共查询到20条相似文献,搜索用时 62 毫秒
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以N-长链烷基脒为原料,在CO2氛围下制备得到N-长链烷基脒基碳酸氢盐。系统研究其表面活性发现:N-长链烷基脒基碳酸氢盐具有很好的表面活性,γcmc在20.5~32.3 mN/m之间;随着疏水链长的增加,N-长链烷基甲脒碳酸氢盐和N-长链烷基乙脒碳酸氢盐溶液的cmc和γcmc均逐渐降低,但N-长链烷基甲脒碳酸氢盐的cmc和γcmc均比N-长链烷基乙脒碳酸氢盐高;30~70℃时,N-长链烷基脒基碳酸氢盐溶液的表面张力均随温度的升高先降低后增大,热重分析表明这是由于在高温下脒盐会发生分解,溶液中的脒盐会部分转化成为中性脒,使得溶液中的脒盐浓度降低,表面张力变大。 相似文献
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通过考察酯基Gem in i型季铵盐表面活性剂Ⅱ-10-n(n=3,4,6)与十二烷基聚氧乙烯(9)醚(AEO9)的复配体系的表面活性发现,复配体系的临界胶团总浓度CMCT值介于二元复配体系中各组分的临界胶团浓度CMC01和CMC02之间。当溶液中含有少量AEO9时(在溶液体相中的摩尔分数α2=0.1),混合胶团中AEO9的摩尔分数均已超过0.35;随着溶液中AEO9含量的增大,混合胶团中逐渐以AEO9为主成分。复配体系的混合胶团聚集数介于二元复配体系中各组分的胶团聚集数之间,随着溶液中酯基Gem in i型季铵盐表面活性剂含量的增加,混合胶团聚集数逐渐减少。 相似文献
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Unsteady extraction from a system of semi-infinite capillaries to the flow of a fluid with a linear velocity gradient is studied. An assumption that the diffusion in the flow is a quasi-steady-state process is taken to obtain a linear equation for the local mass flux from the pore space, which involves fractional derivatives with respect to time and flow coordinate. Limiting solutions for the total diffusion flux at small and large times that cover the entire time interval are found. 相似文献
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Isidora Cekic‐Laskovic Christian Wlke Kang Xu Martin Winter 《Israel journal of chemistry》2021,61(1-2):85-93
In this article we take a stroll through the metaphorical rose garden, part of the flower garden, that is electrochemical storage systems. We take a closer look at batteries as the center‐pieces – the roses – and especially at the system component of batteries, the electrolyte and its development, throughout history. Just as a rose can only develop its unique beauty when taken good care of and provided with clean water and suitable nutrients, a battery cell cannot function without its electrolyte; the seemingly trivial component that has to juggle a multitude of requirements in order to make batteries truly bloom. 相似文献
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Measured propagation speeds are given for the combustion front in a blind gap in a condensed substance, which are related to gap height and mean pressure. The front may propagate monotonically, which is characteristic of relatively high pressures and wide gaps, or as a result of additional burning foci arising at a certain distance from the main front. At low pressures and particularly with small gap heights, the front propagates in an unstable fashion over the surface.Moscow. Translated from Fizika Goreniya i Vzryva, Vol. 28, No. 4, pp. 49–53, July–August, 1992. 相似文献
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Phase studies on a mixture of two polymers are presented, one of which is mesomorphic. We have systematically examined the influence of the molecular weight of the flexible polymer (including the oligomers) and of the semi-flexible polymer. In addition to the effect of the molecular weight, specific interactions are important for compatibility and formation of a homogeneous mesomorphic phase. The nature of this phase is demonstrated to be cholesteric and the pitch is determined. 相似文献
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Diffusion of a gas through a membrane 总被引:1,自引:0,他引:1
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Formulas associated with simple beam or plate theories are used extensively in structural design, to determine You's modulus, and to determine fracture strength of brittle nonmetallic materials. The question may arise as to whether the proper ratio of beam-width-to-beam-depth is such that the bent structural element can be considered as a beam and, if not, what is the correction factor that should be used with the simple beam formula. These questions are answered for a range of structural metallic and brittle nonmetallic materials. 相似文献
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G.K. Seevaratnam H. Ding O. Michel J.Y.Y. Heng O.K. Matar 《Chemical engineering science》2010,65(16):4523-4534
We study the deformation of oil droplets of varying viscosity adhering to a solid, rigid wall in a rectangular channel induced by a pressure-driven, laminar flow of water. Our experimental investigation involves the systematic study of the effects of initial droplet volume, flow rate and viscosity ratio on the various modes of droplet motion and deformation; this is performed via direct visualisation of the flow in a glass cell using a high-speed camera. Our results are used to construct flow maps that delineate the critical conditions for droplet ‘sliding’, ‘crawling’ and detachment from the channel wall as a function of system parameters. Comparisons of our experimental results with numerical predictions obtained using a procedure based on the diffuse-interface method yield reasonably good agreement for certain flow regimes. 相似文献
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S. A. Zhdan 《Combustion, Explosion, and Shock Waves》2003,39(4):458-463
The problem of a detonation wave propagating in a cylindrical column of a chemically active bubbly medium screened by a liquid from the tube walls is formulated and numerically solved within the framework of the Iordanskii–Kogarko two-phase model with allowance for energy dissipation due to acoustic radiation of bubbles. The wave structure of the reaction zone and the detonation velocity of the bubbly medium column are calculated. It is found that the self-sustaining wave can propagate with a velocity greater than the velocity of one-dimensional bubble detonation by a factor of 1.5–2.5. 相似文献