Fiber Wobbling Method for Dynamic Viscoelastic Measurement of Liquid Lubricant Confined in Molecularly Narrow Gaps

An understanding of the viscoelastic properties of molecularly thin lubricant film is essential to clarify tribological issues of head-disk interface (HDI) in high-density recording hard disk drives. Characteristic conditions for the HDI occur when lubricant molecules are extremely confined in the gap between the head and the disk surfaces, and the surfaces slide at high speeds. The lower the flying height, the more this confinement affects the flying characteristics. However, a few attempts have been made at clarifying the dynamic viscoelastic properties of confined lubricant molecules. This is because a method of measuring the dynamic shear force has not yet been established. Fiber wobbling method enables us to measure the shear force with a detection limit of less than 1 nN. Additionally, frequency of shear can be set at several kHz. Further, the gap which confines the lubricant is controlled with a resolution of 0.1 nm. Using the FWM, we investigated the effect that confinement had on the dynamic viscoelastic properties of perfluoropolyether lubricants on a magnetic disk. We found that the viscosity started to increase at a gap width that was less than a few hundred nanometers, which is hundreds of times larger than the molecular size. On the other hand, elasticity suddenly appeared at a gap width that was less than a few nanometers, which is equivalent to a few molecular sizes. Both the viscosity and elasticity increased monotonically as the gap decreased.     

Dynamic microwaviness measurements of super smooth disk media used in magnetic hard disk drives

Recent technological advances in magnetic storage suggest the feasibility of extremely high-density magnetic recording up to 1 terabit per square inch (1 Tbit=10¹² bits) areal densities. Modelling indicates that approximately 3 nanometers (nm) of physical head-disk spacing is required for such high recording densities. When the recording slider is flying at such ultra low spacing over a high-speed rotating disk, it is experiencing disturbances from various different sources and of a wide frequency range. These disturbances may cause the recording slider to vibrate significantly, a condition that is known as fly height modulation (FHM), which may result in data loss. A significant source of excitation is from the surface irregularities of the rotating disk and is termed dynamic microwaviness. The term dynamic microwaviness has been introduced recently to differentiate from regular topographical features that are measured statically. In this paper, the procedure for making reliable dynamic microwaviness measurements of disk media used in hard disk drive (HDD) systems is described. Furthermore, such measurements are performed on different super smooth magnetic disks that are intended for extremely high recording densities using non-contact laser vibrometry. The root-cause of the dynamic microwaviness is investigated by measuring disk topographical features under static conditions and the interaction with system dynamics. It is found that dynamic microwaviness is primarily due to topographical features of spatial wavelengths ranging from 58.8 to 250 μm, and secondarily due to system dynamic effects.     

Contact analysis of impact in magnetic head disk interfaces

Three-dimensional finite element analysis of head and disk contact effects induced by impact in magnetic head disk interface (HDI) are presented. Elastic–plastic contact simulations are performed using . The entire contact–impact procedures during head disk collision under the dynamic loading of half-sine pulse acceleration with profiles of 300 and 500 g amplitude and 1.0 ms in duration are described in detail. Simulation results for the contact pressure distribution at HDI, von Mises equivalent stress, and equivalent plastic strain fields are examined and interpreted in terms of impact history. A comprehensive history of head disk relative displacement and von Mises equivalent stresses within contact region are provided and the evolution of plasticity are discussed. It is shown that finite element method can provide the simulation of the contact behavior resulting from the dynamic loading.     

Thermomechanical analysis of elastoplastic medium in sliding contact with fractal surface

The effects of mechanical and thermal surface loadings on deformation of elastic–plastic semi-infinite medium were analyzed simultaneously by using the finite element method. Rigid rough surface of a magnetic head and smooth surface of an elastic–plastic hard disk were chosen to perform a comprehensive thermo-elastic–plastic contact analysis at the head–disk interface (HDI). A two-dimensional finite element model of a rigid rough surface characterized by fractal geometry sliding over an elastic–plastic medium was then developed. The evolution of deformation in the semi-infinite medium due to thermomechanical surface loading is interpreted in terms of temperature, von Mises equivalent stress, and equivalent plastic strain. In addition to this, the effects of friction coefficient, sliding, and interference distance on deformation behavior were also analyzed. It is shown that frictional heating increases not only the contact area but also the contact pressure and stresses.     

Effects of End Groups on the Tribochemical Reactions of Lubricants at Head-Disk Interface

Mass spectrometry was used to monitor in-situ gaseous species that were generated at the head-disk interface (HDI) in a high vacuum. It was found that the end groups of the lubricants significantly affected the wear durability at the HDI; piperonyl (–CH₂-phe = (O)₂ = CH₂) terminated Fomblin AM3001 lubricant exhibited longer life than hydroxyl (–OH) terminated Fomblin ZDOL lubricant. The continuous removal of the lubricants resulted in a continuously increasing friction coefficient. Further, the characteristics of tribochemical reactions of the lubricants (Fomblin Z series) with different end groups was investigated in details using Time-of-Flight Secondary Ion Mass Spectroscopy (TOF-SIMS) just after the sliding tests. It was found that the decomposition of the end groups was more significant than that of the backbone. The lubricants terminated with the following groups showed the following order of increasing decomposition: –CH₂O-CH₂-phe = (O)₂ = CH₂ (AM3001), –CH₂OH (ZDOL) < –CH₂OCH₂CH(OH)CH₂OH (Z Tetraol) < –CH₂(OCH₂CH₂)_nOH (ZDOL-TX), –COOH (Z Diac). The decomposition of the lubricants appeared to start from the end groups.     

Tribological Performance and Transfer Behavior of Lubricating Oils at Head-Disk Interface under Volatile Organic Contamination

Tribological performance of head-disk interface (HDI) under volatile organic contamination was investigated using a contact start/stop (CSS) tester. Slider and disk surfaces were analyzed using Time-of-Flight Secondary Ion Mass Spectroscopy (TOF-SIMS) after CSS tests. The CSS test results indicated that the friction forces were high and unstable under contamination. Transfer of lubricating oil onto the slider surface was detected after the CSS tests. The transfer amount of lubricating oil was revealed to be dependent on the chemical structure of the terminal group in the lubricating oil. Piperonyl (–CH₂−phe=(O)₂=CH₂) terminated AM3001 lubricating oil was lost more easily than two hydroxyl (–OH) terminated Tetraol lubricating oil, probably because of the weak attractive force of the piperonyl groups with carbon overcoat. TOF-SIMS chemical images indicated that the transferring behavior of the lubricating oil onto the slider surface during CSS tests was dependent on the chemical structure of volatile organic contaminants. The lubricating oil became built up on the slider surface when the dioctyl sebacate (DOS) pollutant used. In contrast, the lubricating oil distribution on the slider surface was uniform under a polydimethylsiloxane (PDMS) vapor. The different transfer behavior of lubricating oil onto the slider surface may be resulted from the changeable surface properties of slider and disk because of the coexistence with gaseous contaminants.     

Effect of Molecularly Thin Lubricant on Roughness and Adhesion of Magnetic Disks Intended for Extremely High-Density Recording

For extremely high-density recording using conventional technologies, the fly-height needs to decrease to less than ten nanometers. To allow such operation, disk and slider surfaces must become extremely smooth, down to root-mean-square (RMS) roughness values of a few angstroms. For super-smooth disks, molecularly thin lubricants are applied to improve tribological performance of head/disk interfaces. The focus of this study is to quantify the effect of lubricant thickness in terms of detailed roughness parameters and to evaluate the effect of roughness and molecularly thin lubricant on adhesion of magnetic disks intended for extremely high-density recording. Three identical ultra-low-flying disks have been fabricated from the same batch for this particular experiment. To investigate the effect of molecularly thin lubricants on disk roughness, super-smooth magnetic disks with increasing lubricant thickness have been measured and studied, using a primary roughness parameter set. It describes amplitude, spatial, hybrid, and functional aspects of surface roughness and is used to quantify the extremely smooth disk roughness as a function of lubricant thickness. It is found that in addition to simple amplitude parameters, hybrid and functional parameters also capture small features on the disk roughness and show distinct trends with increasing lubricant thickness. Subsequently, a continuum-based adhesion model that uses three parameters from the primary roughness parameter set, is used to predict how the varying thickness of molecularly thin lubricant and the resulting disk roughness affect intermolecular forces at ultra-low-flying head-disk interfaces. It is found that a thicker lubricant layer of 2nm causes higher adhesion forces for ultra-low-flying-heights in the range of 1–3 nm     

Effect of lubricant bonding fraction at the head–disk interface

Tribochemical studies of the effect of lubricant bonding on the tribology of the head–disk interface (HDI) were conducted using hydrogenated (CHx) carbon disk samples coated with perfluoropolyether ZDOL lubricant. The studies involved drag tests with uncoated and carbon-coated Al₂O₃–TiC sliders and also thermal desorption experiments in an ultrahigh vacuum (UHV) tribochamber. The friction and catalytic decomposition mechanisms as well as the thermal behavior of ZDOL are described. We observed that a larger mobile lubricant portion significantly enhances the wear durability of the HDI by providing a reservoir to constantly replenish the lubricant displaced in the wear track during drag tests. In the thermal desorption tests we observed two distinct temperatures of desorption. The mobile ZDOL layer is desorbed at the lower thermal desorption temperature and the residual bonded ZDOL layer is desorbed at the higher thermal desorption temperature.     

Adhesion and friction properties of hydrogenated amorphous carbon films measured by atomic force microscopy

Atomic force microscopy has been used to measure adhesion and friction forces at the interface between an oxidized metal probe tip and amorphous carbon films of varying hydrogen contents (12.3–39.0 atomic percent hydrogen). The interface of an oxide surface and a hard carbon coating models the unlubricated head-disk interface of current hard disk products. Adhesion forces normalized by the radius of curvature of the contacting tip range from 1.09 to 8.53 N/m. Coefficients of friction values, measured as the slope of the friction versus load plot, range from 0.33 to 0.87. A trend of increasing adhesion forces and coefficients of friction is observed for increasing hydrogen content in the films. We attribute the increase in adhesion and friction to increases in the surface free energy of the carbon films with the incorporation of hydrogen.     

Head design considerations for lower thermal pole tip recession and alumina overcoat protrusion

The magnetic/mechanical spacing between the transducer and the disk significantly decreases due to thermal expansion of pole tips at stressed high temperature and high humidity tests. The protruded pole tips and alumina overcoat result increased thermal asperities and can interfere with the higher disc asperities and be damaged due to high contact. The damage at the head-disk interface due to protruded pole tips and alumina overcoat may become a major roadblock in the drive mechanical performance when flying height is below 10 nm. In this study, the thermal PTR defined as change in PTR with temperature is measured using an optical profiler and an AFM for heads having stack design with single and dual layers of writer coil. The pole tips protrude above the ABS surface by 3–4 nm when the temperature of the head is raised by 50°C. Heads with single layer of writer coil exhibit significantly lower thermal PTR than those with dual layers of coils.     

Effects of temperature dependent air properties on the performances of a thermal actuated slider

Thermal actuated sliders have been widely used in today's hard disk drive industry for its advantages of easier control of flying height (FH) and less risk of contacts with the disk over the conventional slider. In this paper, we used a coupled-field analysis method, which includes an air bearing model, a heat transfer model and a thermal-structural finite element (FE) model to investigate the flying and thermal performances of a thermal actuated slider at various environmental temperatures. We also proposed a generalized mean free path model to incorporate various molecular dynamics models and consider temperature effects of the mean free path. Some temperature dependent air properties, such as the viscosity and the thermal conductivity are also considered in the simulation. It is found that the mean free path is a crucial parameter in determine air bearing and heat transfer across the head-disk interface (HDI). Our simulation results also show that the temperature effects of the viscosity and the thermal conductivity are contrary to that of the mean free path, which limit the variations of air bearing and heat transfer as the environmental temperature increases. However, their temperature effects still need to be considered for an accurate simulation, especially when the disk drives operate in a wide temperature range.     

A Computer-Controlled Magnetic Resonance Spectrometer with a Pulsed Magnetic Field

An automatic magnetic resonance spectrometer with a pulsed magnetic field is described. It has the following characteristics: a field range of 0–100 kOe, a frequency band of 25–140 GHz, a temperature range of 4.2–300 K, and a pulse duration of 12.6 ms. The spectrometer is automated to the CAMAC standard using standard modules. To record a magnetic-resonance spectrum, the following procedure is applied: the resonance-absorption signal is determined by a 10-bit analog-to-digital converter, and the magnetic filed is scanned by simulating a current pulse in a discharge circuit of the solenoid using a single input parameter—the initial charge voltage of the capacitor bank. In calibration measurements performed with spherical yttrium–iron-garnet samples, the average measurement error was 0.15%.     

Inert Gas Filled Head–Disk Interface for Future Extremely High Density Magnetic Recording

Inert gas filled head–disk interface (HDI) is a possible solution in reducing the magnetic spacing between the magnetic head and the magnetic media for achieving further increased recording density of a magnetic recording system. This article investigated the flying and thermal performances of a thermal actuated slider at inert gas filled HDI by using a couple-field analysis method which consists of a finite element model of the entire slider, an air bearing model based on the generalized lubrication equation and a heat transfer model which incorporates various molecular dynamics models and considers temperature effects. The simulation studies showed that the variation of gap flying height (FH) with the heater power in the inert gas is quite similar to that in air. It is also found that the slider’s thermal actuation efficiency in helium is slightly better than those in argon and air. However, the temperature effects in a fully sealed drive are totally different to those in an open drive. As a result, the inert gas filled HDI normally requires a larger thermal actuation stroke due to the temperature effects in a fully sealed drive.     

The Contribution of Thin PFPE Lubricants to Slider–Disk Spacing

We have investigated the effect of the molecular weight (MW) and film thickness of a perfluoropolyether lubricant, Zdol, on the slider–disk spacing loss, or clearance. The major conclusion of this work is that Zdol films as thin as 10 Å can reduce the slider–disk clearance by 2 nm or more in the molecular weight range of 1000–5000 amu. This is attributed to the attractive van der Waals interaction between the slider and the disk surface that causes the Zdol main chain to interact with the slider surface, giving rise to a friction force. When the film thickness of the lubricant exceeds the monolayer thickness, dewetting can take place. The droplets that form occupy the space between the slider and disk surface reducing the slider–disk clearance by as much as 4 nm. There is a step increase in the acoustic emission signal at the dewetting thickness transition, indicative of a slider–disk interference.     

Evaluation of head/disk pseudo-impact contact byacoustic emission technique

Pseudo-impact contact at the interface between proximity slidersand magnetic rigid disks were investigated by acoustic emission(AE) technique. Under a hot/wet condition of 60°C/80% RH andan operation speed of 19.15 m/s, AE responses were collected inreal time to monitor interaction events at the head/diskinterface (HDI). The profile of AE responses shows various eventsat the HDI which could be correlated to the micro-wear of thecarbon overcoat andlubricant degradation. These events were also detected by opticalsurface analysis (OSA). These wear and degradation eventsindicate the need for choosing the proper lubricant anddemonstrate that AE is a suitable tool to detect these events atthe head/disk interface.     

Physicomechanical Properties of the Rust-Resisting Austenitic–Martensitic Steel 13Kh15N4AMZSh as Functions of the Heat Treatment Regimes

Physicomechanical properties and parameters of the resonance electromagnetic–acoustic conversion (EMAC) are studied as functions of the heat treatment regimes for high-strength rust-resisting steel of the 13Kh15N4AMZSh austenitic-martensitic sort. It is shown that variations of the coercive force, the saturation magnetization, the specific electrical conductivity and the hardness as functions of the quenching temperature are due to the austenite–martensite ratio and the degree of alloying. A deviation from the optimum quenching temperature (1070°C) by ± 50°C affects only slightly the values of the above characteristics. The quality monitoring of products tempered on the interval 100–500°C is possible by measuring the resonance frequency of the EMAC signal. The optimum variant of the tempering quality monitoring is that on the basis of measuring two parameters: the coercive force (or the residual induction) and one of the EMAC-signal parameters (signal amplitude, quality, or resonance frequency).     

Effect of relative humidity and disk acceleration on tribocharge build-up at a slider–disk interface

High performance disk drives require high spindle speed. The spindle speed of typical hard disk drives has increased in recent years from 5400 to 15000 rpm and even higher speeds are anticipated in the near future. The increasing disk velocity leads to increasing disk acceleration and slider–disk interaction. As the head-to-disk spacing continues to decrease to facilitate increasing recording densities in disk drives, the slider–disk interaction has become much more severe due to the direct contact of head and disk surfaces in both start/stop and flying cases. The slider–disk interaction in contact-start-stop (CSS) mode is an important source of particle generation and tribocharge. Charge build-up in the slider–disk interface can cause electrostatic discharge (ESD) damage and lubricant decomposition. In turn, ESD can cause severe melting damage to MR or GMR heads. We measured the tribocurrent/voltage build-up generated at increasing disk acceleration. In addition, we examined the effects of relative humidity on the tribocharge build-up. We found that the tribocurrent/voltage was generated during pico-slider/disk interaction and that its level was below 250 pA and 0.5 V, respectively. Tribocurrent/voltage build-up was reduced with increasing disk acceleration. Higher humidity conditions (75–80%) yielded lower levels of tribovoltage/current. Therefore, a higher tribocharge is expected at a lower disk acceleration and lower relative humidity condition.     

Boundary lubrication with anti-wear additives: study of interface film formation by electrical contact resistance

It has been shown that a rapid measuring technique for electrical contact resistance (ecr) has potential applications in lubricant additives studies. In boundary lubrication of a metallic interface with zinc dialkyl dithiophosphate (DTPZn) or other anti-wear additives blended in the lubricant, anti-wear efficiency relies on interface film formation which acts also as an insulating barrier for electrical current. Investigations in the 1ω to 10 Mω range of resistance, with subsequent and appropriate ecr signal treatment and analysis, indicate that systematic use of ecr permits visualisation and study of interface film formation. This paper shows that two interface films can be detected, with two different levels of average ecr, 0–1 kω and 100k–10Mω. Discussion is based on an interface model and attempts to find what kind of further information on film formation may be obtained from ecr measurements     

Effect of self-assembled monolayers modified slider on head-disk tribology under volatile organic contamination

Self-assembled monolayers (SAMs) with different endgroups were established on slider surface. The effect of the SAMs coated slider on head-disk tribology under volatile organic contamination (VOC) of octamethylcyclotetrasiloxane (D₄) was investigated using a contact start/stop (CSS) tester. The slider surfaces before and after the CSS tests were analyzed using Time-of-Flight Secondary Ion Mass Spectroscopy (TOF-SIMS). The contact angle measurement and TOF-SIMS analysis proved that the SAMs were successfully formed on the slider surface. All the SAMs reduced the friction under the pollutant vapor. The transfer of lubricating oil onto the slider surface was detected after the CSS tests. It was found that the slider with a low surface free energy associated with small amount of lubricating oil transfer. The little the lubricating oil transfer was, the low the frictions were. These results indicate that a slider with low surface free energy can reduce the loss of lubricating oil from the disk surface, and hence improve the tribological properties of hard-disk interface (HDI) under VOC.     

A Facility for Investigating Ultrasound Velocity and Absorption in Light and Heavy Water at High Temperatures and High Pressures

An experimental facility was designed to study the velocity and absorption factor of ultrasound in light and heavy water at high temperatures (up to 550°C) and high pressures (as great as 550 atm.) using the continuous variable-baseline interferometer method. The facility is composed of an autoclave, a liquid nitric thermostat, systems for temperature and pressure measurements and control, mechanical and electrical systems of the acoustical interferometer, and a deaeration and filling unit. Due to the design features of the facility and the measuring technique, which ensure a low temperature gradient and a small ballast volume, the velocity and absorption factor of ultrasound can be simultaneously measured with a high degree of accuracy (0.05–0.09% and 7–10%, respectively), and their frequency dependences can be obtained in the range 0.5–10.0 MHz even in the critical region.__________Translated from Pribory i Tekhnika Eksperimenta, No. 4, 2005, pp. 127–133.Original Russian Text Copyright © 2005 by Erokhin, Kompaniets.