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保康磷矿是我国八大磷矿基地之一,而白竹磷矿又是保康矿区中储量最大而且进行了详探的矿区,开发的条件最为优越,为此对白竹磷矿进行了多种选矿方法的研究。 一、矿石性质 白竹磷矿层产于震旦系上统陡山沱组下段,为一浅海地台相磷块岩矿床。该磷矿石以白云质条带状磷块岩为主,其次为泥质条带状磷块岩、薄层状磷块岩、云质蠕虫状磷块岩和致密块状磷块岩。主要有用矿物为胶磷矿和磷灰石,主要脉石矿物为白云石,石英和粘土。磷大部富集在磷质条带中。三、四矿段储量占绝大部分,多元素分析如下: 相似文献
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<正> 晋宁磷矿属大型浅海相沉积层状磷块岩矿床。矿层结构单一,无夹层。贫富矿之间无明显界线。品级逐渐过渡,五氧化二磷含量由上至下逐渐降低,杂质含量由上至下逐渐升高。矿石为低镁风化磷矿,氧化镁含量<1%,铁、铝氧化物的含量变化较大,在2.5~6.8%之间。露采境界内的储量中富矿占52.64%, 相似文献
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安宁市县街磷矿床属古生代下寒武统梅树村组大型浅海相层状磷块岩矿床。磷矿层有上、下两层,分别产于梅树村组中谊村段的1m1-3和1m1-1两个层位。中低品位磷矿石产于下矿层,主要由磷酸盐矿物和脉石矿物两部分组成,含较多碎屑成分,矿石品位10%~20%。磷酸盐矿物以胶磷矿为主,主要呈球粒或集合体球粒产出,以及在基质中呈胶结物。矿石类型主要为白云质球粒磷块岩、碎屑状砂屑磷块岩。矿石结构、构造主要为内碎屑结构、条带状构造。矿层相对稳定,但P2O5含量与矿石结构构造关系密切,品位变化明显。 相似文献
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硅质磷块岩去除水溶液中铅离子的研究 总被引:4,自引:0,他引:4
硅质磷块岩可以有效地降低水溶液中铅离子的浓度,其反应机理属于一种广义的吸附作用。当反应条件一定时,硅质磷块岩具有稳定的铅离子吸附量,而且其吸附量可以通过超细粉碎或改性活化作用得到显著提高。 相似文献
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《云南化工》2019,(11)
云南是我国的富磷省份之一,绝大部分磷矿石适于露天开采。先期开采的浅表风化中高品位磷矿石,P2O5品位高、MgO含量低、倍半氧化物高,以1989年云南磷化集团海口磷矿30万t/a擦洗厂的建成投用为标志,采用擦洗分级脱泥的方法,脱除部分泥质,提高矿石品质,使中高品位磷矿石得到了有效利用。随着开采埋藏的加深和风化富矿的不断减少,开采的大量中低品位半风化、原生矿石,以云南磷化集团有限公司研究开发的中低品位磷矿浮选产业化技术为支撑,2007年云南磷化集团海口200万t/a浮选厂的建成投用为标志,采用浮选法,脱除有害杂质,提高矿石品质,使中低品位磷矿石得到了有效利用。云南胶磷矿的选矿产业化开发利用,有力地支撑了云南磷化工支柱产业的可持续发展。 相似文献
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云南浮选风化磷矿生产湿法磷酸起泡原因研究 总被引:1,自引:0,他引:1
风化磷矿是碳酸盐类磷矿经风化作用形成的一种高质量矿石,是一种新的磷矿石工业类型。二水湿法磷酸生产企业采用浮选风化磷矿作为生产原料时萃取槽会出现大量稳定性泡沫。经过实验,证明起泡的主要原因来自于风化磷矿浮选药剂,而非风化矿自身的物理性质。解决起泡的关键在于调整浮选药剂配方,即使用高效低泡浮选药剂以及在萃取工序增加必要的消泡措施。 相似文献
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《分离科学与技术》2012,47(4):587-597
The adsorption of cadmium and chromium from aqueous solutions with epichlorohydrin cross-linked α, β, and γ-cyclodextrin polymers (CDPs) was investigated under a wide range of experimental conditions including pH, metal concentration, and CDP amounts. Recent studies have shown that α, β, and γ-CDPs follow the Freundlich, Langmuir, and Brunauer–Emmett–Teller models and are capable of reducing heavy metal ion concentrations in water to desirable levels with enhanced sorption capabilities. The removal of cadmium and chromium achieved equilibrium in 4 h. The pH of effective cadmium removal was 6.5 to 7.5, and phosphate buffer favored the removal of cadmium in the presence of potassium ion. Chromium removal was optimal at pH 3.6 to 6.5. Current technologies can remove 99% cadmium ions from solution, yet this process is not very efficient for chromium ions. Furthermore, a small amount of CDPs can remove large quantities of heavy metal ions and can then be regenerated with acid for reuse. The present results are promising for using inexpensive CDPs as a low-cost material that is effective in remediating waters contaminated with heavy metal species. The sorption kinetics of CDPs along with the conditions to adsorb cadmium and chromium are reported here for the first time. 相似文献
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Zahia Benredjem Rachid Delimi Assia Khelalfa Samia Saaidia Ahmed Mehellou 《分离科学与技术》2016,51(4):718-726
Phosphate rock is a valuable material that is used for the production of large phosphorus chemicals. However, this natural material usually contains some toxic elements such as cadmium (Cd). Cd is a non-nutritive metal regarded as harmful to both humans and the environment. The main toxic effects of Cd on human health are the kidney and renal cortex diseases. Other effects were observed on pulmonary, cardiovascular, and musculoskeletal systems, in addition to including Cd as a human carcinogen. In order to reduce the cadmium content in the phosphate ore, an original method was studied and consists of coupling both leaching and electrodialysis. The effects of process parameters, such as reaction time, nature, and concentration of the extracting agent, liquid/phosphate ore ratio, pH, temperature, and current density, were investigated. The obtained results show that the cadmium extraction from phosphate ore using simple batch leaching does not reduce the cadmium content to the required level. However, the application of leaching- electrodialysis coupled method at optimum current density of 10 mA cm?2 increases the cadmium extraction efficiency up to 84.3%. This synergetic process could be applied to the treatment of phosphate ore containing cadmium. 相似文献
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采用常压微波消解法前处理磷矿样品,使用GGX-9型原子吸收光谱仪测定磷矿中铅、镉、汞含量,铅、镉、汞检出限分别为0.009 3、0.012 0、0.011 0μg/g,加标回收率分别为100.06%~100.18%、99.73%~100.18%、99.51%~100.63%,3种元素的相对标准偏差均在1%左右。 相似文献
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Andrea Engl Benno Kunz 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1995,63(3):257-261
Studies took place to investigate the effects of different nutrient conditions on the biosorption ability and selectivity of heavy metals by Saccharomyces cerevisiae. After having grown in media supplemented with additional glucose, ammonium, phosphate or cysteine, the yeast was exposed to an equimolar solution of lead, cadmium, zinc and copper. Lead removal from a mixed solution was significantly higher than that of copper, followed by zinc and cadmium. Generally, yeasts from cysteine-rich media showed greatest sorption capacity whereas phosphate addition influenced zinc selectivity. In addition, glucose, fructose and sucrose as carbon sources were examined. Cultures grown in glucose had a better uptake than those cultivated with fructose at an incubation time of 30 min. 相似文献
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T. F. Al-Fariss H. O. Ozbelge A. M. Abdulrazik 《Nutrient Cycling in Agroecosystems》1991,29(2):203-208
A large portion of the world's phosphate reserves are sedimentary type containing appreciable amounts of carbonate minerals. These are the most difficult type of deposits to beneficiate. The depletion of other reserves easier to beneficiate, necessitates research to find methods of mineral processing for carbonate rich sedimentary phosphate deposits. In this study, a new flotation method is described which was applied successfully in a laboratory scale flotation cell. Flotation of Al-Jalamid phosphate rock (sedimentary type with high carbonates and low silica content) found in northern Saudi Arabia was studied using a fatty acid as collector and sodium sulfate as a flotation aid. 相似文献
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H. Ö. Özbelge T. F. Al-Fariss A. M. Abdulrazik 《Nutrient Cycling in Agroecosystems》1993,34(3):217-222
There is an appreciable amount of carbonaceous sedimentary phosphate deposits in the northern Africa and the Middle East which are expected to gain importance in the near future because of the depletion of the deposits in Florida. In many of the regions where phosphate deposits are found there is a shortage of fresh water, and sea is not very far. The use of sea water instead of fresh water in flotation of carbonaceous phosphate rock is successfully demonstrated. Thus an appreciable reduction in the operating cost and an ample amount of saving in the fresh water resources of the region is expected. 相似文献