Generalized matrix method for calculation of internal light energy flux in mixed coherent and incoherent multilayers

A generalized matrix method to treat multilayer systems with mixed coherent and incoherent optical behavior is presented. The method is based on the calculation of the light energy flux inside the multilayer, whose internal light absorption is straightforwardly derived. The Poynting vector is used to derive the light energy flux in the case of a layer with coherent behavior. Multilayer structures with any distribution of layers with coherent or incoherent behavior can be treated, including the case of oblique incidence. Use of the light energy flux instead of the more commonly used light intensity permits the calculation of light absorption with a better accuracy and a much shorter computation time.     

A study on an online measurement method to determine the oil discharge ratio by utilizing Coriolis mass flow meter in a calorimeter

In this paper, an online measurement method of oil discharge ratio (ODR) is experimentally investigated based on a compressor calorimeter with the Coriolis mass flowmeter (CMF). In this method, the oil concentration is determined by a linear mixing law of the specific volume model using the density of the refrigerant, oil and refrigerant-oil mixture obtained by CMF. During the testing, the light absorption method is also conducted simultaneously for the comparison. The results indicate that the presented CMF based density method has an average relative deviation of 4.28%. The accuracy of the CMF based density method is superior to the light absorption method, which has the relative deviation of −8∼23% compared with the standard sampling method. The presented CMF-based method can be expected to be used for future ODR measurement due to its non-sampling, online, and accurate features.     

Real-time absorption and scattering characterization of slab-shaped turbid samples obtained by a combination of angular and spatially resolved measurements

We present a fast and accurate method for real-time determination of the absorption coefficient, the scattering coefficient, and the anisotropy factor of thin turbid samples by using simple continuous-wave noncoherent light sources. The three optical properties are extracted from recordings of angularly resolved transmittance in addition to spatially resolved diffuse reflectance and transmittance. The applied multivariate calibration and prediction techniques are based on multiple polynomial regression in combination with a Newton--Raphson algorithm. The numerical test results based on Monte Carlo simulations showed mean prediction errors of approximately 0.5% for all three optical properties within ranges typical for biological media. Preliminary experimental results are also presented yielding errors of approximately 5%. Thus the presented methods show a substantial potential for simultaneous absorption and scattering characterization of turbid media.     

3D range acquisition through differential light absorption

A 3D camera based on the differential absorption of light by a colored liquid is described. The range image is obtained from two illuminance images taken at two different wavelengths. The theoretical aspects of range-from-absorption are discussed in detail. Practical considerations for the calibration and implementation of the method are also covered. The accuracy of the 3D camera is discussed, and experimental results are presented     

Multiple path analysis of reflectance from turbid media

A novel method to calculate the reflectance of light from a turbid medium is presented. The method takes an approach similar to that of the Beer-Lambert law, where the intensity of light is attenuated by an exponential factor involving the path length and the absorption coefficient. Due to scatter, however, there are many path lengths; in the present method all possible path lengths are weighted by their probabilities and summed over. A path length probability density is derived by considering a photon random walk through the medium. The result is a simple expression for the reflectance based on the physical properties of the medium.     

Spectral model of a fluorescent ink halftone

A model is presented of a fluorescent ink halftone. Unlike a nonfluorescent ink, which only absorbs, a fluorescent ink absorbs higher-energy photons and emits lower-energy photons. The amount of fluorescent light produced depends on the percent absorption of the incident light. For fluorescent ink printed on paper, both photon scattering within the paper substrate and multiple internal reflections between the ink layer and the paper substrate significantly increase the percent absorption, so a realistic model must include these effects. The model presented here utilizes the generalized Clapper-Yule theory, which accounts for photon diffusion that is due to both scatter and internal reflection. It is shown that while multiple internal reflections alone only marginally increase the percent absorption, when there are both scattering and internal reflection, the percent absorption is increased significantly. The current study is a theoretical model and does not present experimental results.     

Diffractive optical chemical sensor based on light absorption

A new type of chemical sensor based on light absorption is proposed. An array of zones alternatively containing the pH indicator thymolphthalein is formed in a gelatin film. By changing the sample solution from acidic to alkaline, a blue stripe appears in the gelatin film. This acts as a transmission grating and diffracts the introduced laser beam. Theory predicts that this method, which is based on light absorption/beam diffraction, is as sensitive as or more sensitive than fluorometry.     

Dual beam light profile microscopy: a new technique for optical absorption depth profilometry

Light profile microscopy (LPM) is a recently developed technique of optical inspection that is used to record micrometer-scale images of thin-film cross-sections on a direct basis. In single beam mode, LPM provides image contrast based on luminescence, elastic, and/or inelastic scatter. However, LPM may also be used to depth profile the optical absorption coefficient of a thin film based on a method of dual beam irradiation presented in this work. The method uses a pair of collimated laser beams to consecutively irradiate a film from two opposing directions along the depth axis. An average profile of the beam's light intensity variation through the material is recovered for each direction and used to compute a depth-dependent differential absorbance profile. This latter quantity is shown from theory to be related to the film's depth-dependent optical absorption coefficient through a simple linear model that may be inverted by standard methods of numerical linear algebra. The inverse problem is relatively well posed, showing good immunity to data errors. This profilometry method is experimentally applied to a set of well-characterized materials with known absorption properties over a scale of tens of micrometers, and the reconstructed absorption profiles were found to be highly consistent with the reference data.     

X-Ray Efficiency and Modulation Transfer Function of Fluorescent Rare Earth Screens,Determined by the Monte Carlo Method

The overall, X-Rays to light conversion efliciency and the modulation transfer function of radiographic single front screens have been computed using the Monte Carlo method to simulate the generation and the multiple-scattering diffusion and absorption of light photons in the screen. The computation is based on a set of probability functions related to the absorption of X-Ray photons, free-path lengths and absorption of light photons and reflection conditions at the boundaries. A constant scattering angle has been used for light photons colliding with phosphor grains. For a given phosphor volume fraction, results are shown as a function of phosphor grain size, screen thickness and light wavelength. Some computed results have been checked experimentally.

A comparison is made between screens based on mainly green emitting terbium activated gadolinium oxysulphide, and conventional screens based on blue emitting lead activated calcium tungstate. Screens having equal packing volume, thickness and phosphor grain size show a much higher conversion efficiency and improvement in modulation transfer functions when made of Gd₂O₂S:Tb.     

A One-Dimensional Solution of the Photoacoustic Wave Equation and its Relationship with Optical Absorption

A study based on the general solution of the one-dimensional photoacoustic (PA) wave equation for an acoustic plane source is presented. This study relies on obtaining the impulse response of the PA system considering a heating function proportional to the Lambert–Beer law and spatially bounded by a rectangle function. The PA pressure is obtained by convoluting the impulse response with the temporal profile of the exciting pulse of light. With the obtained solution, it is possible to comprise, on a single expression, the PA pressure profile for optically thin samples (whose dimensions are smaller than the optical absorption length) and optically opaque samples (whose dimensions are larger than the optical absorption length). In the limit of weak absorption, the solution is in good agreement with the one for a uniform distribution of energy. Also, a study of the dependence of the acoustic pressure with the duration of the laser pulse is included.     

Estimation of scattering error in spectrophotometric measurements of light absorption by aquatic particles from three-dimensional radiative transfer simulations

We present an approach based on three-dimensional Monte Carlo radiative transfer simulations for estimating scattering error in measurements of light absorption by aquatic particles with a typical laboratory double-beam spectrophotometer. The scattering error is calculated by combining the weighting function describing the angular distribution of photon losses that are due to scattering on suspended particles with the volume scattering function of particles. We applied this method to absorption measurements made on marine phytoplankton, a diatom Thalassiosira pseudonana and a cyanobacterium Synechococcus. Assuming that the scattering phase function is described by the Henyey-Greenstein formula, we determined the backscatter probability of phytoplankton, which yields the best correction for scattering error at a light wavelength of 750 nm, where true absorption is null. The backscattering ratio estimated for both phytoplankton species is significantly higher than previously reported data based on Mie-scattering calculations for homogeneous spheres. Depending on the type of particles, the corrected absorption spectra obtained with our method may be similar or significantly different from spectra obtained with the null-point correction based on wavelength-independent scattering error.     

Tunable Spectrum Selectivity for Multiphoton Absorption with Enhanced Visible Light Trapping in ZnO Nanorods

Observation of visible light trapping in zinc oxide (ZnO) nanorods (NRs) correlated to the optical and photoelectrochemical properties is reported. In this study, ZnO NR diameter and c‐axis length respond primarily at two different regions, UV and visible light, respectively. ZnO NR diameter exhibits UV absorption where large ZnO NR diameter area increases light absorption ability leading to high efficient electron–hole pair separation. On the other hand, ZnO NR c‐axis length has a dominant effect in visible light resulting from a multiphoton absorption mechanism due to light reflection and trapping behavior in the free space between adjacent ZnO NRs. Furthermore, oxygen vacancies and defects in ZnO NRs are associated with the broad visible emission band of different energy levels also highlighting the possibility of the multiphoton absorption mechanism. It is demonstrated that the minimum average of ZnO NR c‐axis length must satisfy the linear regression model of Z _p,min = 6.31d to initiate the multiphoton absorption mechanism under visible light. This work indicates the broadening of absorption spectrum from UV to visible light region by incorporating a controllable diameter and c‐axis length on vertically aligned ZnO NRs, which is important in optimizing the design and functionality of electronic devices based on light absorption mechanism.     

Practical test of a point-source integrating cavity absorption meter: the performance of different collector assemblies

A prototype point-source integrating cavity absorption meter (PSICAM) is presented and compared with spectrophotometric absorption measurements. Different light collector assemblies of the PSICAM were tested regarding their capability to determine the absorption of water constituents accurately over a wide range of concentrations and scattering properties. The PSICAM setup with a radiance-type sensor showed the best performance. It was compared with a photometric absorption determination using nonscattering dye solutions. The mean difference between both methods was less than 2.4% in the spectral range of 400-700 nm. The absorption determination with the PSICAM, when equipped with a radiance sensor as a light collector, was only little affected by scattering and temperature. We conclude that the PSICAM can be used to determine the absorption of natural seawater samples at ambient temperatures.     

A Precision Spectrophotometric Method for Determining U,Pu, Nd,and Rh,Based on the Internal Standardization Principle

The principle of spectrophotometric determination of the concentrations of elements based on internal standardization of the sample analyzed is presented. As the function of the parameter to be determined, namely, the concentration of element in solution, we suggest the ratio of two signals, one of which is the light intensity at the wavelength of an absorption band of an element being analyzed and the other is the reference signal of a sample, namely, the light intensity at a wavelength at which the solution of the element being analyzed is virtually transparent. The analysis is performed with a specially designed two-channel spectrophotometer in which fairly strict correlation between the signals is provided by measuring their intensities virtually simultaneously, with the same detector and amplification system. The signals are isolated by a monochromator and interference light filters. The spectrophotometer operation control and data processing are effected by a PC. The metrological characteristics of the method proposed were experimentally determined. The relative root-mean-square deviation of the uranium, plutonium, neodymium, and rhodium concentrations in pure solutions of their salts was within 0.1-0.25%.     

基于正交偏振光的瓦斯浓度传感器研究

介绍了瓦斯浓度传感器系统的基本原理,提出了基于正交偏振光的差分吸收式瓦斯浓度检测模型,建立了瓦斯浓度传感器的数学模型,设计了传感器系统结构以及光路和气室结构,并对传感器进行了实验研究.传感器系统利用起偏器将两束不同波长的单色光转变为正交偏振光,然后让这两束正交偏振光同时通过检测气室,最后用渥拉斯顿棱镜将两束单色光分开,...     

Long-wavelength cutoff filters of a new type

A method for the design of cutoff filters is proposed that is based on the use of light at nonnormal angles of incidence and on the use of coating materials with a large dispersion of the optical constants. The optical constants are presented of several films made from indium tin oxide-a material that satisfies this requirement. The filtering is due to absorption, critical angle effects, or both. The theory of this type of filter is described, and the calculated performance of two long-wavelength cutoff filters based on the use of indium tin oxide films is given. The angular performance and the producibility of one of these filters are examined. Some applications for these filters are considered, and the feasibility of producing similar filters for other spectral regions is discussed.     

Determination of methotrimeprazine in pharmaceutical preparations by visible spectrophotometry

A spectrophotometric method is described for determination of methotrimeprazine (levomepromazine). The aim of this work was to develop a simple, rapid, precise, and accurate visible spectrophotometric method for determination of methotrimeprazine in tablet, oral solution, and injection. The method is based on methotrimeprazine reaction with bromophenol blue, resulting in a stable, light yellow-green ion-pair complex that, after extraction with chloroform, presented maximum absorption at 409 nm. Beer's law was obeyed in the concentration range from 5.0 to 25.0 μg/ml. The proposed standardized method was applied to commercially available and simulated samples. The accuracy of the method was confirmed by recovery tests.     

Development of an algorithm for the calculation of the scattering properties of agglomerates

A new, improved, and more efficient algorithm for calculation of the scattering, extinction, and absorption characteristics of agglomerates consisting of Rayleigh-size primary particles is presented. The computer code is based on a new formulation of the light scattering for such agglomerates and is more than 10 times faster than the codes based on previous formulations. The computational times required by the old and the new algorithms, run on VAX 7000, IBM 3090, and UNIX RS6000 mainframe computers, are compared for different agglomerate configurations, such as straight chains, clusters, and randomly branched chains. A distributed-parallel-computing scheme was used to run the new algorithm on four UNIX RS6000 processors concurrently, resulting in computational times 47 times faster than required for the calculations. Furthermore, the robustness and convenience of the algorithm are assessed.     

Imaging of highly turbid media by the absorption method

The results of a study on imaging that is based on the absorption method are presented. This method is based on attenuation measurements carried out in the presence of a sufficiently high absorption coefficient by the use of a continuous-wave source. The benefit of absorption on image quality comes from the strong attenuation of photons traveling along long trajectories. When the absorption coefficient is increased, the received energy decreases, but the mean path length of received photons decreases. The effect of increasing the absorption coefficient is similar to that of decreasing the gating time when the time-gating technique is used. Experimental results showed that the spatial resolution obtained with the absorption technique is similar to that obtained with the time-gating technique.     

New Al2O3:C,Mg crystals for radiophotoluminescent dosimetry and optical imaging

Optical and dosimetric properties of a new radiophotoluminescent material based on aluminum oxide doped with carbon and magnesium (Al2O3:C,Mg) and having aggregate oxygen vacancy defects are presented. The Al2O3:C,Mg crystals are characterized by several new optical absorption and emission bands. It is suggested that the main optical properties of this material are due to the formation of aggregate defects composed of two oxygen vacancies and two Mg-impurity atoms. Radiation-induced optical absorption bands are centered at 335 and 620 nm and produce fluorescent emission at 750 nm with a 75 +/- 5 ns lifetime. The dose measurements are performed by illumination of the Al2O3:C,Mg crystal with 335 nm or 650 nm light and by measuring the intensity of the 750 nm fluorescence. The detector material is insensitive to room light before and after the irradiation and the traps are stable up to 600 degrees C. A dose measurement range between 5 mGy and 200 Gy, suitable for therapeutic radiology applications, was demonstrated. The short luminescent lifetime and nondestructive readout is favorable for imaging applications.