Optimal sizing of a fuel processor for auxiliary power applications of a fuel cell-powered passenger car

The present study considers the optimal sizing of a three-way hybrid powertrain consisting of a compact reformer, a compact battery and a low temperature PEM fuel cell stack serving as the main power unit. A simulation model consisting of the relevant characteristic parameters of the three power sources has been developed and has been used to study the fuel utilization features of the hybrid powertrain while going through the NEDC driving cycle with a given auxiliary power requirement. The optimality is based on minimizing fuel cost while having an assured range of 500 km under practical driving conditions and a further 100 km under reduced auxiliary power usage. It is shown that for performance characteristics of Toyota Mirai and for average auxiliary power consumption of 5 kW, a smaller NiMH battery size of 1.3 kWh together with a fuel processor of 5.6 kW constant output would be optimal with a further requirement of 25% more hydrogen and 33 kg of ethanol to be carried on-board. Substantial reductions in vehicle mass and fuel load can be achieved for more modest performance characteristics and auxiliary power consumption.     

Dynamic analysis of a PEM fuel cell hybrid system with an on-board dimethyl ether (DME) steam reformer (SR)

Low-temperature polymer electrolyte membrane fuel cell (PEMFC) acts as a promising energy source due to the non-pollution and high-energy density. However, as hydrogen supply is a major constraint limiting the wide spread of fuel cell vehicles, a dimethyl ether (DME)-steam on-board reformer (SR) based on catalytic reforming via a catalytic membrane reactor with a channel structure is a possible solution to a direct hydrogen supply. The DME-SR reaction scheme and kinetics in the presence of a catalyst of CuO/ZnO/Al₂O₃+ZSM-5 are functions of the temperature and hydrocarbon ratio in the hydrogen-reforming reaction. An electric heater is provided to keep the temperature at a demanded value to produce hydrogen. As there is no available analysis tool for the fuel cell battery hybrid vehicle with on-board DME reformer, it is necessary to develop the tool to study the dynamic characteristics of the whole system. Matlab/Simulink is utilized as a dynamic simulation tool for obtaining the hydrogen production and the power distribution to the fuel cell. The model includes the effects of the fuel flow rate, the catalyst porosity, and the thermal conductivity of different subsystems. A fuel cell model with a battery as a secondary energy storage is built to validate the possible utilization of on-board reformer/fuel cell hybrid vehicle. In consideration of time-delay characteristic of the chemical reactions, the time constant obtained from the experiment is utilized for obtaining dynamic characteristics. The hydrogen supplied by the reformer and the hydrogen consumed in the PEMFC prove that DME reformer can supply the adequate hydrogen to the fuel cell hybrid vehicle to cope with the required power demands.     

On the road performance simulation of hydrogen and hybrid cars

An assessment is made of on-the-road performance, for a pure hydrogen fuel cell car, a pure battery operated car, and a hydrogen fuel cell-battery hybrid car. The tool used for this study is the modular software-package ADVISOR [Markel T, et al. ADVISOR. J Power Sources 2002; 110:255–66], which is well tested and offers a range of simple, parametrized sub-models or more detailed physical models for the fuel cell stack, the batteries, the electric motor, the exhaust control, the transmission and entire power train including controls and control strategies. The basis configurations of the cars modelled is characterized by high energy efficiency, before adding a fuel cell and electric motor also of high conversion efficiencies. Preceding the presentation of results, the best way to characterize energy efficiency is discussed.     

Dynamic behaviour of Li batteries in hydrogen fuel cell power trains

A Li ion polymer battery pack for road vehicles (48 V, 20 Ah) was tested by charging/discharging tests at different current values, in order to evaluate its performance in comparison with a conventional Pb acid battery pack. The comparative analysis was also performed integrating the two storage systems in a hydrogen fuel cell power train for moped applications. The propulsion system comprised a fuel cell generator based on a 2.5 kW polymeric electrolyte membrane (PEM) stack, fuelled with compressed hydrogen, an electric drive of 1.8 kW as nominal power, of the same typology of that installed on commercial electric scooters (brushless electric machine and controlled bidirectional inverter). The power train was characterized making use of a test bench able to simulate the vehicle behaviour and road characteristics on driving cycles with different acceleration/deceleration rates and lengths. The power flows between fuel cell system, electric energy storage system and electric drive during the different cycles were analyzed, evidencing the effect of high battery currents on the vehicle driving range. The use of Li batteries in the fuel cell power train, adopting a range extender configuration, determined a hydrogen consumption lower than the correspondent Pb battery/fuel cell hybrid vehicle, with a major flexibility in the power management.     

Efficiencies of hydrogen storage systems onboard fuel cell vehicles

Energy efficiency, vehicle weight, driving range, and fuel economy are compared among fuel cell vehicles (FCV) with different types of fuel storage and battery-powered electric vehicles. Three options for onboard fuel storage are examined and compared in order to evaluate the most energy efficient option of storing fuel in fuel cell vehicles: compressed hydrogen gas storage, metal hydride storage, and onboard reformer of methanol. Solar energy is considered the primary source for fair comparison of efficiencies for true zero emission vehicles. Component efficiencies are from the literature. The battery powered electric vehicle has the highest efficiency of conversion from solar energy for a driving range of 300 miles. Among the fuel cell vehicles, the most efficient is the vehicle with onboard compressed hydrogen storage. The compressed gas FCV is also the leader in four other categories: vehicle weight for a given range, driving range for a given weight, efficiency starting with fossil fuels, and miles per gallon equivalent (about equal to a hybrid electric) on urban and highway driving cycles.     

Innovative design of an hydrogen powertrain via reverse engineering

In this paper the powertrain of a zero emission vehicle powered by hydrogen has been designed with an innovative approach via reverse engineering.The use of a zero environmental impact vehicles is particularly stringent in urban area where high air pollutant concentrations could be reached. In particular, in this paper, the use of fuel cell vehicles plus ultracapacitors has been considered to minimize the TTW (Tank to Wheels) global efficiency in comparison with the conventional vehicles powered by ICE.A zero emissions city-car is designed by optimization of the components (in particular the energy storage) in order to minimize both its weight and its bulk with particular reference to the functions (passenger vehicles, minibus, freight distribution), the areas where the vehicle is driven (characteristic drive cycles, traffic) and the users (different driving style). In particular the design discussed in this paper was carried out through a process of reverse engineering. The energy needs, in fact, were calculated starting from real drive cycles obtained during an on-board data acquisition campaign carried out in Rome urban area.In this paper the powertrain is designed starting from the acquisition of real drive cycles obtained during acquisitions campaign in an urban area. The data collected by the on-board acquisitions systems has been used to evaluate the power required by the wheels as a function of time in a generic urban drive cycle and the energy needs of an urban vehicle. Thus, the analysis performed takes into account not only global energy consumption, but also the power needs that are affected by both the congested traffic conditions and the driving style.     

Research and development of on-board hydrogen-producing fuel cell vehicles

Combining with the characteristics of different types of electric vehicles, the on-board hydrogen-producing fuel cell vehicle design is adopted, which eliminates the problems about the high-pressure hydrogen storage and the hydrogenation process. The fuel cell is used as the main power source to drive the motor, and the lithium battery is used as the auxiliary power source to accelerate and recycle energy in order to meet the special requirements, like energy recovery, power and dynamic characteristics, of fuel cell vehicles. On the ADVISOR simulation platform based on MATLAB/Simulink environment, a hybrid drive model and a pure fuel cell drive model are built, and simulation and comparative analysis are performed. In the hybrid drive model, fuel cells and lithium batteries work in the highly efficient and safe operating areas respectively, and the output power of fuel cell has small fluctuations, improving energy utilization efficiency and extending the service life of the fuel cell. At the same time, the charge and discharge of the lithium battery can be effectively managed to ensure the safety of charging and prolong the service life of the lithium battery.     

Energy management of a fuel cell hybrid ultra-energy efficient vehicle

This paper focuses on energy management in an ultra-energy efficient vehicle powered by a hydrogen fuel cell with rated power of 1 kW. The vehicle is especially developed for the student competition Shell Eco-marathon in the Urban Concept category. In order to minimize the driving energy consumption a simulation model of the vehicle and the electric propulsion is developed. The model is based on vehicle dynamics and real motor efficiency as constant DC/DC, motor controllers and transmission efficiency were considered. Based on that model five propulsion schemes and driving strategies were evaluated. The fuel cell output parameters were experimentally determined. Then, the driving energy demand and hydrogen consumption was estimated for each of the propulsion schemes. Finally, an experimental study on fuel cell output power and hydrogen consumption was conducted for two propulsion schemes in case of hybrid and non-hybrid power source. In the hybrid propulsion scheme, supercapacitors were used as energy storage as they were charged from the fuel cell with constant current of 10 A.     

Metal membrane-type 25-kW methanol fuel processor for fuel-cell hybrid vehicle

A 25-kW on-board methanol fuel processor has been developed. It consists of a methanol steam reformer, which converts methanol to hydrogen-rich gas mixture, and two metal membrane modules, which clean-up the gas mixture to high-purity hydrogen. It produces hydrogen at rates up to 25 N m³/h and the purity of the product hydrogen is over 99.9995% with a CO content of less than 1 ppm. In this fuel processor, the operating condition of the reformer and the metal membrane modules is nearly the same, so that operation is simple and the overall system construction is compact by eliminating the extensive temperature control of the intermediate gas streams. The recovery of hydrogen in the metal membrane units is maintained at 70–75% by the control of the pressure in the system, and the remaining 25–30% hydrogen is recycled to a catalytic combustion zone to supply heat for the methanol steam-reforming reaction. The thermal efficiency of the fuel processor is about 75% and the inlet air pressure is as low as 4 psi. The fuel processor is currently being integrated with 25-kW polymer electrolyte membrane fuel-cell (PEMFC) stack developed by the Hyundai Motor Company. The stack exhibits the same performance as those with pure hydrogen, which proves that the maximum power output as well as the minimum stack degradation is possible with this fuel processor. This fuel-cell ‘engine’ is to be installed in a hybrid passenger vehicle for road testing.     

Hybrid electric power plant sizing strategy based on ab-initio fuel cell design for weight minimization

This work presents a methodology for the design of a hydrogen fuel cell-based hybrid electric power plant for hybrid electric vehicles (HEV), where a battery bank and ultracapacitors are also considered as components of the hybrid power plant. The methodology considers the design features of an electric vehicle and evaluates its energy and power requirements as to fulfil a driving cycle. The work starts by weight minimizing a fuel cell taking into consideration its physical and electrochemical characteristics. Batteries and ultracapacitors are then sized according to their dynamic response features and considering specifications from commercial candidate cells, to propose an electric configuration and specify the baseline for a hybrid power plant. In order to illustrate the methodology, a crossover utility electric vehicle and a WLTC class I drive cycle are used. This work shows that by reducing the power plant size, power and energy requirements can also be minimized and the overall performance can be increased promoting fuel and costs savings. For comparison and to show the impact of weight minimization on the energy on board and cost, this work presents the energy and power required by different power plant configurations. Results showed that including ultracapacitors to the power plant offers more benefits, such as less stress on batteries, at a marginal initial cost compared to a case without ultracapacitors, where batteries should attend transients with a limited capability for energy recovery from regenerative breaking. The methodology is easily implemented and does not large computational resources providing with a power plant baseline for further design stages, such as particular energy management approaches depending on particular priorities for the developer, such as range, productivity and performance, economy and others.     

Performance optimization of hybrid hydrogen fuel cell-electric vehicles in real driving cycles

In this research study, a fuel cell-electric hybrid car is studied. This car includes an electric motor that is connected to a fuel cell and a complex which includes a battery pack and an Ultracapacitor. The assessment of this hybrid vehicle is conducted by using various driving cycles such as FTP-75 driving cycle, NEDC driving cycle and SFTP-SC03 driving cycle. Battery state of charge (SoC) and hydrogen fuel consumption are the effective parameters influencing the vehicle performance. For analysing the performance of this vehicle, an innovative computational model is considered. In this innovative computational model, an accurate control strategy is considered in order to control the power demand, staying the battery packs and the Ultracapacitor state of charge in a limited domain. Results show that in NEDC driving cycle, by means of using Ultracapacitor in this model, 3.3% reduction in fuel consumption and 20.2% decrease in the difference between initial and final State of Charge (SoC) in battery pack can be achieved. In addition, a robust regenerative braking control strategy is used in order to recover some parts of the wasted energy in braking driving modes.     

Test of hybrid power system for electrical vehicles using a lithium-ion battery pack and a reformed methanol fuel cell range extender

This work presents the proof-of-concept of an electric traction power system with a high temperature polymer electrolyte membrane fuel cell range extender, usable for automotive class electrical vehicles. The hybrid system concept examined, consists of a power system where the primary power is delivered by a lithium ion battery pack. In order to increase the run time of the application connected to this battery pack, a high temperature PEM (HTPEM) fuel cell stack acts as an on-board charger able to charge a vehicle during operation as a series hybrid. Because of the high tolerance to carbon monoxide, the HTPEM fuel cell system can efficiently use a liquid methanol/water mixture of 60%/40% by volume, as fuel instead of compressed hydrogen, enabling potentially a higher volumetric energy density.     

Models of energy sources for EV and HEV: fuel cells,batteries, ultracapacitors,flywheels and engine-generators

Resulting from a Ph.D. research a Vehicle Simulation Programme (VSP) is proposed and continuously developed. It allows simulating the behaviour of electric, hybrid, fuel cell and internal combustion vehicles while driving any reference cycle [Simulation software for comparison and design of electric, hybrid electric and internal combustion vehicles with respect to energy, emissions and performances, Ph.D. Thesis, Department Electrical Engineering, Vrije Universiteit Brussel, Belgium, April 2000]. The goal of the simulation programme is to study power flows in vehicle drive trains and the corresponding component losses, as well as to compare different drive train topologies. This comparison can be realised for energy consumption and emissions as well as for performances (acceleration, range, maximum slope, etc.).The software package and its validation are described in [J. Automot. Eng., SAE IEE 215 (9) (2001) 1043L]. Different hybrid and electric drive trains are implemented in the software [Views on hybrid drive train power management strategies, in: Proceedings of the EVS-17, Montreal, Canada, October 2000]. The models used for the energy sources like fuel cells, batteries, ultracapacitors, flywheels and engine-generator units will be discussed in this paper in three stages: first their functionality and characteristics are described, next the way these characteristics can be implemented in a simulation model will be explained and finally some calculation results will illustrate the approach.This paper is aimed to give an overview of simulation models of energy sources for battery, hybrid and fuel cell electric vehicles. Innovative is the extreme modularity and exchangeability of different components functioning as energy sources. The unique iteration algorithm of the simulation programme allows to accurately simulate drive train maximum performances as well as all kind of power management strategies in different types of hybrid drive trains [IEEE Trans. Veh. Technol., submitted for publication].     

An experimental study of a PEM fuel cell power train for urban bus application

An experimental study was carried out on a fuel cell propulsion system for minibus application with the aim to investigate the main issues of energy management within the system in dynamic conditions. The fuel cell system (FCS), based on a 20 kW PEM stack, was integrated into the power train comprising DC–DC converter, Pb batteries as energy storage systems and asynchronous electric drive of 30 kW. As reference vehicle a minibus for public transportation in historical centres was adopted. A preliminary experimental analysis was conducted on the FCS connected to a resistive load through a DC–DC converter, in order to verify the stack dynamic performance varying its power acceleration from 0.5 kW s⁻¹ to about 4 kW s⁻¹. The experiments on the power train were conducted on a test bench able to simulate the vehicle parameters and road characteristics on specific driving cycles, in particular the European R40 cycle was adopted as reference. The “soft hybrid” configuration, which permitted the utilization of a minimum size energy storage system and implied the use of FCS mainly in dynamic operation, was compared with the “hard hybrid” solution, characterized by FCS operation at limited power in stationary conditions. Different control strategies of power flows between fuel cells, electric energy storage system and electric drive were adopted in order to verify the two above hybrid approaches during the vehicle mission, in terms of efficiencies of individual components and of the overall power train.     

Experimental study of a fuel cell power train for road transport application

The development of fuel cell electric vehicles requires the on-board integration of fuel cell systems and electric energy storage devices, with an appropriate energy management system. The optimization of performance and efficiency needs an experimental analysis of the power train, which has to be effected in both stationary and transient conditions (including standard driving cycles).In this paper experimental results concerning the performance of a fuel cell power train are reported and discussed. In particular characterization results for a small sized fuel cell system (FCS), based on a 2.5 kW PEM stack, alone and coupled to an electric propulsion chain of 3.7 kW are presented and discussed. The control unit of the FCS allowed the main stack operative parameters (stoichiometric ratio, hydrogen and air pressure, temperature) to be varied and regulated in order to obtain optimized polarization and efficiency curves. Experimental runs effected on the power train during standard driving cycles have allowed the performance and efficiency of the individual components (fuel cell stack and auxiliaries, dc–dc converter, traction batteries, electric engine) to be evaluated, evidencing the role of output current and voltage of the dc–dc converter in directing the energy flows within the propulsion system.     

Modeling and control of a portable proton exchange membrane fuel cell-battery power system

A portable proton exchange membrane (PEM) fuel cell-battery power system that uses hydrogen as fuel has a higher power density than conventional batteries, and it is one of the most promising environmentally friendly small-scale alternative energy sources. A general methodology of modeling, control and building of a proton exchange membrane fuel cell-battery system is introduced in this study. A set of fuel cell-battery power system models have been developed and implemented in the Simulink environment. This model is able to address the dynamic behaviors of a PEM fuel cell stack, a boost DC/DC converter and a lithium-ion battery. To control the power system and thus achieve proper performance, a set of system controllers, including a PEM fuel cell reactant supply controller and a power management controller, were developed based on the system model. A physical 100 W PEM fuel cell-battery power system with an embedded micro controller was built to validate the simulation results and to demonstrate this new environmentally friendly power source. Experimental results demonstrated that the 100 W PEM fuel cell-battery power system operated automatically with the varying load conditions as a stable power supply. The experimental results followed the basic trend of the simulation results.     

A novel predictive power flow control strategy for hydrogen city rail train

Hydrogen-based vehicular traction has already reached a mature technological level and can replace the more polluting diesel engines. The adoption of this technology can also alleviate the carbon footprint issue of the rail trains running on non-electrified lines.This study presents a model and a numerical performance analysis of an electric hybrid train in an urban context. The train uses hydrogen as fuel and operates over non-electrified lines with zero local emission.The electric traction motors of the train are fed by a hybrid power unit consisting of several hydrogen fuel cell stacks operating independently in on/off mode and a set of flywheel energy storage devices.Each component of the power train is modeled separately and its operating limits are chosen on the base of technical literature.An innovative predictive logic to manage power flows is defined and proposed with the aim to minimize the fuel consumption. Furthermore, this approach uses a regenerative electrical braking and eliminates dissipative devices, like rheostats, which are commonly utilized onboard electric trains.This predictive approach is based on the optimal management of the power unit components according to the advanced knowledge of the data of the rail vehicle, the characteristics of path, drive cycle and payload for an established route.The fuel cell stacks operate accordingly to the average traction power requirement in each railway line section, whereas the flywheel energy storage system manages the dynamic power.A parametric model of the system and a respective software tool have been developed; this implementation, that incorporates many tunable parameters of the train and rail path, is able to simulate the rail train operating on a specific railway path by implementing the novel control strategy.An existing single track non-electrified line, designed again for urban service, has been selected as a case study to evaluate the performance of the proposed system.The specific fuel consumptions obtained with the novel control strategy and with a single fuel cell system operating at constant power are compared under the same operating conditions.The results highlight that significant fuel savings can be achieved.     

Dynamic modeling of a three-stage low-temperature ethanol reformer for fuel cell application

A low-temperature ethanol reformer based on a cobalt catalyst for the production of hydrogen has been designed aiming the feed of a fuel cell for an autonomous low-scale power production unit. The reformer comprises three stages: ethanol dehydrogenation to acetaldehyde and hydrogen over SnO₂ followed by acetaldehyde steam reforming over Co(Fe)/ZnO catalyst and water gas shift reaction. Kinetic data have been obtained under different experimental conditions and a dynamic model has been developed for a tubular reformer loaded with catalytic monoliths for the production of the hydrogen required to feed a 1 kW PEMFC.     

Design of a methanol reformer for on-board production of hydrogen as fuel for a 3 kW High-Temperature Proton Exchange Membrane Fuel Cell power system

The method of Computational Fluid Dynamics is used to predict the process parameters and select the optimum operating regime of a methanol reformer for on-board production of hydrogen as fuel for a 3 kW High-Temperature Proton Exchange Membrane Fuel Cell power system. The analysis uses a three reactions kinetics model for methanol steam reforming, water gas shift and methanol decomposition reactions on Cu/ZnO/Al₂O₃ catalyst. Numerical simulations are performed at single channel level for a range of reformer operating temperatures and values of the molar flow rate of methanol per weight of catalyst at the reformer inlet. Two operating regimes of the fuel processor are selected which offer high methanol conversion rate and high hydrogen production while simultaneously result in a small reformer size and a reformate gas composition that can be tolerated by phosphoric acid-doped high temperature membrane electrode assemblies for proton exchange membrane fuel cells. Based on the results of the numerical simulations, the reactor is sized, and its design is optimized.     

Fuel cell-battery hybrid powered light electric vehicle (golf cart): Influence of fuel cell on the driving performance

A light electric vehicle (golf cart, 5 kW nominal motor power) was integrated with a commercial 1.2 kW PEM fuel cell system, and fuelled by compressed hydrogen (two composite cylinders, 6.8 L/300 bar each). Comparative driving tests in the battery and hybrid (battery + fuel cell) powering modes were performed. The introduction of the fuel cell was shown to result in extending the driving range by 63–110%, when the amount of the stored H₂ fuel varied within 55–100% of the maximum capacity. The operation in the hybrid mode resulted in more stable driving performances, as well as in the increase of the total energy both withdrawn by the vehicle and returned to the vehicle battery during the driving. Statistical analysis of the power patterns taken during the driving in the battery and hybrid-powering modes showed that the latter provided stable operation in a wider power range, including higher frequency and higher average values of the peak power.