Hydrogen combustion in a compression ignition diesel engine

The investigation presented in this paper concerns both pure hydrogen combustion under HCCI (homogeneous charge compression ignition) conditions and hydrogen–diesel co-combustion in a compression ignition (CI) engine.     

Impacts of low temperature combustion and diesel post injection on the in-cylinder production of hydrogen in a lean-burn compression ignition engine

Strategies were investigated for increased in-cylinder formation of hydrogen. The use of low intake oxygen with a post injection was proposed. An intake oxygen sweep was conducted on a lean-burn compression ignition engine by adjusting of the exhaust gas recirculation rate. The results revealed that the yield of hydrogen increased exponentially when the intake oxygen was reduced to achieve low temperature combustion. Further tests showed that low temperature combustion operation consistently produced more hydrogen than high temperature combustion for similar air-to-fuel ratios.To increase the hydrogen yield further, a post injection timing sweep was carried out with low temperature combustion operation. Increased yields of hydrogen were obtained, up to 0.76% by volume, when then the post injection timing was advanced from 70 to 20° crank angle after top dead centre. At the same time, the indicated NO_X emissions reduced to 0.013 g/kW·hr and the smoke emissions were 0.14 FSN. Thus, the tests established that the combination of low temperature combustion, low intake oxygen, and an early post injection produced a high yield of hydrogen with simultaneously ultra-low NO_X and smoke emissions. The main drawback of this strategy was the increased formation of methane, up to 3015 ppm by volume. However, further analysis showed that the hydrogen to methane ratio actually increased under low temperature combustion operation.     

The utilization of hydrogen in hydrogen/diesel dual fuel engine

A hydrogen fueled internal combustion engine has great advantages on exhaust emissions including carbon dioxide (CO₂) emission in comparison with a conventional engine fueling fossil fuel. In addition, if it is compared with a hydrogen fuel cell, the hydrogen engine has some advantages on price, power density, and required purity of hydrogen. Therefore, they expect that hydrogen will be utilized for several applications, especially for a combined heat and power (CHP) system which currently uses diesel or natural gas as a fuel.A final goal of this study is to develop combustion technologies of hydrogen in an internal combustion engine with high efficiency and clean emission. This study especially focuses on a diesel dual fuel (DDF) combustion technology. The DDF combustion technology uses two different fuels. One of them is diesel fuel, and the other one is hydrogen in this study. Because the DDF engine is not customized for hydrogen which has significant flammability, it is concerned that serious problems occur in the hydrogen DDF engine such as abnormal combustion, worse emission and thermal efficiency.In this study, a single cylinder diesel engine is used with gas injectors at an intake port to evaluate performance swung the hydrogen DDF engine with changing conditions of amount of hydrogen injected, engine speed, and engine loads. The engine experiments show that the hydrogen DDF operation could achieve higher thermal efficiency than a conventional diesel operation at relatively high engine load conditions. However, it is also shown that pre-ignition with relatively high input energy fraction of hydrogen occurred before diesel fuel injection and its ignition. Therefore, such abnormal combustion limited amount of hydrogen injected. Fire-deck temperature was measured to investigate causal relationship between fire-deck temperature and occurrence of pre-ignition with changing operative conditions of the hydrogen DDF engine.     

A review of ammonia as a compression ignition engine fuel

During the past decades, the diesel engine has been through times of upheaval, boom and bust. At the beginning of the century, almost 50% of the new vehicle registrations in the European market were diesel-powered. However, the news of deadly diesel NO_x emissions supported by the diesel emission scandals caused a shock to the diesel engine market, and the sustainability of the diesel engine is currently in dispute.Recently major automotive manufacturers announced the development of diesel-powered vehicles with negligible NO_x emissions. Moreover, the NO_x emissions production is of lower concern for heavy-duty, marine or power generations applications where the implementation of advanced aftertreatment systems is feasible. However, despite the tackle of NO_x emissions, the decarbonisation of the automotive, marine and power generation markets is mandatory for meeting greenhouse gas emissions targets and limiting global warming.The decarbonisation of the diesel engine can be achieved by the implementation of a carbon-free fuel such as ammonia. This paper provides a detailed overview of ammonia as a fuel for compression ignition engines. Ammonia can be combusted with diesel or any other lower autoignition temperature fuel in dual-fuel mode and lead to a significant reduction of carbon-based emissions. The development of advanced injection strategies can contribute to enhanced performance and overall emissions improvement. However, ammonia dual-fuel combustion currently suffers from relatively high unburned ammonia and NO_x emissions because of the fuel-bound nitrogen. Therefore, the implementation of aftertreatment systems is required. Hence, ammonia as a compression ignition fuel can be currently seen as a feasible solution only for marine, power generation and possibly heavy-duty applications where no significant space constraints exist.     

A review of hydrogen as a compression ignition engine fuel

Diesel fuelled engines emit higher levels of carbon dioxide and other harmful air pollutants (such as noxious gases and particulates) per litre of fuel than gasoline engines. This fact, combined with the recent diesel emission scandal and the rumours of more widespread cheating by automotive manufacturers have initiated a long discussion about the future and sustainability of diesel engines.Improving the compression ignition engine is a direct way of going green. Reducing the harmful emissions can be achieved by future developments in the engine technology but also the implementation of alternative fuels. Hydrogen is a renewable, high-efficient and clean fuel that can potentially save the future of diesel-type engines. The evolution of high-efficiency renewable hydrogen production methods is the most important path for the start of a new hydrogen era for the compression ignition engine that can improve its sustainability and maximum efficiency.This paper provides a detailed overview of hydrogen as a fuel for compression ignition engines. A comprehensive review of the past and recent research activities on the topic is documented. The review focuses on the in-cylinder combustion of hydrogen either as a primary fuel or in dual fuel operation. The effects of injection strategies, compression ratio and exhaust gas recirculation on the combustion and emission characteristics of the hydrogen fuelled engine are fully analysed. The main limitations, challenges and perspectives are presented.     

An experimental study of a direct injection compression ignition hydrogen engine

This paper describes the development of an experimental setup for the testing of a diesel engine in the direct injection hydrogen-fuelled mode. Test results showed that the use of hydrogen direct injection in a diesel engine gave a higher power to weight ratio when compared to conventional diesel-fuelled operation, with the peak power being approximately 14% higher. The use of inlet air heating was required for the hydrogen-fuelled engine to ensure satisfactory combustion, and a large increase in the peak in-cylinder gas pressure was observed. A significant efficiency advantage was found when using hydrogen as opposed to diesel fuel, with the hydrogen-fuelled engine achieving a fuel efficiency of approximately 43% compared to 28% in the conventional, diesel-fuelled mode. A reduction in nitrogen oxides emission formation of approximately 20% was further observed.     

Energy and exergy analysis of a combined injection engine using gasoline port injection coupled with gasoline or hydrogen direct injection under lean-burn conditions

Hydrogen is considered to be a suitable supplementary fuel for Spark Ignition (SI) engines. The energy and exergy analysis of engines is important to provide theoretical fundaments for the improvement of energy and exergy efficiency. However, few studies on the energy and exergy balance of the engine working under Hydrogen Direct Injection (HDI) plus Gasoline Port Injection (GPI) mode under lean-burn conditions are reported. In this paper, the effects of two different modes on the energy and exergy balance of a SI engine working under lean-burn conditions are presented. Two different modes (GPI + GDI and GPI + HDI), five gasoline and hydrogen direct injection fractions (0, 5%, 10%, 15%, 20%), and five excess air ratios (1, 1.1, 1.2, 1.3, 1.4) are studied. The results show that the cooling water takes the 39.40% of the fuel energy on average under GPI + GDI mode under lean-burn conditions, and the value is 40.70% for GPI + HDI mode. The exergy destruction occupies the 56.12% of the fuel exergy on average under GPI + GDI mode under lean-burn conditions, and the value is 54.89% for GPI + HDI mode. The brake thermal efficiency and exergy efficiency of the engine can be improved by 0.29% and 0.31% at the excess air ratio of 1.1 under GPI + GDI mode on average, and the average values are 0.56% and 0.71% for GPI + HDI mode.     

Experimental investigation of the effects of simultaneous hydrogen and nitrogen addition on the emissions and combustion of a diesel engine

Overcoming diesel engine emissions trade-off effects, especially NO_x and Bosch smoke number (BSN), requires investigation of novel systems which can potentially serve the automobile industry towards further emissions reduction. Enrichment of the intake charge with H₂ + N₂ containing gas mixture, obtained from diesel fuel reforming system, can lead to new generation low polluting diesel engines.     

Effects of split injection proportion and the second injection timings on the combustion and emissions of a dual fuel SI engine with split hydrogen direct injection

In this paper, a new kind of injection mode, split hydrogen direct injection, was presented for a dual fuel SI engine. Six different first injection proportions (IP1) and five different second injection timings were applied at the condition of excess air ratio of 1, first injection timing of 300°CA BTDC, low speed, low load conditions and the Minimum spark advance for Best Torque (MBT) on a dual fuel SI engine with hydrogen direct injection (HDI) plus port fuel injection (PFI). The result showed that, split hydrogen direct injection can achieve a higher brake thermal efficiency and lower emissions compared with single HDI. In comparison with single HDI, the split hydrogen direct injection can form a controlled stratified condition of hydrogen which could make the combustion more complete and faster. By adding an early spray to form a more homogeneous mixture, the split hydrogen direct injection not only can help to form a flame kernel to make the combustion stable, but also can speed up the combustion rate through the whole combustion process, which can improve the brake thermal efficiency. By split hydrogen direct injection, the torque reaches the highest when the first injection proportion is 33%, which improves by 1.13% on average than that of single HDI. With the delay of second injection timing, the torque increases first and then decreases. With the increase of first injection proportion, the best second injection timing is advanced. Furthermore, by forming a more homogeneous mixture, the split hydrogen direct injection can reduce the quenching distance to reduce the HC emission and reduce the maximum temperature to reduce the NO_X. The split hydrogen direct injection can reduce the HC emission by 35.8%, the NO_X emissions by 7.3% than that of single HDI.     

Use of hydrogen in dual-fuel diesel engines

Hydrogen is a promising future energy carrier due to its potential for production from renewable resources. It can be used in existing compression ignition diesel engines in a dual-fuel mode with little modification. Hydrogen's unique physiochemical properties, such as higher calorific value, flame speed, and diffusivity in air, can effectively improve the performance and combustion characteristics of diesel engines. As a carbon-free fuel, hydrogen can also mitigate harmful emissions from diesel engines, including carbon monoxide, unburned hydrocarbons, particulate matter, soot, and smoke. However, hydrogen-fueled diesel engines suffer from knocking combustion and higher nitrogen oxide emissions. This paper comprehensively reviews the effects of hydrogen or hydrogen-containing gaseous fuels (i.e., syngas and hydroxy gas) on the behavior of dual-fuel diesel engines. The opportunities and limitations of using hydrogen in diesel engines are discussed thoroughly. It is not possible for hydrogen to improve all the performance indicators and exhaust emissions of diesel engines simultaneously. However, reformulating pilot fuel by additives, blending hydrogen with other gaseous fuels, adjusting engine parameters, optimizing operating conditions, modifying engine structure, using hydroxy gas, and employing exhaust gas catalysts could pave the way for realizing safe, efficient, and economical hydrogen-fueled diesel engines. Future work should focus on preventing knocking combustion and nitrogen oxide emissions in hydrogen-fueled diesel engines by adjusting the hydrogen inclusion rate in real time.     

Influence of operating parameters on performance and emissions for a compression-ignition engine fueled by hydrogen/diesel mixtures

Hydrocarbon exhaust emissions are mainly recognized as a consequent of carbon-based fuel combustion in compression ignition (CI) engines. Alternative fuels can be coupled with hydrocarbon fuels to control the pollutant emissions and improve the engine performance. In this study, different parameters that influence the engine performance and emissions are illustrated with more details. This numerical work was carried out on a dual-fuel CI engine to study its performance and emission characteristics at different hydrogen energy ratios. The simulation model was run with diesel as injected fuel and hydrogen, along with air, as inducted fuel. Three-dimensional CFD software for numerical simulations was implemented to simulate the direct-injection CI engine. A reduced-reaction mechanism for n-heptane was considered in this work instead of diesel. The Hiroyasu-Nagel model was presented to examine the rate of soot formation inside the cylinder. This work investigates the effect of hydrogen variation on output efficiency, ignition delay, and emissions. More hydrogen present inside the engine cylinder led to lower soot emissions, higher thermal efficiency, and higher NO_x emissions. Ignition timing delayed as the hydrogen rate increased, due to a delay in OH radical formation. Strategies such as an exhaust gas recirculation (EGR) method and diesel injection timing were considered as well, due to their potential effects on the engine outputs. The relationship among the engine outputs and the operation conditions were also considered.     

Effects of Fischer-Tropsch diesel fuel on combustion and emissions of direct injection diesel engine

Effects of Fischer-Tropsch (F-T) diesel fuel on the combustion and emission characteristics of a single-cylinder direct injection diesel engine under different fuel delivery advance angles were investigated. The experimental results show that F-T diesel fuel exhibits shorter ignition delay, lower peak values of premixed burning rate, lower combustion pressure and pressure rise rate, and higher peak value of diffusion burning rate than conventional diesel fuel when the engine remains unmodified. In addition, the unmodified engine with F-T diesel fuel has lower brake specific fuel consumption and higher effective thermal efficiency, and presents lower HC, CO, NO _x and smoke emissions than conventional diesel fuel. When fuel delivery advance angle is retarded by 3 crank angle degrees, the combustion duration is obviously shortened; the peak values of premixed burning rate, the combustion pressure and pressure rise rate are further reduced; and the peak value of diffusion burning rate is further increased for F-T diesel fuel operation. Moreover, the retardation of fuel delivery advance angle results in a further significant reduction in NO _x emissions with no penalty on specific fuel consumption and with much less penalty on HC, CO and smoke emissions. __________ Translated from Chinese Internal Combustion Engine Engineering, 2007, 28(2): 19–23 [译自: 内燃机工程]     

Study on cottonseed oil as a partial substitute for diesel oil in fuel for single-cylinder diesel engine

The experiments were undertaken to obtain the knowledge necessary for raising the thermal efficiency of mixed oil composed of cottonseed oil and conventional diesel oil and for improving the performance of engine fuelled by the mixture. The experimental results obtained showed that a mixing ratio of 30% cottonseed oil and 70% diesel oil was practically optimal in ensuring relatively high thermal efficiency of engine, as well as homogeneity and stability of the oil mixture. A quadratic regressive orthogonal design test method was adopted in the experiment designed to examine the relationship between specific fuel consumption and four adjustable working parameters (intake-valve-closing angle (α), exhaust-valve-opening angle (β), fuel-delivery angle (θ) and injection pressure (P, in 10⁴ Pa)) when the above-mentioned oil mixture was used. The mathematical equations characterizing the relationship were formulated. The equation of specific fuel consumption derived from the regressive test under each operating condition was set as the objective function and the ranges for the four adjustable working parameters were the given constraint condition. Models of non-linear programming were then constructed. Computer-aided optimization of the working parameters for 30:70 cottonseed oil/diesel oil mixed fuel was achieved. It was concluded that the predominant factor affecting the specific fuel consumption was fuel-delivery angle θ, the approximate optimal value of which, in this specific case, was 3–5° in advance of that for engine fuelled by pure diesel oil. The experimental results also provided useful reference material for selection of the most preferable combination of working parameters.     

Analysis of different combustion chamber geometries using hydrogen / diesel fuel in a diesel engine

ABSTRACT

In this study, the effects on combustion characteristics and emission were investigated in a direct injection diesel engine. In experimental and numerical studies, the engine was operated at 2000 rpm. The analyzes were made in the AVL-FIRE ESE Diesel part with Computational Fluid Dynamics (CFD) software. Standard combustion chamber (SCC) and Modified combustion chamber (MCC) geometry were compared in the modeling. By means of the designed MCC combustion chamber geometry, the fuel released from the injector was directed to the piston bowl area. Therefore, the mixture was homogenized and the combustion had been improved. In addition, the evaporation rate of the mixture increased with the MCC geometry. Also, lower NO and CO emissions were obtained with the MCC model compared to the SCC model. On the other hand, diesel fuel and mass 5% hydrogen fuel was used into diesel fuel as fuel in the study. The combustion process was investigated using hydrogen in different combustion chambers. The use of hydrogen as additional fuel resulted in higher combustion pressure, temperature and NO emissions. Compared to SCC type combustion chamber in the MCC type combustion chamber used diesel fuel, CO emission decreased of 6% and 3% for hydrogen-added mixture fuel. Also, compared to SCC type combustion chamber in the MCC type combustion chamber used diesel fuel, NO emission decreased of 11% and 32% for hydrogen-added mixture fuel. Moreover, flame velocity, heat release rate and flame propagation increased with the addition of hydrogen fuel.     

Influence of hydrogen co-combustion with diesel fuel on performance,smoke and combustion phases in the compression ignition engine

The main objective of this study was to examine impact of hydrogen addition to the compression ignition engine fueled with either rapeseed methyl ester (RME) or 7% RME blended diesel fuel (RME7) on combustion phases and ignition delay as well as smoke and exhaust toxic emissions. Literature review shows in general, hydrogen in those cases is used in small amounts below lower flammability limits. Novelty of this work is in applying hydrogen at amounts up to 44% by energy as secondary fuel to the compression ignition engine. Results from experiments show that increase of hydrogen into the engine makes ignition delay shortened that also affects main combustion phase. In all tests the trends of exhaust HC and CO toxic emissions vs. hydrogen addition were negative. The trend of smokiness decreased steadily with increase of hydrogen. Amounts of hydrogen addition by energy share were limited to nearly 35% due to combustion knock occurring at nominal load.     

Analysis of the particulate emissions and combustion performance of a direct injection spark ignition engine using hydrogen and gasoline mixtures

Three different fractions (2%, 5%, and 10% of stoichiometric, or 2.38%, 5.92%, and 11.73% by energy fraction) of hydrogen were aspirated into a gasoline direct injection engine under two different load conditions. The base fuel was 65% iso-octane, and 35% toluene by volume fraction. Ignition sweeps were conducted for each operation point. The pressure traces were recorded for further analysis, and the particulate emission size distributions were measured using a Cambustion DMS500. The results indicated a more stable and faster combustion as more hydrogen was blended. Meanwhile, a substantial reduction in particulate emissions was found at the low load condition (more than 95% reduction either in terms of number concentration or mass concentration when blending 10% hydrogen). Some variation in the results occurred at the high load condition, but the particulate emissions were reduced in most cases, especially for nucleation mode particulate matter. Retarding the ignition timing generally reduced the particulate emissions. An engine model was constructed using the Ricardo WAVE package to assist in understanding the data. The simulation reported a higher residual gas fraction at low load, which explained the higher level of cycle-by-cycle variation at the low load.     

Effect of water injection and spark timing on the nitric oxide emission and combustion parameters of a hydrogen fuelled spark ignition engine

One of the main problems with hydrogen fuelled internal combustion engines is the high NO level due to rapid combustion. Use of diluents with the charge and retardation of the spark ignition timing can reduce NO levels in Hydrogen fuelled engines. In this work a single cylinder hydrogen fuelled engine was run at different equivalence ratios at full throttle. NO levels were found to rise after an equivalence ratio of 0.55, maximum value was about 7500 ppm. High reductions in NO emission were not possible without a significant drop in thermal efficiency with retarded spark ignition timings. Drastic drop in NO levels to even as low as 2490 ppm were seen with water injection. In spite of the reduction in heat release rate (HRR) no loss in brake thermal efficiency (BTE) was observed. There was no significant influence on combustion stability or HC levels.     

Study on rapeseed oil as alternative fuel for a single-cylinder diesel engine

This study was undertaken to provide knowledge necessary for raising the thermal efficiency of mixed oil composed of rapeseed oil and conventional diesel oil and for improving the performance of an engine fuelled by the mixture. The experimental results obtained showed that a mixing ratio of 30% rapeseed oil and 70% diesel oil was practically optimal in ensuring relatively high thermal efficiency of engine as well as homogeneity and stability of the oil mixture. Method of quadratic regressive orthogonal design test method was adopted in experiment designed to examine the dependence of specific fuel consumption on four adjustable working parameters when the above –mentioned oil mixture was used. These parameters were: intake-valve-closing angle (α), exhaust-valve-opening angle (β), fuel-delivering angle (θ) and injection pressure (P, in 10⁴ Pa). Relationship between these parameters and specific fuel consumption was analyzed under two typical operating conditions and mathematical equations characterizing the relationship were formulated. The equation of specific fuel consumption derived from the regressive test under each operating condition was set as the objective function and the ranges for the four adjustable working parameters were the given constraint condition. Models of non-linear programming were then constructed. Computer aided optimization of the working parameters for 30:70 rapeseed oil/diesel oil mixed fuel was achieved. It was concluded that the predominant factor affecting the specific fuel consumption was fuel-delivering angle θ, the approximate optimal value of which, in this specific case, was 2–3 degrees in advance of that for engine fuelled by pure diesel oil. The experimental results also provided useful reference material for selection of the most preferable combination of working parameters.     

Numerical simulation of the mixture distribution and its influence on the performance of a hydrogen direct injection engine under an ultra-lean mixture condition

In this study, a three-dimensional numerical model of a hydrogen direct-injection engine was established, and the combustion model was verified by experimental data. The influence of the injection timing and nozzle diameter on ultra-lean combustion was evaluated. The results suggest that, with the delay in the injection timing, the mixture concentration near the spark plug and combustion speed gradually increase. The maximum thermal efficiency increased from 47.44% to 49.87%. The combustion duration and ignition lag are shortened from 19.15°CA to 11.15°CA to 16.13°CA and 5.92°CA, respectively. As the nozzle diameter increased, the injection duration was shortened, and the mixture distribution area became more concentrated. Furthermore, under ultra-lean combustion, the combustion rate is more sensitive to the distribution of the mixture. Appropriately increasing the equivalence ratio near the spark plug can significantly shorten the ignition lag and combustion duration and obtain a higher thermal efficiency.