共查询到17条相似文献,搜索用时 171 毫秒
1.
介绍了中国石化催化剂北京燕山分公司的裂解重C+9馏分一段加氢工况,采用了低压、低空速、高氢油比和高循环比的加氢工艺。依据工业装置原料性质、反应温度和反应器进、出口压力变化情况,统计分析了使用YN-1型镍系催化剂没有经过再生进行一段加氢产品的溴价和双烯含量变化,工业应用结果表明,YN-1型镍系催化剂具有优异的加氢活性和长周期运行的稳定性。 相似文献
2.
介绍中国石化抚顺石油化工研究院开发的C_6馏分选择性加氢催化剂在550 kt·a-1苯抽提蒸馏装置原料预处理C_6馏分选择性加氢单元的工业应用。结果表明,C_6馏分选择性加氢脱烯烃工艺替代传统白土精制工艺,C_6馏分原料溴指数为(7 500~12 000) mg-Br·(100g)^(-1),在反应器入口温度130℃、入口压力1.8 MPa、氢油体积比250∶1~280∶1和空速2.5 h^(-1)条件下,反应产物溴指数小于5 mg-Br·(100g)^(-1),且芳烃损失接近于0,达到国内同类装置先进水平。 相似文献
3.
4.
研制一种新型耐硫、抗胶质镍系加氢催化剂,在固定床液相加氢装置评价催化剂性能,考察催化剂制备方法、载体和助剂种类对裂解C9馏分加氢性能的影响。结果表明,浸渍法制备的催化剂活性较高,添加稀土分子筛及助剂后的催化剂低温活性更好。在反应器入口温度(60~80) ℃、空速1.5 h-1、反应压力3.0 MPa和氢油体积比500∶1条件下,对催化剂进行240 h稳定性实验,裂解C9馏分的双烯值由5.3 g-I2·(100g)-1降至约0.60 g-I2·(100g)-1,溴值由57.2 g-Br2·(100g)--1降至约25.5 g-Br2·(100g)-1,稳定性良好。 相似文献
5.
为了提高C4馏分的利用价值并实现扩大乙烯裂解料的来源,使用自制的镍系加氢催化剂和钴-钼-镍系加氢精制催化剂,在固定床200 mL绝热评价装置上对C4馏分液化石油气物料进行全加氢实验,论证镍系加氢催化剂适用于含有低碳含硫化合物C4馏分的可行性,对模拟的某化工厂C4馏分原料进行加氢饱和性能考察,对含有高浓度双烯烃和炔烃的丁二烯抽提装置尾气进行原料模拟和全加氢评价。结果表明,自制催化剂适用于含有低碳硫化物的C4馏分全加氢,可以处理高含双烯烃的C4物料,并具有良好的低温活性。 相似文献
6.
综述了二硝基甲苯液相加氢合成甲苯二胺催化剂的研究进展,并介绍了(Pd+Pt)/C等贵金属催化剂、雷尼镍催化剂、负载型镍基催化剂、非晶态镍催化剂和漆原镍催化剂的最新研究成果。通过对比上述各催化剂在生产成本、制备工艺及催化二硝基甲苯加氢性能等方面的优缺点,发现非晶态镍催化剂不但价格低廉,而且在1 MPa低压二硝基甲苯液相加氢的反应中表现出与(Pd+Pt)/C工业催化剂相似的活性和选择性,是替代二硝基甲苯液相加氢贵金属和雷尼镍工业催化剂的首要选择;漆原镍催化剂制备工艺简单,价格低廉,且在众多的加氢反应中表现出与骨架镍催化剂相似的催化性能,也具有较大的工业化潜质。 相似文献
7.
8.
9.
10.
11.
The selective catalytic reduction (SCR) of NO by hydrocarbon is an efficient way to remove NO emission from lean-burn gasoline and diesel exhaust. In this paper, a thermally and hydrothermally stable Al–Ce-pillared clay (Al–Ce-PILC) was synthesized and then modified by SO42−, whose surface area and average pore diameter calcined at 773 K were 161 m2/g and 12.15 nm, respectively. Copper-impregnated Al–Ce-pillared clay catalyst (Cu/SO42−/Al–Ce-PILC) was applied for the SCR of NO by C3H6 in the presence of oxygen. The catalyst 2 wt% Cu/SO42−/Al–Ce-PILC showed good performance over a broad range of temperature, its maximum conversion of NO was 56% at 623 K and remained as high as 22% at 973 K. Furthermore, the presence of 10% water slightly decreased its activity, and this effect was reversible following the removal of water from the feed. Py-IR results showed SO42− modification greatly enhanced the number and strength of Brönsted acidity on the surface of Cu/SO42−/Al–Ce-PILC, which played a vital role in the improvement of NO conversion. TPR and XPS results indicated that both Cu+ and isolated Cu2+ species existed on the optimal catalyst, mainly Cu+, as Cu content increased to 5 wt%, another species CuO aggregates which facilitated the combustion of C3H6 were formed. 相似文献
12.
Coprecipitated catalyst systems containing BaCO3 and La2On(CO3)m (n≥1.5) with La/Ba = 0.05-10 were tested for catalytic activity, selectivity and stability in the oxidative coupling of methane reaction (OCM). Maximum C2+ selectivities of 78% and C2+ yields of 11% were obtained. The results show that La is the more active cation component of the system. The presence of BaCO3 in the system leads to decreasing crystal size of the La phases, and to higher C2+ selectivities at equal methane conversions. Life time tests showed that the Ba- La-containing catalysts were quite stable. Na impurities in the system lead to larger crystals in the La phases, and to less selective and less stable catalysts for the OCM reaction. Na is lost during reaction. 相似文献
13.
ZHOU Jun CHU Wei ZHANG Hui XU Huiyuan ZHANG Tao 《Frontiers of Chemical Science and Engineering》2008,2(3):315
The effect of Fe content on FeMn/MgO catalysts for light alkenes synthesis through CO hydrogenation was investigated. Catalysts were prepared by a conventional co-impregnation method, characterized using BET, X-ray powder diffraction (XRD) and Temperature-programmed reduction (H2-TPR) techniques. High activity was obtained over the catalyst with 9 wt-% Fe content, over which CO conversion and the selectivity of C2=–C4= reached 91.36% and 58.48%, respectively. With the increase of Fe content, both the conversion and the selectivity were improved within a certain range and then decreased. The results show that the surface area of the catalyst played an important role in the catalytic reaction. With the increase of Fe loading, the interaction action between Fe and Mn was enhanced and FeMn solid solution was formed. 相似文献
14.
2,5-二甲氧基苯基乙胺是一种有机合成中间体,在医药和精细化工行业具有重要价值。系统研究有机均相催化体系中以负载型催化剂Ru/AC和Ru-Pd/AC对2-(2,5-二甲氧基苯基)硝基乙烯进行催化加氢制备2,5-二甲氧基苯基乙胺。结果表明,采用Ru/AC催化体系,在氢压5.0 MPa、Ru浓度4.9×10-3mol·L~(-1)、反应时间5 h和反应温度150℃条件下,可以获得纯度较高的CC加氢与硝基完全加氢的目标产物,转化率达到100%,目标产物选择性可达93%;采用Ru-Pd/AC催化体系,在氢压3.0 MPa、Ru和Pd总浓度2.46×10-3mol·L~(-1)、反应时间5 h和反应温度190℃条件下,转化率可以达到100%,目标产物选择性为84%。反应结束后,抽滤即可分离催化剂和产物。 相似文献
15.
采用等体积浸渍法制备了Pd、Cu-Pd改性的S-1催化剂,利用介质阻挡放电(DBD)等离子体反应器研究了甲烷无氧转化制低碳烯烃(C2~C4=)的性能,重点关注了乙烯的产量。探讨了Ar的添加和特定输入能量(SIE)对甲烷转化率以及产物分布的影响。实验结果表明,等离子体与催化剂协同催化与仅使用等离子体相比性能更优异,使乙烯选择性提高了3.1倍,C2~C4=的选择性提高了2.7倍;与S-1相比,Pd/S-1具有更高的乙烯选择性,这是因为在S-1上负载金属Pd有助于乙炔原位加氢生成乙烯;适宜的Pd负载量有利于提高烯烃选择性,而过高的Pd负载量倾向于不饱和烃的连续加氢,导致了烷烃的生成;与单金属Pd改性相比,Cu-Pd双金属改性抑制了乙烯的进一步加氢,提高了乙烯的选择性。通过扫描电子显微镜(SEM)、透射电子显微镜(TEM)、高倍透射电子显微镜(HRTEM)、X射线粉末衍射(XRD)、X射线光电子能谱(XPS)对催化剂进行了表征分析。结果表明,Cu的加入使自身电子向Pd转移,增加了Pd电子密度;另外,Cu的存在提高了Pd的分散性。以2Cu-0.1Pd/S-1为催化剂时可以得到更优异的反应性能。 相似文献
16.
采用沉淀-水热法制备了系列不同Mg/Fe/Mn配比的MgFeMn-HTLcs类水滑石前体,经焙烧、浸渍法K改性用于CO加氢制烯烃反应。采用XRD、SEM、TG、N2吸附-脱附、H2-TPR、XPS等手段对催化剂进行了表征。结果表明,制备的Mg-Fe-Mn前体均具有类水滑石层状结构,Mn的添加使结晶度下降;焙烧后,Mg-Fe样品主要生成MgO,Mg-Fe-Mn样品生成Mg2MnO4、MgO和MgFe2O4物相;反应后主要为MgCO3和FeCO3混合物相,伴随FeO-MnO和FexCy的生成;与K/Mg-Fe样品相比,Mn的加入进一步促进了Fe的分散,使得Fe2O3到Fe3O4还原度增加,其供电子效应促使Fe电子结合能向低偏移。在CO加氢反应中,K/Mg-Fe-Mn催化剂均表现出较高的反应活性和烯烃选择性。其中,K/3Mg-1Fe-2Mn催化剂的效果较好,CH4含量较低,O/P值达5.20,C2=~C4=质量分数为43.03%。 相似文献