Development of 1 kW SOFC power package for dual-fuel operation

A compact SOFC power generation system was developed by integrating a 1 kW SOFC stack and balance-of-plant. The system was designed for dual-fuel operation using both natural gas (NG) and liquefied petroleum gas (LPG). An adiabatic pre-reformer was employed in a fuel processing system to convert C₂₊ hydrocarbons in the fuel into CH₄-rich gas which was further processed in a main reformer to produce H₂-rich gas for the SOFC stack. The SOFC system was operated for 350 h under thermally self-sustaining condition, and on-load fuel switching from NG to LPG was carried out during the operation. The system performance was not significantly affected by NG/LPG composition ratios and the performance was stable during continuous operation in NG or LPG.     

Economic evaluation of natural gas transportation from Iran’s South-Pars gas field to market

The worldwide consumption of natural gas is rapidly increasing. To satisfy such a demand, there are some plans to transport natural gas from South-Pars gas field, the largest natural gas field of Iran, to some energy consuming countries. There are several possible technologies for transporting gas from production fields to consuming markets as gas, including PNG (pipeline natural gas), LNG (liquefied natural gas), CNG (compressed natural gas) and NGH (natural gas hydrate). Gas transmission projects are sensitive to technology selection and depending on the capacity and distance; chosen technology may affect the economy of the entire project noticeably. In this work, transporting 100 × 10⁶ standard m³/d natural gas from port of Assaluyeh in south of Iran to potential markets using alternative technologies such as PNG, LNG, CNG and NGH has been investigated. To do such a study, required processes for converting natural gas to desired product and then transporting it to market have been designed and using an economical model, cost of transporting natural gas as a function of distance, has been estimated. Results show for the investigated case, PNG has the lowest production cost for distances up to 7600 km and for larger distances, LNG has the lowest production cost.     

Thermodynamic analysis of an SOFC–GT–ORC integrated power system with liquefied natural gas as heat sink

To recover the waste heat from solid oxide fuel cell (SOFC) and improve the overall electrical efficiency, a new integrated power system driven by SOFC is proposed to achieve the cascade energy utilization. This system integrates an SOFC–GT system with an organic Rankine cycle (ORC) using liquefied natural gas (LNG) as heat sink to recover the cryogenic energy of LNG. Based on the mathematical model, a parametric analysis is conducted to examine the effects of some key thermodynamic parameters on the system performance. The results indicate that the overall electrical efficiency of 67% can be easily achieved for the current system, which can be further improved with parametric optimization. An increase in fuel flow rate of SOFC can raise the net power output, but it has a negative effect on SOFC and overall electrical efficiency. The compressor pressure ratio contributes to an increase in SOFC and overall electrical efficiency, which are contrary to the effects of air flow rate and steam-to-carbon ratio. Under the given conditions, compared with the Kalina sub-system, the ORC sub-system produces 12.6% more power output by utilizing the cryogenic energy of LNG with simple configuration.     

Durability test and degradation behavior of a 2.5 kW SOFC stack with internal reforming of LNG

Forschungszentrum Jülich has demonstrated SOFC stacks and systems ranging from 50 W to 20 kW. Previous studies have shown the reproducible stable long-term performance of the F10-design short stacks developed in Forschungszentrum Jülich. Within this work, a 2.5 kW F20-stack consisting of eighteen cells was assembled, and tested at a furnace temperature of 700 °C mainly with the simulated reformate gas, which corresponds to 10% pre-reforming of liquefied natural gas (LNG). The current density and fuel utilization were mostly kept at 0.5 A cm⁻² and 70%, respectively. The purpose was to investigate the behavior of the stack in the kW-range for at least 5000 h with internal reforming of LNG or methane at a fuel utilization of at least 60%. A voltage degradation rate of around 0.3%/1000 h was obtained during the operation with pre-reformed LNG. The stack performance under normal working conditions and an unplanned redox cycle, as well as the results from post mortem analysis are discussed.     

Use of hydrogen produced by the air conversion of motor diesel fuel in an electrochemical generator

At present, the production of electric energy consumer remote from agro-based centralized networks is done using diesel-generator technology with limited service life of the engine and the extremely low efficiency in the use of expensive fuel. In this paper, is considered an innovative technology of combined production of electricity and heat using a preliminary conversion of diesel fuel in the synthesis gas and then serving it at high temperature electrochemical generator. Synthetic gas to operate the generator air conversion is made of an electrochemical engine diesel fuels in catalytic reactor-burner. On the basis of heat balances of the torch, battery power and boiler are calculated: battery electric efficiency SOFC, chemical efficiency burner, SOFC anode temperature, EMF Planar element, the proportion of hydrogen, oxidized anode SOFC, unit cost of diesel fuel for the production of electricity and thermal energy. Specific consumption of diesel fuel for the production of electrical energy 114 g/kWh (162 g. w. t./kWh), and thermal 31.7 kg/Gj (45.1 kg/GJ, w. t. 189 kg standard fuel/Gcal).     

Removal of sulphur-containing odorants from fuel gases for fuel cell-based combined heat and power applications

Natural gas (NG) and liquefied petroleum gas (LPG) are important potential feedstocks for the production of hydrogen for fuel cell-based (e.g. proton exchange membrane fuel cells (PEMFC) or solid oxide fuel Cells (SOFC) combined heat and power (CHP) applications. To prevent detrimental effects on the (electro)catalysts in fuel cell-based combined heat and power installations (FC-CHP), sulphur removal from the feedstock is mandatory. An experimental bench-marking study of adsorbents has identified several candidates for the removal of sulphur containing odorants at low temperature. Among these adsorbents a new material has been discovered that offers an economically attractive means to remove TetraHydroThiophene (THT), the main European odorant, from natural gas at ambient temperature. The material is environmentally benign, easy to use and possesses good activity (residual sulphur levels below 20 ppbv) and capacity for the common odorant THT in natural gas. When compared to state-of-the-art metal-promoted active carbon the new material has a THT uptake capacity that is up to 10 times larger, depending on temperature and pressure. Promoted versions of the new material have shown potential for the removal of THT at higher temperatures and/or for the removal of other odorants such as mercaptans from natural gas or from LPG.     

Thermodynamic modeling and exergy investigation of a hydrogen-based integrated system consisting of SOFC and CO2 capture option

The current study deals with the thermodynamic modeling of an innovative integrated plant based on solid oxide fuel cell (SOFC) with liquefied natural gas (LNG) cold energy supply. For the suggested innovative plant the energy, and exergy simulations are fully extended and the plant comprehensively analyzed. According to mathematical simulations of the proposed plant, a MATLAB code has been extended. The results indicate that under considered initial conditions, the efficiencies of SOFC and net power generation calculated 58% and 78%, respectively and the CO₂-capture rate is obtained 79 kg/h. This study clearly shows that the integrated system reached high efficiency while having zero emissions. In addition, the efficiencies and net amount of power generation, cooling or heating output and SOFC power generation are discussed in detail as a function of different variables such utilization factor, air/fuel ratio, or SOFC inlet temperature. For enhancing the power production efficiency of SOFC, the net electricity, and CCHP exergy efficiency the plant should run in higher utilization factor and lower air/fuel ration also it's important to approximately set SOFC temperature to its ideal temperature.     

A comparison of compressed hydrogen and CNG storage

CNG and compressed hydrogen are compared to illustrate why CNG, but not compressed hydrogen, is a viable alternative vehicle fuel. It is shown that natural gas has a greater energy content per mole than hydrogen and that more moles of natural gas than hydrogen may be stored in a given volume under identical conditions. Natural gas stored at 20.78 MPa (3000 psig) and 21.1°C (70°F) contains five times as much energy as hydrogen stored under the same conditions. Natural gas stored in a representative size CNG cylinder provides a range of about 100 km, while hydrogen in the same cylinder would provide a range of only 26 km, even assuming 30% greater efficiency from the hydrogen-fueled engine.     

车用发动机代用燃料的研究现状及发展趋势

详细介绍了车用发动机的几种代用燃料——压缩天然气(CNG)、液化天然气(LNG)、天然气合成油 (GTL)、液化石油气(LPG)、氢气、乳化燃油、醇类燃料、水煤浆、二甲醚(DME)、生物燃料、碳酸二甲酯(DMC)的研究现状。并简单阐述了代用燃料的发展趋势。     

Optimal sizing of a fuel processor for auxiliary power applications of a fuel cell-powered passenger car

The present study considers the optimal sizing of a three-way hybrid powertrain consisting of a compact reformer, a compact battery and a low temperature PEM fuel cell stack serving as the main power unit. A simulation model consisting of the relevant characteristic parameters of the three power sources has been developed and has been used to study the fuel utilization features of the hybrid powertrain while going through the NEDC driving cycle with a given auxiliary power requirement. The optimality is based on minimizing fuel cost while having an assured range of 500 km under practical driving conditions and a further 100 km under reduced auxiliary power usage. It is shown that for performance characteristics of Toyota Mirai and for average auxiliary power consumption of 5 kW, a smaller NiMH battery size of 1.3 kWh together with a fuel processor of 5.6 kW constant output would be optimal with a further requirement of 25% more hydrogen and 33 kg of ethanol to be carried on-board. Substantial reductions in vehicle mass and fuel load can be achieved for more modest performance characteristics and auxiliary power consumption.     

Development of a Solid Oxide Fuel Cell for the utilization of coal mine gas

Apart from natural gas there is another important natural source of methane. The so-called coal mine gas is a by-product of the geochemical process of the carbonization of sediments from marsh woods of the Earth's Carboniferous Period. Methane evaporates from the coal and has to be removed out of the active mines where it represents one of the main safety risks. Methane also evaporates in abandoned coal mines. In the federal state Saarland in Germany exists above ground a more than 110 km pipeline for the drained coal mine gas from 12 different sources. The content of methane varies between 25 and 90%, the oxygen content (from air) is in the range up to 10%. This wide range or variation, respectively, of fuel and oxygen content, causes a lot of problems for the use in conventional engines. Therefore the company Evonik New Energies GmbH is interested in using SOFC with coal mine gas as efficient as possible to produce electric power. For that purpose at Forschungszentrum Jülich the available SOFC technology was adapted to the use with coal mine gas and a test facility was designed to operate an SOFC stack (approximately 2 kW electrical power output) together with a pre-reformer.This paper presents the results of the coal mine gas analysis and the effect on the pre-reformer and the fuel cell. The composition of the coal mine gas was determined by means of micro-gas chromatography. The results obtained from preliminary tests using synthetic and real coal mine gas on the pre-reformer and on the fuel cell are discussed.     

Fuel cell-battery hybrid powered light electric vehicle (golf cart): Influence of fuel cell on the driving performance

A light electric vehicle (golf cart, 5 kW nominal motor power) was integrated with a commercial 1.2 kW PEM fuel cell system, and fuelled by compressed hydrogen (two composite cylinders, 6.8 L/300 bar each). Comparative driving tests in the battery and hybrid (battery + fuel cell) powering modes were performed. The introduction of the fuel cell was shown to result in extending the driving range by 63–110%, when the amount of the stored H₂ fuel varied within 55–100% of the maximum capacity. The operation in the hybrid mode resulted in more stable driving performances, as well as in the increase of the total energy both withdrawn by the vehicle and returned to the vehicle battery during the driving. Statistical analysis of the power patterns taken during the driving in the battery and hybrid-powering modes showed that the latter provided stable operation in a wider power range, including higher frequency and higher average values of the peak power.     

Improving the performance of dual fuel engines running on natural gas/LPG by using pilot fuel derived from jojoba seeds

The use of jojoba methyl ester as a pilot fuel was investigated for almost the first time as a way to improve the performance of dual fuel engine running on natural gas or liquefied petroleum gas (LPG) at part load. The dual fuel engine used was Ricardo E6 variable compression diesel engine and it used either compressed natural gas (CNG) or LPG as the main fuel and jojoba methyl ester as a pilot fuel. Diesel fuel was used as a reference fuel for the dual fuel engine results. During the experimental tests, the following have been measured: engine efficiency in terms of specific fuel consumption, brake power output, combustion noise in terms of maximum pressure rise rate and maximum pressure, exhaust emissions in terms of carbon monoxide and hydrocarbons, knocking limits in terms of maximum torque at onset of knocking, and cyclic variability data of 100 engine cycles in terms of maximum pressure and its pressure rise rate average and standard deviation. The tests examined the following engine parameters: gaseous fuel type, engine speed and load, pilot fuel injection timing, pilot fuel mass and compression ratio. Results showed that using the jojoba fuel with its improved properties has improved the dual fuel engine performance, reduced the combustion noise, extended knocking limits and reduced the cyclic variability of the combustion.     

Combustion analysis of a spark ignition i. c. engine fuelled alternatively with natural gas and hydrogen-natural gas blends

This paper describes an experimental activity performed on a passenger car powered by a spark ignition engine fuelled alternatively with natural gas (CNG) and hydrogen-natural gas blends, with 15% (HCNG15) and 30% (HCNG30) of hydrogen by volume. The vehicle was tested on a chassis dynamometer over different driving cycles, allowing the investigation of more realistic operating conditions than those examined on an engine test bed at steady state conditions. Fuel consumption was estimated using the carbon balance methodology, allowing the comparison of engine average efficiency over the driving cycles for the tested fuels. Furthermore, cylinder pressure was measured and, by processing the pressure signal, a combustion analysis was performed allowing to estimate the burning rate and combustion phasing. Ignition timing was the same for all the tested fuels, in order to assess their interchangeability on in-use vehicles. Results showed CO₂ emission reduction between 3% and 6% for HCNG15 and between 13% and 16% for HCNG30 respect to natural gas. Fuel consumption in MJ/km did not show significant differences between CNG and HCNG15, while reductions between 3% and 7% have been observed with HCNG30. The heat release rate increased with hydrogen content in the blends, reaching values higher than those attained using CNG. The combustion duration, calculated as the angle between 10% and 90% of heat released, has been shortened, with 16% reduction for HCNG15 and 21% for HCNG30 respect to CNG at 2.5 bar imep and 2400 rpm. As a consequence, hydrogen addition resulted in a combustion phasing advance respect to CNG. Cycle-by-cycle variability decreased, particularly at low loads, due to the positive effect of hydrogen on combustion stability.     

Comparisons of hazard distances and accident durations between hydrogen vehicles and CNG vehicles

A comparison study is conducted to reveal the differences of hazard distances and accident durations between hydrogen vehicles and CNG vehicles during a representative accident in an open environment, i.e gas release from thermally-activated pressure relief device (TPRD). The analysis is performed for the scenario of impinging jet fires released from 4.2 mm TPRD diameter, with release inventory assumption on the basis of similar driving range: 4 kg hydrogen storage at 35 MPa and 20 kg methane storage at 25 MPa. Results show that the release duration for CNG vehicle is over two times longer than that for hydrogen vehicle, indicating that CNG vehicle jet fire accident is more time-consuming and firefighters have to wait a longer time before they can safely approach the vehicle. For both hydrogen vehicle and CNG vehicle, the longest hazard distance near the ground occur at a few seconds after the initiation of the TPRD. Afterwards the flames will shrink and the hazard distances will decrease. For firefighters with bunker gear, they must stand at least 6 m and 14 m away from the hydrogen vehicle and CNG vehicle, respectively. For general public, a perimeter of 12 m and 29 m should be set around the accident scene for hydrogen vehicle and CNG vehicle, respectively.     

Assessing the operation and different refuelling cost scenarios of a fuel cell electric bicycle under low-pressure hydrogen storage

The transition to low- or zero-emission vehicles in the transportation sector is a challenging task toward meeting the greenhouse gas emission targets set by the majority of countries. One way of achieving this goal is to utilise hydrogen gas via fuel cell electric vehicles. This paper investigates the operation, driving range and refuelling process of a fuel cell electric bicycle. The methodology applied includes an estimation of the bike's range under different routes and riders, the riders' opinions and a financial evaluation of the hydrogen fuel cost compared to other urban vehicle alternatives. The results showed a minimum median range-to-energy consumption ratio of 20.5 km/kWh, while the maximum hydrogen cost was found to reach 0.025 €/km when refuelling the hydrogen bicycle in an autonomous hydrogen station. The outcome of this study indicates that the introduction of light-duty hydrogen vehicles in urban transportation may adequately meet the average daily driving distance of city residents.     

Safe and waste-free technologies using hydrogen electric power generation

A task of the Arctic integrated development affects the development of the new safe and waste-free technologies of waste processing using hydrogen electric power generation. This problem is multifaceted and concerns both large port cities and small towns, mines, islands, platforms, mining and processing plants, etc., despite the fact that many of them have not removed the wastes from their previous activities. The presence of melting permafrost, especially in the Western part of the Russian Arctic, high logistics costs, a small number of indigenous people and mainly rotational method of development make use of new technologies for the production of electricity, heat, water treatment, which provide the use of hydrogen power on the basis of liquefied natural gas (LNG). The use of LNG as a fuel is not effective enough, especially in the Arctic, given the low efficiency of diesel and gas turbine power plants, as well as the environmental degradation from their use. A more effective, environmentally friendly and integrated solution is the use of hydrogen electric power generation together with hydrogen fuel cells (HFC).The structure and method of waste-free technologies of waste processing are analyzed. The structure of wastes is multifaceted and contains: the most common solid waste from industry and life, including natural and man-made landfills; liquid wastes including sewage sludge from household and rainwater, oil-containing and other industrial wastes; leachate from landfills, including landfill gases; wastes resulted from transportation and transshipment of oil products, etc.In the paper purification methods are described; industrial shipping equipment and its characteristics for the application at facilities of the Arctic are presented. These installations include: incinerators, installations for treatment and filtrate of sewage from municipal solid wastes (MSW), desalination plants of reverse osmosis, snow-and ice-melting installations, cleaning and filtration of flue gases with an emphasis on methods of electric cleaning, cargo arms for loading and unloading the oil products and hazardous wastes. The advantages of hydrogen sources and energy storage using LNG in the Arctic both in terms of energy efficiency and ecology, the possibility of their use in conjunction with the above waste treatment plants are shown.Characteristics of solid oxide fuel cells (SOFC) and solid polymer fuel cells and their scope are presented. For the most dynamically developing solid oxide elements, their characteristics in the traditional and cogeneration cycles are given and the scope of their application in small and distributed energy at power up to 10 kW is shown. Atmospheric hybrid schemes for thermodynamic efficiency are significantly inferior to schemes under pressure, but in large-capacity plants, for example, with coal gasification, they can be quite promising. Modern SOFC work under pressure of 7–9 bar; with the growth of their capacity over 1–5 MW in hybrid power plants (HPPs) it is necessary to increase the pressure up to 11 bar and even more. For HPPs with capacity over 10 MW, cogeneration cycle with gas turbines (CCGT) is the most efficient. The highest electrical efficiency of HPPs with the capacity over 10 MW reaches 75% with the use of CCGT and boilers at three pressure units with intermediate superheating.The paper presents the characteristics of traditional sources of electricity based on ship and aircraft gas turbine units operating on LNG, which can be used in autonomous power supply networks of Arctic facilities. Their advantages in terms of specific power in comparison with diesel power plants and storage devices are shown, but high LNG consumption and environmental indicators limit their use in the Arctic, taking into account the logistics problems. Comparison of the energy efficiency of traditional sources and hydrogen storage shows significant advantages of the latter, and if the efficiency of traditional sources increases with their power, the efficiency of storage devices does not change in the entire range of capacities. This circumstance makes the use of hydrogen sources and accumulators uncontested in the field of small capacities typical for Arctic consumers, especially taking into account the possibilities for safe and waste-free technology for processing industrial and life wastes.     

A direct flame solid oxide fuel cell for potential combined heat and power generation

A sealant-free solid oxide fuel cell (SOFC) micro-stack was successfully operated inside a liquefied petroleum gas (LPG) flame during cooking. This micro-stack consisted of 4 single cells with infiltrated La_0.75Sr_0.25Cr_0.5Mn_0.5O_3-δ (LSCM) based composite anodes, achieving an open circuit voltage of 0.92 V and a peak power density of 348 mW cm⁻². This performance is significantly better than that of stack with its cathode operation outside flame. The results confirmed that the perovskite oxide anode showed good properties of carbon-free, redox-stability, quick-start (less than 1 min) and successful operation under a wide range of oxygen partial pressure. For comparison, the conventional Ni/yttria-stabilized zirconia (Ni/YSZ) anode was prepared and tested under the same conditions, showing an open circuit voltage of 0.915 V and a peak power density of 366 mW cm⁻², but obvious carbon deposition, poor stability and slow/difficult-start. The direct flame SOFC (DFFC) with a new configuration and design has a potential for combined heat and power generation for many applications.     

Energy distribution analyses of an additional traction battery on hydrogen fuel cell hybrid electric vehicle

Hydrogen is the most abundant element in the world and produces only water vapor as a result of chemical reaction that occurred in fuel cells. Therefore, fuel cell electric vehicles, which use hydrogen as fuel, continue its growing trend in the sector. In this study, an energy distribution comparison is carried out between fuel cell electric vehicle and fuel cell hybrid electric vehicle. Hybridization of fuel cell electric vehicle is designed by equipped a traction battery (15 kW). Modeled vehicles were prepared under AVL Cruise program with similar chassis and same fuel cell stacks for regular determining process. Numerical analyses were presented and graphed with instantaneous results in terms of sankey diagrams with a comparison task. WLTP driving cycle is selected for both vehicles and energy input/output values given with detailed analyses. The average consumption results of electric and hydrogen usage is found out as 4.07 kWh and 1.125 kg/100 km respectively for fuel cell electric vehicle. On the other hand, fuel cell hybrid electric vehicle’s average consumption results figured out as 3.701 kWh for electric and 0.701 kg/100 km for hydrogen consumption. As a result of this study, fuel cell hybrid electric vehicle was obtained better results rather than fuel cell electric vehicle according to energy and hydrogen consumption with 8% and 32%, respectively.     

Effects of methane processing strategy on fuel composition,electrical and thermal efficiency of solid oxide fuel cell

Natural gas is a cheap and abundant fuel for solid oxide fuel cell (SOFC), generally integrating the SOFC system with methane pre-treating system for improving the stability of SOFC. In this paper, the accurate effects of methane processing strategy on fuel composition, electrical efficiency and thermal efficiency of SOFC are investigated based on the thermodynamic equilibrium. Steam reforming of methane is an endothermic process and can produce 3 mol of H₂ and 1 mol of CO from 1 mol of methane, and thus the electrical efficiency of SOFC is high at the same O/C ratio and equivalent fuel utilization, whereas the thermal efficiency is low. On the contrary, partial oxidation of methane is an exothermal process and only produces 2 mol of H₂ and 1 mol of CO from 1 mol of methane, and thus the electrical efficiency of SOFC is low at the same O/C ratio and equivalent fuel utilization, whereas the thermal efficiency is high. When the O/C ratio is 1.5, the electrical efficiency of SOFC is 55.3% for steam reforming of methane, while 32.7% for partial oxidation of methane. High electrical efficiency of SOFC can be achieved and carbon deposition can be depressed by selecting suitable O/C ratio from methane pretreatment according to the accurate calculation and analysis of effects of different methane processing strategies on the electrical efficiency and thermal efficiency of SOFC.