Analysis of MOX fuel behavior in reduced-moderation water reactor by fuel performance code FEMAXI-RM

To assess the feasibility of the 31% Pu-MOX fuel rod design of reduced-moderation water reactor (RMWR) in terms of thermal and mechanical behaviors, a single rod assumed to be irradiated in the core of RMWR up to 106 GWd/tHM has been analyzed by a fuel performance code FEMAXI-RM which is an extended version of FEMAXI-6 code. In the analysis, design specifications of fuel rod and irradiation conditions have been input, and available models of both MOX fuel and UO₂ fuel have been used as appropriate. The results are: fission gas release is several tens of percent, rod internal pressure does not exceed the coolant pressure, and the highest fuel center temperature is 2400 K, while cladding diameter increase caused by pellet swelling is within 1% strain. These predictions suggest that the MOX fuel rod integrity will be held during irradiation in RMWR, though actual behavior of MOX pellet swelling and cladding oxidation require to be investigated in detail.     

Thermal conductivity evaluation of high burnup mixed-oxide (MOX) fuel pellet

The thermal conductivity formula of fuel pellet which contains the effects of burnup and plutonium (Pu) addition was proposed based on the Klemens’ theory and reported thermal conductivities of unirradiated (U, Pu) O₂ and irradiated UO₂ pellets. The thermal conductivity of high burnup MOX pellet was formulated by applying a summation rule between phonon scattering parameters which show the effects of plutonium addition and burnup. Temperature of high burnup MOX fuel was evaluated based on the thermal conductivity integral which was calculated from the above-mentioned thermal conductivity formula. Calculated fuel temperatures were plotted against the linear heat rates of the fuel rods, and were compared with the fuel temperatures measured in a test reactor. Since both values agreed well, it was confirmed that the proposed thermal conductivity formula of MOX pellets is adequate.     

Transport of MOX fuel: continuous challenge

Abstract

For 45 years TN International has been involved in the radioactive materials transportation field. Since the beginning the spent nuclear fuel transportation has been its core business. During all these years TN International, now part of AREVA, has been able to anticipate and fulfil the needs for new transport or storage casks design to fit the nuclear industry evolutions. A whole fleet of casks able to transport all the materials of the nuclear fuel cycle has been developed. This paper focuses on the casks used to transport the fresh and used mix oxide (MOX) fuel. To transport the fresh MOX boiling water reactor and pressurised water reactors fuel, TN International has developed two designs of casks: the MX 6 and the MX 8. These casks are and have been used to transport MOX fuel for French, German, Swiss and in a near future Japanese nuclear power plants. A complete set of baskets have been developed to optimise the loading in terms of integrated dose and also of course capacity. Mixed oxide used fuel has now its dedicated cask: the TN 112 which certificate of approval has been obtained in July 2008. This cask is able to transport 12 MOX spent fuel elements with a short cooling time. The first loading of the cask has been performed in September 2008 in the Electricité de France nuclear power plant of Saint-Laurent-des-Eaux. By its continuous involvement in the nuclear transportation field, TN International has been able to face the many challenges linked to the radioactive materials transportation especially talking of MOX fuel. TN International will also have to face the increasing demand linked to the nuclear renaissance.     

Irradiation performance of fast reactor MOX fuel pins with ferritic/martensitic cladding irradiated to high burnups

The ACO-3 irradiation test, which attained extremely high burnups of about 232 GWd/t and resisted a high neutron fluence (E > 0.1 MeV) of about 39 × 10²⁶ n/m² as one of the lead tests of the Core Demonstration Experiment in the Fast Flux Test Facility, demonstrated that the fuel pin cladding made of ferritic/martensitic HT-9 alloy had superior void swelling resistance. The measured diameter profiles of the irradiated ACO-3 fuel pins showed axially extensive incremental strain in the MOX fuel column region and localized incremental strain near the interfaces between the MOX fuel and upper blanket columns. These incremental strains were as low as 1.5% despite the extremely high level of the fast neutron fluence. Evaluation of the pin diametral strain indicated that the incremental strain in the MOX fuel column region was substantially due to cladding void swelling and irradiation creep caused by internal fission gas pressure, while the localized strain near the MOX fuel/upper blanket interface was likely the result of the pellet/cladding mechanical interaction (PCMI) caused by cesium/fuel reactions. The evaluation also suggested that the PCMI was effectively mitigated by a large gap size between the cladding and blanket column.     

A nondestructive method for discriminating MOX fuel from LEU fuel for safeguards purposes

Plutonium-rich mixed oxide fuel (MOX) is increasingly used in thermal reactors. However, spent MOX fuel could be a potential source of nuclear weapons material and a safeguards issue is therefore to determine whether a spent nuclear fuel assembly is of MOX type or of LEU (Low Enriched Uranium) type.     

Specific low temperature release of Xe from irradiated MOX fuel

A particular low temperature behaviour of the ¹³¹Xe isotope was observed during release studies of fission gases from MOX fuel samples irradiated at 44.5 GWd/tHM. A reproducible release peak, representing 2.7% of the total release of the only ¹³¹Xe, was observed at ∼1000 K, the rest of the release curve being essentially identical for all the other xenon isotopes. The integral isotopic composition of the different xenon isotopes is in very good agreement with the inventory calculated using ORIGEN-2. The presence of this particular release is explained by the relation between the thermal diffusion and decay properties of the various iodine radioisotopes decaying all into xenon.     

Burn-up characteristics of ADS system utilizing the fuel composition from MOX PWRs spent fuel

Burn-up characteristics of accelerator-driven system, ADS has been evaluated utilizing the fuel composition from MOX PWRs spent fuel. The system consists of a high intensity proton beam accelerator, spallation target, and sub-critical reactor core. The liquid lead–bismuth, Pb–Bi, as spallation target, was put in the center of the core region. The general approach was conducted throughout the nitride fuel that allows the utilities to choose the strategy for destroying or minimizing the most dangerous high level wastes in a fast neutron spectrum. The fuel introduced surrounding the target region was the same with the composition of MOX from 33 GWd/t PWRs spent-fuel with 5 year cooling and has been compared with the fuel composition from 45 and 60 GWd/t PWRs spent-fuel with the same cooling time. The basic characteristics of the system such as burn-up reactivity swing, power density, neutron fluxes distribution, and nuclides densities were obtained from the results of the neutronics and burn-up analyses using ATRAS computer code of the Japan Atomic Energy research Institute, JAERI.     

Effect of Pu-rich agglomerates in MOX fuel on reactivity analysis of light water reactor MOX core physics experiments

The effect of Pu-rich agglomerates in U-Pu mixed oxide (MOX) on the reactivity analysis of light water reactor MOX core physics experiments was studied with the continuous-energy Monte Carlo calculation code MVP II. First, the following three different models were compared in the analysis of a representative unit cell of a MOX core tested at the KRITZ reactor: a Lattice model where Pu-rich agglomerates were assumed to exist in a fixed pitch, a statistical geometry (STG) model of MVP II, and a Random model where the random distribution of Pu-rich agglomerates was directly modeled. Since the three models gave comparable results, the STG model was used in parametric calculations to systematically understand the reactivity effect depending on the characteristics of Pu-rich agglomerates. In addition, the selected unit cells composing the MOX cores and one representing MOX core tested at the EOLE criticality facility were analyzed with the measured characteristics of Pu-rich agglomerates in MOX fuel. Consequently, the reactivity differences between the calculations assuming the homogeneous Pu distributions and those considering Pu-rich agglomerates were less than 0.0005 Δk/k/k', indicating that the effect of Pu-rich agglomerates was small on the reactivity analysis of the MOX cores tested in the EOLE facility.     

我国压水堆装载MOX燃料对核燃料循环情景影响初步分析

为了满足持续增长的国家能源需求,核电将有更大规模的发展。本文对我国未来的核电发展和核燃料循环进行了情景研究,预测了2050年前核电对天然铀资源和燃料制造能力的需求情况,核电站产生的乏燃料量,分离钚产生量。乏燃料后处理能力作为我国核燃料循环体系的重要组成部分,将对我国核燃料循环情景产生重要影响。本文对后处理规模和分离钚的利用进行了假设,研究了两种情景模式下后处理和分离钚利用对我国铀资源需求和核废物产生的影响。     

MOX燃料在轻水堆核电站中的应用

目前MOX燃料已成为一种可用于轻水堆核电站成熟的核燃料。简要介绍了国外该领域的发展状况以及MOX燃料对反应堆性能的主要影响和应对措施。探讨了MOX燃料在国内压水堆核电站中的应用问题。     

Void coefficient analysis of an LWR lattice experiment with high-enrichment MOX fuel

A series of physics experiments performed between 1985 and 1990 in the PROTEUS reactor at the Paul Scherrer Institute in Switzerland included the investigation of a Pu-fuelled light water reactor (LWR) lattice with a moderator-to-fuel volume ratio of 2.07 and an effective enrichment of about 8%. The analysis of the measurements in this test lattice and in the tighter light water high conversion reactor (LWHCR) lattices investigated previously permits the determination of the k_∞ void coefficient of the LWR lattice for cases of partial and total voiding. A comparison of the measured changes of k_∞ with values calculated using the cell codes WIMS and KAPER4 shows a satisfactory prediction of the partial void coefficient in the range from 0–54% voidage. Discrepancies increase up to twice the estimated experimental error in cases of further voiding to 100% void. The total void coefficient (0–100% void) results from large compensating effects from individual reaction rate ratios. Its accurate prediction by cell calculations appears to be fortuitous. Improved nuclear data and refined calculational methods are thus required for a more accurate calculation of the void coefficient in high-enrichment MOX-LWRs.     

Wavelet-based angular dependence analysis of the heterogeneous calculation on MOX fuel lattice

A wavelet-based transport method is developed to satisfy the high order angular approximation, which has been proved to be necessary in the heterogeneous calculation of MOX fuel lattice. Based on the new angular discretization scheme, the angular dependence of flux is analysed to find out the origin of complicated angular anisotropy and its effects on the heterogeneous calculation. Both of the geometric and neutronic effects are investigated quantitatively to find out the angular dependence in heterogeneous calculations. Comparisons between the traditional S_N angular discretization scheme and wavelet-based scheme are analysed to indicate the challenges brought from the MOX fuel lattice heterogeneous calculation. An effective solution is given by using wavelets in the angular discretization of neutron transport equation. Improvements of high order angular approximation are suggested.     

On the influence of spatial discretization in LWR-burnup calculations with HELIOS 1.9 – Part II: Mixed oxide (MOX) fuel

Cell and burnup calculations are the basis for all deterministic static and transient 3D full core calculations for different operational states of the reactor. The arising differences in the integral transport solution (neutron flux and k_inf) for different discretization strategies during the burnup of mixed oxide (MOX) fuel due to different spatial discretization are demonstrated. The influence of different discretization strategies on the calculation of homogenized few group cross-sections is investigated. The influence of the discretization strategies on the calculation time is evaluated.     

Evaluation of high plutonia (44% PuO2) MOX as a fuel for fast breeder test reactor

Uranium plutonium mixed oxide (MOX) containing up to 30% plutonia is the conventional fuel for liquid metal cooled fast breeder reactor (LMFBR). Use of high plutonia (>30%) MOX fuel in LMFBR had been of interest but not pursued. Of late, it has regained importance for faster disposition of plutonium and also for making compact fast reactors. Some of the issues of high plutonia MOX fuels which are of concern are its chemical compatibility with liquid sodium coolant, dimensional stability and low thermal conductivity. Available literature information for MOX fuel is limited to a plutonium content of 30%. Thermodynamic assessment of mixed oxide fuels indicate that with increasing plutonia oxygen potential of the fuel increases and the fuel become more prone to chemical attack by liquid sodium coolant in case of a clad breach. In the present investigation, some of these issues of MOX fuel have been studied to evaluate this fuel for its use in fast reactor. Extensive work on the out-of-pile thermo-physical properties and fuel-coolant chemical compatibility under different simulated reactor conditions has been carried out. Results of these studies were compared with the available literature information on low plutonia MOX fuel and critically analyzed to predict in reactor behaviour of this fuel containing 44% PuO₂. The results of these out-of-pile studies have been very encouraging and helped in arriving at a suitable and achievable fuel specification for utilization of this fuel in fast breeder test reactor (FBTR). As a first step of test pin irradiation programme in FBTR, eight subassemblies of the MOX fuel are undergoing irradiation in FBTR.     

Use of Thorium-Plutonium MOX in the inner pins of CANDU fuel bundles

This research is focused on using Thorium-Plutonium MOX fuel in the inner fuel pins of the CANDU fuel bundles for plutonium incineration and reduction of uranium demand and to reduce coolant void reactivity. The delayed neutron fraction and the power distribution amongst the fuel elements of the fuel bundle have been considered as main safety parameters.The 700 MWe Advanced CANDU Reactor (ACR-700) was selected as a case study. The inner eight UO₂ fuel pins of the ACR-700 fuel bundle are replaced by Thorium-Plutonium MOX fuel pins in the proposed design with 3% reactor grade PuO₂. This amount represents 23.4 w/o of the fuel in the bundle. The outer two fuel rings (35 pins) enrichment is reduced from 2.1 w/o U-235 to 2 w/o U-235. The simulation using MCNP6 showed that about 27% reduction of uranium demand can be achieved. The proposed fuel bundle eliminate the use of burnable poisons in the central pin that was used for negative coolant void reactivity and more reduction in the coolant void reactivity was achieved (about 3.5 mk less than the reference fuel bundle). The power distribution throughout the fuel bundle is more flat in the proposed fuel bundle. Use of this fuel bundle reduces the delayed neutron fraction from 540 pcm in the reference case to 480 pcm in the proposed case.     

Benchmark on deterministic 2-D MOX fuel assembly transport calculationswithout spatial homogenization

An important issue of deterministic transport methods for whole core calculations concerns the accuracy of homogenization techniques. A direct calculation for whole core heterogeneous geometries was not feasible in the past due to the limited capability of computers. With modern computational abilities, direct whole core heterogeneous calculations are becoming feasible. This paper explores a recent OECD/NEA benchmark problem proposed to test the accuracy of modern deterministic transport methods when applied to reactor core problems without spatial homogenization.

For this work a two-dimensional configuration was investigated and an accurate Monte Carlo reference solution was obtained. Twenty participants submitted solutions for the two-dimensional configuration and all of the participant solutions were compared to a reference Monte Carlo solution. Overall all the results submitted by the participants agreed well with the reference solution. A majority of the participants obtained solutions that were more than acceptable for typical reactor calculations and the remaining errors in the participant solutions can be attributed to the high order space-angle approximation necessary to solve this particular benchmark problem. It is important to note that the high order space-angle approximation needed for this benchmark is not necessary typical for all such whole-core heterogeneous problems.     

Restructure behavior analysis in fast breeder reactor MOX fuel by X-ray CT

Both high- and low-density MOX fuel pellets of uranium and plutonium oxides were irradiated in the experimental fast reactor JOYO. After irradiation, these fuel pellets were examined by X-ray CT and their irradiation behavior was evaluated for formation of the central void. In particular, the central void size and temperature of fuel pellets at the beginning and end of irradiation were analyzed. The central voids in the low-density fuel pellets were bigger than those of the high-density fuel pellets at the same linear heating rate (LHR), and the threshold LHR and temperature at which the central voids were formed were lower than those of the high-density fuel pellets. It was understood from these results that the irradiation behaviors of high- and low-density fuel pellets were different.     

Upgrading of X-ray CT technology for analyses of irradiated FBR MOX fuel

The X-ray CT technology previously developed by JAEA was upgraded. The shape of the X-ray source beam was changed from a circular shape to an elliptical one and the collimator slit width was decreased from 0.3 to 0.1 mm. The X-ray detector was improved by changing a CdWO₄ scintillator to a highly sensitive silicon semiconductor detector. The analysis code of X-ray CT image was revised with respect to the number of points by using two kinds of experimental results and taking into account the effects of crack existence and deviation of the central void position from the radial center of a fuel pellet. As a result, high resolution X-ray CT images could be obtained on the transverse cross section of irradiated fuel assemblies. The error of the dimensional measurement was improved from ±0.1 to ±0.03 mm by upgrading the instrument and revising the analysis code of X-ray CT image. The discriminating accuracy of density difference could be increased, and the low density region (undisturbed region) and high density region (equi-axial and columnar regions) in the X-ray CT image on the cross section of irradiated fuel could be discriminated from each other. The reliability of fuel performance analysis improves because a large number of PIE data can be collected, compared with the conventional destructive PIE.     

Design and optimization of an equilibrium reload with MOX fuel with minor actinides

In this work the design and optimization of an equilibrium core for a boiling water reactor (BWR), loaded with fuel composed of plutonium and minor actinides (Np, Am and Cm), is presented. The plutonium and minor actinides are obtained from the recycling of the spent fuel of a BWR, and are mixed with depleted uranium obtained from the enrichment tails. The design and optimization of the equilibrium reload is achieved in two steps. In the first step, the fuel assembly is adjusted and the reload pattern is designed, in order to obtain the target cycle length. In order to improve the shutdown margin, two actions were taken: to increase the boron-10 content in the control rods, and to add a burnable absorber (gadolinia) in some fuel rods. In the second step, the reload pattern, obtained in the first step, is optimized to maximize the energy, under the thermal and reactivity margins constraints; a system based on Genetic Algorithms was used in the optimization process. Results show that 5% more energy was obtained with the optimized reload.