共查询到20条相似文献,搜索用时 56 毫秒
1.
HDPE/炭黑导电复合材料的改性 总被引:1,自引:0,他引:1
本文研究了导电炭黑的品种、含量及其对高密度聚乙烯(HDPE)性能的影响,以及动态硫化对改善HDPE/导电炭黑复合材料物性的贡献。结果表明,HG-4型导电炭黑填充HDPE具有很好的导电性,复合材料力学性能较差;ACET炭黑导电性较差,复合材料力学性能最好。炭黑并用能有效地降低生产成本,而且保持了材料的性能。动态硫化法可以克服复合材料物性差的弱点,并能保持改性材料的高导电性。在HG-4型炭黑含量为7份时,材料的拉伸强度13MPa,断裂伸长率350%,体积电阻率为2.1Ω·cm。 相似文献
2.
LDPE/炭黑导电复合材料电学及力学性能研究 总被引:6,自引:1,他引:5
研究了炭黑种类及用量、极性共聚物(E-AE-MAH)、润滑剂种类及用量和交联剂(DCP)对LDPE/炭黑导电复合材料电学及力学性能的影响。结果表明,HG-4型炭黑导电性最好,ACET炭黑导电性较差。极性共聚物能提高复合材料的导电性和力学性能。高分子蜡改善复合材料电学及力学性能的效果优于液体石蜡。交联剂使复合材料导电性变差,但力学性能提高 相似文献
3.
4.
HDPE抗静电复合材料性能的研究 总被引:4,自引:0,他引:4
本文介绍通过在HDPE中添加经表面处理的高导电炭黑,制备炭黑/HDPE抗静电复合材料,研究了炭黑含量对炭黑/HDPE抗静电性能、拉伸和流变性能的影响。由于采用高导电炭黑为导电填料,炭黑的加入量(质量分数)为10%~15%时,就能制得具有抗静电性能的复合材料;由于对炭黑进行了表面处理,改善了炭黑与HDPE的相容性,使所制复合材料的拉伸强度下降较少,材料呈假塑性流体特征,非牛顿粘度随炭黑含量提高有一定程度的升高,但材料的非牛顿性变化不大。 相似文献
5.
用孟山都流交仪测定了不同共混比的甲基乙烯基硅橡胶(VMQ)/EPDM共混混炼胶的流变性能;用网笼法测定了炭黑在共混体系两相中的比例;研究了薄通次数对共混硫化胶体积电阻率的影响;用透射电镜观察了硫化胶的形态。根据试验结果得出:适当并用比和炭黑填充量的VMQ/EPDM共混硫化胶具有高导电性的原因是:两相粘度相差较大,共混体系为明显的“海-岛”结构,而且炭黑在共混体系两相中的浓度不同;具有高导电性及其加工稳定性的VMQ/EPDM共混导电橡胶的最佳并用比例为80/20—70/30。 相似文献
6.
高结构导电炭黑填充硅橡胶复合材料的性能 总被引:13,自引:1,他引:12
研究了导电炭黑(HG-CB)的高结构对乙烯基甲基硅橡胶(VMQ-110)复合材料电性能和机构性能的影响。由TEM观察看出,随HG-CB用量增加,其在硫化胶中形成的导电网络逐渐完善,用量达19份(质量份,下同)时已形成完整的导电网络,导电机理可用电子隧道效应来解释,同时随HG-CB填充量增加,复合材料的拉伸强度、硬度增大,但对VMQ-110的硫化有影响。欠硫现象严重,HG-CB的用量一般控制在10~15份,所得硅橡胶复合材料具有较佳的电性能和机械性能。 相似文献
7.
炭黑填充型导电塑料加工工艺与性能 总被引:3,自引:1,他引:3
本文研究了炭黑填充HDPE复合材料加工工艺条件与性能的关系。实验结果表明,采用双辊混炼时,主要应考虑炭黑在树脂中的分散问题,而采用密炼机混炼时,则要注意剪切作用切勿太强,否则会使导电性下降,尤其对高结构和超高结构的导电专用炭黑更是如此。 相似文献
8.
炭黑对复合型导电高分子材料电性能影响 总被引:1,自引:0,他引:1
阐述了炭黑填充型导电高分子复合材料的导电机理,讨论了炭黑基本物性、填充量以及分散状态对材料导电性的影响,并探讨了影响炭黑分散状态的因素。 相似文献
9.
PVC/华光特导电炭黑(HG—CB)复合材料的性能 总被引:2,自引:0,他引:2
研究了PVC填充华光特导电炭黑及其他导电填料的复合材料的工艺性能、物理性能及导电性能的变化规律。实验结果表明:填入11-12份HG-CB后,复合材料的导电性能达到了一个临界点。电阻率约降低8个数量级。表面电阻率约为10^4-10^5数量级。在温度为160-170℃和压出速率为40-60rpm时,可获得性能良好的表面光滑的抗静电压出制品。 相似文献
10.
11.
12.
M. S. J. Simmonds W. M. Blaney F. Delle Monache M. Marquina Mac-Quhae G. B. Marini Bettolo 《Journal of chemical ecology》1985,11(12):1593-1599
Vismiones and ferruginins, representatives of a new class of lypophilic anthranoids from the genusVismia were found to inhibit feeding in larvae of species ofSpodoptera, Heliothis, and inLocusta migratoria. 相似文献
13.
14.
Cheng-Le Zhao Shane Porzio Alan Smith Haiyan Ge H. T. Davis L. E. Scriven 《Journal of Coatings Technology and Research》2006,3(2):109-115
Despite its industrial importance, the subject of freeze-thaw (F/T) stability of latex coatings has not been studied extensively.
There is also a lack of fundamental understanding about the process and the mechanisms through which a coating becomes destabilized.
High pressure (2100 bar) freezing fixes the state of water-suspended particles of polymer binder and inorganic pigments without
the growth of ice crystals during freezing that produce artifacts in direct imaging scanning electron microscopy (SEM) of
fracture surfaces of frozen coatings. We show that by incorporating copolymerizable functional monomers, it is possible to
achieve F/T stability in polymer latexes and in low-VOC paints, as judged by the microstructures revealed by the cryogenic
SEM technique. Particle coalescence as well as pigment segregation in F/T unstable systems are visualized. In order to achieve
F/T stability in paints, latex particles must not flocculate and should provide protection to inorganic pigment and extender
particles. Because of the unique capabilities of the cryogenic SEM, we are able to separate the effects of freezing and thawing,
and study the influence of the rate of freezing and thawing on F/T stability. Destabilization can be caused by either freezing
or thawing. A slow freezing process is more detrimental to F/T stability than a fast freezing process; the latter actually
preserves suspension stability during freezing.
Presented at the 82nd Annual Meeting of the Federation of Societies for Coatings Technology, October 27–29, 2004 in Chicago,
IL. Tied for first place in The John A. Gordon Best Paper Competition. 相似文献
15.
Ethanol and (−)-α-Pinene: Attractant Kairomones for Bark and Ambrosia Beetles in the Southeastern US
In 2002–2004, we examined the flight responses of 49 species of native and exotic bark and ambrosia beetles (Coleoptera: Scolytidae
and Platypodidae) to traps baited with ethanol and/or (−)-α-pinene in the southeastern US. Eight field trials were conducted
in mature pine stands in Alabama, Florida, Georgia, North Carolina, and South Carolina. Funnel traps baited with ethanol lures
(release rate, about 0.6 g/day at 25–28°C) were attractive to ten species of ambrosia beetles (Ambrosiodmus tachygraphus, Anisandrus sayi, Dryoxylon onoharaensum, Monarthrum mali, Xyleborinus saxesenii, Xyleborus affinis, Xyleborus ferrugineus, Xylosandrus compactus, Xylosandrus crassiusculus, and Xylosandrus germanus) and two species of bark beetles (Cryptocarenus heveae and Hypothenemus sp.). Traps baited with (−)-α-pinene lures (release rate, 2–6 g/day at 25–28°C) were attractive to five bark beetle species
(Dendroctonus terebrans, Hylastes porculus, Hylastes salebrosus, Hylastes tenuis, and Ips grandicollis) and one platypodid ambrosia beetle species (Myoplatypus flavicornis). Ethanol enhanced responses of some species (Xyleborus pubescens, H. porculus, H. salebrosus, H. tenuis, and Pityophthorus cariniceps) to traps baited with (−)-α-pinene in some locations. (−)-α-Pinene interrupted the response of some ambrosia beetle species
to traps baited with ethanol, but only the response of D. onoharaensum was interrupted consistently at most locations. Of 23 species of ambrosia beetles captured in our field trials, nine were
exotic and accounted for 70–97% of total catches of ambrosia beetles. Our results provide support for the continued use of
separate traps baited with ethanol alone and ethanol with (−)-α-pinene to detect and monitor common bark and ambrosia beetles
from the southeastern region of the US. 相似文献
16.
17.
18.
Halyomorpha halys (Stål) (Pentatomidae), called the brown marmorated stink bug (BMSB), is a newly invasive species in the eastern USA that is rapidly spreading from the original point of establishment in Allentown, PA. In its native range, the BMSB is reportedly attracted to methyl (E,E,Z)-2,4,6-decatrienoate, the male-produced pheromone of another pentatomid common in eastern Asia, Plautia stali Scott. In North America, Thyanta spp. are the only pentatomids known to produce methyl 2,4,6-decatrienoate [the (E,Z,Z)-isomer] as part of their pheromones. Methyl 2,4,6-decatrienoates were field-tested in Maryland to monitor the spread of the BMSB and to explore the possibility that Thyanta spp. are an alternate host for parasitic tachinid flies that use stink bug pheromones as host-finding kairomones. Here we report the first captures of adult and nymph BMSBs in traps baited with methyl (E,E,Z)-2,4,6-decatrienoate in central Maryland and present data verifying that the tachinid, Euclytia flava (Townsend), exploits methyl (E,Z,Z)-2,4,6-decatrienoate as a kairomone. We also report the unexpected finding that various isomers of methyl 2,4,6-decatrienoate attract Acrosternum hilare (Say), although this bug apparently does not produce methyl decatrienoates. Other stink bugs and tachinids native to North America were also attracted to methyl 2,4,6-decatrienoates. These data indicate there are Heteroptera in North America in addition to Thyanta spp. that probably use methyl 2,4,6-decatrienoates as pheromones. The evidence that some pentatomids exploit the pheromones of other true bugs as kairomones to find food or to congregate as a passive defense against tachinid parasitism is discussed. 相似文献
19.
中蓝晨光化工研究院有限公司《塑料工业》编辑部 《塑料工业》2009,37(3)
收集了2007年7月~2008年6月世界塑料工业的相关资料,介绍了2007~2008年国外塑料工业的发展情况,提供了世界塑料产量、消费量及全球各类树脂的需求量及产能情况.按通用热塑性树脂(聚乙烯、聚丙烯、聚苯乙烯、聚氯乙烯、ABS树脂)、工程塑料(尼龙、聚碳酸酯、聚甲醛、热塑性聚酯、聚苯醚)、特种工程塑料(聚苯·硫醚、液晶聚合物、聚醚醚酮)、通用热固性树脂(酚醛、聚氨酯、不饱和聚酯树脂、环氧树脂)不同品种的顺序,对树脂的产量、消费量、供需状况及合成工艺、产品应用开发、树脂品种的延伸及应用的进一步扩展等技术作了详细介绍. 相似文献
20.
中蓝晨光化工研究院《塑料工业》编辑部 《塑料工业》2007,35(3):1-25,67
收集了2005年7月~2006年6月国外塑料工业的相关资料,介绍了2005—2006年国外塑料工业的发展情况。提供了世界塑料产量、消费量及全球各类树脂生产量以及各国塑料制品的进出口情况。作为对比,介绍了中国塑料的生产情况。按通用热塑性树脂(聚乙烯、聚丙烯、聚苯乙烯、聚氯乙烯、ABS树脂)、工程塑料(聚酰胺、聚碳酸酯、聚甲醛、热塑性聚酯、聚苯醚)、通用热固性树脂(酚醛、聚氨酯、不饱和树脂、环氧树脂)、特种工程塑料(聚苯硫醚、液晶聚合物、聚醚醚酮)的品种顺序,对树脂的产量、消费量、供需状况及合成工艺、产品开发、树脂品种的延伸及应用的扩展作了详细的介绍。 相似文献