Effects of Rare Earth Elements on Properties and Structure of WC－14TiC－8Co Cemented Carbide

ＥｆｆｅｃｔｓｏｆＲａｒｅＥａｒｔｈＥｌｅｍｅｎｔｓｏｎＰｒｏｐｅｒｔｉｅｓａｎｄＳｔｒｕｃｔｕｒｅｏｆＷＣ－１４ＴｉＣ－８ＣｏＣｅｍｅｎｔｅｄＣａｒｂｉｄｅＨｅＣｏｎｇ－Ｘｕｎ；（贺从训）；ＷａｎｇＹｏｕ－Ｍｉｎｇ；（汪有明）；ＬｉｎＣｈｅｎ－Ｇｕ...     

Preparation of Yttrium－Barium－Copper Trinary Master Alloys by Electrolysis from Molten Fluoride－oxide

ＰｒｅｐａｒａｔｉｏｎｏｆＹｔｔｒｉｕｍ－Ｂａｒｉｕｍ－ＣｏｐｐｅｒＴｒｉｎａｒｙ　ＭａｓｔｅｒＡｌｌｏｙｓｂｙＥｌｅｃｔｒｏｌｙｓｉｓｆｒｏｍ　ＭｏｌｔｅｎＦｌｕｏｒｉｄｅ－ｏｘｉｄｅＴｏｎｇＹｅｘｉａｎｇ（童叶翔）；ＬｉｕＧｕａｎｋｕｎ（刘冠昆）...     

Study on the Synergistic Extraction of Ytterbium with 1－Phenyl－3－Methyl－4－（α－Furoyl）－5－Pyrazolone and Neutral Extractant

ＳｔｕｄｙｏｎｔｈｅＳｙｎｅｒｇｉｓｔｉｃＥｘｔｒａｃｔｉｏｎｏｆＹｔｔｅｒｂｉｕｍｗｉｔｈ１－Ｐｈｅｎｙｌ－３－Ｍｅｔｈｙｌ－４－（α－Ｆｕｒｏｙｌ）－５－ＰｙｒａｚｏｌｏｎｅａｎｄＮｅｕｔｒａｌＥｘｔｒａｃｔａｎｔ￥ＤｉｎｇＺｈｏｎｇ－Ｔａｏ；Ｌ...     

Extraction Separation of Scandium，Iron and Lutetium with Isopropyl Phosphonic Acid Mono（1－hexyl－4－ethyl）OctylEster

ＥｘｔｒａｃｔｉｏｎＳｅｐａｒａｔｉｏｎｏｆＳｃａｎｄｉｕｍ，ＩｒｏｎａｎｄＬｕｔｅｔｉｕｍｗｉｔｈＩｓｏｐｒｏｐｙｌＰｈｏｓｐｈｏｎｉｃＡｃｉｄＭｏｎｏ（１－ｈｅｘｙｌ－４－ｅｔｈｙｌ）ＯｃｔｙｌＥｓｔｅｒＳｕｎＪｉｎｇ；ＬｉＤｅｑｉａｎ（Ｌａｂｏ...     

Effect of Rare Earth Metals on Microstructure of Directional Solidified Al－3Li Alloy

ＥｆｆｅｃｔｏｆＲａｒｅＥａｒｔｈＭｅｔａｌｓｏｎＭｉｃｒｏｓｔｒｕｃｔｕｒｅｏｆＤｉｒｅｃｔｉｏｎａｌＳｏｌｉｄｉｆｉｅｄＡｌ－３ＬｉＡｌｌｏｙ￥ＷａｎｇＬｉ－Ｍｉｎ；ＤａｎｇＰｉｎｇ；ＤｕＦｕ－Ｙｉｎｇ；ＺｈａｏＭｉｎ－Ｓｈｏｕ（Ｃｈａｎｇｃｈｕ...     

Effect of Rare Earth Additives on the Catalytic Property ofVanadium－Phosphorus Catalyst

ＥｆｆｅｃｔｏｆＲａｒｅＥａｒｔｈＡｄｄｉｔｉｖｅｓｏｎｔｈｅＣａｔａｌｙｔｉｃＰｒｏｐｅｒｔｙｏｆＶａｎａｄｉｕｍ－ＰｈｏｓｐｈｏｒｕｓＣａｔａｌｙｓｔＬｉＭｉｎｇｘｉｕ（李铭岫）；ＹａｎｇＳｈｕｔａｏ（杨述韬）；ＬｉｕＣｕｉｇｅ（刘翠格）（Ｄｅｐ...     

Study of the Effect of Hot－pressing Techniques on the Magnetic Properties of Pr－Fe－B Alloys

ＳｔｕｄｙｏｆｔｈｅＥｆｆｅｃｔｏｆＨｏｔ－ｐｒｅｓｓｉｎｇＴｅｃｈｎｉｑｕｅｓｏｎｔｈｅＭａｇｎｅｔｉｃＰｒｏｐｅｒｔｉｅｓｏｆＰｒ－Ｆｅ－ＢＡｌｌｏｙｓ￥ＹａｎｇＸｉａｎｊｉｎ（杨贤金），ＹａｏＪｉａｘｉｎ（姚家鑫），ＺｈａｏＮａｉｑｉｎ（赵乃勤...     

Electrochemical Behavior of Eu~（3＋） on Eastman AQ－29D Chemically Modified Electrode

ＥｌｅｃｔｒｏｃｈｅｍｉｃａｌＢｅｈａｖｉｏｒｏｆＥｕ~（３＋）ｏｎＥａｓｔｍａｎＡＱ－２９ＤＣｈｅｍｉｃａｌｌｙＭｏｄｉｆｉｅｄＥｌｅｃｔｒｏｄｅＹｅＸｉａｎ－Ｚｅｎｇ（叶宪曾）；ＢｕＹｉ－Ｇｏｎｇ（卜一工）；ＬｉＮａｎ－Ｑｉａｎｇ（李南强）（Ｄｅ?..     

Scanning Analysis of REE in Bastnaesite with Synchrotron Radiation X－Ray Fluorescence Microprobe

ＳｃａｎｎｉｎｇＡｎａｌｙｓｉｓｏｆＲＥＥｉｎＢａｓｔｎａｅｓｉｔｅｗｉｔｈＳｙｎｃｈｒｏｔｒｏｎＲａｄｉａｔｉｏｎＸ－ＲａｙＦｌｕｏｒｅｓｃｅｎｃｅＭｉｃｒｏｐｒｏｂｅＡｎＱｉｎｇｘｉａｎｇ（安庆骧）；ＷａｎｇＲｕｉｂｉｎｇ（王锐兵）；ＤｅｎｇＳａ...     

Report on Rare Earth Market Evolution and Involvement of Rhone－Poulenc in the Market

ＲｅｐｏｒｔｏｎＲａｒｅＥａｒｔｈＭａｒｋｅｔＥｖｏｌｕｔｉｏｎａｎｄＩｎｖｏｌｖｅｍｅｎｔｏｆＲｈｏｎｅ－ＰｏｕｌｅｎｃｉｎｔｈｅＭａｒｋｅｔＭａｔｔｈｅｗｓＪＤ；ＶａｎｄｅｒｓｔｒｉｃｈｔＪＰ（Ｒｈｏｎｅ－ＰｏｕｌｅｎｃＲａｒｅＥａｒｔｈｓａｎｄ...     

Microstructure and mechanical properties of Mg-7Zn-3Al alloy with Nd and Y additions

The effects of combined addition of 0.6 wt.% Nd and 0.4 wt.% Y on the microstructure and mechanical properties of Mg-7Zn-3Al alloy were investigated.The results indicated that the Nd and Y addition led to obvious dendrite coarsening.However,it could modify the morphology and distribution of-Mg 32(Al,Zn) 49 intermetallics.Moreover,Al 2 REZn 2 phase could be introduced into the alloy with the Nd and Y addition.With the effective second-phase strengthening,the ultimate tensile strength and elongation in as-cast state can be improved by the Nd and Y addition.After ageing treatment,the alloy with the Nd and Y addition exhibited better precipitation strengthening effects by forming finer MgZn 2 and Mg 32(Al,Zn) 49 precipitates into the-Mg matrix.As a result,the yield and ultimate strength of Mg-7Zn3Al-0.6Nd-0.4Y alloy could be increased to 182 and 300 MPa by peak-ageing treatment.     

Effect of alloying elements on the formation of rolling texture in Mg-Nd-Zr and Mg-Li alloys

The effect of alloying on the texture of Mg-Nd-Zr and Mg-Li alloy sheets is studied using pole and inverse pole figures. The basal texture intensity in rolling of Mg-Nd-Zr alloys is shown to be substantially decreased due to the precipitation of dispersed intermetallic Mg₁₂Nd phase particles. As a result, the workability characteristics during deep drawing can be increased. Lithium alloying causes the formation of a prismatic rolling texture, which is unusual for magnesium alloys, as a result of the phase transformation of the lithium-based bcc phase into the magnesium-based hexagonal close-packed phase that obeys the Burgers orientation relationships.     

Microstructure and Properties of Mg-10%Al-(0～3%)Di Alloys

The effects of didymium(Nd:Pr=3:1)on the microstructure and mechanical properties of Mg-10%Al alloy were studied with the additions of 0～3%Di. The small block-like Al2(Nd,Pr) phase appears in 1%Di alloy, the block-like Al2(Nd,Pr) and needle-like Al11(Nd,Pr)3 phases appear synchronously in 2%Di and 3%Di alloys, while the network of (Mg17Al12) β phase is broken up. The tensile properties can be improved with the addition of didymium. When the addition of didymium in Mg-10%Al alloy reaches 2%, the alloy exhibits the best combination of strength and ductility, but the strength and ductility drop at the addition of 3%Di due to the obvious increase of the size and quantity of the needle-like Al11(Nd,Pr)3 phase.     

纳米晶Al-Cu-Mg合金的微观组织与力学性能研究

以工程实际中应用较广的Al-Cu-Mg铝合金作为研究对象, 用Al-Cu-Mg铝合金气体雾化粉末作为原材料, 通过低温液氮球磨获得纳米晶后, 再经真空热压和热挤压制备了致密的大块体纳米材料. 通过力学性能测试, 挤压态的纳米晶Al-Cu-Mg块体材料抗拉强度达470 MPa, 经过T4处理后, 抗拉强度达到590 MPa, 远远超过常规方法制备的Al-Cu-Mg铝合金抗拉强度. 对纳米晶Al-Cu-Mg块体材料进行微观组织观察, 分析了材料强度提高的原因.     

热处理工艺对低温挤压Zn-15Al锌合金组织及性能的影响

采用拉伸试验和扫描电镜分析技术手段,研究了不同冷却速度对200℃挤压Zn-15Al锌合金的微观组织和室温力学性能的影响.结果表明:经320℃处理1 h后,变形态细小的α(Al)相发生了粗化.经水淬后α(Al)相发生了连续析出,形成了α(Al)+η(Zn)细小的粒状组织,使其强度稍有提高,塑性明显降低.而经空冷后α(Al)相发生了共析分解,形成了细片层状组织,导致其强度提高约1倍,塑性下降约80%.这意味着能够通过热处理工艺来调整变形态Zn-15Al锌合金的力学性能,以满足不同应用领域的要求.     

Investigation on the icosahedral quasicrystal phase in Mg70.8Zn28Nd1.2 alloy

Mg70.8Zn28Nd1.2 (mole fraction) alloy containing icosahedral quasicrystal phase (I-phase) was prepared under conventional metal casting conditions. The microstructure, phase constitution and phase structure of the alloy were investigated by means of scanning electron microscopy (SEM), X-ray diffraction (XRD), energy dispersive spectrometer (EDS) and transmission electron microscopy (TEM). The re-sults showed that the spherical phase in MgT70.8Zn28Nd1.2 alloy was a simple icosahedral quasicrystal with stoichiometric composition of Mg40Zn55Nd5 and quasi-lattice of 0.525 nm. In this research, the as-cast microstructure of Mg70.8Zn28Nd1.2 alloy mainly consisted of Mg40Zn55Nd5 icosahedral quasicrystal phase and Mg7Zn3 columnar crystal matrix. In the growing process of Mg40Zn55Nd5 icosahedral qua-sicrystal phase, the growth morphology mainly depended on interface energy, adsorption effect of Nd and cooling rate.     

热处理制度对TB2钛合金带材力学性能及显微组织的影响

研究了固溶处理温度、冷却方式及时效处理温度对0．8mm厚TB2钛合金带材显微组织及力学性能的影响。结果表明：固溶处理时,冷却方式对TB2钛合金带材的力学性能影响较大,真空水淬与真空气淬均能得到较高的综合力学性能,但从可操作性来看,应采用真空气淬的方式冷却;TB2钛合金带材的较佳固溶处理温度为800℃,经800oc×12min真空气淬固溶处理后,可获得较高的强度和延伸率;TB2钛合金带材的较佳时效处理温度为480℃,经480℃X8h／FC时效处理后,其抗拉强度可达1250MPa以上,延伸率达到18％以上,组织中的等轴口晶α粒内均匀分布着细小的相。     

Effect of Neodymium on As-Cast Microstructure and Mechanical Properties of AZ31 Wrought Alloy

Nd in the form of powder or intermediate alloy was added to AZ31 wrought alloy. The as-obtained alloy was characterized and tested with respect to its microstructure and mechanical properties. The relationship between the microstructure, mechanical properties and tensile fracture mechanism were discussed, with relevant alloys as reference for comparison. Experimental results show that the same quantity of Nd was added into AZ31 in powder form or in intermediate alloy, the absorption rate of Nd reached only 10.8% for the former case and as high as 95% for the later case. Pure Nd powder was added, no new compound was detected, but it served as reductant and purified alloy melt, resulting in improving the tensile strength while Nd was added into AZ31 as Mg-Nd intermediate alloy. The compound Al2Nd and Mg12 Nd were formed in magnesium alloy, which were distributed in the matrix in the shapes of strip and particle, evidently refined the as-cast structure. The as-cast tensile strength (228MPa) of adding pure Nd powder approximated to the figure (245MPa) of adding Mg-Nd intermediate alloy. The tensile fracture mchanism of as-cast AZ31 transformed from cleavage fracture into quasi-cleavage fracture.     

钛合金固态相变的归纳与讨论（Ⅳ）——钛合金热处理的归类

通过对钢、铝合金和钛合金热处理过程中相变特点的分析,总结了金属材料热处理的三大分类：淬火＋回火,固溶＋时效,淬火＋时效。在此基础上细致的分析了三类热处理的异同、并根据钛合金热处理的相变特点,将其划归为第三类热处理。