Some Aspects of Freeze Drying of Dairy Biomaterials

ABSTRACT

Different theoretical and experimental aspects of freeze drying of dairy biomaterials are reported. The following dairy biomaterials were chosen for investigations: three kefir bacterial cultures and one bacterial concentrate of a dairy vaccine. Experiments were performed both at one-region conductive or radiative heating and at combined two-region conductive-radiative heating. Emphasis was put on quality interactions between physical and biological properties of the material to be dried and freeze drying process parameters. Qualitative estimations of the following properties of biomaterials: a) colour, b)suppleness to caking and c) suppleness to scraping born the hot surface in dependence with the process parameters were performed using four-step subjective scales. On the basis of this estimations a synthetic quality criterion SQC was defined whose numerical value reflects general product quality. The results of mathematical modelling, numerical solution of the model and comparison with experimental data indicated that the process was heat transfer controlled and that the main factors resulting in good product quality and high SQC are low temperature of the conductive heated surface and vacuum chamber pressure affecting sublimation temperature. The influence of the sample freezing parameters on the elimination of the foaming or puffing and on the product quality was observed and examined. Furthermore, preliminary measurements of the dauy biomaterials viability after freeze drying were presented.     

Prediction of Transient Temperature Distribution During Freeze Drying of Yoghurt

ABSTRACT

A one dimensional heat and mass transfer analysis is employed to predict the temperature distribution in the dry layer of a frozen food sample in the form of a slab undergoing freeze drying. The method avoids the use of the effective diffusivity and the Knudsen diffusivity, both parameters dependent upon the stnrcture of the food product. The accu acy of the numerical solution is validated with published data as well as data of present study obtained for the freeze drying of yoghurt. The predicted surface temperature of the food sample is in good agreement with the experimental data. Energy supplied to product surface through conduction across evacuated head space was found to be significant. The model is useful for the analysis of freeze drying of a food product.     

Atmospheric Freeze Drying—Modeling and Simulation of a Tunnel Dryer

Drying is an important unit operation in processing of foods and other biotechnological products. Vacuum freeze drying is said to be the best drying technology regarding product quality of the end product, but the disadvantages are, among others, expensive operational costs and batch drying. Atmospheric freeze drying was introduced to lower the production costs of high-quality dried foods, and the need of simulation tools became important in estimations of the industrial drying processes.

A simplified mathematical model (AFDsim) is developed based on uniformly retreating ice front (URIF) considerations. The model is used to calculate theoretical drying curves of atmospheric freeze dried foods in a tunnel dryer. Studies of thermal and mass transfer properties during drying are essential for understanding the changes in product quality and for designing and dimensioning the drying process. The model can be used to simulate industrial atmospheric freeze drying of different foodstuff in a tunnel. The results from AFDsim modeling are in good accordance with the experimental results.     

Modeling of Vacuum Desorption in Freeze-Drying Process

A mathematical model of multicomponent vacuum desorption, which occurs in vacuum freeze-drying process, was developed. In freeze-drying porous biomaterials and pharmaceuticals are considered and the vacuum freeze-drying process, especially the moisture desorption in its final stage, is investigated. In this article, the drying with conductive heating and constant contact surface temperature was considered. Pressure drop is taken into account in the model formulation but was neglected in process simulation because of thin material layers undergoing freeze-drying. Model equations were solved by numerical method of lines. Moisture content and temperature distributions within the drying material were predicted from the model as a function of drying time.     

Atmospheric Freeze Drying—Modeling and Simulation of a Tunnel Dryer

Drying is an important unit operation in processing of foods and other biotechnological products. Vacuum freeze drying is said to be the best drying technology regarding product quality of the end product, but the disadvantages are, among others, expensive operational costs and batch drying. Atmospheric freeze drying was introduced to lower the production costs of high-quality dried foods, and the need of simulation tools became important in estimations of the industrial drying processes.

A simplified mathematical model (AFDsim) is developed based on uniformly retreating ice front (URIF) considerations. The model is used to calculate theoretical drying curves of atmospheric freeze dried foods in a tunnel dryer. Studies of thermal and mass transfer properties during drying are essential for understanding the changes in product quality and for designing and dimensioning the drying process. The model can be used to simulate industrial atmospheric freeze drying of different foodstuff in a tunnel. The results from AFDsim modeling are in good accordance with the experimental results.     

Prediction of Transient Temperature Distribution During Freeze Drying of Yoghurt

A one dimensional heat and mass transfer analysis is employed to predict the temperature distribution in the dry layer of a frozen food sample in the form of a slab undergoing freeze drying. The method avoids the use of the effective diffusivity and the Knudsen diffusivity, both parameters dependent upon the stnrcture of the food product. The accu acy of the numerical solution is validated with published data as well as data of present study obtained for the freeze drying of yoghurt. The predicted surface temperature of the food sample is in good agreement with the experimental data. Energy supplied to product surface through conduction across evacuated head space was found to be significant. The model is useful for the analysis of freeze drying of a food product.     

Modeling of Vacuum Desorption in Freeze-Drying Process

Abstract

A mathematical model of multicomponent vacuum desorption, which occurs in vacuum freeze-drying process, was developed. In freeze-drying porous biomaterials and pharmaceuticals are considered and the vacuum freeze-drying process, especially the moisture desorption in its final stage, is investigated. In this article, the drying with conductive heating and constant contact surface temperature was considered. Pressure drop is taken into account in the model formulation but was neglected in process simulation because of thin material layers undergoing freeze-drying. Model equations were solved by numerical method of lines. Moisture content and temperature distributions within the drying material were predicted from the model as a function of drying time.     

Influence of inner vapor transfer property of a freeze dryer on the design space of drying process

A freeze dryer with a radiative heating device was constructed and the inner vapor transfer property was regulated by separating the drying chamber and the condenser with an orifice. A mathematical model was used to obtain the contour diagrams of the selected parameters (e.g., product temperature and total drying period) during drying as a function of the heating condition and chamber pressure. Furthermore, the inner vapor transfer coefficients of the freeze dryer were used to draw the operation lines on the diagrams. The combinations of contour diagrams and operation lines clearly depict the design spaces. It was confirmed that the inner vapor transfer property substantially affected the acceptable operation range, and it was revealed that this coefficient is key to quantify the performance of a freeze dryer. This coefficient could also be used to predict the occurrence of choked flow during a freeze-drying run.     

瓶装物料的冻干规律研究

以脱脂牛奶为物料,进行了瓶装物料的冷冻干燥试验,探索了加热温度,辐射温度与冻干室压强对冻干过程的影响规律,分析了所得冻干曲线的特征,并对冻干机理和物料温度的监测井行阐述,得到在加热温度与辐射温度相同时恒温恒压操作的最佳参数,并提出了一些强经冻干过程的措施。本研究对实验冻干生产有一定的指导作用,也为瓶装物料的二维理论模型研究提供了基础。     

A Two-Stage Vacuum Freeze and Convective Air Drying Method for Strawberries

Strawberries were dehydrated in a two-stage combination drying consisting of vacuum freeze drying (FD) followed by hot air drying (AD), and in a two-stage hybrid method involving FD and finish AD(FAD) to obtain dehydrated strawberries of high quality at reduced cost. Energy consumption and physicochemical properties of the FAD product were compared with single-stage AD and single-stage FD. The quality parameters of the products were also analyzed. It was found that the quality of combined FAD-dried products approximated that of single-stage FD. Hence, the proposed two-stage combination drying method is recommended for dehydration of strawberries to obtain a high-quality product at lower cost when compared with vacuum freeze drying alone.     

A Two-Stage Vacuum Freeze and Convective Air Drying Method for Strawberries

Strawberries were dehydrated in a two-stage combination drying consisting of vacuum freeze drying (FD) followed by hot air drying (AD), and in a two-stage hybrid method involving FD and finish AD(FAD) to obtain dehydrated strawberries of high quality at reduced cost. Energy consumption and physicochemical properties of the FAD product were compared with single-stage AD and single-stage FD. The quality parameters of the products were also analyzed. It was found that the quality of combined FAD-dried products approximated that of single-stage FD. Hence, the proposed two-stage combination drying method is recommended for dehydration of strawberries to obtain a high-quality product at lower cost when compared with vacuum freeze drying alone.     

The drying strategy of atmospheric freeze drying apple cubes based on glass transition

Freeze drying (FD) yields the best quality of dried apple cubes but at the cost of long drying time and also the overall cost. To achieve economical freeze drying along with a high quality product an atmospheric freeze drying (AFD) technique was developed to dry apple cubes. The effect of different air temperature loading scheme on product quality and drying process was studied during AFD. According to the glass transition temperature of apple, a step-up temperature loading strategy for AFD process was developed to reduce the drying time by almost half and provided a similar good product quality.     

Relationship of Product Structure, Sorption Characteristics, and Freezing Point of Atmospheric Freeze-Dried Foods

Drying is an important unit operation in processing of foods with a long shelf life. The drying process influences product properties and quality; the products may shrink, break, or undergo rheological, physical, and biochemical changes. Important parameters responsible for product quality changes during drying are temperature, relative humidity, and residence time. Studies of thermal and mass transfer properties during drying are essential for understanding the changes in product quality and for designing and dimensionalizing the drying process.

Drying kinetics, sorption properties, shrinkage, and freezing point depression were determined during atmospheric freeze drying (AFD) of pieces of apple, turnip cabbage, and cod. Adsorption rate and sorption isotherms were determined in the end product. The drying temperature affected the physical properties. Drying at -5°C resulted in a larger shrinkage than drying at -11°C. GAB modeling was used to characterize the sorption properties of the products. No typical sigmoidal shape was found of the moisture sorption isotherms of the products, which is in accordance with the Guggenheim constant found from the same results. Experimental data on freezing point depression were used to find product constants E and b in the Schwartzberg equation for the freezing point depression. Freezing point depression, as a function of the dry matter content, was determined using Schwartzberg's equation and a component composition model (CCM). The result indicates an influence of structural effects on freezing point depression.     

Relationship of Product Structure,Sorption Characteristics,and Freezing Point of Atmospheric Freeze-Dried Foods

Drying is an important unit operation in processing of foods with a long shelf life. The drying process influences product properties and quality; the products may shrink, break, or undergo rheological, physical, and biochemical changes. Important parameters responsible for product quality changes during drying are temperature, relative humidity, and residence time. Studies of thermal and mass transfer properties during drying are essential for understanding the changes in product quality and for designing and dimensionalizing the drying process.

Drying kinetics, sorption properties, shrinkage, and freezing point depression were determined during atmospheric freeze drying (AFD) of pieces of apple, turnip cabbage, and cod. Adsorption rate and sorption isotherms were determined in the end product. The drying temperature affected the physical properties. Drying at ?5°C resulted in a larger shrinkage than drying at ?11°C. GAB modeling was used to characterize the sorption properties of the products. No typical sigmoidal shape was found of the moisture sorption isotherms of the products, which is in accordance with the Guggenheim constant found from the same results. Experimental data on freezing point depression were used to find product constants E and b in the Schwartzberg equation for the freezing point depression. Freezing point depression, as a function of the dry matter content, was determined using Schwartzberg's equation and a component composition model (CCM). The result indicates an influence of structural effects on freezing point depression.     

预冻在冻干过程中的作用简

预冻环节中降温速度、冻结温度、冻结时间都是重要的工艺参数,它们互相作用,影响着冻结体的结晶情况,最终会对冻干过程形成决定性的影响。本文通过实例,介绍了预冻过程中冻结速率对冻干结果的影响。说明适当的预冻参数可大大提高冻干效率和产品质量。     

VACUUM CONTACT DRYING OF SELECTED BIOTECHNOLOGY PRODUCTS

The paper is mainly concentrated on investigations of the vacuum contact drying of the following biomaterials: (1) beer yeast, (2) whey and its components: proteinaceous liquid, lactose, post-lactose liquid, (3) saturated solution of the citric acid, (4) post-fermentation broth of the fodder antibiotic bacitracin. The investigations of vacuum contact drying process in which dried material adheres closely to a hot surface were performed. In order to make possible the determination of optimal process parameters the measurements were performed for various constant temperatures of the hot surface, total pressures in vacuum chamber and layer thickness of biomaterials.

The effective thermal properties for dry layers of selected biomaterials depending on temperature and total pressure were also experimentally determined.

A mathematical model of the vacuum contact drying for most intensive regime of its performance i.e. boiling one was presented. It will enable the process simulation and estimation of the dryers efficiency depending on process parameters.

In addition, investigations of beer yeast viability depending on the hot surface temperature and the total pressure were performed.     

A Novel Atmospheric Freeze-Drying System Using a Vibro-Fluidized Bed with Adsorbent

Atmospheric freeze drying (AFD) in a vibro-fluidized bed dryer coupled with an adsorbent and multimode heat input is proposed for dehydration of food products at lower cost than the traditional freeze-drying process under vacuum. The aim of this project is to study the proposed AFD system using a vortex tube to produce low-temperature dry air, an alternative for producing dried food products of high quality. An experimental setup was designed and built to permit simultaneous application of convection, conduction, and radiation heat input to the drying material above its freezing point to ensure sublimation. A parametric evaluation over a broad range of possible parameter values was carried out using cubic-shaped potato and carrot as model heat-sensitive products. The influence of various system parameters on drying kinetics, quality, and functional properties of the dried products (color, rehydration properties, and morphology) were investigated. Comparison between physical quality and drying characteristics of the AFD system with AFD using fixed bed, fluidized bed dryer, and also with traditional vacuum freeze drying were carried out to investigate the viability of this new system. Results indicate that proposed system is an alternative to reduce the process time as well as to maintain the product quality at lower cost.     

A Novel Atmospheric Freeze-Drying System Using a Vibro-Fluidized Bed with Adsorbent

Atmospheric freeze drying (AFD) in a vibro-fluidized bed dryer coupled with an adsorbent and multimode heat input is proposed for dehydration of food products at lower cost than the traditional freeze-drying process under vacuum. The aim of this project is to study the proposed AFD system using a vortex tube to produce low-temperature dry air, an alternative for producing dried food products of high quality. An experimental setup was designed and built to permit simultaneous application of convection, conduction, and radiation heat input to the drying material above its freezing point to ensure sublimation. A parametric evaluation over a broad range of possible parameter values was carried out using cubic-shaped potato and carrot as model heat-sensitive products. The influence of various system parameters on drying kinetics, quality, and functional properties of the dried products (color, rehydration properties, and morphology) were investigated. Comparison between physical quality and drying characteristics of the AFD system with AFD using fixed bed, fluidized bed dryer, and also with traditional vacuum freeze drying were carried out to investigate the viability of this new system. Results indicate that proposed system is an alternative to reduce the process time as well as to maintain the product quality at lower cost.     

食品冷冻干燥过程的模型及影响因素

在合理简化的基础上,得到了只需较少参数的冷冻干燥过程一维数学模型。通过对胡萝卜和土豆食品的冷冻干燥实验,研究了加热方式、加热搁板温度和干燥室真空度对干燥时间的影响,模型的数值解与实验值吻合良好。     

食品和农产品干燥的一种有效方法-红外加热法

农业和食品行业需要能源高效和环境友好的干燥技术,最近红外加热干燥的应用得到广泛研究。作为现代干燥技术的另一种选择,红外干燥具有加热均匀、干燥速率高、干燥时间短、节约能源、产品品质和安全性高等引人注目的优点。研究表明。将红外方法可以减少干燥时间并且节能。与热可以对果蔬实现同步漂烫和干燥,干燥和热风干燥相结合能够有效的减少干燥时间。所开发的红外冷冻相继干燥常规的空气干燥或冷冻干燥相比,更适合于生产高品质的酥脆果蔬片。红外加对稻谷进行同步干燥和杀虫。本文将综述红外加热技术的最新研究和进展。