餐饮业烹调油烟气的组成与危害及净化方法探讨

阐述了烹调油烟气的形成过程，油烟气的组成与危害，并对目前国内市场上流通的几种油烟净化方法进行探讨。针对我国对油烟治理起步较晚，治理技术还不成熟，希望环保科研部门开发出更为高效的油烟净化器。     

饮食业油烟污染及净化技术探讨

阐述饮食业油烟废气的产生原因和危害,对油烟净化技术进行比较分析,介绍复合式油烟净化技术的优缺点.并对治理中存在的问题提出对策.     

玻璃窑炉烟气净化方法的选择与实例说明

介绍玻璃窑炉烟气净化方法并以实例说明其技术设计特点,对其进展及应用前景进行分析.     

餐饮油烟对人体健康的危害

餐饮油烟是雾霾和细颗粒物污染的主要污染源之一,其组成繁杂,含有多种有毒有害化学成分,严重影响人体健康。本文阐述了餐饮油烟的产生和组成成分,以及对人体的呼吸系统、循环系统、免疫系统、生殖系统、神经系统造成的健康危害。     

烟气中SOx,NOx的净化方法及效果的试验研究

通过理论分析和试验研究发现，将锅炉排污水喷入锅炉尾部烟道时对烟气中ＳＯｘ、ＮＯｘ的净化具有良好的效果。当排污水占锅炉蒸发量的４－５．５％时，脱硫效率可达到１７．０２－５７．３７％以上，脱氮效率可达１３．４０－３９．４３％以上。排污水的喷入量和喷水方式对脱硫，脱氧有显著的影响。图３表３参５     

铝冶炼烟气净化余热利用技术的探讨

近十几年来,我国的铝冶炼工业迅速发展,为国民经济的增长做出了重要贡献.但在冶炼铝生产过程中,会产生大量有害烟气,这种气体严重危害人类的健康,破坏生态环境.由于受经济利益的驱动,环保领域和扩大产量方面的研究工作成果较多,降低能耗方面的研究尚待深入进行.以铝冶炼烟气净化余热利用技术为研究内容,通过建立烟气净化余热利用系统,解决铝冶炼生产过程中的能源利用问题,从而实现能源再生的目的.     

垃圾焚烧发电厂烟气净化技术方案的选择

分析比较垃圾焚烧发电厂烟气净化技术特点.通过综合考虑进行决策,选出最优的技术方案.给出了烟气净化技术方案选择的方法.     

电石炉烟气余热回收及净化技术

文章通过对常规电石炉烟气余热回收及净化技术的研究，指出常规电石炉余热锅炉在运行中存在的问题，并提出了一些解决问题的方法。     

新型复合式油烟净化器的开发及应用

利用离心、吸附、洗涤等原理,提出复合式油烟净化新工艺,经广泛使用表明:复合式净化工艺对油烟的去除率在85%以上,净化后的油烟排放浓度均能达到国家排放标准,且运行可靠,操作方便,适合于中、小型餐馆使用。     

生活垃圾焚烧电站烟气净化技术的应用

阐述目前我国生活垃圾的特点,提出生活垃圾焚烧的必要性,简述生活垃圾焚烧过程中所产生的烟气污染成分。根据国家对垃圾焚烧电站烟气处理的要求和排放标准,提出现阶段国内外较常运用的三种生活垃圾电站的烟气净化技术工艺,并对比其优缺点。总结出目前最受国内外欢迎的垃圾电站烟气净化技术工艺特点和应用实例,归纳出半干法烟气净化技术净化效率较高、投资和运行费用低、流程简单等优点,是一种极具发展前途的生活垃圾焚烧电站烟气净化技术工艺。     

Optimization of biodiesel production from waste cooking oil

The sequences of development that cut across industrialization, population growth, environmental and economic reasons led individuals and organizations to have direct responsibilities in the development and implementation of sound technologies that will curtail the emissions of hazardous gases and particulate matter. As a result, this study focuses on the optimization and characterization of biodiesel from waste cooking oil. It involves the characterization of the feed stock, the transesterification, the purification of the transesterified waste cooking oil, the optimization of the biodiesel produced using 2⁴ factorial experimental designs, and the characterization of the biodiesel produced from waste cooking oil. Result obtained reveals that operating temperature of 30°C, transesterification time of 60 min, catalyst weight of 0.5%, and alcohol to oil ratio of 6:1 are the optimum conditions with optimum yield of 90% of biodiesel from waste cooking oil. Experimental determinations of some useful properties of the biodiesel produced were carried out for the purpose of confirming the quality as well as the identification of the biofuel. These were moisture content, specific gravity, viscosity, acid value, sulfated ash, cetane number, cloud point, flash point, distillation characteristic, and refractive index. The results obtained were 0.097%, 0.854, 4.90 mm²/s, 0.80 mgKOH/g, 0.01%, 48.00, 53°F, 143°C, 320°C, and 1.412, respectively. The results obtained showed that all the parameters compare favorably with literatures and the standard biodiesel specifications; hence production of biodiesel from waste cooking oil is possible.     

Biodiesel production from waste cooking oil over sulfonated catalysts

Biodiesel production from waste cooking oil with methanol was carried out in the presence of poly(vinyl alcohol) with sulfonic acid groups (PVA-SO₃H) and polystyrene with sulfonic acid groups (PS-SO₃H), at 60°C. The PVA-SO₃H catalyst showed higher catalytic activity than the PS-SO₃H one. In order to optimize the reaction conditions, different parameters were studied. An increase of waste cooking oil conversion into fatty acid methyl esters with the amount of PVA-SO₃H was observed. When the transesterification and esterification of WCO was carried out with ethanol over PVA-SO₃H, at 60°C, a decrease of biodiesel production was also observed. The WCO conversion into fatty acid ethyl ester increased when the temperature was increased from 60 to 80°C. When different amounts of free fatty acids were added to the reaction mixture, a slight increase on the conversion was observed. The PVA-SO₃H catalyst was reused and recycled with negligible loss in the activity.     

Potential of biodiesel from waste cooking oil in Mexico

The aim of this study is to evaluate the potential use of biodiesel produced from waste cooking oil (WCO) in Mexico and its CO₂ emission reduction potential for the Mexican transport sector and associated costs. The results show, based on 2010 data, that the potential of biodiesel from WCO is between 7.8 PJ and 17.7 PJ that represent between 1.5% and 3.3% of petro-diesel consumption for the road transport sector and can reduce between 0.51 and 1.02 Mt of CO₂, (1.0%–2.7% of CO₂-associated emissions), depending on the recovery ratio of WCO from vegetable oil consumption for cooking and considering CO₂ emissions for biodiesel production and methanol emissions during production and combustion in the blend. Primary energy used to produce 1 MJ of WCO-biodiesel is 0.8727 MJ, while literature reports 1.2007 MJ to produce 1 MJ of petro-diesel. Biodiesel costs are similar to petro-diesel costs if WCO is free. The paper offers suggestions for policies that promote increased recollection of WCO for biodiesel production and reduced illegal marketing of WCO, which is the main barrier to increase biodiesel production from WCO. The data used for the analysis is based on a case study of a WCO biodiesel plant that operates in Mexico City.     

Production possibility frontier analysis of biodiesel from waste cooking oil

This paper presents an assessment of the productive efficiency of an advanced biodiesel plant in Japan using Data Envelopment Analysis (DEA). The empirical analysis uses monthly input data (waste cooking oil, methanol, potassium hydroxide, power consumption, and the truck diesel fuel used for the procurement of waste cooking oil) and output data (biodiesel) of a biodiesel fuel plant for August 2008–July 2010. The results of this study show that the production activity with the lowest cost on the biodiesel production possibility frontier occurred in March 2010 (production activity used 1.41 kL of waste cooking oil, 0.18 kL of MeOH, 16.33 kg of KOH, and 5.45 kW h of power), and the unit production cost in that month was 18,517 yen/kL. Comparing this efficient production cost to the mean unit production cost on the production possibility frontier at 19,712 yen/kL, revealed that the cost of producing 1 kL of biodiesel could be reduced by as much as 1195 yen. We also find that the efficiency improvement will contribute to decreasing the cost ratio (cost per sale) of the biodiesel production by approximately 1% during the study period (24 months) between August 2008 and July 2010.     

A bone-based catalyst for biodiesel production from waste cooking oil

Biodiesel production via transesterification of waste cooking oil (WCO) with methanol using waste chicken bone-derived catalyst was investigated. The calcium carbonate content in the waste chicken bone was converted to calcium oxide (CaO) at a calcinations temperature of 800°C. The catalysts were prepared by calcination at 300–800°C for 5 h and catalyst characterization was carried out by X-ray diffraction (XRD) and Brunauer–Emmett–Teller (BET) surface area measurement. CaO was used as catalyst for biodiesel production. The results of the optimization imply that the catalyst concentration of 3.0 wt%, methanol to oil ratio of 3:1, and reaction temperature of 80°C for 3 h provide the maximum values of yield in methyl ester production. Reusability of the catalyst from calcined waste chicken bone was studied for four times, with a good yield.     

Optimisation of FAME production from waste cooking oil for biodiesel use

This study consists of the development and optimisation of the potassium hydroxide-catalysed synthesis of fatty acid methyl esters (FAME) from waste cooking oil. A factorial design of experiments and a central composite design have been used. The variables chosen were fatty acid concentration in the waste cooking oil, temperature and initial catalyst concentration by weight of waste cooking oil, while the responses were FAME purity and yield. The initial catalyst concentration is the most important factor, having a positive influence on FAME purity, but a negative one on FAME yield due to the positive influences of the yield losses (triglyceride saponification and methyl ester dissolution in glycerol). Fatty acid concentration in the waste cooking oil is the second factor of importance, having negative influences in FAME purity and yield. Temperature has an insignificant effect on FAME purity, but it has a significant negative influence on FAME yield due to the positive effect of temperature on the yield losses. Second-order models were obtained to predict the responses analysed as a function of these variables.     

Tribological behavior of diesel/biodiesel blend from waste cooking oil and ethanol

One kind of novel biodiesel waste cooking oil ethyl ester (WCOEE) was prepared via transesterfication reaction between waste cooking oil and ethanol. The tribological behavior of diesel/WCOEE blend was evaluated with a four-ball tribometer. The wear resistance, extreme pressure, and friction reduction of the blend were improved with increasing WCOEE. The optimal content of WCOEE in the blend was 20 vol%. It was also found that free fatty acids (FFAs) had a positive effect on the wear resistance of blend. The lubrication improvement of the blend was ascribed to the formation of polyester film and high polarity of fatty acid ethyl ester.     

Optimization of biodiesel production from waste cooking oil using waste bone as a catalyst

This work determined the association between several parameters of biodiesel production from waste cooking oil (WCO) using waste bovine bone (WBB) as catalyst to achieve a high conversion to fatty acid methyl ester (%FAME). The effect of three independent variables was used as the optimum condition using response surface methodology (RSM) for maximizing the %FAME. The RSM analysis showed that the ratio of MeOH to oil (mol/mol), catalyst amount (%wt), and time of reaction have the maximum effects on the transform to FAME. Moreover, the coefficient of determination (R²) for regression equations was 99.19%. Probability value (P < 0.05) demonstrated a very good significance for the regression model. The optimal values of variables were MeOH/WCO ratio of 15.49:1 mol/mol, weight of catalyst as 6.42 wt%, and reaction time of 128.67 min. Under the optimum conditions, %FAME reached 97.59%. RSM was confirmed to sufficiently describe the range of the transesterification parameters studied and provide a statistically accurate estimate of the best transform to FAME using WBB as the catalyst.     

Optimization of heterogeneous biodiesel production from waste cooking palm oil via response surface methodology

Heterogeneous transesterification of waste cooking palm oil (WCPO) to biodiesel over Sr/ZrO₂ catalyst and the optimization of the process have been investigated. Response surface methodology (RSM) was employed to study the relationships of methanol to oil molar ratio, catalyst loading, reaction time, and reaction temperature on methyl ester yield and free fatty acid conversion. The experiments were designed using central composite by applying 2⁴ full factorial designs with two centre points. Transesterification of WCPO produced 79.7% maximum methyl ester yield at the optimum methanol to oil molar ratio = 29:1, catalyst loading = 2.7 wt%, reaction time = 87 min and reaction temperature = 115.5 °C.     

A green route for biodiesel production from waste cooking oil over base heterogeneous catalyst

The present work describes the synthesis of porous BaSnO₃ by eco‐friendly sol‐gel method using albumin as a bio‐template agent, and its application as a solid base catalyst in biodiesel production from waste cooking oil. The physico‐chemical, textural, and morphological properties of the catalyst were evaluated by X‐ray diffraction (XRD), Brunauer‐Emmett‐Teller (BET), field emission scanning electron microscopy (FESEM), and temperature programmed desorption (TPD)–CO₂ techniques. The synthesized catalyst showed considerable stability, efficient catalytic activity, and negligible metal leaching. The satisfactory performance of the catalyst could be ascribed to the presence of basic sites of different strength on the surface of the catalyst. The catalyst produced maximum biodiesel yield of 96% at optimum reaction conditions of 90°C reaction temperature, methanol to oil molar ratio of 10:1, catalyst dosage of 6 wt%, and reaction time of 2 hours. Moreover, the catalyst showed substantial reusability up to five reaction cycles without any considerable decrease in transesterification activity.