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《Hydrometallurgy》2007,88(3-4):140-147
This study presents the feasibility of recovering palladium from the spent silica waste wherein palladium is adsorbed on silica as palladium phthalocyanine complexes. The spent silica having palladium phthalocyanine complexes adsorbed on it is thermally calcined in air to partially burn the organic moiety of the complex followed by palladium dissolution as H2PdCl4 in hydrochloric acid. The palladium is recovered as PdCl2 by judiciously adjusting the pH of filtrate obtained. Recovered silica retains its structure and can be re-used. 相似文献
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氧化钯使用常规的酸溶方法难溶。采用水合肼作为还原剂,于80 ℃时,在氧化钯的悬浮水溶液中,将氧化钯还原为金属钯黑,过滤后,该金属钯黑连同滤纸经过盐酸及硝硫混酸碳化处理后,钯进入溶液,从而解决了难溶氧化钯的溶样难题。然后,于pH 5.8的醋酸-醋酸钠缓冲介质中,以二甲酚橙为指示剂,锌盐返滴定过量EDTA,用丁二酮肟析出与钯等量的EDTA,三氯甲烷萃取丁二酮肟-钯沉淀,锌盐滴定析出的EDTA以测定钯含量,从而建立了水合肼还原-EDTA滴定法测定难溶氧化钯中钯的方法。按照实验方法测定实际样品中钯,结果的相对标准偏差(RSD,n=5)在0.12%~0.20%之间。对基准物质氧化钯中钯进行分析,测定值与理论值相符合。 相似文献
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Anomalous helium-bubble growth in palladium 总被引:1,自引:0,他引:1
R Rajaraman B Viswanathan MC Valsakumar KP Gopinathan 《Canadian Metallurgical Quarterly》1994,50(1):597-600
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The cyclic oxidation-reduction of submicrometer sized palladium powder was investigated over the temperature range 848 to
923 K. The total oxygen uptake was found to decrease with increasing number of cycles as a consequence of sintering. Furthermore,
sintering was found to be restricted to the reduction steps in these cycles. The relationships for the rate constants of the
oxidation and reduction processes are, respectively, Kx, = (1.04)106 exp[-(74.1)103/RT],k
r = (7.63)1012 exp[—(207.9)103/RT]. The activation energies for the oxidation of palladium powder and the reduction of palladium oxide are 74.1 and 207.9
kJ mol−1, respectively. 相似文献
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The demand for clean and green energy has raised the consumption of hydrogen continuously during the last years. Hydrogen is most economically produced in large scale systems by methane steam reforming followed by pressure swing adsorption (PSA). However, with a rising demand for small-scale production of hydrogen, and as down-scaling to smaller PSA-systems (?<?500?Nm3/h H2) is not economic, a substantial demand for hydrogen generation using palladium membranes has emerged.Porous tubes made of an oxide dispersion strengthened powder metallurgy Fe-Cr alloy (trade name ITM) constitute the backbone for the thin solid Pd films. The tubes provide mechanical and chemical long-term stability in atmospheres with hydrogen- and carbon-species at operation temperatures up to 600°C. A porous ceramic diffusion barrier layer (DBL) is deposited between the ITM-backbone and the Pd thin-film to avoid Pd diffusion into the Fe-Cr substrate and thereby ensure long-term integrity of the system. The Pd thin-film with a thickness <?10?μm is applied onto the DBL by a proprietary coating technology.This paper describes the production route of a tube/diffusion-barrier-layer/Pd-membrane system, its structure and permeation properties. 相似文献
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试样经火试金法熔炼和灰吹富集后,贵金属合粒以王水分解,在盐酸介质中,用火焰原子吸收分光光度法测定钯量。该方法的标准样品加入回收率为98.2%~104.1%。 相似文献
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