Effect of the microchannel obstacles on the pressure performance and flow behaviors of the hydrogen Knudsen compressor

The hydrogen Knudsen compressor has potential applications on the hydrogen transmission for the microdevices and systems. In this paper, the numerical model of the hydrogen Knudsen compressor was established, combining the NS continuity equations with the slip boundary conditions. The effect of structures on the performance of the hydrogen Knudsen compressor is studied by generating different obstacles in the microchannels. This paper is mainly concerned on the rectangular and the triangular obstacles, and the influence of the obstacles length and height are investigated, respectively. The Knudsen number distribution and the rarefaction of the hydrogen gas flow are analyzed. Also, the characteristic of the pressure increase for the compressor under different parameters are investigated and discussed. The effect of the structure parameters on the flow velocity distributions are detailed described, as well as the velocity contour and the vortex distributions. Moreover, the variation of the Knudsen layers of the hydrogen gas flow in the hydrogen Knudsen compressor is presented, and the key factor of the Knudsen layers is analyzed and discussed. The results is significantly beneficial for the applications and designs of hydrogen Knudsen compressor.     

Flow and transmission characteristics of the multistage hydrogen Knudsen pump in the micro-power system

The multistage hydrogen Knudsen pump based on the thermal transpiration effect has exciting application prospects for hydrogen transport in the micro-power system. The multistage hydrogen Knudsen pump with the silica microchannel is beneficial to its temperature control, which can accurately provide hydrogen transport and storage for the micro-power system. In this paper, the model of the multistage hydrogen Knudsen pump with the silica microchannel is established. The effects of the microchannel height, width and parallel number on the flow and transmission characteristics of the multistage hydrogen Knudsen pump are studied by using the method of N–S equations with the slip boundary. The temperature difference, Knudsen number, thermal transpiration effect, maximum mass flow rate, maximum pressure difference and performance curve under different microchannel parameters are analyzed in detail. The results show that the thermal transpiration effect increases with the microchannel height and decreases with the microchannel width. As the number of parallel microchannels increases, the microchannel is closer to the silicon cantilever, and the thermal transpiration effect becomes stronger. The pumping performance increases with the microchannel height, width and parallel number. The pressurization performance increases with the microchannel height and parallel number. The research results have important guiding significance for the application and design of the multistage hydrogen Knudsen pump in the micro-power system.     

Non-equilibrium evolution and characteristics of the serrated microchannel hydrogen knudsen compressor

The hydrogen Knudsen compressor has great potential to transport hydrogen and provide the required pressure in MEMS and microfluidic systems. The microchannel composed of cold and hot serrated surfaces is beneficial to the temperature control of the multistage Knudsen compressor. In the present study, a serrated hydrogen Knudsen compressor model is established initially, and the non-equilibrium evolution is numerically studied by using the method of N–S equations with the slip boundary. The key factors affecting the non-equilibrium evolution are comprehensively analyzed. The flow behaviors and performance of the serrated hydrogen Knudsen compressor in different times are studied. It is found that the main factors affecting the non-equilibrium evolution are the thermal expansion flow, thermal transpiration flow, and Poiseuille flow. Meanwhile, the serrated structure affects the local flow in the serrated microchannel at different times. Under the interaction of the thermal transpiration flow and the Poiseuille flow, the pressure difference between the two containers first increases rapidly and then decreases slowly, and finally approaches 1886 Pa. The research reveals the flow mechanisms of the hydrogen Knudsen compressor in the non-equilibrium evolution, which provides theoretical support for the safety and reliability of the hydrogen Knudsen compressor.     

Three dimensional channel effect on the flow characteristics and the performance of hydrogen Knudsen compressors

As a new type of the micro fluidic device, Knudsen compressor can provide the potential utilizations on the hydrogen transport in the micro systems. Considering actual structure of the compressor is three-dimensional, flow characteristic studies are the key issue for the performance predictions. Firstly, the model of three-dimensional Knudsen compressor is built, and the validity of the model is proved by comparison with the experimental result. Secondly, the flow behaviors in the three-dimensional model is investigated, and the distributions of pressure and velocity are investigated. Also, the performance of the hydrogen Knudsen compressor in two-dimensional structure and three-dimensional structure are compared and discussed. Thirdly, the three-dimensional hydrogen Knudsen compressors with different width are analyzed, and the pressure increase in different cases of the hydrogen Knudsen compressors are studied.     

Characteristics of thermal transpiration effect and the hydrogen flow behaviors in the microchannel with semicircular obstacle

The thermal transpiration effect has great potential applications for the hydrogen energy. In this paper, the thermal transpiration effect and the hydrogen flow behaviors are studied in the microchannel with the semicircular obstacles. Firstly, the slip boundary model is used in the simulation of the flow performance in the microchannel. The validity of the model at different Kn is verified by comparing with some previous work. Then, the hydrogen flow characteristics of the thermal transpiration effect with the semicircular obstacle are investigated. The result shows that as the size of the semicircular obstacle increases, the hydrogen flow path of the thermal transpiration effect becomes longer, and the temperature gradient decreases. As the characteristic length of the hydrogen flow decreases, there is an obviously negative influence on the thermal transpiration flow. A deeper analysis shows that the thermal driven flow and the pressure driven flow will produce y-component velocity, which leads to a backflow under the effect of semicircles, and the semicircular obstacles make the Knudsen layer spread to the channel center.     

Calibration of low-pressure MEMS gas sensor for detection of hydrogen gas

Detection of hydrogen by sensors are significant for improvement and safe usage of hydrogen gas as an energy source. In this paper, the application of the MEMS gas sensor for detection of hydrogen gas is numerically studied to develop the application of this device in different industrial applications. The flow feature and force generation mechanism inside a rectangular enclosure with heat and cold arms as the non-isothermal walls are inclusively discussed. In this study, the pressure of hydrogen is varied from 62 to 1500 pa correspond to Knudsen number from 0.1 to 4.5 to investigate all characteristics of the thermal-driven force inside the MEMS sensor. In order to simulate a rarefied gas inside the micro gas detector, Boltzmann equations are applied to obtain high precision results. To solve these equations, Direct Simulation Monte Carlo (DSMC) approach is used as a robust method for the non-equilibrium flow field. The effects of length, thickness and temperature of arms are comprehensively investigated in different ambient pressures. In addition, the effect of various hydrogen concentrations on the Knudsen force is studied. Our findings show that maximum Knudsen force occurs at P = 387 pressure and intensifies when the length of the arms is increased from 50 μm to 150 μm. In addition, the obtained results demonstrate that the generated force is highly sensitive to hydrogen gas species and this enables device for detection of hydrogen gas.     

Numerical investigation on the wave transformation in the ionic liquid compressor for the application in hydrogen refuelling stations

The ionic liquid compressor exhibits excellent advantages in hydrogen refuelling stations due to the specific design based on the hydraulic system and the ionic liquid piston. The application of the ionic liquid column results in a complex two-phase flow issue inside the compression chamber. This two-phase flow behaviour is critical for the compressor design as it influences the wave dynamics during the compression, but it is absent in the open literature. In this paper, transit numerical simulations were carried out to investigate the wave transformation during a compression cycle by the volume of fluid (VOF) method under different heights of the ionic liquid piston. The effect of liquid height on the wave transformation, discharged quantity of ionic liquid and hydrogen gas, and the turbulence kinetic energy was analysed. The minimum crest value of the turbulent kinetic energy was observed as 0.54 kJ in the cases of 30 and 40 mm. The optimal height of the ionic liquid piston was recommended 40 mm under the presented design condition based on the simulation results.     

Gas mixing in microchannels using the direct simulation Monte Carlo method

Mixing in microchannels is an important problem because the flow is always laminar flow even though the velocity may be high. The present paper analyzes the inherent factors affecting micro gas mixing using the direct simulation Monte Carlo (DSMC) method at high Knudsen numbers. The discretization errors in the DSMC method were analyzed to ensure numerical accuracy. The simulation results show that the wall characteristics have little effect on the mixing length when the main gas flow velocities for different wall characteristics were the same. The mixing length is nearly inversely proportional to the gas temperature. The dimensionless mixing coefficient, which is the ratio of the mixing length to the channel height, is proportional to the Mach number and inversely proportional to the Knudsen number. This conclusion was validated for microscale gas flows, but is expected to apply to all laminar gas flows at all scales.     

Description and characterization of an electrochemical hydrogen compressor/concentrator based on solid polymer electrolyte technology

Proton-exchange membrane (PEM) technology is commonly used for manufacturing water electrolysers, H₂/O₂ fuel cells and unitized regenerative fuel cells. It can also be used to develop electrochemical compressors, for the purpose of concentrating and/or pressurizing gaseous hydrogen. The aim of the work reported here was to evaluate the main operating characteristics of a laboratory scale (≈10 N liter/h) monocell compressor. The role of various operating parameters (current density, temperature of electrochemical cell, water vapor partial pressure in the hydrogen feed gas, anodic gas composition, etc.) has been evaluated and is discussed. It is shown that the relative humidity of hydrogen oxidized at the anode of the compressor should be adapted to the current density during operation to avoid mass transfer limitations or electrode flooding. A cell voltage of 140 mV is required at 0.2 A cm⁻² to compress hydrogen in one step from atmospheric pressure up to 48 bar, corresponding to an energy consumption of ca. 0.3 kW h/Nm³. Experiments have been performed up to 130 bar. Series connection of several compressors is recommended to reach output pressures higher than 50 bar. To reduce gas cross-permeation effects which can negatively impact the efficiency of the compressor, additional experiments have been made using Nafion membrane modified by addition of zirconyl phosphate. Finally, data related to the extraction of hydrogen from H₂-N₂ gas mixtures are also reported and discussed.     

Thermal transpiration effect on the mass transfer and flow behaviors of the pressure-driven hydrogen gas flow

Thermal transpiration is a rarefied gas effect that drives the gas flow creeping in a microchannel due only to an imposed temperature gradient, which is often encountered in the hydrogen-transportation microfluidic applications such as proton exchange membrane fuel cell (PEMFC). Because of its impact on the pressure-driven flow behavior in the microchannel, this pumping phenomenon needs to be studied in designing and improving microfluidic devices for hydrogen transportation. However, so far little literature has discussed the thermal transpiration effects on the flow behaviors under normal boundary conditions. In this paper, a DSMC-SPH coupled multiscale approach is proposed on the study of the thermal transpiration effect on hydrogen gas multiscale flow behaviors. Various wall temperature distributions are used under a pressure-driven condition. The remarkable influence of thermal transpiration on the multiscale hydrogen gas flow are investigated and discussed. Since the thermal transpiration effect is often occurred in hydrogen transportation, the present simulation results can provide significant insights for designing and improving proton exchange membrane fuel cell (PEMFC).     

微通道内气体-近壁颗粒流动传热数值模拟研究

数值模拟了微通道受限空间内气体-近璧颗粒流动与传热过程,所建模型考虑微尺度气体的可压缩与交物性特征,且在通道和颗粒壁面采用速度滑移和温度跳跃边界条件以考虑滑移区气体动量/能量非连续效应.在此基础上,计算分析了克努森数(Kn)和颗粒偏移比对颗粒表面拖曳力系数(CD)以及传热努塞尔数(Nu)的影响规律.研究结果表明:受气体...     

Dynamic behaviour of non-isothermal compressible natural gases mixed with hydrogen in pipelines

This paper focuses on non-isothermal transient flow in mixed hydrogen–natural gas pipelines. The effect of hydrogen injection into natural gas pipelines has been investigated in particular the pressure and temperature conditions, Joule–Thomson effect, linepack and energy consumption of the compressor station. The gas flow is described by a set of partial differential equations resulting from the conservation of mass, momentum and energy. Real gas effects are determined by the predictive Soave–Redlich–Kwong group contribution method. The Yamal-Europe gas pipeline on Polish territory has been selected as case study.     

Study on the dynamic characteristics of the free piston in the ionic liquid compressor for hydrogen refuelling stations by the fluid-structure interaction modelling

The ionic liquid compressor is promising for hydrogen refuelling stations, where the dynamic characteristics of the free piston are crucial for adjusting the compressor performance. This paper presents an investigation of the dynamic characteristics of the free piston in the ionic liquid compressor through a fluid-structure interaction modelling in three typical conditions. The results show that in the typical condition with no impact, phenomenons of buffering, oil charging, and oil overflow are observed in the oil pressure variation. Three features are found in the motion curve: asymmetric motion with a delay of reversal due to the buffering effect, variable location of the dead centre, and fluctuation in the piston velocity. When the impact occurs at the TDC, an opposite variation trend is observed in the gas and oil pressure curve. In the typical condition with impact at the BDC, the oil pressure drops below the atmospheric pressure.     

Evaluation of hydrogen concentration effect on the natural gas properties and flow performance

The natural gas flowing through transmission pipeline is impure and has a wide range of non-hydrocarbons components at different concentrations like hydrogen. The presence of hydrogen in the natural gas mixture influences its properties and flow performance. The effect of hydrogen concentration on the natural gas flowing through a transportation pipeline has not been adequately investigated and widely comprehended. In this paper, several mixtures flow through pipeline include typical natural gas and hydrogen at different concentrations up to 10% are evaluated to demonstrate their impact on the flow assurance and the natural gas properties. The string Ruswil – Griespass part from the Transitgas project with 94 km length is simulated applying Aspen Hysys Version 9 and validated using Aspen Plus. The simulation specifications were 1.228 1 10⁶ kg/h mass flowrate, 1200 mm and 1164 mm the outer and inner diameters, and 75 bar and 29.4 °C operating pressure, and temperature. The effect of different hydrogen concentrations has been examined and the differences from the typical mixture are estimated. The results show that the presence of hydrogen in the natural gas mixture reduces its density, 10% hydrogen content records 11.78% reduction in the density of typical natural gas. Interestingly, it has been found that up to 2% of hydrogen concentration turns in elevating the viscosity of the typical natural gas while the viscosity decreases at the point that hydrogen content increases above 2%. In addition, the pressure losses over the transmission pipeline increases due to the presence of hydrogen, 10% hydrogen concentration turns in 5.39% increase in the pressure drop of the natural gas mixture. Also, the temperature drop across the pipeline decreases as the hydrogen concentration increases; 10% hydrogen content can result in a 6.14% reduction in the temperature drop across the pipeline. As well as, the findings prove that the hydrogen strongly impacts the phase envelope by changing from size symmetric to size asymmetric diagram. The effect of pipeline elevations has been investigated by changing the elevation up to 25 m uphill and 25 m downhill. The results state that increase the pipeline elevation turns in increasing the pressure losses over the pipeline length. Along with this, the results illustrate that the presence of hydrogen in the mixture elevates the critical pressure and reduces the critical temperature.     

A review of technical and regulatory limits for hydrogen blending in natural gas pipelines

There is rising interest globally in the use of hydrogen for the provision of electricity or heat to industry, transport, and other applications in low-carbon energy systems. While there is attention to build out dedicated hydrogen infrastructure in the long-term, blending hydrogen into the existing natural gas pipeline network is also thought to be a promising strategy for incorporating hydrogen in the near-term. However, hydrogen injection into the existing gas grid poses additional challenges and considerations related to the ability of current gas infrastructure to operate with blended hydrogen levels. This review paper focuses on analyzing the current understanding of how much hydrogen can be integrated into the gas grid from an operational perspective and identifies areas where more research is needed. The review discusses the technical limits in hydrogen blending for both transmission and distribution networks; facilities in both systems are analyzed with respect to critical operational parameters, such as decrease in energy density, increased flow speed and pressure losses. Safety related challenges such as, embrittlement, leakage and combustion are also discussed. The review also summarizes current regulatory limits to hydrogen blending in different countries, including ongoing or proposed pilot hydrogen blending projects.     

Millisecond methane steam reforming for hydrogen production: A computational fluid dynamics study

The potential of methane steam reforming to produce hydrogen in thermally integrated micro-chemical systems at short contact times was theoretically explored. Methane steam reforming coupled with methane catalytic combustion in microchannel reactors for hydrogen production was studied numerically. A two-dimensional computational fluid dynamics model with detailed chemistry and transport was developed. To provide guidelines for optimal design, reactor behavior was studied, and the effect of design parameters such as catalyst loading, channel height, and flow arrangement was evaluated. To understand how steam reforming can happen at millisecond contact times, the relevant process time scales were analyzed, and a heat and mass transfer analysis was performed. The importance of energy management was also discussed in order to obtain a better understanding of the mechanism responsible for efficient heat exchange between highly exothermic and endothermic reactions. The results demonstrated the feasibility of the design of millisecond reforming systems, but only under certain conditions. To achieve this goal, process intensification through miniaturization and the improvement in catalyst performance is very important, but not sufficient; very careful design and implementation of the system is also necessary to enable high thermal integration. The channel height plays an important role in determining the efficiency of heat exchange. A proper balance of the flow rates of the combustible and reforming streams is an important design criterion. Reactor performance is significantly affected by flow arrangement, and co-current operation is recommended to achieve a good energy balance within the system. The catalyst loading must be carefully designed to avoid insufficient reactant conversion or hot spots. Finally, operating windows were identified, and engineering maps for designing devices with desired power were constructed.     

Research on the hydrogen production performance of methanol reforming microchannels with multi-scale structures

Methanol microreactors are of much application value in mobile hydrogen production (HP) thanks to their tiny volume, flexibility and safety and all that. Microchannels, the core of a reactor, provide a site and heat supply for the reaction. In this paper, a microchannel with multi-scale structures, i.e. submicro structure, corrugated structure, fin structure and matrix structure, is designed. Then the influence mechanism of these structures on the hydrogen production of methanol reforming is studied. Specifically, the influences of microstructures like submicro and corrugated structures on the performance of the catalyst in the microchannel as well as the influence of fin structure and matrix structure on the heat and mass transfer performance of the channel are studied. From the experimental research on the methanol conversion rate and H₂ flow rate of the microchannel with multi-scale structures, the influence rule of different structures on the HP performance of the channel is summarized. The experimental results show that these multi-scale structures not only improve the loading of the catalyst of the microchannel, but also its heat and mass transfer, which increases the methanol conversion rate of the microchannel with multi-scale structures by 33% and its H₂ flow rate by 0.266 mol/h.     

Recommendations on X80 steel for the design of hydrogen gas transmission pipelines

By limiting the pipes thickness necessary to sustain high pressure, high-strength steels could prove economically relevant for transmitting large gas quantities in pipelines on long distance. Up to now, the existing hydrogen pipelines have used lower-strength steels to avoid any hydrogen embrittlement. The CATHY-GDF project, funded by the French National Agency for Research, explored the ability of an industrial X80 grade for the transmission of pressurized hydrogen gas in large diameter pipelines. This project has developed experimental facilities to test the material under hydrogen gas pressure. Indeed, tensile, toughness, crack propagation and disc rupture tests have been performed. From these results, the effect of hydrogen pressure on the size of some critical defects has been analyzed allowing proposing some recommendations on the design of X80 pipe for hydrogen transport. Cost of Hydrogen transport could be several times higher than natural gas one for a given energy amount. Moreover, building hydrogen pipeline using high grade steels could induce a 10 to 40% cost benefit instead of using low grade steels, despite their lower hydrogen susceptibility.     

Effect of non-condensable gas on the performance of steam-water ejector in a trigeneration system for hydrogen production: An experimental and numerical study

An ejector containing phase changing gas-liquid flow process acts as a popular and decisive device in multiple industrial applications, including the hydrogen production, electricity production, fuel cells, refrigeration, petroleum industry and desalination systems. However, non-condensable gas is inevitable for the usual operation of phase-changing gas-liquid ejector in the trigeneration or electrolyzer system for hydrogen production, and rarely research is concerned with this issue. In the present study, the effect of non-condensable gas contained in the condensable gas on the characteristics of gas-centered water ejector is presented, with steam, water and air acting as the gas, liquid and non-condensable gas, respectively. Experimentally, the flow rate of steam is controlled to be 1.45 g/s with an absolute pressure of 120 kPa, the air flow rate varies from 0 to 0.14 g/s, resulting in a non-condensable gas concentration ranging from 0 to 9%, and the resulted water flow rate at 100 kPa and 282.15 K changes from 34.7 to 37.3 g/s. Combined with the numerical methods, the performance of ejector expressed in ejected water flow rate was found to increase firstly with a small amount of non-condensable gas, and decrease when the non-condensable gas reaches a certain amount. In addition, the distributions of multiple local flow parameters including pressure, condensation rate and gas volume fraction, velocity and temperature inside the ejector were shown for different non-condensable concentration, by which the mechanism for the change of ejector performance under varying non-condensable concentration was demonstrated. These findings are initiative and insightful for the ejector design optimization in the trigeneration system for hydrogen production and the proposed numerical models can be utilized in analysis and design of steam ejector with non-condensable gas involved.     

The optimization via response surface method for micro hydrogen gas actuator

Development of an innovative sensor for detection of hydrogen gas is essential for new applications and devices. In current article, inclusive parametric analysis has been performed to disclose the chief operative term on the performance of the micro sensor of MIKRA for the detection of the hydrogen in the mixture. The main mechanism of this micro actuator highly relies on the value of the exerted Knudsen force which occurs owing to the temperature gradient in the low-pressure region. The response surface methodology (RSM) is applied to obtain an optimized formula for the evaluation of sensor performance. Besides, analysis of variance (ANOVA) is employed to analyze the influence of individual factors on sensor formulation. This work tries to estimate the effect of major parameters such as a gap of the arm, the pressure of domain, mass fraction and temperature difference on the value of Knudsen force. Moreover, reliable correlations for the estimation of the Knudsen force are presented to determine the efficiency of the micro gas actuator in the various operating conditions. Our findings confirm that the precision of the sensor enhances as the temperature difference of the cold and hot arms as well as the hydrogen mass fractions augment in our actuator.