to enhance grid stability and secure the reliable energy supply for all times. The current demand for clean energy is unprecedented, and it seems that hydrogen can meet such demand only when produced and stored in large quantities. This paper presents an overview of the main hydrogen production and storage technologies, along with their challenges. They are presented to help identify technologies that have sufficient potential for large-scale energy applications that rely on hydrogen. Producing hydrogen from water and fossil fuels and storing it in underground formations are the best large-scale production and storage technologies. However, the local conditions of a specific region play a key role in determining the most suited production and storage methods, and there might be a need to combine multiple strategies together to allow a significant large-scale production and storage of hydrogen.     

Exploring the potential of hydrogen in decarbonizing China's light-duty vehicle market

The Chinese government has pledged to achieve overall carbon neutrality by 2060. Currently, the transportation sector contributes to about 10% of total greenhouse gas (GHG) emissions in China. Hence, China has created a well-defined energy vehicle development strategy to reduce GHG emissions from the transportation sector, further expanding into hydrogen vehicle technologies. In this study, the Transportation Energy Analysis Model (TEAM) investigates the potential of hydrogen internal combustion engine vehicles (H₂-ICEVs) and fuel cell vehicles (FCEVs) as a reliable pathway towards the government's aspiration of carbon neutrality in the transportation sector. According to TEAM, by adopting FCEVs and H₂-ICEVs in the vehicle market, hydrogen demand could reach 25% of the total light-duty transportation energy demand in 2050. Consequently, this will lead to an annual reduction of more than 35 million tons GHG compared to only counting on the electrification pathway in the decarbonization task. Besides, FCEVs would take longer to penetrate the light-duty vehicle market compared to H₂-ICEVs, as the current fuel cell technology still requires much improvement to attain a competitive vehicle cost of production.     

Production of hydrogen for export from wind and solar energy,natural gas,and coal in Australia

Hydrogen production for export to Japan and Korea is increasingly popular in Australia. The theoretically possible paths include the use of the excess wind and solar energy supply to the grid to produce hydrogen from natural gas or coal. As a contribution to this debate, here I discuss the present contribution of wind and solar to the electricity grid, how this contribution might be expanded to make a grid wind and solar only, what is the energy storage needed to permit this supply, and what is the ratio of domestic total primary energy supply to electricity use. These factors are required to determine the likeliness of producing hydrogen for export. The wind and solar energy capacity, presently at 6.7 and 11.4 GW, have to increase almost 8 times up to values of 53 and 90 GW respectively to support a wind and solar energy only electricity grid for the southeast states only. Additionally, it is necessary to build-up energy storage of actual power >50 GW and stored energy >3000 GW h to stabilize the grid. If the other states and territories are considered, and also the total primary energy supply (TPES) rather than just electricity, the wind and solar capacity must be increased of a further 6–8 times. It is concluded that it is extremely unlikely that hydrogen for export could be produced from the splitting of the water molecule by using excess wind and solar energy, and it is very unlikely that wind and solar may fully cover the local TPES needs. The most likely scenario is production hydrogen via syngas from either natural gas or coal. Production from natural gas and coal needs further development of techniques, to include CO₂ capture, a way to reuse or store CO₂, and finally, the better energy efficiency of the conversion processes. There are several challenges for using natural gas or coal to produce hydrogen with near-zero greenhouse gas emissions. Carbon capture, utilization, and storage technologies that ensure no CO₂ is released in the production process, and new technologies to separate the oxygen from the air, and in case of natural gas, the water, and the CO₂ from the combustion products, are urgently needed to make sense of the fossil fuel hydrogen production. There is no benefit from producing hydrogen from fossil fuels without addressing the CO₂ issue, as well as the fuel energy penalty issue during conversion, that is simply translating in a net loss of fuel energy with the same CO₂ emission.     

Resource assessment for green hydrogen production in Kazakhstan

Kazakhstan has long been regarded as a major exporter of fossil fuel energy. As the global energy sector is undergoing an unprecedented transition to low-carbon solutions, new emerging energy technologies, such as hydrogen production, require more different resource bases than present energy technologies. Kazakhstan needs to consider whether it has enough resources to stay competitive in energy markets undergoing an energy transition. Green hydrogen can be made from water electrolysis powered by low-carbon electricity sources such as wind turbines and solar panels. We provided the first resource assessment for green hydrogen production in Kazakhstan by focusing on three essential resources: water, renewable electricity, and critical raw materials. Our estimations showed that with the current plan of Kazakhstan to keep its water budget constant in the future, producing 2–10 Mt green hydrogen would require reducing the water use of industry in Kazakhstan by 0.6–3% or 0.036–0.18 km³/year. This could be implemented by increasing the share of renewables in electricity generation and phasing out some of the water- and carbon-intensive industries. Renewable electricity potential in South and West Kazakhstan is sufficient to run electrolyzers up to 5700 and 1600 h/year for wind turbines and solar panels, respectively. In our base case scenario, 5 Mt green hydrogen production would require 50 GW solar and 67 GW wind capacity, considering Kazakhstan's wind and solar capacity factors. This could convert into 28,652 tons of nickel, 15,832 tons of titanium, and many other critical raw materials. Although our estimations for critical raw materials were based on limited geological data, Kazakhstan has access to the most critical raw materials to support original equipment manufacturers of low-carbon technologies in Kazakhstan and other countries. As new geologic exploration kicks off in Kazakhstan, it is expected that more deposits of critical raw materials will be discovered to respond to their potential future needs for green hydrogen production.     

Solar decomposition of fossil fuels as an option for sustainability

This paper presents an overview on solar-thermal decomposition of fossil fuels as a viable option for transition path from today's permanent dependency on fossil fuels to tomorrow's solar fuels via solar thermochemical technology. The paper focuses on the thermochemical hydrogen generation technologies from concentrated solar energy and gives an assessment of the recent advancements in the hydrogen producing solar reactors. The advantages and obstacles of hydrogen generation via solar cracking and solar reforming are presented along with some discussions on the feasibility of industrial scaling of these technologies. Solar cracking and solar reforming processes are discussed as promising hybrid solar/fossil technologies to take considerable share during transition from fossil fuel dependency to clean energy based sustainability.     

Renewable-powered hydrogen economy from Australia's perspective

This article broadly reviews the state-of-the-art technologies for hydrogen production routes, and methods of renewable integration. It outlines the main techno-economic enabler factors for Australia to transform and lead the regional energy market. Two main categories for competitive and commercial-scale hydrogen production routes in Australia are identified: 1) electrolysis powered by renewable, and 2) fossil fuel cracking via steam methane reforming (SMR) or coal gasification which must be coupled with carbon capture and sequestration (CCS). It is reported that Australia is able to competitively lower the levelized cost of hydrogen (LCOH) to a record $(1.88–2.30)/kg_H2 for SMR technologies, and $(2.02–2.47)/kg_H2 for black-coal gasification technologies. Comparatively, the LCOH via electrolysis technologies is in the range of $(4.78–5.84)/kg_H2 for the alkaline electrolysis (AE) and $(6.08–7.43)/kg_H2 for the proton exchange membrane (PEM) counterparts. Nevertheless, hydrogen production must be linked to the right infrastructure in transport-storage-conversion to demonstrate appealing business models.