A quantitative assessment of the hydrogen storage capacity of the UK continental shelf

Increased penetration of renewable energy sources and decarbonisation of the UK's gas supply will require large-scale energy storage. Using hydrogen as an energy storage vector, we estimate that 150 TWh of seasonal storage is required to replace seasonal variations in natural gas production. Large-scale storage is best suited to porous rock reservoirs. We present a method to quantify the hydrogen storage capacity of gas fields and saline aquifers using data previously used to assess CO₂ storage potential. We calculate a P50 value of 6900 TWh of working gas capacity in gas fields and 2200 TWh in saline aquifers on the UK continental shelf, assuming a cushion gas requirement of 50%. Sensitivity analysis reveals low temperature storage sites with sealing rocks that can withstand high pressures are ideal sites. Gas fields in the Southern North Sea could utilise existing infrastructure and large offshore wind developments to develop large-scale offshore hydrogen production.     

On capital utilization in the hydrogen economy: The quest to minimize idle capacity in renewables-rich energy systems

The hydrogen economy is currently experiencing a surge in attention, partly due to the possibility of absorbing variable renewable energy (VRE) production peaks through electrolysis. A fundamental challenge with this approach is low utilization rates of various parts of the integrated electricity-hydrogen system. To assess the importance of capacity utilization, this paper introduces a novel stylized numerical energy system model incorporating the major elements of electricity and hydrogen generation, transmission and storage, including both “green” hydrogen from electrolysis and “blue” hydrogen from natural gas reforming with CO₂ capture and storage (CCS). Concurrent optimization of all major system elements revealed that balancing VRE with electrolysis involves substantial additional costs beyond reduced electrolyzer capacity factors. Depending on the location of electrolyzers, greater capital expenditures are also required for hydrogen pipelines and storage infrastructure (to handle intermittent hydrogen production) or electricity transmission networks (to transmit VRE peaks to electrolyzers). Blue hydrogen scenarios face similar constraints. High VRE shares impose low utilization rates of CO₂ capture, transport and storage infrastructure for conventional CCS, and of hydrogen transmission and storage infrastructure for a novel process (gas switching reforming) that enables flexible power and hydrogen production. In conclusion, all major system elements must be considered to accurately reflect the costs of using hydrogen to integrate higher VRE shares.     

Power-to-gas in a smart city context – Influence of network restrictions and possible solutions using on-site storage and model predictive controls

Power-to-gas (P2G or PtG) technology can provide energy storage capacity to the energy system by converting excess electrical energy into hydrogen and feeding it into the natural gas network, where it can be stored. However nowadays hydrogen feed-in has to be limited to certain percentages in order to keep the characteristics of the resulting gas mixture (i.e. heating value) within the national standards. For P2G plants in urban areas this can strongly impact the economic viability. This paper investigates the use of on-site storage and model predictive controller (MPC) to ease the negative effect of restrictions in the gas and power grid on the economics of P2G systems. Three different use-cases for P2G in an urban setting are considered: Optimal utilisation of renewable electricity produced within the boundaries of the city, optimised electricity purchase at the spot market and optimal usage of electric network. MPC is compared to an optimised rule-based control approach. Results show that both controls can be used to meet the objectives and operate the power-to-gas plant. However, the MPC approach results in a smoother operation of the plant and significantly improved economic performance in all cases and is recommended. The results indicate the beneficial effects of on-site hydrogen storage on system operation and economics. For the investigated cases a storage capacity around 6 full load hours of the electrolyser was sufficient to improve results significantly.     

Dynamic modeling and characteristic analysis of natural gas network with hydrogen injections

With the transformation of energy structure, the proportion of renewable energy in the power grid continues to increase. However, the power grid's capacity to absorb renewable is limited. In view of this, converting the excess renewable energy into hydrogen and injecting it into natural gas network for transportation can not only increase the absorption capacity of renewable energy but also reduce the transportation cost of hydrogen. While this can lead to the problem that hydrogen injection will make the dynamic characteristics of the pipeline more complicated, and hydrogen embrittlement of pipeline may occur. It is of great significance to simulate the dynamic characteristics of gas pipeline with hydrogen injection, especially the hydrogen mixture ratio. In this paper, the cell segmentation method is used to solve each natural gas pipeline model, the gas components are recalculated in each cell and the parameters of partial differential equation are updated. Additionally, the dynamic simulation model of natural gas network with hydrogen injections is established. Simulation results show that for a single pipeline, when the inlet hydrogen ratio changes, whether or not hydrogen injection has little influence on the pressure and flow. The propagation speed of hydrogen concentration is far less than that of the pressure and flow rate, and it takes about 1.2 × 10⁵ s for the 100 km pipeline hydrogen ratio to reach the steady state again.     

Steady-state analysis of a natural gas distribution network with hydrogen injection to absorb excess renewable electricity

Natural gas networks, thanks to their extensiveness and capillarity, could play a crucial role in the green transition of the energy sector. The decarbonization of a gas network can be achieved by injecting green hydrogen into the grid. This work aims to simulate a low-pressure natural gas distribution network serving industrial and residential users and subjected to one localized injection of hydrogen produced by renewable energy sources. The main quality indexes and fluid dynamics parameters of the gas mixture are analysed to understand the feasibility of injecting hydrogen into a natural gas network. Firstly, the network was examined under nominal steady conditions with a constant hydrogen injection. Then, the same grid was simulated considering a 24-h pattern of hydrogen injection, according to the power daily surplus. The results show that the grid can help to buffer the surplus of renewable power produced. The conclusions derived by the results underline that the effect of H2 injection is maximum during the highest excess of electricity and the importance of an accurate choice of the injection node: a wrong choice leads, at the peak of power production, leads to an amplification of the H2 injection impact and hence to a reduction of the Wobbe Index value that overcomes the safety lower limit.     

Experimental assessment of the combustion performance of an oven burner operated on pipeline natural gas mixed with hydrogen

With the increasing need to reduce greenhouse gas emission and adopt sustainability in combustion systems, injection of renewable gases into the pipeline natural gas is of great interest. Due to high specific energy density and various potential sources, hydrogen is a competitive energy carrier and a promising gaseous fuel to replace natural gas in the future. To test the end use impact of hydrogen injection into the natural gas pipeline infrastructure, the present study has been carried out to evaluate the fuel interchangeability between hydrogen and natural gas in a residential commercial oven burner. Various combustion performance characteristics were evaluated, including flashback limits, ignition performance, flame characteristics, combustion noise, burner temperature and emissions (NO, NO₂, N₂O, CO, UHC, NH₃). Primary air entrainment process was also investigated. Several correlations for predicting air entrainment were compared and evaluated for accuracy based on the measured fuel/air concentration results in the burner. The results indicate that 25% (by volume) hydrogen can be added to natural gas without significant impacts. Above this amount, flashback in the burner tube is the limiting factor. Hydrogen addition has minimal impact on NO_X emission while expectedly decreasing CO emissions. As the amount of hydrogen increases in the fuel, the ability of the fuel to entrain primary air decreases.     

Research on the dynamic characteristics of natural gas pipeline network with hydrogen injection considering line-pack influence

Hydrogen energy has the advantages of renewable, clean and high energy density, which is considered as the most potential secondary energy in the 21st century. But transportation is a major constraint on development of hydrogen. A possible solution is to inject hydrogen into natural gas network for transport. Due to the obvious differences in the properties of natural gas and hydrogen, it is necessary to establish natural gas pipeline model with hydrogen injection to explore the influence of hydrogen on pipeline. The line-pack of natural gas network can improve the flexibility of the system to deal with uncertainties, and the line-pack has a significant impact on the dynamic characteristics of the natural gas network under the change of external conditions. When hydrogen is injected into the natural gas network, the line-pack is affected by both pressure and hydrogen mixture ratio, and the line-pack influence on the dynamic characteristics of the network is more complicated. In this paper, a natural pipe network with hydrogen injection is established based on the finite difference method, and simulation is carried out under different situations to explore the influence of different line-pack on the dynamic characteristics of the natural gas network. The results show that the response speed of hydrogen mixture ratio is faster under the condition of low line-pack, which is conducive to reducing the risk of hydrogen embrittlement when the hydrogen mixture ratio surges for a short time. However, the pressure loss caused by the increase of flow can be reduced in the high line-pack state.     

The economic feasibility study of a 100-MW Power-to-Gas plant

Power-to-Gas (PtG) is a grid-scale energy storage technology by which electricity is converted into gas fuel as an energy carrier. PtG utilizes surplus renewable electricity to generate hydrogen from Solid-Oxide-Cell, and the hydrogen is then combined with CO₂ in the Sabatier process to produce the methane. The transportation of methane is mature and energy-efficient within the existing natural gas pipeline or town gas network. Additionally, it is ideal to make use of the reverse function of SOC, the Solid-Oxide-Fuel-Cell, to generate electricity when the grid is weak in power. This study estimated the cost of building a hypothetical 100-MW PtG power plant with energy storage and power generation capabilities. The emphasis is on the effects of SOC cost, fuel cost and capacity factor to the Levelized Cost of Energy of the PtG plant. The net present value of the plant is analyzed to estimate the lowest affordable contract price to secure a positive present value. Besides, the plant payback period and CO₂ emission are estimated.     

Long-term power-to-gas potential from wind and solar power: A country analysis for Italy

Challenges related to variability of renewable energy sources (RES) recently arose in many countries and several solutions based on energy storage were proposed; among them, a promising option is Power-to-Gas (P2G), able to recover excess and unbalanced electrical energy. In this work, an assessment of long-term P2G potential is performed on a country scale, based on the analysis of electrical system historical data series, rescaled in order to consider the evolution of load and installed wind and solar capacity. In a long-term perspective, it is assumed the complete exploitation of the technical potential of the RES, which represents an upper deployment boundary with current technology. Once satisfied the electric load, residual energy to the P2G system and hydrogen production are calculated on a hourly basis; P2G installed capacity is a consequence of the assumed target on minimum operation on a yearly basis. The Italian case is analyzed, evidencing that the recovered excess energy from RES could substitute nearly 5% of current natural gas consumption or about 7% of national fuel consumption when used for hydrogen mobility. A range of options and a sensitivity analysis on assumptions is presented, showing scenarios with up to 200 GW of installed RES and a 50% additional load with respect to current one. In addition, the extension of the model to a zonal grid structure evidences the impact of transmission lines saturation that may increase gas production up to 50%. Results are compared with the German case, considered in a previous work, evidencing differences due to the diverse energy production mix.     

Large-scale hydrogen energy storage in salt caverns

Large-scale energy storage methods can be used to meet energy demand fluctuations and to integrate electricity generation from intermittent renewable wind and solar energy farms into power grids. Pumped hydropower energy storage method is significantly used for grid electricity storage requirements. Alternatives are underground storage of compressed air and hydrogen gas in suitable geological formations. Underground storage of natural gas is widely used to meet both base and peak load demands of gas grids. Salt caverns for natural gas storage can also be suitable for underground compressed hydrogen gas energy storage. In this paper, large quantities underground gas storage methods and design aspects of salt caverns are investigated. A pre-evaluation is made for a salt cavern gas storage field in Turkey. It is concluded that a system of solar-hydrogen and natural gas can be utilised to meet future large-scale energy storage requirements.     

Transient simulation and techno-economic assessment of a near-zero energy building using a hydrogen storage system and different backup fuels

Proposing a cost-effective off-grid Hybrid Renewable Energy System (HRES) with hydrogen energy storage with a minimum CO2 emission is the main objective of the current study. The electricity demand of an office building is considered to be supplied by Photovoltaic Panels and wind turbines. The office building, modeled in Energy Plus and Open studio, has annual electricity consumption of 500 MWh electricity. 48.9% of the required electricity can be generated via renewable resources. Considering a system without energy storage, the remaining amount of electricity is generated from diesel generators. Hence, for reducing CO2 emission and fuel costs, a hydrogen energy storage system (ESS) is integrated into the system. Hydrogen ESS is responsible for supplying 38.6% of the demand electricity, which means that it can increase the energy supplying ability of the system from 48.9% to 87.5%. In addition to analyzing the application of the hydrogen storage system, the effect of four different kinds of fuel is considered as well. effects of Natural gas, Diesel, Propane, and LPG on the system's application are investigated in this study. Results indicate that natural gas emits less amount of CO2 compared to other fuels and also has a fuel cost of 3054 $/year, while hydrogen ESS is available. For the renewable system without ESS, the fuel cost rises to 10,266 $/year. However, liquid gas, Propane, and LPG have better performance in terms of CO2 emission and fuel cost, respectively.     

Conversion of individual natural gas to district heating: Geographical studies of supply costs and consequences for the Danish energy system

Replacing individual natural gas heating with district heating based to increasing shares of renewable energy sources may further reduce CO₂-emissions in the Danish Building mass, while increasing flexibility of the energy system to accommodate significantly larger amounts of variable renewable energy production. The present paper describes a geographical study of the potential to expand district heating into areas supplied with natural gas. The study uses a highly detailed spatial database of the built environment, its current and potential future energy demand, its supply technologies and its location relative to energy infrastructure. First, using a spatially explicit economic model, the study calculates the potentials and costs of connection to expanded district heating networks by supply technology. Then a comprehensive energy systems analysis is carried out to model how the new district heat can be supplied from an energy system with higher shares of renewable energy. It can be concluded on the basis of these analyses that the methods used proved highly useful to address issues of geographically dependent energy supply; however the spatio-economic model still is rather crude. The analyses suggest to expand district heating from present 46% to somewhere in between 50% and 70%. The most attractive potential is located around towns and cities. The study also suggests that CO₂-emissions, fuel consumption and socio-economic costs can be reduced by expanding district heating, while at the same time investing in energy savings in the building mass as well as increased district heating network efficiency.     

Operation optimization for gas-electric integrated energy system with hydrogen storage module

Hydrogen is gradually becoming one of the important carriers of global energy transformation and development. To analyze the influence of the hydrogen storage module (HSM) on the operation of the gas-electricity integrated energy system, a comprehensive energy system model consisting of wind turbines, gas turbines, power-to-hydrogen (P2H) unit, and HSM is proposed in this paper. The model couples the natural gas network and power grid bidirectionally, and establishes a mixed integer nonlinear programming problem considering HSM. The linearization model of the natural gas pipeline flow equation and the generator set equation is constructed by piecewise linearization method to improve the efficiency of solving the model. And the energy flow distribution in the gas-electricity integrated energy system is finally solved. In Model 1, compared with not considering the installation of P2H units, when the hydrogen doping ratio is 10%, the operating cost can be reduced by 6.63%, and the wind curtailment cost can be reduced by 17.54%, and the carbon emission can be reduced by 298.7 tons. The optimization results of Model 2 reveal that compared with no HSM, the system operating cost is reduced by 5.96%, the hydrogen content level in the natural gas pipeline network is increased by 42.12%, and the carbon emission of the system is reduced by 117.6 tons, and the fluctuation of wind power is suppressed. This study demonstrates the feasibility of large-scale absorption of renewable energy through HSM.     

Development and modelling of a novel electricity-hydrogen energy system based on reversible solid oxide cells and power to gas technology

Compared to the conventional thermal units and electrolytic devices, reversible fuel cells have very high efficiencies on both fuel cell mode of generating electricity and electrolysis mode of producing hydrogen or CH_x. However, previous studies about fuel cells and its benefits of power to gas are not fully investigated in the electricity-gas energy system. Moreover, state-of-art studies indicate that hydrogen could be directly injected to the existing natural gas (NG) pipeline within an amount of 5%–20%, which are considered to make a slight influence on the natural gas technologies. This work proposes a novel electricity-hydrogen energy system based on reversible solid oxide cells (RSOCs) to demonstrate the future vision of multi-energy systems on integrating multiple energy carriers such as electricity, pure hydrogen, synthetic natural gas (SNG) and mixed gas of H₂-natural gas. The P2G processes of RSOC are sub-divided modelled by power to H₂ (P2H) and power to SNG (P2SNG). The co-electrolysis/generation processes and time-dependent start-up costs are considered within a unit commitment model of RSOC. The proposed electricity-hydrogen energy system optimization model is formulated as mixed-integer linear programming (MILP), where the H₂-blended mixed gas flow is linearized by an incremental linearize relaxation technic. The aim of the optimization is to reduce the energy cost and enhance the system's ability to integrate sufficient renewables through NG networks. Besides quantified the benefits of renewable level and H₂ injection limit on the P2G process, the numerical results show that RSOC combined with H₂/SNG injection results in productive economic and environmental benefits through the energy system.     

Hydrogen production through renewable and non-renewable energy processes and their impact on climate change

The urbanization and increase in the human population has significantly influenced the global energy demands. The utilization of non-renewable fossil fuel-based energy infrastructure involves air pollution, global warming due to CO₂ emissions, greenhouse gas emissions, acid rains, diminishing energy resources, and environmental degradation leading to climate change due to global warming. These factors demand the exploration of alternative energy sources based on renewable sources. Hydrogen, an efficient energy carrier, has emerged as an alternative fuel to meet energy demands and green hydrogen production with zero carbon emission has gained scientific attraction in recent years. This review is focused on the production of hydrogen from renewable sources such as biomass, solar, wind, geothermal, and algae and conventional non-renewable sources including natural gas, coal, nuclear and thermochemical processes. Moreover, the cost analysis for hydrogen production from each source of energy is discussed. Finally, the impact of these hydrogen production processes on the environment and their implications are summarized.     

Use of hydrogen as a seasonal energy storage system to manage renewable power deployment in Spain by 2030

Spain has presented a plan (known as PNIEC) to reduce conventional energy sources (shutting down 16 GW) and to increase the use of renewable sources (incorporating 65 GW). This generation portfolio leads to a situation in which there will be a surplus of electrical energy in spring and summer, which will be lacking in autumn and winter. The plan sets a target on batteries, but insufficient to manage more than 10 TWh over 6 months. This paper proposes the deployment of electrolysers to produce hydrogen with the surplus energy, using the already existing Spanish natural gas network to store it. The resulting gas (up to 15% blend of hydrogen in natural gas) could be used subsequently in turbines to alleviate the energy deficit. With this strategy, up to 7.27 TWh of the surplus renewable energy could be reused, and 2.54 million tons of CO2 equivalent would be avoided yearly.     

Assessing the viability of the ACT natural gas distribution network for reuse as a hydrogen distribution network

The Australian Capital Territory (ACT) has legislated and aims to be net zero emissions by 2045. Such ambitious targets have implications for the contribution of hydrogen and its storage in gas distribution networks Therefore, we need to understand now the impacts on the gas distribution network of the transition to 100% hydrogen. Assessment of the viability of decarbonising the ACT gas network will be partly based on the cost of reusing the gas network for the safe and reliable distribution of hydrogen. That task requires each element of the natural gas safety management system to be evaluated.This article describes the construction of a test facility in Canberra, Australia used to identify issues raised by 100% hydrogen use in the medium pressure distribution network, consisting of nylon and polyethylene (PE) as a means of identifying measures necessary to ensure ongoing validity of the network's regulatory safety case.Evoenergy (the ACT's gas distribution company) have constructed a Test Facility, incorporating an electrolyser, a gas supply pressure reduction and mixing skid a replica gas network and a domestic installation with gas appliances. Jointly with Australian National University (ANU) and Canberra Institute of Technology (CIT) the Company has commenced a program of “bench testing”, initially with 100% hydrogen to identify gaps in the safety case specifically focusing on the materials, work practices and safety systems in the ACT.The facility is designed to assess: ? Materials in use including aged network materials and components ? Construction and installation techniques both greenfield and live gas work ? Purging and filling techniques ? Leak detection both underground and above ground ? Emergency response and make safe techniques ? Issues associated with use of hydrogen in light commercial and domestic appliances.To educate and train: ? Technicians and gas fitters on infrastructure installation and management ? Emergency response services on responding to hydrogen related emergencies in a network environment; and ? manage public perceptions of hydrogen in a network environment.Australia has an enviable safety record for the safe and reliable transport, distribution and use of natural gas. The ACT natural gas network owned and operated by Evoenergy is one of the newest in Australia and has leveraged off the best materials and practices in Australia to build its network.The paper addresses major safety issues relating to the production/storage, distribution and consumer end use of hydrogen injected into existing gas distribution networks. The analysis is guided by the Safety Management System. The Hydrogen Testing Facility described in the paper provide tools for evaluation of hydrogen safety matters in the ACT and Australia-wide.Testing to date has confirmed that polyethylene and nylon pipe and their respective jointing techniques can contain 100% hydrogen at pressures used for the distribution of natural gas. Testing has also confirmed that current installation work practices on polyethylene and nylon pipe and joints are suitable for hydrogen service. This finding is subject to variation attributable to staff training and skill levels and further testing has been programmed as outlined in this paper.Testing of gas isolation by clamping and simulated repair on the hydrogen network has established that standard natural gas isolation techniques work with 100% hydrogen at natural gas pressures.     

The economics of power generation and energy storage via Solid Oxide Cell and ammonia

Green hydrogen finds its vital role in bridging the intermittent supplied renewable energy and fossil fuel infrastructure in a broad energy transition context. The bottleneck still lies in hydrogen's low volumetric energy density, prohibiting long-distance, large-scale, and cost-effective transportation. As a promising hydrogen carrier, ammonia possesses mature production, storage, transportation, and distribution supply chains. These advantages of ammonia enabled the possibility of transforming the renewable hydrogen at a minimum initial cost. This paper investigates the technological and economic feasibility of green ammonia utilization in the Solid Oxide Cells for power generation and energy storage. The result shows that the cost of Ammonia induced energy (183.75 US$/MWh) is significantly higher than that of natural gas power plants (81.77 US$/MWh). The main contributor is the fuel cost. In the optimum case, with fuel costs substantially dropping, the conceptual plant can be highly feasible, and the generated energy (97.40 USS$/MWh) is comparable to the conventional power plant.     

Energy prosumerism using photovoltaic power plant and hydrogen combustion engine: Energy and thermo-ecological assessment

Renewable Energy Sources (RES) represent an attractive way to save natural resources and improve the overall impact of power systems on the environment. A continuous increase of share of RES in national energy mixes is observed, and due to the energy policy of the European Union and many other countries, further increase is expected. A disadvantage of RES is their random, weather-dependent availability, which requires energy storage. A promising method of integrating RES with the energy system is the use of hydrogen as an energy carrier (e.g. coupling RES with electrolyzers in order to directly use the renewable electricity for production of hydrogen). In the present work, a simulation of cooperation of a photovoltaic power plant with a gas piston engine fueled by hydrogen was performed, with and without the presence of energy storage. The aim of the analysis is twofold. First, the “compensation losses” due to forced part-load operation of the engine coupled with RES are evaluated and compared with “storage losses” resulting from the thermodynamic imperfectness of the storage; this allows to calculate the minimum round-trip efficiency of storage required for positive energy effect. The “compensation losses” have been determined to be of the order of magnitude of 2%, and the minimum round-trip efficiency of storage to be at the level of 85%. Second, a thermo-ecological analysis was carried out to determine the impact of the source of hydrogen on the overall ecological effectiveness of the system. Contrary to the commonly used measure of “energy efficiency” describing a local balance boundary, thermo-ecological cost (TEC) evaluates the consumption of non-renewable exergy within a global balance boundary. The analysis confirmed that comparing various hydrogen production methods (especially renewable and non-renewable) in terms of local energy efficiency is inadequate, because it does not tell much about their sustainability. For a hydrogen energy system basing on the water electrolysis – hydrogen transport/storage – combustion in a gas piston engine pathway to be considered sustainable, the input electricity to the electrolysis process should be characterized by TEC lower than ∼0.15 J1/J, a value which even some renewable energy sources fail to achieve.     

A multi-model method to assess the value of power-to-gas using excess renewable

Power-to-Gas (P2G) is a process that produces a gas from electricity, which is most commonly hydrogen via electrolysis. While some studies have considered hydrogen as a power-to-power storage vector, it could also be used as a fuel across the energy system, for example for transport or heat generation. Here, two energy models are used to explore the potential contribution of P2G as a cost-effective source of hydrogen, particularly for future energy systems with high variable renewable energy (VRE) in which there are occasional periods when electricity supply exceeds demand. A detailed electricity system model is iterated with a multi-vector energy system model using a soft-linking approach. This iterative approach addresses shortcomings in each model to better understand the optimal capacity of P2G and the potential economic capture rate of excess VRE. The modelling method is applied to Great Britain in 2050 as a case study. A substantial proportion of excess VRE in 2050 can be captured by P2G, and it is economically competitive compared with alternative sources. Moreover, the effectiveness and economic viability of P2G for reducing excess renewable is robust at even very high levels of renewable penetration.