Optimum energy evaluation and life cycle cost assessment of a hydrogen liquefaction system assisted by geothermal energy

In this study, analyses of the thermodynamic performance and life cycle cost of a geothermal energy-assisted hydrogen liquefaction system were performed in a computer environment. Geothermal water at a temperature of 200 °C and a flow rate of 100 kg/s was used to produce electricity. The produced electricity was used as a work input to liquefy the hydrogen in the advanced liquefaction cycle. The net work requirement for the liquefaction cycle was calculated as 8.6 kWh/kg LH₂. The geothermal power plant was considered as the work input in the liquefaction cycle. The hydrogen could be liquefied at a mass flow rate of 0.2334 kg/s as the produced electricity was used directly to produce liquid hydrogen in the liquefaction cycle. The unit costs of electricity and liquefied hydrogen were calculated as 0.012 $/kWh and 1.44 $/kg LH₂. As a result of the life cycle cost analysis of the system, the net present value (NPV) and levelized annual cost (LAC) were calculated as 123,100,000 and 14,450,000 $/yr. The simple payback period (N_spp) and discount payback period (N_dpp) of the system were calculated as 2.9 and 3.6 years, respectively.     

Performance analysis and optimization of a hydrogen liquefaction system assisted by geothermal absorption precooling refrigeration cycle

The present paper deals with the hydrogen liquefaction with absorption precooling cycle assisted by geothermal water is modeled and analyzed. Uses geothermal heat in an absorption refrigeration process to precool the hydrogen gas is liquefied in a liquefaction cycle. High-temperature geothermal water using the absorption refrigeration cycle is used to decrease electricity work consumption in the gas liquefaction cycle. The thermoeconomic optimization procedure is applied using the genetic algorithm method to the hydrogen liquefaction system. The objective is to minimize the unit cost of hydrogen liquefaction of the composed system. Based on optimization calculations, hydrogen gas can be cooled down to ?30 °C in the precooling cycle. This allows the exergetic cost of hydrogen gas to be reduced to be 20.16 $/GJ (2.42 $/kg LH₂). The optimized exergetic cost of liquefied hydrogen is 4.905 $/GJ (1.349 $/kg LH₂), respectively.     

Thermo-economic investigation on the hydrogen production through the stored solar energy in a salinity gradient solar pond: A comparative study by employing APC and ORC with zeotropic mixture

In this paper, a salinity gradient solar pond (SGSP) is used to harness the solar energy for hydrogen production through two cycles. The first cycle includes an absorption power cycle (APC), a proton exchange membrane (PEM) electrolyzer, and a thermoelectric generator (TEG) unit; in the second one, an organic Rankine cycle (ORC) with the zeotropic mixture is used instead of APC. The cycles are analyzed through the thermoeconomic vantage point to discover the effect of key decision variables on the cycles’ performance. Finally, NSGA-II is used to optimize both cycles. The results indicate that employing ORC with zeotropic mixture leads to a better performance in comparison to utilizing APC. For the base mode, unit cost product (UCP), exergy, and energy efficiency when APC is employed are 59.9 $/GJ, 23.73%, and 3.84%, respectively. These amounts are 47.27 $/GJ, 29.48%, and 5.86% if ORC with the zeotropic mixture is utilized. The APC and ORC generators have the highest exergy destruction rate which is equal to 6.18 and 10.91 kW. In both cycles, the highest investment cost is related to the turbine and is 0.8275 $/h and 0.976 $/h for the first and second cycles, respectively. In the optimum state the energy efficiency, exergy efficiency, UCP, and H₂ production rate of the system enhances 42.44%, 27.54%,15.95%, and 38.24% when ORC with the zeotropic mixture is used. The maximum H₂ production is 0.47 kg/h, and is obtained when the mass fraction of R142b, LCZ temperature, pumps pressure ratio, generator bubble point temperature are 0.603, 364.35 K, 2.12, 337.67 K, respectively.     

Investigation of green hydrogen production and development of waste heat recovery system in biogas power plant for sustainable energy applications

In this study, biogas power production and green hydrogen potential as an energy carrier are evaluated from biomass. Integrating an Organic Rankine Cycle (ORC) to benefit from the waste exhaust gases is considered. The power obtained from the ORC is used to produce hydrogen by water electrolysis, eliminate the H₂S generated during the biogas production process and store the excess electricity. Thermodynamic and thermoeconomic analyses and optimization of the designed Combined Heat and Power (CHP) system for this purpose have been performed. The proposed study contains originality about the sustainability and efficiency of renewable energy resources. System design and analysis are performed with Engineering Equation Solver (EES) and Aspen Plus software. According to the results of thermodynamic analysis, the energy and exergy efficiency of the existing power plant is 28.69% and 25.15%. The new integrated system's energy, exergy efficiencies, and power capacity are calculated as 41.55%, 36.42%, and 5792 kW. The total hydrogen production from the system is 0.12412 kg/s. According to the results of the thermoeconomic analysis, the unit cost of the electricity produced in the existing power plant is 0.04323 $/kWh. The cost of electricity and hydrogen produced in the new proposed system is determined as 0.03922 $/kWh and 0.181 $/kg H₂, respectively.     

The performance assessment of a combined organic Rankine-vapor compression refrigeration cycle aided hydrogen liquefaction

In this study, the performance of the combined cooling cycle with the Organic Rankine power cycle, which provides cooling of the hydrogen at the compressor inlet which compresses the constant temperature in the Claude cycle used for hydrogen liquefaction, on the system is examined. The Organic Rankine combined cooling cycle was considered to be using a geothermal source with a flow rate of 120 kg/s at a temperature of 200 °C. The first and second law performance evaluations of the whole system were made depending on the heat energy at different levels taken from the geothermal source. The thermodynamic analysis of the equipment making up the system has been done in detail. The temperature values at which the hydrogen can be effectively cooled were determined in the presented combined system. The efficiency coefficient of the total system was calculated based on varying pre-cooling values. As a result of the study, it was determined that cold entry of hydrogen into the Claude cycle reduced the energy consumption required for liquefaction. Amount of hydrogen cooled to specified temperature increase by increase in mass flow of geothermal water and its temperature. Liquefaction cost is calculated to be 0.995 $/kg H₂ and electricity produced by itself is calculated to be 0.025 $/kWh by the new model of liquefaction system. Cost of the liquefaction in the proposed system is about 39.7% lower than direct value of hydrogen liquefaction of 1.650 $/kg given in the literature.     

Thermoeconomic analysis and artificial neural network based genetic algorithm optimization of geothermal and solar energy assisted hydrogen and power generation

The study aims to optimize the geothermal and solar-assisted sustainable energy and hydrogen production system by considering the genetic algorithm. The study will be useful by integrating hydrogen as an energy storage unit to bring sustainability to smart grid systems. Using the Artificial Neural Network (ANN) based Genetic Algorithm (GA) optimization technique in the study will ensure that the system is constantly studied in the most suitable under different climatic and operating conditions, including unit product cost and the plant's power output. The water temperature of the Afyon Geothermal Power Plant varies between 70 and 130 °C, and its mass flow rate varies between 70 and 150 kg/s. In addition, the solar radiation varies between 300 and 1000 W/m² for different periods. The net power generated from the region's geothermal and solar energy-supported system is calculated as 2900 kW. If all of this produced power is used for hydrogen production in the electrolysis unit, 0.0185 kg/s hydrogen can be produced. The results indicated that the overall energy and exergy efficiencies of the integrated system are 4.97% and 16.0%, respectively. The cost of electricity generated in the combined geothermal and solar power plant is 0.027 $/kWh if the electricity is directly supplied to the grid and used. The optimized cost of hydrogen produced using the electricity produced in geothermal and solar power plants in the electrolysis unit is calculated as 1.576 $/kg H₂. The optimized unit cost of electricity produced due to hydrogen in the fuel cell is calculated as 0.091 $/kWh.     

Methanol synthesis from renewable H2 and captured CO2 from S-Graz cycle – Energy,exergy, exergoeconomic and exergoenvironmental (4E) analysis

Thermodynamic, economic and environmental analyses of a combined CO₂ capturing system, including, geothermal driven dual fluid organic Rankine cycle (ORC), proton exchange membrane electrolyzer (PEME), S-Graz cycle and methanol synthesis unit (MSU) were carried out. The presented zero emission system was designed based on the oxy-fuel combustion carbon capturing to produce power, hydrogen and methanol, while released CO₂ can be captured. Generated renewable power by the ORC was utilized by the PEME to produce renewable hydrogen. Part of the produced hydrogen is fed to the MSU, while the rest was stored in hydrogen tanks. In fact, CO₂ hydrogenation to produce methanol suggested via direct methanol synthesis in order to utilize the captured CO₂ from the S-Graz cycle. Exergy efficiency of the system defined to analyze the system thermodynamically, while SPECO method utilized to evaluate system economically. Results revealed that the most important part of the system is the S-Graz cycle, from the viewpoint of capital investment. Also, the average product unit cost of 24.88 $/GJ obtained for the whole system.     

Comprehensive assessment on a hybrid PEMFC multi-generation system integrated with solar-assisted methane cracking

A hybrid proton exchange membrane fuel cell (PEMFC) multi-generation system model integrated with solar-assisted methane cracking is established. The whole system mainly consists of a disc type solar Collector, PEMFC, Organic Rankine cycle (ORC). Methane cracking by solar energy to generate hydrogen, which provides both power and heat. The waste heat and hydrogen generated during the reaction are efficiently utilized to generate electricity power through ORC and PEMFC. The mapping relationships between thermodynamic parameters (collector temperature and separation ratio) and economic factors (methane and carbon price) on the hybrid system performance are investigated. The greenhouse gas (GHG) emission reductions and levelized cost of energy (LCOE) are applied to environmental and economic performance evaluation. The results indicate that the exergy utilization factor (EXUF) and energy efficiency of the novel system can reach 21.9% and 34.6%, respectively. The solar-chemical energy conversion efficiency reaches 40.3%. The LCOE is 0.0733 $/kWh when the carbon price is 0.725 $/kg. After operation period, the GHG emission reduction and recovered carbon can reach 4 × 10⁷ g and 14,556 kg, respectively. This novel hybrid system provides a new pathway for the efficient utilization of solar and methane resources and promotes the popularization of PEMFC in zero energy building.     

Economics of hydrogen production and liquefaction by geothermal energy

Seven models are considered for the production and liquefaction of hydrogen by geothermal energy. In these models, we use electrolysis and high-temperature steam electrolysis processes for hydrogen production, a binary power plant for geothermal power production, and a pre-cooled Linde–Hampson cycle for hydrogen liquefaction. Also, an absorption cooling system is used for the pre-cooling of hydrogen before the liquefaction process. A methodology is developed for the economic analysis of the models. It is estimated that the cost of hydrogen production and liquefaction ranges between 0.979 $/kg H₂ and 2.615 $/kg H₂ depending on the model. The effect of geothermal water temperature on the cost of hydrogen production and liquefaction is investigated. The results show that the cost of hydrogen production and liquefaction decreases as the geothermal water temperature increases. Also, capital costs for the models involving hydrogen liquefaction are greater than those for the models involving hydrogen production only.     

Techno-economic assessment of a solar-geothermal multigeneration system for buildings

A techno-economic assessment is conducted for a multigeneration system comprised of two renewable energy subsystems—geothermal and solar—to supply electrical power, cooling, heating, hydrogen and hot water for buildings. The proposed system is evaluated in terms of energy and exergy efficiencies. The simulation results show that the electrolyzer produces 2.7 kg/h hydrogen. A parametric study is carried out to assess the effect of various parameters on the system energy and exergy efficiencies. The economic assessment, performed using the Hybrid Optimization of Multiple Energy Resources (HOMER) software, shows that the net present cost of the optimized electrical power system is $476,000 and the levelized cost of electricity is $0.089/kWh.     

Process optimization for large-scale hydrogen liquefaction

The investment in the hydrogen infrastructure for hydrogen mobility has lately seen a significant acceleration. The demand for energy and cost efficient hydrogen liquefaction processes has also increased steadily. A significant scale-up in liquid hydrogen (LH₂) production capacity from today's typical 5–10 metric tons per day (tpd) LH₂ is predicted for the next decade. For hydrogen liquefaction, the future target for the specific energy consumption is set to 6 kWh per kg LH₂ and requires a reduction of up to 40% compared to conventional 5 tpd LH₂ liquefiers. Efficiency improvements, however, are limited by the required plant capital costs, technological risks and process complexity. The aim of this paper is the reduction of the specific costs for hydrogen liquefaction, including plant capital and operating expenses, through process optimization. The paper outlines a novel approach to process development for large-scale hydrogen liquefaction. The presented liquefier simulation and cost estimation model is coupled to a process optimizer with specific energy consumption and specific liquefaction costs as objective functions. A design optimization is undertaken for newly developed hydrogen liquefaction concepts, for plant capacities between 25 tpd and 100 tpd LH₂ with different precooling configurations and a sensitivity in the electricity costs. Compared to a 5 tpd LH₂ plant, the optimized specific liquefaction costs for a 25 tpd LH₂ liquefier are reduced by about 50%. The high-pressure hydrogen cycle with a mixed-refrigerant precooling cycle is selected as preferred liquefaction process for a cost-optimized 100 tpd LH₂ plant design. A specific energy consumption below 6 kWh per kg LH₂ can be achieved while reducing the specific liquefaction costs by 67% compared to 5 tpd LH₂ plants. The cost targets for hydrogen refuelling and mobility can be reached with a liquid hydrogen distribution and the herewith presented cost-optimized large-scale liquefaction plant concepts.     

Integrated design evaluation of propulsion,electric power,and re-liquefaction system for large-scale liquefied hydrogen tanker

This study proposes the integrated designs of energy systems and a re-liquefaction system for ocean-going LH₂ tankers. Five prospective energy systems (Systems A to E) are suggested, using LNG as fuel, and a re-liquefaction system with a Claude cycle is developed. Their economic value, technological feasibility, and environmental impact are evaluated. The re-liquefaction systems' exergy efficiency and specific energy consumption ranges were 26.79–46.27% and 3–7.45 kWh/kg, respectively. The re-liquefaction system in System C is economically feasible up to $2/kg of H₂. LCC of the integrated designs shows that System C has the lowest cost of $140 million. The shipping costs for each design are reviewed, and the lowest one is $447/ton of H₂ for System C. Although System C CAPEX is the second expensive, it has the highest efficiency. Consequently, System C with the low-pressure engine, SOFC, and the re-liquefaction system is determined to be the optimal one.     

Exergy,exergoeconomic and multi-objective optimization of a clean hydrogen and electricity production using geothermal-driven energy systems

In this research paper, comprehensive thermodynamic modeling of an integrated energy system consisting of a multi-effect desalination system, geothermal energy system, and hydrogen production unit is considered and the system performance is investigated. The system's primary fuel is a geothermal two-phase flow. The system consists of a single flash steam-based power system, ORC, double effect water–lithium bromide absorption cooling system, PEM electrolyzer, and MED with six effects. The effect of numerous design parameters such as geothermal temperature and pressure on the net power of steam turbine and ORC cycle, the cooling capacity of an absorption chiller, the amount of produced hydrogen in PEM electrolyzer, the mass flow rate of distillate water from MED and the total cost rate of the system are studied. The simulation is carried out by both EES and Matlab software. The results indicate the key role of geothermal temperature and show that both total exergy efficiency and total cost rate of the system elevate with increasing geothermal temperature. Also, the impact of changing absorption chiller parameters like evaporator and absorber temperatures on the COP and GOR of the system is investigated. Since some of these parameters have various effects on cost and efficiency as objective functions, a multi-objective optimization is applied based on a Genetic algorithm for this system and a Pareto-Frontier diagram is presented. The results show that geothermal main temperature has a significant effect on both system exergy efficiency and cost of the system. An increase in this temperature from 260 C to 300 C can increase the exergy efficiency of the system for an average of 12% at various working pressure and also increase the cost of the system by 13%.     

Energy,exergy and economic analyses and multiobjective optimization of a novel solar multi-generation system for production of green hydrogen and other utilities

Renewable energy based multi-generation systems can help solving energy-related environmental problems. For this purpose, a novel solar tower-based multi-generation system is proposed for the green hydrogen production as the main product. A solar-driven open Brayton cycle with intercooling, regeneration and reheat is coupled with a regenerative Rankine cycle and a Kalina cycle-11 as a unique series of power cycles. Significant portion of the produced electricity is utilized to produce green hydrogen in an electrolyzer. A thermal energy storage, a single-effect absorption refrigeration cycle and two domestic hot water heaters are also integrated. Energy, exergy and economic analyses are performed to examine the performance of the proposed system, and a detailed parametric analysis is conducted. Multiobjective optimization is carried out to determine the optimum performance. Optimum energy and exergy efficiencies, unit exergy product cost and total cost rate are calculated as 39.81%, 34.44%, 0.0798 $/kWh and 182.16 $/h, respectively. Products are 22.48 kg/h hydrogen, 1478 kW power, 225.5 kW cooling and 7.63 kg/s domestic hot water. Electrolyzer power size is found as one of the most critical decision variables. Solar subsystem has the largest exergy destruction. Regenerative Rankine cycle operates at the highest energy and exergy efficiencies among power cycles.     

Thermo-economic and thermo-environmental assessment of hydrogen production,an experimental study

Nowdays, the topic involvement of green hydrogen in energy transformation is getting attention in the world. The current research examined, thermo-economic and thermo-environmental analyses of the organic Rankine cycle (ORC) system and the hydrogen production system integrated into the solar collector with medium temperature density are investigated. The presented study is a holistic evaluation of experimentally solar-assisted electricity and hydrogen production. The studied model is comprised of an evacuated tube solar collector for thermal energy generation, ORC system for electricity generation and proton exchanger membrane electrolyzer (PEMe) for hydrogen production. According to the results of the thermodynamic analysis, the energy and exergy efficiency of the whole system are calculated as 39.01% and 17.37%, respectively. Also exergoenviroeconomic and exergoenviromental analysis of the whole system is found as 71.48 kgCO₂/kWh and 0.139 $/kgCO₂, respectively. In addition, the sustainability index of the presented system is obtained as 1.21. In this study, in addition to thermodynamic analysis, parameters such as energy and exergy affecting environmental and economic efficiency, are explained. Ambient temperature plays a prominent role in energy-based environmental analysis. On the contrary, the ambient temperature did not cause a significant change in the exergy-based environmental analysis.     

Performance comparison and parametric optimization of subcritical Organic Rankine Cycle (ORC) and transcritical power cycle system for low-temperature geothermal power generation

Organic Rankine Cycle (ORC) is a promising technology for converting the low-grade energy to electricity. This paper presents an investigation on the parameter optimization and performance comparison of the fluids in subcritical ORC and transcritical power cycle in low-temperature (i.e. 80–100 °C) binary geothermal power system. The optimization procedure was conducted with a simulation program written in Matlab using five indicators: thermal efficiency, exergy efficiency, recovery efficiency, heat exchanger area per unit power output (APR) and the levelized energy cost (LEC). With the given heat source and heat sink conditions, performances of the working fluids were evaluated and compared under their optimized internal operation parameters. The optimum cycle design and the corresponding operation parameters were provided simultaneously. The results indicate that the choice of working fluid varies the objective function and the value of the optimized operation parameters are not all the same for different indicators. R123 in subcritical ORC system yields the highest thermal efficiency and exergy efficiency of 11.1% and 54.1%, respectively. Although the thermal efficiency and exergy efficiency of R125 in transcritical cycle is 46.4% and 20% lower than that of R123 in subcritical ORC, it provides 20.7% larger recovery efficiency. And the LEC value is relatively low. Moreover, 22032L petroleum is saved and 74,019 kg CO₂ is reduced per year when the LEC value is used as the objective function. In conclusion, R125 in transcritical power cycle shows excellent economic and environmental performance and can maximize utilization of the geothermal. It is preferable for the low-temperature geothermal ORC system. R41 also exhibits favorable performance except for its flammability.     

Performance and economic investigation of a combined phosphoric acid fuel cell/organic Rankine cycle/electrolyzer system for sulfuric acid production; Energy-based organic fluid selection

In this article, the application of a hybrid phosphoric acid fuel cell and organic Rankine cycle (PAFC/ORC) system was thermo-economically investigated for sulfuric acid production in Sarcheshmeh copper complex (SCC); the second largest copper deposit worldwide. The electricity that is produced by the system is consumed by electrolyzer to produce the hydrogen and sulfuric acid. Two scenarios were considered for applying the PAFC thermal energy as thermal source of the ORC to produce further power. The performance of the system was investigated considering various important parameters such as organic fluid type, PAFC current density (I_PAFC ), fuel & air consumption factors as well as the ORC turbine inlet pressure (P_{i, ORC} ). The unit cost of sulfuric acid and the hybrid system simple payback period were obtained as 0.0215$/kg and 3.65 years, respectively.     

The feasibility of using geothermal energy in hydrogen production

A feasibility study exploring the use of geothermal energy in hydrogen production is presented. It is possible to use a thermal energy to supply heat for high temperature electrolysis and thereby substitute a part of the relatively expensive electricity needed. A newly developed HOT ELLY high temperature steam electrolysis process operates at 800 – 1000°C. Geothermal fluid is used to heat fresh water up to 200°C steam. The steam is further heated to 900°C by utilising heat produced within the electrolyser. The electrical power of this process is reduced from 4.6 kWh per normalised cubic meter of hydrogen (kWh/Nm³ H₂) for conventional process to 3.2 kWh/Nm³ H₂ for the HOT ELLY process implying electrical energy reduction of 29.5%. The geothermal energy needed in the process is 0.5 kWh/Nm³ H₂. Price of geothermal energy is approximately 8–10% of electrical energy and therefore a substantial reduction of production cost of hydrogen can be achieved this way. It will be shown that using HOT ELLY process with geothermal steam at 200°C reduces the production cost by approximately 19%.     

Investigation of hydrogen production performance of chlor-alkali cell integrated into a power generation system based on geothermal resources

In present study, hydrogen production performance of chlor-alkali cell integrated into a power generation system based on geothermal resource is studied. The basic elements of the novel system are a separator, a steam power turbine, an organic Rankine cycle (ORC), an air cooled condenser, a saturated NaCl solution reservoir tank and a chlor-alkali cell. To enhance the performance of the cell, the saturated NaCl solution is heated by the waste heat from the ORC. So, this integrated system generates significant amount of electricity for the city grid and also yields three main products those are hydrogen, chlorine and sodium hydroxide. According to the parametric study, when the temperature of a geothermal resource varies from 140 to 155 °C, the electrical power generation increases from nearly 2.5 MW to 3.9 MW and hydrogen production increases from 10.5 to 21.1 kg-h. Thus, when the geothermal resource temperature of 155 °C, the energy efficiency of the system is 6.2% and the exergetic efficiency is 22.4%. As a result, the geothermal energy potential plays a key role on the integrated system performance and the hydrogen production rate.     

A 3E,hydrogen production,irrigation, and employment potential assessment of a hybrid energy system for tropical weather conditions – Combination of HOMER software,shannon entropy,and TOPSIS

The increasing threat to environmental sustainability as a result of greenhouse gas (GHG) emissions from fossil fuel base power plants has necessitated the need to find sustainable energy sources to meet the world's energy demands. This study focuses on assessing the potential of a hybrid power plant for the production of electricity, hydrogen for the production of fertilizer for agricultural activities, farmland irrigation, environmental impact as well as its employment potential in northern Ghana. The Shannon entropy weight and TOPSIS multi-criteria decision-making approach were adopted to rank and identify the optimal configuration out of five possible options for the study area. Results from the simulation show that the winning system, i.e., Hydro + Battery system would generate a total electricity of 1,095,679 kWh/year. A cost of electricity of 0.06 $/kWh with an operating cost (OC) of $18,318 was recorded for the winning system. The total produced hydrogen by the optimum configuration is 8816 kg/year at a levelized cost of hydrogen (LCOH) of 4.47 $/kg. The quantity of low-carbon fertilizer that can be produced from the produced hydrogen is also assessed. The optimum configuration also recorded an employment potential of 4 persons in 25 years. A total GHG equivalence of 383.49 metric tons of CO₂ equivalent indicating the level of emissions that will be avoided should the optimum system be used to meet the demands specified in this study was obtained.