Construction and operation of hydrogen energy utilization system for a zero emission building

A bench-scale stationary hydrogen energy utilization system with renewable energy (RE) that realizes a zero emission building (ZEB) is presented. To facilitate compactness, safety, and mild operation conditions, a polymer electrolyte membrane (PEM) electrolyzer for hydrogen production (5 Nm³/h), PEM fuel cells (FC) for hydrogen use (3.5 kW), and metal hydride (MH) tanks for hydrogen storage (80 Nm³) are incorporated. Each hydrogen apparatus and Li-ion batteries (20 kW/20 kWh) are installed in a 12-ft. container and 20-kW photovoltaic panels provide power. A building energy management system (BEMS) controlled these system components in an integrated manner. The PEM Ely and FC have fast start-up and high efficiency under partial load operations, indicating suitability for daily start-stop operations. An AB-type TiFe-based alloy (520 kg) is used as the MH (not an AB₅-type rare earth alloy that has been commonly used in bench-scale hydrogen store) because, in addition to being low-cost, it is non-hazardous material under Japanese regulations. The results of a 24-h operation experiment verify ZEB attainment. PEM FC and TiFe-based tanks thermal integration results indicate that hydrogen use operation is achievable without external heat sources.     

Thermal management and power saving operations for improved energy efficiency within a renewable hydrogen energy system utilizing metal hydride hydrogen storage

To ensure the energy efficiency of renewable hydrogen energy systems, power conservation and thermal management are necessary. This study applies these principals to the operation of metal hydride tanks (MHTs) in a bench-scale hydrogen system, named Hydro Q-BiC?, comprising photovoltaic panels (20 kW), an electrolyzer (5 Nm³/h), MHTs containing a TiFe-based MH (40 Nm³), fuel cells (FC; 3.5 kW(power)/2.5 kW(heat)), and Li-ion batteries (20 kW/20 kWh). Here, we show that in a modified hydrogen production operation, with limited use of auxiliaries for cooling the MHTs, the power consumption of the MHTs was reduced by more than 99% compared to a typical operation. The thermal requirements for the MHTs were reduced by ceasing production in a pressurized state. During the hydrogen use operation, the power consumption was reduced to 1/4 and the FC heat output could be fully used; hence, the overall energy efficiency (power-to-hydrogen-to-power/heat) was as high as ~ 60% (43% for the typical operation).     

Renewable energy systems based on hydrogen for remote applications

An integrated renewable energy (RE) system for powering remote communication stations and based on hydrogen is described. The system is based on the production of hydrogen by electrolysis whereby the electricity is generated by a 10 kW wind turbine (WT) and 1 kW photovoltaic (PV) array. When available, the excess power from the RE sources is used to produce and store hydrogen. When not enough energy is produced from the RE sources, the electricity is then regenerated from the stored hydrogen via a 5 kW proton exchange membrane fuel cell system. Overview results on the performances of the WT, PV, and fuel cells system are presented.     

Design and transient-based analysis of a power to hydrogen (P2H2) system for an off-grid zero energy building with hydrogen energy storage

In this study, zero energy building (ZEB) with four occupants in the capital and most populated city of Iran as one of the biggest greenhouse gas producers is simulated and designed to reduce Iran's greenhouse emissions. Due to the benefits of hydrogen energy and its usages, it is used as the primary energy storage of this building. Also, the thermal comfort of occupants is evaluated using the Fanger model, and domestic hot water consumption is supplied. Using hydrogen energy as energy storage of an off-grid zero energy building in Iran by considering occupant thermal comfort using the fanger model has been presented for the first time in this study. The contribution of electrolyzer and fuel cell in supplying domestic hot water is shown. For this simulation, Trnsys software is used. Using Trnsys software, the transient performance of mentioned ZEB is evaluated in a year. PV panels are used for supplying electricity consumption of the building. Excess produced electricity is converted to hydrogen and stored in the hydrogen tank when a lack of sunrays exists and electricity is required. An evacuated tube solar collector is used to produce hot water. The produced hot water will be stored in the hot water tank. For supplying the cooling load, hot water fired water-cooled absorption chiller is used. Also, a fan coil with hot water circulation and humidifier are used for heating and humidifying the building. Domestic hot water consumption of the occupants is supplied using stored hot water and rejected heat of fuel cell and the electrolyzer. The thermal comfort of occupants is evaluated using the Fanger model with MATLAB software. Results show that using 64 m² PV panel power consumption of the building is supplied without a power outage, and final hydrogen pressure tank will be higher than its initial and building will be zero energy. Required hot water of the building is provided with 75 m² evacuated tube solar collector. The HVAC system of the building provided thermal comfort during a year. The monthly average of occupant predicted mean vote (PMV) is between ?0.4 and 0.4. Their predicted percentage of dissatisfaction (PPD) is lower than 13%. Also, supplied domestic hot water (DHW) always has a temperature of 50 °C, which is a setpoint temperature of DHW. Finally, it can be concluded that using the building's rooftop area can be transformed to ZEB and reduce a significant amount of greenhouse emissions of Iran. Also, it can be concluded that fuel cell rejected heat, unlike electrolyzer, can significantly contribute to supplying domestic hot water requirements. Rejected heat of electrolyzer for heating domestic water can be ignored.     

Management of photovoltaic excess electricity generation via the power to hydrogen concept: A year-round dynamic assessment using Artificial Neural Networks

This paper assesses energetically and economically the power-to-hydrogen concept by exploring the excess power resulting from the mismatch between the photovoltaic (PV) generation and the electric demand of a medium-size commercial structure located in Morocco. The variability in the building electric load is considered and the power flows from the PV field to the building are predicted using Artificial Neural Networks for a time-resolution of 15 min. A MATLAB code was implemented to estimate the instantaneous hydrogen production based on a semi-empirical mathematical formulation of an Alkaline type electrolyzer with a nominal capacity of 15 kW. These combined approaches are for the first time adopted to evaluate the feasibility of integrated PV hydrogen systems under the Moroccan context. Using a set of 5 electrolyzers coupled to the 104 kW_p currently installed solar PV field, it was possible to generate about 18,622 Nm³/year of hydrogen by exploring the PV excess power. The overall efficiency of the integrated system ranged from 9.5% (in March) to 10.1% (in May). Such an approach allowed enhancing the effective efficiency and capacity factor to values of 9.873% and 26.87%, respectively compared to 6.325% and 10.163% for the base case scenario without hydrogen systems. From an economic perspective, it was found that the integrated PV-hydrogen plant engendered levelized cost of electricity and hydrogen of 12.56 c$/kWh and 21.55 $/kg, respectively.     

Operation of first solar-hydrogen system in China

The first solar-hydrogen (S-H) system in China, which consists a 2 kW PV cell array, a 48 V/300Ah lead-acid battery bank, an 0.5 Nm³/h hydrogen production capacity alkaline water electrolyzer, a 10 Nm³ LaNi₅ alloy hydrogen storage tank and a 200 W H₂/air PEM fuel cell, was installed in the Institute of Nuclear and New Energy Technology (INET) of Tsinghua University and has been operated for several months. The goal of the system was to study the technical and economical feasibility of using such a system to produce hydrogen in large scale for the future hydrogen energy society. With two months operation, experimental results reveal 40.68% energy transformed to hydrogen with 7.21 kWh/Nm³ H₂ electricity consumption. Economic analysis results illustrate that the present system is not cost-efficient and the energy conversion efficiencies of PV panel and electrolyzer are suggested to increase in technology improvement to cut down cost.     

The wind/hydrogen demonstration system at Utsira in Norway: Evaluation of system performance using operational data and updated hydrogen energy system modeling tools

An autonomous wind/hydrogen energy demonstration system located at the island of Utsira in Norway was officially launched by Norsk Hydro (now StatoilHydro) and Enercon in July 2004. The main components in the system installed are a wind turbine (600 kW), water electrolyzer (10 Nm³/h), hydrogen gas storage (2400 Nm³, 200 bar), hydrogen engine (55 kW), and a PEM fuel cell (10 kW). The system gives 2–3 days of full energy autonomy for 10 households on the island, and is the first of its kind in the world. A significant amount of operational experience and data has been collected over the past 4 years. The main objective with this study was to evaluate the operation of the Utsira plant using a set of updated hydrogen energy system modeling tools (HYDROGEMS). Operational data (10-min data) was used to calibrate the model parameters and fine-tune the set-up of a system simulation. The hourly operation of the plant was simulated for a representative month (March 2007), using only measured wind speed (m/s) and average power demand (kW) as the input variables, and the results compared well to measured data. The operation for a specific year (2005) was also simulated, and the performance of several alternative system designs was evaluated. A thorough discussion on issues related to the design and operation of wind/hydrogen energy systems is also provided, including specific recommendations for improvements to the Utsira plant. This paper shows how important it is to improve the hydrogen system efficiency in order to achieve a fully (100%) autonomous wind/hydrogen power system.     

A flexible analytical model for operational investigation of solar hydrogen plants

Hydrogen will become a dominant energy carrier in the future and the efficiency and lifetime cost of its production through water electrolysis is a major research focus. Alongside efforts to offer optimum solutions through plant design and sizing, it is also necessary to develop a flexible virtualised replica of renewable hydrogen plants, that not only models compatibility with the “plug-and-play” nature of many facilities, but that also identifies key elements for optimisation of system operation. This study presents a model for a renewable hydrogen production plant based on real-time historical and present-day datasets of PV connected to a virtualised grid-connected AC microgrid comprising different technologies of batteries, electrolysers, and fuel cells. Mathematical models for each technology were developed from chemical and physical metrics of the plant. The virtualised replica is the first step toward the implementation of a digital twin of the system, and accurate validation of the system behaviour when updated with real-time data. As a case study, a solar hydrogen pilot plant consisting of a 60 kW Solar PV, a 40 kW PEM electrolyser, a 15 kW LIB battery and a 5 kW PEM fuel cell were simulated and analysed. Two effective operational factors on the plant's performance are defined: (i) electrolyser power settings to determine appropriate hydrogen production over twilight periods and/or overnight and (ii) a user-defined minimum threshold for battery state of charge to prevent charge depletion overnight if the electrolyser load is higher than its capacity. The objective of this modelling is to maximise hydrogen yield while both loss of power supply probability (LPSP) and microgrid excess power are minimised. This analysis determined: (i) a hydrogen yield of 38–39% from solar DC energy to hydrogen energy produced, (ii) an LPSP <2.6 × 10^?4 and (iii) < 2% renewable energy lost to the grid as excess electricity for the case study.     

Hydrogen-based PEM auxiliary power unit

Hydrogen is an energy carrier which can be used for the storage of intermittent and renewable energy sources. In this paper, the general characteristics of an integrated and automated hydrogen-based auxiliary power unit (APU) are presented. A PEM water electrolyzer (production capacity ranging from zero up to 1 Nm³ H₂/h), which can be powered by a panel of photovoltaic cells, is used to produce hydrogen at day hours. Hydrogen is dried and stored in hydride reservoir tanks (the storage capacity of individual reservoirs is 1 Nm³ H₂). Then hydrogen is used for the co-generation of heat and electricity at night hours using a PEM fuel cell (1 kW maximum output power). The main electrochemical and technological features of the overall system are presented. This kind of APU can potentially be used as an electric power source for domestic applications, for the production of electricity on remote sites or as a mobile hydrogen refuelling station for transport applications in urban areas.     

Hydrogen production and storage analysis of a system by using TRNSYS

In this study, hydrogen production and storage were investigated. The Transient System Simulation Program (TRNSYS) and Generic Optimization Program (GenOpt) packages were combined for the design and optimization of a system that produces hydrogen from water and stores the hydrogen it produced in the compressed gas tank. The system design is based on the electricity grid. Electrical energy produced in photovoltaic (PV) panels was used to electrolyze water. The systems for Izmir, Istanbul and Ankara provinces which are in different climate zones of Turkey were optimized and the annual system performances based on the optimum angles were analyzed. For the mentioned provinces, the PV tilt angles which minimize electricity drawn from the grid at the electrolyzer are also investigated. The electrical energy produced in the photovoltaic panels, the hydrogen and oxygen amounts produced, the efficiency of the electrolyzer, the gas and pressure levels in the hydrogen tank were compared. According to the results of the analysis, the annual total power produced in photovoltaic panels is 42803.66 kW in İzmir, 42573.74 kW in Istanbul and 44613.95 kW in Ankara. Hydrogen levels produced in the system are calculated as 10488.39 m³ year⁻¹ in Izmir, 9824.70 m³ year⁻¹ in Istanbul, and 10368.65 m³ year⁻¹ in Ankara.     

Simulation of off-grid generation options for remote villages in Cameroon

Off-grid generation options have been simulated for remote villages in Cameroon using a load of 110 kWh/day and 12 kWp. The energy costs of proposed options were simulated using HOMER, a typical village load profile, the solar resource of Garoua and the flow of river Mungo. For a 40% increase in the cost of imported power system components, the cost of energy was found to be 0.296 €/kWh for a micro-hydro hybrid system comprising a 14 kW micro-hydro generator, a 15 kW LPG generator and 36 kWh of battery storage. The cost of energy for photovoltaic (PV) hybrid systems made up of an 18 kWp PV generator, a 15 kW LPG generator and 72 kWh of battery storage was also found to be 0.576 €/kWh for remote petrol price of 1 €/l and LPG price of 0.70 €/m³. The micro-hydro hybrid system proved to be the cheapest option for villages located in the southern parts of Cameroon with a flow rate of at least 200l/s, while the PV hybrid system was the cheapest option for villages in the northern parts of Cameroon with an insolation level of at least 5.55 kWh/m²/day. For a single-wire grid extension cost of 5000 €/km, operation and maintenance costs of 125 €/yr/km and a local grid power price of 0.1 €/kWh, the breakeven grid extension distances were found to be 15.4 km for micro-hydro/LPG generator systems and 37.4 km for PV/LPG generator systems respectively. These results could be used in Cameroon's National Energy Action Plan for the provision of energy services in the key sectors involved in the fight against poverty.     

Off-grid hybrid renewable energy system with hydrogen storage for South African rural community health clinic

Most inhabitants of rural communities in Africa lack access to clean and reliable electricity. This has deprived the rural dwellers access to modern healthcare delivery. In this paper, an off-grid renewable energy system consisting of solar PV and wind turbine with hydrogen storage scheme has been explored to meet the electrical energy demands of a health clinic. The health clinic proposed is a group II with 10 beds located in a typical village in South Africa. First, the wind and solar energy resources of the village were analysed. Thereafter, the microgrid architecture that would meet the energy demand of the clinic (18.67 kWh/day) was determined. Some of the key results reveal that the average annual wind speed at 60 m anemometer height and solar irradiation of the village are 7.9 m/s and 4.779 kWh/m²/day, respectively. The required architecture for the clinic composes of 40 kW solar PV system, 3 numbers of 10 kW wind turbines, 8.6 kW fuel cell, 25 kW electrolyser and 40 kg hydrogen tank capacity. The capital cost of the microgrid was found to be $177,600 with a net present cost of $206,323. The levelised cost of energy of the system was determined to be 2.34 $/kWh. The project has a breakeven grid extension distance of 8.81 km. Since this distance is less than the nearest grid extension distance of 21.35 km, it is established that the proposed renewable energy microgrid with a hydrogen storage system is a viable option for the rural community health clinic.     

Stand-alone operation of an alkaline water electrolyser fed by wind and photovoltaic systems

Over the last few years, hydrogen technologies have established themselves as key enablers in the medium and long-term development of a new energy model that offers greater sustainability and independence than the present-day one. In this respect, the integration of water electrolysis with renewable energy-based systems can play an important part in the large-scale production of sustainable hydrogen. This paper reports on the complete experimental characterisation of a 1 Nm³ h⁻¹ alkaline water electrolyser located in the Public University of Navarre (UPNa). Specifically, a study was made of the electrical performance, hydrogen production rate, purity of the gases generated and energy efficiency, for a range of operating currents (40–120 A), temperatures (35–65 °C) and pressures (5–25 bar). Additionally, an experimental study was conducted on the electrolyser operation under conditions that are characteristic of a stand-alone wind power and PV-based renewable energy system, installed at the UPNa. The results obtained for the wind power and PV emulations showed that the electrolyser performed correctly, with regard to balance of plant and its principal electrochemical characteristics. Furthermore, the mean energy efficiency of the electrolyser was 77.7% for the wind power emulation, and 78.6% for the PV emulation on a day with stable irradiance, and 78.1% on a day with highly variable irradiance (day with scattered clouds).     

A mobile off-grid platform powered with photovoltaic/wind/battery/fuel cell hybrid power systems

Cross utilization of photovoltaic/wind/battery/fuel cell hybrid-power-system has been demonstrated to power an off-grid mobile living space. This concept shows that different renewable energy sources can be used simultaneously to power off-grid applications together with battery and hydrogen energy storage options. Photovoltaic (PV) and wind energy are used as primary sources and a fuel cell is used as backup power. A total of 2.7 kW energy production (wind and PV panels) along with 1.2 kW fuel cell power is supported with 17.2 kWh battery and 15 kWh hydrogen storage capacities. Supply/demand scenarios are prepared based on wind and solar data for Istanbul. Primary energy sources supply load and charge batteries. When there is energy excess, it is used to electrolyse water for hydrogen production, which in turn can either be used to power fuel cells or burnt as fuel by the hydrogen cooker. Power-to-gas and gas-to-power schemes are effectively utilized and shown in this study. Power demand by the installed equipment is supplied by batteries if no renewable energy is available. If there is high demand beyond battery capacity, fuel cell supplies energy in parallel. Automatic and manual controllable hydraulic systems are designed and installed to increase the photovoltaic efficiency by vertical axis control, to lift up & down wind turbine and to prevent vibrations on vehicle. Automatic control, data acquisition, monitoring, telemetry hardware and software are established. In order to increase public awareness of renewable energy sources and its applications, system has been demonstrated in various exhibitions, conferences, energy forums, universities, governmental and nongovernmental organizations in Turkey, Austria, United Arab Emirates and Romania.     

Performance evaluation of a 10 kWp PV power system prototype for isolated building in Thailand

This paper describes the design and testing of a 10 kW_p photovoltaic (PV) system and summarizes its performance results after the first 6 months of operation. This system functions as a stand-alone power system that is used to supply electricity for isolated buildings and is designed for integration with a micro-grid system (MGS), which is the future concept for a renewable energy-based power network system for Thailand. The system is comprised of the following components. An array with three different types of PV modules consisting amorphous thin film of 3672 W, polycrystalline solar cell of 3600 W and hybrid solar cell of 2880 W, making up a total peak power of 10.152 kW. In addition, there are three grid-connected inverters of 3.5 kW each, three bi-directional inverters of 3.5 kW each and an energy storage system of 100 kWh. After the first 6 months of system operation, it was found that all the components and the overall system had worked effectively. In total, the system had generated about 7852 kWh and the average electricity production per day was 43.6 kWh. The average efficiency of amorphous thin film panel, polycrystalline panel, hybrid solar cell panel and entire PV panel system was 6.26%, 10.48%, 13.78% and 8.82%, respectively. From the analysis of the daily energy production, daily energy consumption and energy storage, the results seem to indicate that there was some mismatching between energy supply and demand in the system. However, this can be overcome by integrating the system to a micro-grid network whereby the energy from the system can be diverted to other loads when there is a surplus and additional energy can be drawn from external sources and fed to the system when the internal supply is insufficient.     

Hybrid (solar and wind) energy system for Al Hallaniyat Island electrification

Wind–PV–diesel hybrid power generation system technology is a promising energy option since it provides opportunities for developed and developing countries to harness naturally available, inexhaustible and pollution-less resources. The aim of this study is to assess the techno-economic feasibility of utilizing a hybrid wind–PV–diesel power system to meet the load of Al Hallaniyat Island. Hybrid Optimization Model for Electric Renewables software has been employed to carry out the present study. The simulation results indicate that the cost of generating energy (COE) is $0.222 kWh^?1 for a hybrid system composed of a 70 kW PV system, 60 kW wind turbine and batteries together with a 324.8 kW diesel system. Moreover, using the same system but without batteries will increase the COE to $0.225 kWh^?1, the fuel consumption, the excess energy and the total operating hours for the diesel generators. The PV–wind hybrid option is techno-economically viable for rural electrification.     

The dynamic modeling and the exergy assessment of hydrogen synthesize and storage system with the power-to-gas concept for various locations

In this article, the solar hydrogen storage is modeled and hourly investigated with TRNSYS software. The Photovoltaic (PV) panel is employed for green power generation that is consumed in the electrolyzer subsystem and produced hydrogen. Additionally, the required electricity at the lack of enough solar irradiation is supplied from the grid. The performance of the system is comparatively analyzed for three main cities. Results show that the maximum power generation by PV panel is about 1670 kW in June which approximately is the same for two cities. The energy and Faraday efficiency of electrolyzer changes between 0.85-0.89 and 0.89–0.92 respectively. The amount of hydrogen production reaches 1235 m³/h for one of them in May. The total amount of hydrogen production is 13,181 m³/year in Yazd, 13,143 m³/year in hot city, and 13,141 m³/year in most populated city.     

System level heat integration and efficiency analysis of hydrogen production process based on solid oxide electrolysis cells

The solid oxide electrolysis cells (SOEC) technology is a promising solution for hydrogen production with the highest electrolysis efficiency. Compared with its counterparts, operating at high temperature means that SOEC requires both power and heat. To investigate the possibility of coupling external waste heat with the SOEC system, and the temperature & quantity requirement for the external waste heat, a universal SOEC system operating at atmospheric pressure is proposed, modeled and analyzed, without specific waste heat source assumption such as solar, geothermal or industrial waste heat. The SOEC system flow sheet is designed to create opportunity for external waste heat coupling. The results show that external waste heat is required for feed stock heating, while the recommended coupling location is the water evaporator. The temperature of the external waste heat should be above 130 °C. For an SOEC system with 1 MW electrolysis power input, the required external waste heat is about 200 kW. When the stack operates at thermoneutral state and 800 °C, the specific energy consumption is 3.77 kWh/Nm³-H₂, of which electric power accounts for 84% (3.16 kWh/Nm³-H₂) and external waste heat accounts for 16% (0.61 kWh/Nm³-H₂). The total specific energy consumption remains almost unchanged when operating the SOEC stack around the thermoneutral condition.     

Cost-effective sizing of a hybrid Regenerative Hydrogen Fuel Cell energy storage system for remote & off-grid telecom towers

There is an urgent need to provide cost-effective, clean, distributed electricity to ensure reliability for mobile network operators in Sub-Saharan Africa. A comprehensive semi-empirical MATLAB/Simulink model of a novel low-pressure, solid-hydrogen based energy storage system combined with Solar PV and battery energy storage including dynamic losses of the power conditioning equipment is built. Levenburg-Marquardt least square algorithm is used for semi-empirical parameterisation of the metal-hydride and fuel cell models, simulations are performed using experimentally obtained telecom tower load data. The results show the overall system efficiency of the energy system drop from 21.05% for a Solar/Battery system to 17.43% of the most cost-effective hybridised system, which consists of 16.2 kW Solar PV coupled to a 10kW/40 kWh Li-Ion battery, and a Regenerative Hydrogen Fuel Cell (consisting of a 10 kW PEM Electrolyser, 1,000 kWh Ti-based AB2 Solid-Hydrogen Storage Cell, and 5 kW PEM Fuel Cell). This system achieves a Levelised Cost of Electricity of 17.16 ¢/kWh compared to 73.40 ¢/kWh for a Diesel Genset, with a Net Present Value of $109,236 and an Internal Rate of Return of 15.15%.     

Feasibility study of hydrogen production from wind power in the region of Ghardaia

A feasibility study on hydrogen production from wind power on the site of Ghardaia is carried out. This study is based on the estimation of the hydrogen rate produced by a 5 kW electrolyser fed by the electricity provided by a 10 kW wind turbine.Wind speed data were used to study the monthly variation of the wind power delivered and its variation according to the height of the wind turbine tower.The obtained results show that it is possible to improve the system output by increasing the height of the wind turbine tower. Indeed, it has been obtained 3200 Nm³ of hydrogen production for a 30 m wind turbine height and 4200 Nm³ at 60 m.In addition, it has been noticed that hydrogen production varies strongly with the months of the year. Thus, the production has reached a maximum of 395 Nm³ in May and a minimum of 187 Nm³ during November and October.