挤压态ZK60镁合金棒材的热变形行为

采用MMS-200热力模拟试验机对挤压态ZK60镁合金棒材进行热压缩实验,为ZK60镁合金热压缩变形时合理选择参数范围提供理论指导。分析应变速率、变形温度和流变应力之间的关系;构建ZK60镁合金流变应力本构方程;采用金相显微镜观察微观组织演化规律。结果表明:峰值应力随着应变速率的提高和变形温度的降低而增大,且真应力-真应变曲线中表现出动态再结晶的特征;在给定参数下,通过本构方程计算得到ZK60镁合金的变形激活能Q为128.91kJ/mol,应力指数n为4.8519;降低变形温度、提高应变速率有助于减小再结晶晶粒的平均尺寸。     

镁合金电镀镍涂层的耐蚀性能

以化学镀镍作为保护层,对AZ91D镁合金进行直流电镀镍涂层以提高其耐腐蚀性能,并对镁合金表面两个不同厚度的镀镍涂层进行了比较.采用SEM对涂层的表面形态进行了研究.在X射线下纹理明显.镍涂层硬度约560VHN,远远高于AZ91D镁合金基底的硬度(约100VHN).电化学测量结果表明,在已经研究的镁合金涂层中,镍镀层有最低的腐蚀电流密度和最高的腐蚀电位.加速腐蚀实验中AZ91D镁合金镀镍具有很高的耐腐蚀性能.     

半固态AZ91D流变铸轧正交试验研究

在半固态AZ91D镁合金铸轧工艺试验研究中,选取机械搅拌速度、机械搅拌时间、熔体静置时间和浇铸温度作为试验因子,用正交试验法进行半固态AZ91D镁合金流变铸轧试验;用极差分析法分析了试验结果.结果表明:对半固态AZ91D镁合金组织结构的影响主次顺序为:搅拌速度、静置时间、浇注     

温度和应变速率对ZK60镁合金压缩变形行为的影响

在应变量为0.6（ε=0.6）、不同温度（523~723 K）和应变速率（0.001~10 s-1）条件下,利用Gleeble-1500D热模拟试验机,对铸态ZK60镁合金进行热压缩变形行为的研究,分析变形温度和应变速率对ZK60镁合金压缩变形行为的影响规律,即在相同应变速率条件下,随着变形温度的升高,合金的峰值应力降低。在相同温度条件下,随着应变速率的增大,合金的流变应力增大。计算其应变速率敏感指数m值为0.14和表观激活能Q值为226~254 kJ/mol。研究表明,在温度为573~673 K、应变速率为0.001~0.1 s-1时,合金发生动态再结晶。     

粗镁直接熔炼AZ91D的力学性能及断口分析

为了研究粗镁直接熔炼AZ91D镁合金锭不同位置上的夹杂分布情况,对AZ91D镁合金锭的三个不同取样位置进行了拉伸及冲击试验,通过扫描电子显微镜对拉伸和冲击断口进行了组织形貌上的观察与分析.结果表明:合金锭中间部分的力学性能要明显优于两侧部分,夹杂含量相对于两侧要低; 粗镁直接熔炼的AZ91D镁合金拉伸与冲击断口形貌呈河流状,为脆性断裂.粗镁直接熔炼的合金产生的夹杂物中的主要元素为C、O、Si,并含有少量Fe、K、Ca、S、Cl、Cr等元素; 在夹杂物周围容易出现二次裂纹,夹杂物的数量和种类直接影响着合金的力学性能.     

挤压比对AZ91镁合金组织及力学性能的影响

研究了挤压比对热挤压AZ91镁合金显微组织和拉伸性能的影响.结果表明：热挤压可以显著细化AZ91镁合金的晶粒，而且随着挤压比的增加，晶粒变得更加细小；增大挤压比也可以提高AZ91镁合金在不同实验温度下的抗拉强度和屈服强度，且经过3种挤压比挤压的AZ91镁合金在150 ℃时均呈现最高的抗拉强度和屈服强度；此外，经不同挤压比挤压的AZ91镁合金的伸长率均随实验温度的升高而增加.通过拉伸断口形貌的扫描电镜分析，确定了热挤压AZ91镁合金在室温拉伸时均表现为解理断裂为主的脆性断裂，而在较高温度下拉伸时则基本呈现韧性断裂特征.     

AZ91D镁合金半固态静态剪切流变特征的研究

为了研究镁合金在半固态下的流变特征，依据铸造合金的流变学原理，利用自制的模具，在电子万能试验机上对AZ91D镁合金半固态坯料进行了半固态静态剪切流变试验，分析了保温时间、原始组织等参数对流变特征的影响，建立了AZ91D镁合金半固态流变特征的H1-（N1／H2）-（N2／S）五元件机械模型．结果表明，在加载条件不变的情况下，变形速率随加载时间和保温时间的延长而增大；半固态状态下存在一个发生变形的临界剪切应力；临界剪切应力和最大剪切应力随保温时间的延长而减小．     

挤压态ZK60镁合金的高温力学性能及其超塑性

针对挤压态ZK60镁合金的高温力学性能及其超塑性行为进行了研究.结果表明,挤压态ZK60镁合金的高温力学性能与试验温度、应变速率密切相关.通常,屈服强度和抗拉强度随试验温度的降低和应变速率的增加而提高,而延伸率则随试验温度的升高和应变速率的降低而增大.塑性变形流变应力与温度的倒数之间呈线性关系,而且在应变速率为5×10-4/s下的激活能为93 4kJ/mol.     

热挤压镁合金AZ91的微观组织及其力学行为

研究了热挤压镁合金AZ91的微观组织以及在不同试验温度和不同的热处理条件下的拉伸力学性能.结果表明：热挤压可以显著减小AZ91合金的晶粒尺寸，其拉伸力学性能与试验温度密切相关；可以通过热处理来改善其拉伸力学性能，其中人工时效及固溶时效工艺均是改善和提高挤压后AZ91镁合金力学性能的有效途径.此外，利用扫描电镜分析了AZ91镁合金拉伸试样的断口形貌，并探讨了其拉伸断裂机制.     

AZ81E镁合金的高温流变应力模型及热加工图研究

在应变速率为0．003—3．0s^-1、温度为340～430℃的变形条件下,采用Gleeble-1500热模拟机对AZ81E镁合金进行高温热压缩变形特性研究。结果表明：流变应力随变形温度的升高和应变速率的降低而减小,峰值应力随温度的降低和应变速率的升高向应变较大处转移,进入稳态阶段的临界应变明显增大。结合Arrhenius方程并引入Zener-Hollomon参数,构建AZ81E镁合金的高温流变应力模型,其平均变形激活能为166．15kJ／mol。根据材料动态模型,计算并分析AZ81E镁合金的热加工图。利用热加工图确定热变形的流变失稳区,获得试验参数范围内的热变形过程最佳工艺参数：热加工温度范围为380～420℃,应变速率范围为0．01～0．03S^-1.     

Y和Ce对AZ91D镁合金显微组织和力学性能的影响

为了开发低成本、高强度、耐高温的新型镁合金,研究了微量Y、Ce对AZ91D镁合金显微组织和力学性能的影响。研究结果表明:Y和Ce复合加入AZ91D镁合金,能明显细化组织晶粒,从而改善合金在室温和高温下的力学性能。当加入0.6%Ce-0.3%Y(质量分数)时,合金晶粒细化效果较好,其室温和高温力学性能比较理想。     

Mechanical properties and microstructure of as-cast and extruded Mg-（Ce, Nd）-Zn-Zr alloys

1INTRODUCTION Thebeneficialinfluenceofrareearth(RE)metalsontheambientandelevatedtemperature mechanicalpropertiesofmagnesiumalloyhaslongbeenrecognized[13].Recently,Yttriumisaddedto Magnesiumalloytoimproveitstensilestrength andcreepresistance,andsuchinvestigationsatheat resistantmagnesiumalloyhaveledtothede velopmentofWE43andWE54alloys[4,5].Al thoughsuchalloysexhibitgoodpropertiesupto573Kthroughcastingandextruding,therelativelyhighcostofYttriumrestrictstheapplicationof suchalloys.Otherr…     

Effects of rare earth elements on the microstructure and properties of magnesium alloy AZ91D

The effects of rare earth elements on the microstructure and properties of Magnesium alloy AZ91D alloy were studied.The different proportion of rare earth elements was added to the AZ91D and the tensile tests were carried out at different temperatures.The experimental results show that at room temperature or at 120℃ the AZ91D‘s decrease with the increasing amount of the rare earth elements.however,the ductility is improved.The influence of 0.14%Sb(mass fraction)on the AZ91D‘s strength is like that of rare earth elements(0.2%-0.4%)(mass fraction).Microstructure graphs demonstrate that appropriate amount of rare earth elements (0.1%-0.2%) can fine AZ91D‘s grain and improve its ductility.     

As-cast microstructure,mechanical properties and casting fluidity of ZA84 magnesium alloy containing TiC

The as-cast microstructure, mechanical properties and casting fluidity of ZA84 alloy containing TiC were investigated. The experimental results indicate that adding 0.5wt%TiC to ZA84 alloy can refine the as-cast microstructure, and do not cause the formation of any new phase. After 0.5wt%TiC was added to the ZA84 alloy, the morphology of ternary phases on the grain boundaries changed from coarse quasi-continuous net to fine disconnected net, and the distribution of ternary phases became dispersive and homogeneous. At the same time, the tensile properties of ZA84＋0.5TiC alloy at room temperature were comparable to those of AZ91D alloy, and were higher than those of ZA84 alloy. At 150 ℃, the tensile and creep properties of ZA84＋0.5TiC alloy were also higher than those of ZA84 and AZ91D alloys. In addition, compared with the AZ91D alloy, the casting fluidity of ZA84＋0.5TiC alloy was slightly poor, but better than that of ZA84 alloy. The reason could be related to the effect of TiC on the solidification temperature range of ZA84 alloy.     

钙和碳变质对AZ91D显微组织与性能的影响

镁合金的晶粒细化对于材质的金相组织和力学性能起着决定性作用．本课题通过在AZ91D中加入Ca和C2Cl6晶粒细化剂,分别研究了Ca,C对AZ91D组织以及力学性能的影响．利用熔剂保护法,制备了AZ91D标准拉伸试样,经过T4,T6处理后,采用金相显微镜（Olympus）、扫面电镜（SEM）和能谱分析仪（EDAX）对制备的试样进行了显微组织、断口形貌及成分进行了观察与分析,并测试了抗拉强度和布氏硬度．试验结果表明：经过显微组织和断口形貌观察,加入细化剂后形成Al4C3,有效的抑制了晶粒的长大,使晶粒得到细化,当Ca和C2Cl6复合应用时,使得AZ91D的晶粒细化更加明显,力学性能得到提高,抗拉强度最高达到216N／mm^2,布氏硬度值达到60HB．     

Plastic deformation behavior of ZK60 magnesium alloy with addition of neodymium

The hot deformation simulation of a ZK60 magnesiuln alloy at different temperatures from 373 to 673 K and different strain rates of 0.1, 0.01 and 0.002 s^-1 was studied by using the Gleebe-1500 simulator. The plastic deformation behavior was measured and the deformation activation energy was calculated. The microstructures of ZK60 magnesium alloy with an addition of neodymium during the deformation process were observed by using Polyvar-MET optical microscope and Tecnai G^2 20 TEM. The results show that the working hardening, the dynamic recovery and the dynamic recrystallization occur during the plastic deformation process at different temperatures and strain rates. The dynamic recrystallization starts when the temperature is over 473 K and the DRX grain size after hot deformation is only 5-10 μm. So the refined grains improve both the tensile strength and the elongation of alloys at room temperature. Neodymium is added into the alloy and a precipitate phase Mg12Nd that impedes the movement of dislocations is formed, which benefits to increasing mechanical properties of ZK60 magnesium alloy.     

压铸镁合金材料内耗值的测量与减振机理

采用自行研制的材料内耗检测仪，对AZ91D压铸镁合金材料的内耗值进行测试，并和同体积的钢、铝材料的内耗值对比。结果表明，镁合金比钢、铝等材料具有较高的内耗值，镁合金减振机理为位错钉扎材料晶界，Mg17Al12相及其它杂质、空洞是产生内耗的主要原因。     

不锈钢丝增强AZ91镁合金复合材料的显微组织及其力学性能

采用渗流铸造法制备了体积分数约为40%、60%、80%的不锈钢丝增强AZ91镁合金复合材料.利用万能试验机对其进行压缩实验;并利用扫描电镜观察复合材料的显微组织以及压缩后的断口形貌.结果表明:不锈钢丝在AZ91镁合金基体中的分布随着其体积分数的增加逐步均匀;不锈钢丝与AZ91镁合金界面润湿性较好.压缩试验表明:复合材料的抗压强度较AZ91镁合金抗压强度明显提高,40%、60%、80%体积分数的复合材料断裂强度分别为371、387、553 MPa;随着不锈钢丝体积分数的增加,材料的破坏方式由剪切破坏转变为劈裂.     

The Role of Calcium in Microstructural Refinement of AZ91 Magnesium Alloy

The effect of calcium addition on the microstructures of AZ91 magnesium alloy was investigated. It was found that a small amount of calcium in AZ91 allay produced a large decrease in the α- Mg grain size and the dispersed fine β-Mgt7 Alt2 phases. In addition, some Al4Ca particles were found to exist in the AZ91 alloy containing 0.5wt% Ca. EDS analysis and water-quenched technique revealed that the grain-refining mechanism of calcium for the AZ91 alloys was mainly attributed to the role of restricting growth of calcium in the primary α-Mg crystals.